The document provides the revised syllabus for B.Sc. (I-VI) Semester Course in Chemistry from the academic year 2016-2017 onwards at Gulbarga University, Kalaburagi.
The syllabus outlines the course content and distribution of marks for each semester. It includes 3 units for Inorganic Chemistry, Organic Chemistry, and Physical Chemistry per semester, along with a laboratory course. The topics covered range from chemical periodicity, s-block elements, and coordination chemistry in Inorganic Chemistry to structure and bonding of organic molecules, stereochemistry, and organic reactions in Organic Chemistry. Physical Chemistry topics include mathematical concepts, thermodynamics, phase equilibria, and quantum mechanics. The document also
2. GULBARGA UNIVERSITY,
KALABURAGI
Depqrtment of p.c. Studies
qnd Reseorch in Chemistry
Revised Syllabus for
B.Sc. (l-VI) Semester Course in Chemistrv
From Academic Yc:tr 2016-17 onwar{ls
trffi mr
t
S.B,PRINTER 963229:]26,'
3. T
-:-: uNlvERsITY.
I'{LABUR{GI
DEPARIMENT OF CIIEMISTRY
B.SC.I to VI setnester relis€d sXlt aDns eficctiye froh 2 0l 6-2 0 I 7 onr a rds
B.S. I and II sen. - From 20t6-2017
B.Sc III ud IV sem. - Froh 2017-2018
B.ScV and vI se'n. - From 20I3-2019
FIRSTSE!TESTER
CHT:01r: CHEMISTRV
trNIT-l : INORGANIC CEENIISTRY
I Chemi.al penodiciry
2. S-blockelements
3. Tihinericmalyst
IJNIT'I: I
l.
2.
UNIT. fl:
t.
2.
L
IJI{IT- III
L
2.
3.
cHP-02r
L
2.
06HN.
08ti6.
08H6.
UNIT-II:
L
2.
L
UNIT.III
L
2.
3.
cHP - 0n
1.
2.
ORGANIC CHEMISTRY
Shctue and bondins of organ ic molecules
Alkmes and cy.loalkancs
PEYSICAL CHEMISTRY
MatheDaticd conepts fo. cheDristry:
LABORATORY COURSE- I
SECOND SEMES]ER
CHT:021: CHF.MTSTRV
NORGAI'IC CHEMISTRY
ORCANIC CIIE]tIISTRY
StereochcDistry of org,.ic rnolecules
PHYSICAL CHEMISTRY
LABORATORY COURSE. N
Organic Chcmistry i Quali[Lirc Analysh
Inoredic ChetoisLry : Calibmtions
Physical Cnenrinr) Expernncnts
4. r IiIRD SEIIESTER
CHT:031: CHEtr{ISTRY
UlT- l: IiORGNIC CHEifl S'f RY
I D bl.ckelen.ns:
2. F block elcnEnls:
I Co.rdinadonthcmistrY:
4. Slabiliry of Mct'L ConrPlcxesr
iJIT- II : ORGANIC CllEltISlRY
I Ad.liydcs and kerones
4. Heruroc]'c1ic corlpounds
IINIT- III: PEYSIC,^L CHEMISTRY
l. Themodlnrmics - Il
I LollodJl;ri(L
aHP:0lt i L,BOR (l OR COURSE III
'''''" r;;. i
"' ')- '-'i
oi
"
o' 'i
-e
2 Organic Chenistq'
r n6vq,i ahc (ro
I Rlllsl llfrR
CHT:011 : CHEtrIlSml
INORGANIC C}IEMIS'I'RY
R.acdvn, of M€lal Cornplercs
ORGANIC CI'EIISTRY
UNIT I:
1
2.
IINIT- II:
22llrs
2lIIr
05llr
?lHr
0lt!
