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oxygen. friend or foe?

                                           presented by:

                          Gary Gottfried & Andrew Lazorchak


                                            july 26 2012




swe 2012   T1D   – oxygen friend or foe.
oxygen. friend or foe.
      Program:
                                                    .
      •     Andrew Lazorchak Presents:                      Oxygen = Friend
            Taste flights: 1,2,3. (try to save some #1)
      •     Gary Gottfried Presents:                        Oxygen = Foe
            Taste flights: 1,4,5
      •     Question & Answer.
      •     Wines:
            4 flights of Spring Mtn – Cab Sauv – Napa Valley – 2006
            (special thanks to Spring Mtn Vyds)
            1: poured at 8:00AM 2: poured w/Soirée
      •     3: open 5 days VF              4: open 5 days




swe 2012   T1D   – oxygen friend or foe.
oxygen = friend




swe 2012   T1D   – oxygen friend or foe.
decanter = friend




subconsciously, some people are intimidated by decanters.


  swe 2012   T1D   – oxygen friend or foe.
keep wine fun.




                 playing/exploring with wine is your job.

swe 2012   T1D   – oxygen friend or foe.
why decant?
fun fact:
•originally decanters were made as a tool to allow one rack sediment from wine.


Why:
•because like all things in this atmosphere, oxygen catalyzes “aging”.
•wine is hermetically sealed, and has not seen oxygen in year(s).
•in the case of wine, oxygen allows the chemistry of the wine to expand and then
degrade.
•decanting is not only for fancy wine, everyday wines will show dramatic improvement
when aerated.
•decanters have become decorative, fancy, and unfortunately seldom.




  swe 2012   T1D   – oxygen friend or foe.
69% of people rarely use a decanter.
                   68% drink wine several times a week.
                           35% don’t even own a decanter.




                                 source: WellesleyWinePress.com
                                           http://bit.ly/LPmL5




swe 2012   T1D   – oxygen friend or foe.
68% drink wine several times a week.
                 69% of people rarely use a decanter.
                     35% don’t even own a decanter.



             as educators, it is our job to correct this.




swe 2012   T1D   – oxygen friend or foe.
wine know-it-alls.



common deferments from people that don’t use a decanter or aerator as often as they should:

•I decant wines that need it. (define this)
•I always use a decanter. (BS)
•I like to see the wine develop in the glass. (ok, but joe consumer does not.)
•I am not drinking the whole bottle. (glass by glass aerators exist)
•Our customer won’t know the difference. (You sell the sizzle not the steak)
•Takes up to much table space. (aerators don’t)
•Too hard to clean. (tell that to the winemaker)

Too much goes into making wine to not treat it properly. Be it a $12 bottle or $120 bottle, most wines will
benefit when they have a chance to breathe.




      swe 2012   T1D   – oxygen friend or foe.
oxygen is a catalyst for wine’s development.




     when talking to the average consumer, I like to use the analogy of rust to
      describe how oxygen accelerates a wine’s aging process. the average
      consumer does not understand this or the importance that oxygen can
                     have in improving their wine experiences.


  don’t let tradition or snobbery get in the way of wine.

swe 2012   T1D   – oxygen friend or foe.
options.




    passive decanting:                                active decanting:
           surface area.                              active infusion.
                  Wait                                 Pour voraciously
                 Carafe                                  Shake bottle
             Decanter                                      Aerator


                               convenience is king.

swe 2012   T1D   – oxygen friend or foe.
i decant wait any longer.




swe 2012   T1D   – oxygen friend or foe.
tools/methods to expedite oxygenation:


   •glassware                                      •aerator
   •height of pour                                 •hyper-decant (blender)
   •turbulence in the glass                        •bubbler
   •shaking the bottle.



   Capsules are breathable. Wax & screwcaps don’t breathe.
   97% of the wine bought is consumed within 24 hours of purchase.




swe 2012   T1D   – oxygen friend or foe.
Wine opens up.
                     What does this really mean & why does this happen?




                    organic compounds are the essence of wine aromatics.




swe 2012   T1D   – oxygen friend or foe.
Volatile Compounds of Red and White Wines…
“Wine aroma is attributable to a large range of molecules coming from different
chemical families (e.g., esters, aldehydes, ketones, terpenes, norisoprenoides,
acids, alcohols, and sulfur compounds). Some originate from the grape, and
others are formed during fermentation or during aging.

