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Biogeochemical cycles
The Water Cycle
The Water Cycle
(1) Evaporation: During part of the water
cycle, the sun heats up liquid water and
changes it to a gas by this process.
.
(2) Transpiration: The process of evaporation
from plants.
(3) Condensation: As water (in
the form of gas) rises higher in
the atmosphere, it starts to cool
and become a liquid again. This
process is called condensation.
When a large amount of water
vapor condenses, it results in the
formation of clouds.
(4) Precipitation: When the
water in the clouds gets too
heavy, the water falls back to
the earth. This is called
precipitation.
(5) Runoff: When rain falls on the land, some of
the water is absorbed into the ground forming
pockets of water called groundwater. Most
groundwater eventually returns to the ocean.
Other precipitation runs directly into streams or
rivers. Water that collects in rivers, streams, and
oceans is called runoff.
THE NITROGEN CYCLE
Sources
• Lightning
• Inorganic fertilizers
• Nitrogen Fixation
• Animal Residues
• Crop residues
• Organic fertilizers
Forms of Nitrogen
• Urea  CO(NH2)2
• Ammonia  NH3 (gaseous)
• Ammonium  NH4
• Nitrate  NO3
• Nitrite  NO2
• Atmospheric Dinitrogen N2
• Organic N
Nitrogen Cycles
• Ammonification/mineralization
• Immobilization
• Nitrogen Fixation
• Nitrification
• Denitrification
Sediments
Nitrification
Root
uptake
Biological
fixation
Nitrification
Ammonium NH4
+
Ammonification
Nitrite NO2
-
Dissolved in water
Denitrification
Leaching
Nitrate
NO3
-
Soil organic nitrogen
Atmospheric
fixation
Industrial
fixation
Plant protein
Animal
protein
Atmospheric Nitrogen
Ammonification
• Nitrogen enters the soil through the
decomposition of protein in dead organic
matter
Amino acids + 11/2O2  CO2 + H2O + NH3 + 736kJ
• This process liberates a lot of energy
which can be used by the saprotrophic
microbes
Nitrification
• This involves two oxidation processes
• The ammonia produced by ammonification is an
energy rich substrate for Nitrosomas bacteria
They oxidise it to nitrite:
NH3 + 11/2O2  NO2
- + H2O + 276kJ
This in turn provides a substrate for Nitrobacter
bacteria oxidise the nitrite to nitrate:
NO2
- + 1/2O2  NO3
- + 73 kJ
• This energy is the only source of energy for
these prokaryotes
• They are chemoautotrophs
Nitrogen Fixation
• Energy intensive process :
• N2 + 8H+ + 8e- + 16 ATP = 2NH3 + H2 +
16ADP + 16 Pi
• Performed only by selected bacteria and
actinomycetes
• Performed in nitrogen fixing crops
(ex: soybeans)
Atmospheric nitrogen
fixation
• Electrical storms
• Lightning provides sufficient energy to
split the nitrogen atoms of nitrogen gas,
• Forming oxides of nitrogen NOx and NO2
Denitrification
• Removes a limiting nutrient from the
environment
• 4NO3
-
+ C6H12O6 2N2 + 6 H20
• Inhibited by O2
• Not inhibited by ammonia
• Microbial reaction
• Nitrate is the terminal electron acceptor
CARBON CYCLE
Carbon in Atmosphere
Plants use
carbon to make
food
Animals eat
plants and
take in carbon
Plants and
animals die
Decomposers
break down dead
things, releasing
carbon to
atmosphere and
soil
Bodies not
decomposed —
after many
years, become
part of oil or coal
deposits
Fossil fuels are
burned; carbon
is returned to
atmosphere
Carbon slowly
released from
these substances
returns to
atmosphere
OXYGEN CYCLE
Unit 2 (part 2)  biogeochemical cycles

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Unit 2 (part 2) biogeochemical cycles

  • 3.
  • 5. (1) Evaporation: During part of the water cycle, the sun heats up liquid water and changes it to a gas by this process. . (2) Transpiration: The process of evaporation from plants.
  • 6. (3) Condensation: As water (in the form of gas) rises higher in the atmosphere, it starts to cool and become a liquid again. This process is called condensation. When a large amount of water vapor condenses, it results in the formation of clouds. (4) Precipitation: When the water in the clouds gets too heavy, the water falls back to the earth. This is called precipitation.
  • 7. (5) Runoff: When rain falls on the land, some of the water is absorbed into the ground forming pockets of water called groundwater. Most groundwater eventually returns to the ocean. Other precipitation runs directly into streams or rivers. Water that collects in rivers, streams, and oceans is called runoff.
  • 9. Sources • Lightning • Inorganic fertilizers • Nitrogen Fixation • Animal Residues • Crop residues • Organic fertilizers
  • 10. Forms of Nitrogen • Urea  CO(NH2)2 • Ammonia  NH3 (gaseous) • Ammonium  NH4 • Nitrate  NO3 • Nitrite  NO2 • Atmospheric Dinitrogen N2 • Organic N
  • 11. Nitrogen Cycles • Ammonification/mineralization • Immobilization • Nitrogen Fixation • Nitrification • Denitrification
  • 12. Sediments Nitrification Root uptake Biological fixation Nitrification Ammonium NH4 + Ammonification Nitrite NO2 - Dissolved in water Denitrification Leaching Nitrate NO3 - Soil organic nitrogen Atmospheric fixation Industrial fixation Plant protein Animal protein Atmospheric Nitrogen
  • 13. Ammonification • Nitrogen enters the soil through the decomposition of protein in dead organic matter Amino acids + 11/2O2  CO2 + H2O + NH3 + 736kJ • This process liberates a lot of energy which can be used by the saprotrophic microbes
  • 14. Nitrification • This involves two oxidation processes • The ammonia produced by ammonification is an energy rich substrate for Nitrosomas bacteria They oxidise it to nitrite: NH3 + 11/2O2  NO2 - + H2O + 276kJ This in turn provides a substrate for Nitrobacter bacteria oxidise the nitrite to nitrate: NO2 - + 1/2O2  NO3 - + 73 kJ • This energy is the only source of energy for these prokaryotes • They are chemoautotrophs
  • 15. Nitrogen Fixation • Energy intensive process : • N2 + 8H+ + 8e- + 16 ATP = 2NH3 + H2 + 16ADP + 16 Pi • Performed only by selected bacteria and actinomycetes • Performed in nitrogen fixing crops (ex: soybeans)
  • 16. Atmospheric nitrogen fixation • Electrical storms • Lightning provides sufficient energy to split the nitrogen atoms of nitrogen gas, • Forming oxides of nitrogen NOx and NO2
  • 17. Denitrification • Removes a limiting nutrient from the environment • 4NO3 - + C6H12O6 2N2 + 6 H20 • Inhibited by O2 • Not inhibited by ammonia • Microbial reaction • Nitrate is the terminal electron acceptor
  • 19. Carbon in Atmosphere Plants use carbon to make food Animals eat plants and take in carbon Plants and animals die Decomposers break down dead things, releasing carbon to atmosphere and soil Bodies not decomposed — after many years, become part of oil or coal deposits Fossil fuels are burned; carbon is returned to atmosphere Carbon slowly released from these substances returns to atmosphere