22H
l2ll
05H
96H
I Eth.ft 3ndcl)olides
2. CarbolYlic acids
I Aciddcri!lli!es
I Orsanic.ompouods ol nittusen
llIT- III: ? YSICAL CgENIISTRY
L Elcnrcntu! qudlrnn ni'chmrcs
2 Phasccquillibna
I Plrotoch.nrkur
CHP - 011: LARORAIORY COURSE l'
l. lnorganic ChctrlisrrvPrcparLr'is
) o. rLL L t'nl'tr r$
'Df'ns
i;".;r ,i.; Lr"do'r'i
5. FIFTIISEMESTER
CIIT : l]5I : CqDMISTRY
UNll- l: INORCANIC cIIDMiSTRy
L Inol8anic pdlymes
2. Basic Concepts olChronatog.aphy
UNIT- ll: ORCANIC CIIEMIS-|RY
2. Org.nonrcralti. compounds
i orsaiosulphur compounds
4. Rearmngefr ent rcoclions
UNIT IIIi P}IYSTC,L CIIEMISTRY
L Colligatile potenies
CHP 051| LABOR,TORY COIIRSF.
FIITHSEMESTOR
CllT:052: CIIEMISTRY
UNIT I: INORCANTC CIDNISTRY
L Bio inoBanic chcdlst.y
LOrEanic Rergents iD lnorAanic Analys s
UNIT II: ORCANIC Ci{EMISTRY
I Organic synlhesis via enol.Es
l. Oils, rb*, soaps and dele.gdnrs
4 SyDtheric polymeE
UNIT.III J PIIYSICAL C]IDMISTRY
2. Phlsicd prcpeniesod nolecula.{rudu€
CEP,05?: LABORATORY COTIRSF. VI
L od.'i..t.rr'. O.a {er dl.s.orBi e-v,,r,no,oj'. no.gJr, l..11) ..pr.o,o
^.ut
,a lio.
0:lllN.
04lls.
| .l'. r..l' l- , Ver $ LJr a at.r.
6. tNlT-t:
l
2
3.
uNn -II
l
7
l
UNIT.III
L
l. Ino.gaii. Chcdnt) : (nxtincric Eilmarhis
2. OrraiicChcmh!y : ltcparations
CH'I: 06I: CIIEMISTRY
ANALY'I'ICAL CIlEMISTRY
Evaluationol Atulytical Dab
IORGANIC CII]IMISTRY
Arniro a.ids. peptides 0nd proteins
: PHYSTCAL CIIEMISTRY
SIXTTIS[MDSTOR
CHT:062: CHEM]STRY
UNIT I: INDUSTRIAL Cl[tllSTRY
2. Cerrnric, Rcl.xc0ics xid CLascr
L Pain6. Pigmcnssnd Va ishcs
UNIT - II:ORCANIC CHEMSTRY
L Rcagenh in org0icsynlhesis
2. Cre chcmisiy
3. lotedbr and Jepr.tdcrions
t Mddi.idaLChenisby
LNIT III : ?HYSICAL CHI]XIISlRY
l. d ecb!ndive lnr.c
2 E c.tr!.hemicxl eicrgy solrccs
t:lt h .
PhrlcrlChonierv Jd$nLfrcilal Mcrh.Js ol An.!vsis Il
7. SCHEIE OI' EAMIATIOS:
L l h.rc shlllbc o.e qne{ion pan.r ca.h iirB.Sc. L tl, tttrtutlV senje$c6 tn ChenisLr)
: T[ershr]l bcNdquest,of |rDerselcl i.r B.Sc V nnd!l senicsrursin Chemisna
I J..ldilron there sh lh. Pia.ti.xlExminarr!ns asperrtr. Un^ersirl R.sxhrio..xijine
OLESTIO._ l.PllR PATTER:
L!.hqur{ron fater slixLl rortnin rlmc .rrirn$tSection-A. Se.ri0n B xndSe.rjon-C}
Ans*0 !o all sectiotrs shxllh er rtr.n in rhe samc rnsvd blok.
OnecfmtrkoryqlcsriorcorerinsiLlbrD.|csolohc'ninrlolrhdrune.irnoLvinqFinoen
b ll,."1 . ro '. -illtirricn r ,',
'
, ",,..,,r.rrloJ l5 n ks olni. qu.dil,r.
Ihc.e shrll be si.LUcnn,o, No lionr c.ch bran.h, md)'inq tire rrxrks tn..rch qucsion.