The aroma of wine is determined traditionally by liquid–liquid and solid–liquid
extraction and dynamic headspace…”

Jordi Torrens1, Montserrat Riu-Aumatell2, Elvira López-Tamames2, and Susana Buxaderas2,*




    swe 2012   T1D   – oxygen friend or foe.
some identified aroma compounds.
Methoxypyrazine - grassy, herbaceous aroma compound associated with Cabernet Sauvignon
and Sauvignon blanc.

Monoterpenes -responsible for the floral aromatics of varieties like Gewürztraminer, Muscat and
Riesling. Includes geraniol, linalool and nerol.

Norisoprenoids-Carotenoid derived aromatic compounds[6] that includes megastigmatrienone
which produces some of the spice notes associated with Chardonnay and zingerone responsible
for the different spice notes associated with Syrah. Other norisoprenoids include raspberry
ketone which produces some of the raspberry aromas associated with red wine, damascenone
which produces some of the rose oil aromas associated with Pinot noir and vanillin.

Thiols-sulfur contain compounds that can produce an aroma of garlic and onion that is
considered a wine fault (mercaptans). They have also been found to contribute to some of the
varietal aromas associated with Cabernet Sauvignon, Gewürztraminer, Merlot, Muscat, Petit
Manseng, Pinot blanc, Pinot gris, Riesling, Scheurebe, Semillon and Sylvaner.




 swe 2012   T1D   – oxygen friend or foe.
aroma compounds in testing.
Volatiles:
esters, aldehydes, ketones,
terpenes, norisoprenoides, acids,
alcohols, and sulfur compounds.
chart (right) shows compounds
releasing by temperature. this is
similar, in effect, to aging or opening up.

Ester dynamic are reduced in a quick/
hotter fermentation.

the pH of wine influences the rate
of oxidation in wine.




swe 2012   T1D   – oxygen friend or foe.
dissolved oxygen testing.
Jason Moulton of Cliff Lede Vineyards doing a controlled
dissolved oxygen with various wine aerators.




   swe 2012   T1D   – oxygen friend or foe.
dissolved oxygen testing.

D.O. In ppm = mg/L
•In new bottle                       0.11ppm (control)
•Poured into a glass:                1.07ppm
•Rabbit:                             1.57ppm
•Vinturi:                            1.50ppm
•Soirée:                             1.95ppm




 swe 2012   T1D   – oxygen friend or foe.
works cited.
  Acid and the effect on wine:
  http://www.sasev.org/journal-sajev/sajev-articles/volume-27-2/27_2%202.pdf/view

  Volatiles in wine – thesis concluding aromatic definition via volatile analysis:
  http://photonics.byu.edu/PDMS.parts/paper7.pdf

  Wikipedia:




swe 2012    T1D   – oxygen friend or foe.
swe 2012   T1D   – oxygen friend or foe.
Oxygen: Friend or




swe 2012   T1D   – oxygen friend or foe.
Oxygen: Friend or Foe?
•   A freshly-cut apple turns brown, a bicycle fender becomes rusty and
    a copper penny suddenly turns green. What do all of these events have in common?
    They are all examples of a process called oxidation.
•   Oxidation is defined as the interaction between oxygen molecules and all the different
    substances they may contact, from metal to living tissue. Technically, however, with
    the discovery of electrons, oxidation came to be more precisely defined as the loss of
    at least one electron when two or more substances interact. Those substances may
    or may not include oxygen. (Incidentally, the opposite of oxidation is reduction — the
    addition of at least one electron when substances come into contact with each other.)
    Sometimes oxidation is not such a bad thing, as in the formation of super-durable
    anodized aluminum. Other times, oxidation can be destructive, such as
    the rusting of an automobile or the spoiling of fresh fruit.
•   We often used the words oxidation and rust interchangeably, but not all materials
    which interact with oxygen molecules actually disintegrate into rust. In the case of
    iron, the oxygen creates a slow burning process, which results in the brittle brown
    substance we call rust. When oxidation occurs in copper, on the other hand, the
    result is a greenish coating called copper oxide. The metal itself is not weakened by
    oxidation, but the surface develops a patina after years of exposure to air and water.

swe 2012   T1D   – oxygen friend or foe.
Oxygen Friend or Foe?

