7. Chemical Oxygen Demand
Oxygen equivalent of the organic matter that can be oxidized by a
strong oxidizing agent (potassium dichromate) in an acid medium.
COD > BOD5: (a) Because more compounds can be oxidized chemically
than can be oxidized biologically and
(b) Because BOD5 does not equal ultimate BOD
COD: 3 h
BOD: 5 d
19. 0.04 to 0.05 m3 per capita or 1/3 to 1/2 of septic tank capacity
20.
21. Municipal Wastewater
Treatment Systems
•Pretreatment – removes materials
that can cause operational
problems, equalization optional
•Primary treatment – remove
~60% of SS and ~35% of BOD
(by: settle/float) (no removal: soluble pollutants)
•Secondary treatment – remove
~85% of BOD5 and solids
(removes: soluble BOD 5, biological processes/speed-
up natural processes, not significant N, P, HMs,
pathogens)
•Advanced treatment (AWT) – varies:
95+ % of BOD5, SS, N, P, bacteria
(Chemical treatment/filtration/land application/soil-
crop system)
(Sparkling clean, colourless, odourless, effluent)
22.
23. Bar racks
• Purpose
– remove larger objects
• Solid material stored in
hopper and sent to
landfill
• Mechanically or
manually cleaned
24.
25.
26. Grit Chambers
• Purpose: remove inert
dense material, such as
sand, broken glass, silt and
pebbles
• Avoid abrasion of pumps
and other mechanical
devices
• Material is called “grit”
37. Secondary Treatment
• Provide BOD removal beyond what is achieved
in primary treatment
– removal of soluble BOD
– additional removal of suspended solids
• Basic approach is to use aerobic biological
degradation:
organic carbon + O2 → CO2
• Objective is to allow the BOD to be exerted in
the treatment plant rather than in the stream
38. How is this accomplished?
• Create a very rich
environment for growth
of a diverse microbial
community
39. Basic Ingredients
• High density of microorganisms (keep
organisms in system)
• Good contact between organisms and wastes
(provide mixing)
• Provide high levels of oxygen (aeration)
• Favorable temperature, pH, nutrients (design
and operation)
• No toxic chemicals present (control industrial
inputs)
42. Bacteria: single-celled organisms
no particular species is selected as “the best”
Fungi: multicellular, nonphotosynthetic, heterotrophic
require only half as much nitrogen as bacteria
Algae: uni-/multicellular, net production of oxygen
Protozoa: single-celled
Rotifers and Crustaceans: animals- aerobic, multicellular
chemoheterotrophs
• Rotifers-consume bacteria, small particles of organics
• Crustaceans: shell structure, present in underloaded ponds
presence indicate-> DO, << organic matter
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
61.
62.
63.
64.
65.
66.
67.
68.
69. ASP/TF
Attached growth/fixed film/stationary microbial population
No filtering/straining process
Depth = 1-3 m
Dia. < 60 m
Rocks = 25 – 100 mm dia.
Openings too large to strain out solids
Surface area : large where microbes cling/grow/feed on organics
70.
71.
72. Problems
Under high organic loadings:
slime growth – prolific, plug voids, flooding,
air circulation/ O2 for microbes – restricted
system failure
Solution: alternate media
modules/ corrugated plastic sheets, plastic rings
73.
74.
75.
76.
77.
78.
79. Oxidation Ponds
Small communities
Collective term for all types of ponds
Originally:
Oxidation pond – that received partially treated WW
Sewage lagoon - that received raw WW
Waste stabilization pond – all inclusive
pond/lagoon to treat organic WW
Self purification: DO furnished through photosynthesis + surface re-aeration
80. Classification:
Aerobic – shallow, < 1 m, DO throughout the entire depth, by photosynthesis
Facultative – 1- 2.5 m, zones: anaerobic lower, facultative middle, aerobic upper
Anaerobic – deep ponds, high organic loadings, anaerobic throughout
Maturation/tertiary/polishing –polishing effluents from other biological processes
Aerated lagoons – oxygenated through surface/diffused air aeration
81. Aerobic Ponds.
Shallow
Light penetrates to bottom
Active algal photosynthesis throughout
Daylight hours – large amount of O2 by photosynthesis
Darkness hours–wind mixing of shallow water mass, high degree of surface aeration
Aerobic bacteria predominate
82. Anaerobic Ponds.
Aerobic/anaerobic – function of (a) organic loading and (b) availability of DO
Anaerobic – BOD5 load > O2 production from photosynthesis
To reduce photosynthesis – decrease surface area, increase depth
Turbid – due to reduced metal sulfides,
Reduced light penetration, negligible algal growth
3 stage anaerobic degradation of complex wastes
1st stage: hydrolysis of organic matter
2nd stage (acid fermentation): complex organics broken to short-chain acids+ alcohols
3rd stage (methane fermentation): converted to gases ( primarily CH4 and CO2)
83. Facultative Ponds:
Most common, small communities
Long retention – take care of fluctuations in Q and BOD5
Less capital/operating/maintenance costs
86. Design
BOD load not > 22 kg/ha.d on smallest cell
- To prevent anaerobic conditions
DT (considering total volume of all cells, excluding bottom 0.6 m in vol.)=6 months
- To provide enough storage to hold WW in winter/when receiving stream is frozen
-To provide enough storage to hold WW in summer/when flow in receiving stream
is low to absorb even a small amount of BOD.