Thccandidnres has r.rns1o, rn.v live!uest ons lhcd!Lrarkj lor this sccf.n he ngnvcDq
Thcrcshxllhcsirqrcnions..nyotrnclrlrhrrr$,.lrryin!cilhrnra stor.rdr! c{rr
Ih..rdiorehasroan$!o.n.yfi..qu.{ons.TorxlnD {s tu.rhissectionbcinr ltn.
SCtlUNIEOF It,RKrNC,
Each dreor_i Faper is gf I
SEIJESII]R THFORY
00 nnLl..
't
DIS'I RIBI]TION OF I1RK
Iv
l0lrl}1.
lIANI IOI L
L
toR PRACTtC.L FtX,Nlt.lI():
INTFRNAI, TOlAL
ole: Th. inlcmrL aj.srn,cft nuks r'or rh.ory shiLlb. tr.nrr rnrd lor tndictrts is trn.
otcr-lhc c.nd rtc slrorld producc th. rcrllllcdjounrl iL llr. rlnc olclch scn.nct
c rirtr[!n Ir.Ncrhc.rndilr]lclirilsroiubmitdrc..r(ill.dnnnxt rtr.trh.r:kh
' .' ' 'f
8. FIRST SEIIESTER
CHI:01!:CHEII5TR
llIT: I : INORC.lC CHEIISTR
I Che'nic.'lPdiutlicirr_
I ulu.ti.n. ltrnidc lalvs. l.ng nm .i P:n'li: L.l: .:!r: .r pc'nrdiciiv
r..Ldcnce 0l floferlici.lasinc]lnri olelem.nrj Ln F r- I J -r iblolkr P'iodic
''': f f rri I
r N;iod rftLl!.ne I snNl *fla.ai.n r.r th. ib!:F.r:_-::_: :rro^ d't'mLnLns
A hli i,mls: Con,Dr.tire sludy .l pFpcdics .a Ga'r I ::- -:! i :t r:t'ct lo nlen
n,.,t .'.o . . . . ' ni Jd
".",.,i-,.,.o'l'lrtlon sdc' tlrnre colou'ation ch'nricxl p('r_=:.- _:: :'-1':: :" :rLide' oidcs
'p(
!. dcs.lrJ l,!'Ll.' Ln nc. ilLe
-"t , ' ,.. ..J,r j-.'. :.
, t' lto.r' _'
F' l' . ' ' "
, J
"-L r J. il : r
.1. Titfinel|ic ,n.lt is :
A.i(lbr.tii.ri( : PrinrlDl.olritri'n.ti.rDxlliii:::::. :-_'
, l.: .
U)iIT: Il I ORCIIC CHEUIITR
l. Slructurr rnd bonding oforgrnic nolduls:
Ilonfr rs. ..i.cpL. (yo.s ol bords (ronir. coil.r: r_: :tr:.:ltr'
-,,r cod ' " o .l i r .1-i :
'.n oi| ii 1 i:g&
, '.L.sr
D'.['n!Lon bJr!cr
R.dor trhrlnrns: 1''i|ri . lhco,!,(ilrxlonrun!':.:Ilc5:r':-:'::Jrons'
c(Npl.xon.ti. rilturtuF: hntudud on, :is :'
')T'
ritritrlns:
nI o r. 'r" n 'J l--
. . i.n t o' I '
1.. rti' r J' ir
,, ',1.. "' ' Irr .1., orr'' -- 'r
:. Rcaciion mcdrtnisnr:
H.r,.L!ri. rnd Hctcollic b!trd Lksion. El:.r-'!'_ s a -i"
. nn.r .l | .,. .,., n-r "...