                                     Happens within
                                       5 minutes




                                      What about 24-48
                                          hours?
                                                         ?...
swe 2012   T1D   – oxygen friend or foe.
Why is Wine Preservation Is
             Important?
                                                 Institutional–
  Consumer – retail or
                                                 Restaurant or
     off premise
                                                  On premise

 • Quality                                 •   Quality Assurance
 • Save money                              •   Save money
 • Freedom to Open                         •   Increase revenue
 • Enjoy/Entertain/                        •   Expand variety
   Express                                 •   Market and not
 • Alternative Wines                           manage


swe 2012   T1D   – oxygen friend or foe.
Wine Preservation Options
•   Drink the whole bottle

•   Refrigeration

•   Vacuum

•   Solid Separation

•   Gas

•   Do Nothing




     swe 2012   T1D   – oxygen friend or foe.
Taste Trial




swe 2012   T1D   – oxygen friend or foe.
Test Metrics




swe 2012   T1D   – oxygen friend or foe.
Why what you may have learned
may be of benefit .. to everyone




                  Source: Wine Institute

swe 2012   T1D   – oxygen friend or foe.
Why what you may have learned
may be of benefit .. to everyone




                  Source: Wine Institute

swe 2012   T1D   – oxygen friend or foe.
Why what you may have learned
may be of benefit .. to everyone




swe 2012   T1D   – oxygen friend or foe.
Why what you may have learned
  may be of benefit .. to you
 • Knowledge
 • Educators
      –     Consumer
      –     Winery
      –     Distributor
      –     On Premise
      –     Off Premise
 • Financial Efficiency
 • Experience and Enjoy the Freedom, Everyday

 swe 2012   T1D   – oxygen friend or foe.
QUESTIONS?
                                    (or comments)




                                           thank you


swe 2012   T1D   – oxygen friend or foe.

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Oxygen. Friend or Foe. S.W.E. 1D 7-26-12