.tuba;ions turd c bots shblLq ol .arbN-_:d ft
-_' "
".i' '. 'r'. -l4r
--
9. TyDcsofor$.i. r0lltioDs Nl.chx.,rn ofSNl xnd SN2 roactron by tx{jns hvdnlEn or 1
')l {l.r.r rl ',r,j..,1 tr' ,, tt,r ,,,
lclring erorps. nL.l.ofh les and iollcn(.n Sl d S I nrerhxnnff Ftr rn{t Ll
eliinnixtionr JuErnseir.ntrcr.f..(terinitioDilll.:am es)
L Alkrh.i ,nd .r.loxlkrh.:
lsoDcriin in rLkadc up ro C!, rndhods rlsynrhc$ olnLkan.s hJ,ulz r.a.rnn. Kolbc
r.x.tion rn,l CorelJIou. r.r.hon C!roxlloDcJNo'ncncLantr..sj-nrtr.i,rheDrjc,L
pr.F.ies,Baey.r snfuin dr.ora rid ns liDirxtions Th.orl.lsrrxi . nnq.
r. llrne rnd Jie'
'
' rlll
Allcncs: S!nrlrcsis b! dehydratidr .l rlrohols dehtdr..hxt(iqcNlr!n ot rllivt hrhrtes.
d.hrli)gcnari(nr ofi.iDxldil'rh{lcs. CronncrlErnnrns Adilirrof otoToi. hrt!gcnj xDd
hldrogen hrlidcs. V!.k.rrikofs Nlc xDd puoxidr cl1.cl wirb rrc.hn.(nr xnd saizci -s
DieD.s: 'lcrln s ol5!n[.$ .1 ]. I buradi.nc. .henitrt |.orenjc+ t. 2 rnl t. .l-
xddiri(io ol lir osens. hldtulcn. hi olei hrLldcs. po crizartri rnd DieLs-Ald$
UIT: III : P}nSICjLCHEIIISTRy ,H6
l. tithcmdical Concepls forchemiltr,ar Ut FI.
Lolrilhnic r.ldidN rrh cxrnrfes. t..)on.drirt ral I rboLt. ctrncs rrd rtrn
lnnliuhoni in cftnrilq au'1. 5kcrchiD! lni.. g.rnhs ari cnl.ul,rior ot d.0c!
DiJ1...rrid onoltin.r.ns lrl3cr. i l-og. Sitr: Itdi'ni rnd X,ttDi,r. IncSrIions.t
s.m. rerur tunciois tj.' Jx' i ' J tos{. 1,., Dntr ion xn(t roi,binxrn .s Dc;ir o s hd
( ilical Dhcn..r.nDn P.isoth.rnr o1 r..l gxc rorfnuil) ot slxlcs Thc isortr.rnr ot
c boi dl.id.. rclr!drnrit b.rn'c.n.rri.rlcon$nrs rid vr'rtlo 'rits.on{.n1 Th.
Lr of.o,..|!nding $xt.s xrJ rcdD..d cqrarion ol nrrc Nlotccutxr r.loctrir: Roor
nexn sqLr.! rclo.it]. r..rg. r.Lr)!iL) i no( f(iblh c vclo.irt fi.btenrs.
Quxlrrricarscussionoll1rr.ll)niAorzminndi!tfLhrri!fotnrotcorLrrctootics.
c.lhsion nuirb.r. collliii,n di!neLer drd ne.r frc. |rni.
f'Liquidslile: t0Ll^
vGcosittr D.firjhof. nxr[cn.rjrxL .ntu$ur. clc]liccnr .t iicot .ltid tl
"f
,r or. .. os.i ..
Strnicc Tcrion Dctirrron irdhe'n.rr. qDrssiordL{drcnrr.tunrc.mJfuldrrorrr.
Trohkns Dncnninlri.n or$trtr.. t.6i.n |t N ngsrbgnonrerer.
],xmchDi: DcIn rion. Sugcr cqLrxri(tri ,fDlL!]hons !l p rchord drcliic[!iNc]LriiLiin!
tlr stuc[n..lb.r7.f. n,,1..
'1.