  • 1. oxygen. friend or foe? presented by: Gary Gottfried & Andrew Lazorchak july 26 2012 swe 2012 T1D – oxygen friend or foe.
  • 2. oxygen. friend or foe. Program: . • Andrew Lazorchak Presents: Oxygen = Friend Taste flights: 1,2,3. (try to save some #1) • Gary Gottfried Presents: Oxygen = Foe Taste flights: 1,4,5 • Question & Answer. • Wines: 4 flights of Spring Mtn – Cab Sauv – Napa Valley – 2006 (special thanks to Spring Mtn Vyds) 1: poured at 8:00AM 2: poured w/Soirée • 3: open 5 days VF 4: open 5 days swe 2012 T1D – oxygen friend or foe.
  • 3. oxygen = friend swe 2012 T1D – oxygen friend or foe.
  • 4. decanter = friend subconsciously, some people are intimidated by decanters. swe 2012 T1D – oxygen friend or foe.
  • 5. keep wine fun. playing/exploring with wine is your job. swe 2012 T1D – oxygen friend or foe.
  • 6. why decant? fun fact: •originally decanters were made as a tool to allow one rack sediment from wine. Why: •because like all things in this atmosphere, oxygen catalyzes “aging”. •wine is hermetically sealed, and has not seen oxygen in year(s). •in the case of wine, oxygen allows the chemistry of the wine to expand and then degrade. •decanting is not only for fancy wine, everyday wines will show dramatic improvement when aerated. •decanters have become decorative, fancy, and unfortunately seldom. swe 2012 T1D – oxygen friend or foe.
  • 7. 69% of people rarely use a decanter. 68% drink wine several times a week. 35% don’t even own a decanter. source: WellesleyWinePress.com http://bit.ly/LPmL5 swe 2012 T1D – oxygen friend or foe.
  • 8. 68% drink wine several times a week. 69% of people rarely use a decanter. 35% don’t even own a decanter. as educators, it is our job to correct this. swe 2012 T1D – oxygen friend or foe.
  • 9. wine know-it-alls. common deferments from people that don’t use a decanter or aerator as often as they should: •I decant wines that need it. (define this) •I always use a decanter. (BS) •I like to see the wine develop in the glass. (ok, but joe consumer does not.) •I am not drinking the whole bottle. (glass by glass aerators exist) •Our customer won’t know the difference. (You sell the sizzle not the steak) •Takes up to much table space. (aerators don’t) •Too hard to clean. (tell that to the winemaker) Too much goes into making wine to not treat it properly. Be it a $12 bottle or $120 bottle, most wines will benefit when they have a chance to breathe. swe 2012 T1D – oxygen friend or foe.
  • 10. oxygen is a catalyst for wine’s development. when talking to the average consumer, I like to use the analogy of rust to describe how oxygen accelerates a wine’s aging process. the average consumer does not understand this or the importance that oxygen can have in improving their wine experiences. don’t let tradition or snobbery get in the way of wine. swe 2012 T1D – oxygen friend or foe.
  • 11. options. passive decanting: active decanting: surface area. active infusion. Wait Pour voraciously Carafe Shake bottle Decanter Aerator convenience is king. swe 2012 T1D – oxygen friend or foe.
  • 12. i decant wait any longer. swe 2012 T1D – oxygen friend or foe.
  • 13. tools/methods to expedite oxygenation: •glassware •aerator •height of pour •hyper-decant (blender) •turbulence in the glass •bubbler •shaking the bottle. Capsules are breathable. Wax & screwcaps don’t breathe. 97% of the wine bought is consumed within 24 hours of purchase. swe 2012 T1D – oxygen friend or foe.
  • 14. Wine opens up. What does this really mean & why does this happen? organic compounds are the essence of wine aromatics. swe 2012 T1D – oxygen friend or foe.
  • 15. Volatile Compounds of Red and White Wines… “Wine aroma is attributable to a large range of molecules coming from different chemical families (e.g., esters, aldehydes, ketones, terpenes, norisoprenoides, acids, alcohols, and sulfur compounds). Some originate from the grape, and others are formed during fermentation or during aging. The aroma of wine is determined traditionally by liquid–liquid and solid–liquid extraction and dynamic headspace…” Jordi Torrens1, Montserrat Riu-Aumatell2, Elvira López-Tamames2, and Susana Buxaderas2,* swe 2012 T1D – oxygen friend or foe.
  • 16. some identified aroma compounds. Methoxypyrazine - grassy, herbaceous aroma compound associated with Cabernet Sauvignon and Sauvignon blanc. Monoterpenes -responsible for the floral aromatics of varieties like Gewürztraminer, Muscat and Riesling. Includes geraniol, linalool and nerol. Norisoprenoids-Carotenoid derived aromatic compounds[6] that includes megastigmatrienone which produces some of the spice notes associated with Chardonnay and zingerone responsible for the different spice notes associated with Syrah. Other norisoprenoids include raspberry ketone which produces some of the raspberry aromas associated with red wine, damascenone which produces some of the rose oil aromas associated with Pinot noir and vanillin. Thiols-sulfur contain compounds that can produce an aroma of garlic and onion that is considered a wine fault (mercaptans). They have also been found to contribute to some of the varietal aromas associated with Cabernet Sauvignon, Gewürztraminer, Merlot, Muscat, Petit Manseng, Pinot blanc, Pinot gris, Riesling, Scheurebe, Semillon and Sylvaner. swe 2012 T1D – oxygen friend or foe.
  • 17. aroma compounds in testing. Volatiles: esters, aldehydes, ketones, terpenes, norisoprenoides, acids, alcohols, and sulfur compounds. chart (right) shows compounds releasing by temperature. this is similar, in effect, to aging or opening up. Ester dynamic are reduced in a quick/ hotter fermentation. the pH of wine influences the rate of oxidation in wine. swe 2012 T1D – oxygen friend or foe.
  • 18. dissolved oxygen testing. Jason Moulton of Cliff Lede Vineyards doing a controlled dissolved oxygen with various wine aerators. swe 2012 T1D – oxygen friend or foe.
  • 19. dissolved oxygen testing. D.O. In ppm = mg/L •In new bottle 0.11ppm (control) •Poured into a glass: 1.07ppm •Rabbit: 1.57ppm •Vinturi: 1.50ppm •Soirée: 1.95ppm swe 2012 T1D – oxygen friend or foe.
  • 20. works cited. Acid and the effect on wine: http://www.sasev.org/journal-sajev/sajev-articles/volume-27-2/27_2%202.pdf/view Volatiles in wine – thesis concluding aromatic definition via volatile analysis: http://photonics.byu.edu/PDMS.parts/paper7.pdf Wikipedia: swe 2012 T1D – oxygen friend or foe.
  • 21. swe 2012 T1D – oxygen friend or foe.
  • 22. Oxygen: Friend or swe 2012 T1D – oxygen friend or foe.
  • 23. Oxygen: Friend or Foe? • A freshly-cut apple turns brown, a bicycle fender becomes rusty and a copper penny suddenly turns green. What do all of these events have in common? They are all examples of a process called oxidation. • Oxidation is defined as the interaction between oxygen molecules and all the different substances they may contact, from metal to living tissue. Technically, however, with the discovery of electrons, oxidation came to be more precisely defined as the loss of at least one electron when two or more substances interact. Those substances may or may not include oxygen. (Incidentally, the opposite of oxidation is reduction — the addition of at least one electron when substances come into contact with each other.) Sometimes oxidation is not such a bad thing, as in the formation of super-durable anodized aluminum. Other times, oxidation can be destructive, such as the rusting of an automobile or the spoiling of fresh fruit. • We often used the words oxidation and rust interchangeably, but not all materials which interact with oxygen molecules actually disintegrate into rust. In the case of iron, the oxygen creates a slow burning process, which results in the brittle brown substance we call rust. When oxidation occurs in copper, on the other hand, the result is a greenish coating called copper oxide. The metal itself is not weakened by oxidation, but the surface develops a patina after years of exposure to air and water. swe 2012 T1D – oxygen friend or foe.
  • 24. Oxygen Friend or Foe? Happens within 5 minutes What about 24-48 hours? ?... swe 2012 T1D – oxygen friend or foe.
  • 25. Why is Wine Preservation Is Important? Institutional– Consumer – retail or Restaurant or off premise On premise • Quality • Quality Assurance • Save money • Save money • Freedom to Open • Increase revenue • Enjoy/Entertain/ • Expand variety Express • Market and not • Alternative Wines manage swe 2012 T1D – oxygen friend or foe.
  • 26. Wine Preservation Options • Drink the whole bottle • Refrigeration • Vacuum • Solid Separation • Gas • Do Nothing swe 2012 T1D – oxygen friend or foe.
  • 27. Taste Trial swe 2012 T1D – oxygen friend or foe.
  • 28. Test Metrics swe 2012 T1D – oxygen friend or foe.
  • 29. Why what you may have learned may be of benefit .. to everyone Source: Wine Institute swe 2012 T1D – oxygen friend or foe.
  • 30. Why what you may have learned may be of benefit .. to everyone Source: Wine Institute swe 2012 T1D – oxygen friend or foe.
  • 31. Why what you may have learned may be of benefit .. to everyone swe 2012 T1D – oxygen friend or foe.
  • 32. Why what you may have learned may be of benefit .. to you • Knowledge • Educators – Consumer – Winery – Distributor – On Premise – Off Premise • Financial Efficiency • Experience and Enjoy the Freedom, Everyday swe 2012 T1D – oxygen friend or foe.
  • 33. QUESTIONS? (or comments) thank you swe 2012 T1D – oxygen friend or foe.