R.lirti!c Rlex. srNifi. r xl Dol
'!licrnlqDin b(ion L.rr {lrcncfr. r)rnnld ro.lti.l.n1 rai condn.r lor rrtrdn !l
d .i r,o,' t i.. o . ,r. , rt ,
10. a H?:01t: L,BOR,TOR' COIIRSE _ I
INoRC,IC CHENIISTR}:
LL$lnrtidrolih ir Nl(,lf s sxlr Nins KrCr rO x
'
nrnnrJ roLuflo
I Eslirndn,n olcofncr ir.tfpcr sLhhalc!rlurion ujing iodiun drioiulthxr' as a
I I:{imrtn oIDotxs!tr i De.nanexnalcnsiDsoxlir xc lra s[nJrd solLrur'
',1 Esri.urn ol;r.n in lc.i. chlliride soluri'n bv dr'dxd r"ir
5. iinfutnm oL Fcrcur.nd lidic rcn ln rhc rniturc b usin-! p'oisiNn dr'hromal' !s
o i.i ",,'"
tn."*.t,'r s,sor anLl o!li' !rirlb- rirrxnne rnh roH i'd Kidor'
7.1:srin.rc rLr.xn0rntolcrL.irninch.lkb!KNlnOl
! F{inarellrc.irornroaNrOllanl NrrCO' tiinm b jlndr'J HClnr u on
r). Fntrrxt. rlrc r routofZn bt LDTA r on
t1) lirtr[tlhe!n]ornrot Crb] Stxndard Ll)TA Rrlt(ion
l l D.iemrr.d]. i rotir oJ..clrc rid rI c'nNereirl inr!!'
ORGAIC CHEIISTRI :
ciLib.rrior or th. n!ntrti
!0 tlfN{hnrxlrtr.l. I ll j_Ll'11,ccluilidc)
D.rcrnr nrrion.l ncltirs n.'in,
rr|rh!l.nc 80-!l l3cr/.ir x.id 121 5 122
<,Ti,h n d s,1513i.(Lnna'nrrlLl.5 lll
lll i lll(L..r). llLr(dNrille{!nrrcr)
. n, Diniroben/rdc9l P Di.hloob.nTcrc
AsDirid ll5 rid l ll 5_lll. Sxl cYLir x.id l5l 5'l5S'c'FniliJ'
Dcr..f irr.r on tlboilnrg D!irnsi
Ijrhrnrl1l. C!cloher..81 1.10 ucri.ll!.6. Bcrzen' S0
iii-",i .oir"i n,,.,,r"".-"!oni ur.x crnnaniic l'ir nirur' i coDlrtririon
Dr!ilLili!n,
,"1
LtrL,L,'LzrtJLd I c { I'r! J!}!
s"r,r,,'.i1"" f.,,tr,1. -A"tn]L;u.l: c'Drfhor' NxFhlrrl'De phrlu!icxod ri'lru"iIic
PtlYsIcaI- cHE} Sl R' :
i n",i""r,," ,r," .i.-.]t, "t*" sncD Liqurdsusfs ortr13Ld k'oF'ld (lcnrn cs d'
t lr"i.i"u",L" ',.-.nt "r. =ncn
hLluid usn! lxn trld lico nrtcr xnLi Ll'lon]in' lhc
I
_J"",1ri,.-,r,.
n",i"*+ -"lrosili'tr ol gtr
'tr
Liqurd r i{trc r
sl c' oL x d lrcr )
L si,r' On*akl i sco rctcr
+ O""i.t.,1" ""
i.",""." ol r gi!'n llquid rr rfl' conrfoLRl ui're nalignroncro
11. rnd dcrcDiire thc dcnsitt oIhquid
5 DeteDlDethcsut ce rensiori ols-. gn.d lquids usnrs iehgounere. and crl.uLar.
r|c P!ruc ar klc.sities.lliqunL xrr sren)
6 Ddennrnethe pcr.nr+. comxNitionol liqLrjd mirtucbyS 1. njctl$d lcq rrhll
al.ohoL+ rtc. hd herTer.+nirr.h.f 7.i.l
ole. Enher nrorgrni. .{rnralrons orl,hrsicrlch.Drisl]].yperinrntisencn in thc
.x.D,inlr.n lb ld).
SLCOND SI][IESTER
CHl : 021 : CHENIISTRY
LNIT: l: INORGA:! IC Cl IIIIISTR' 2tHr
L p-bl{'ct rlcDknts: 09HA
(onlorndJot Bo'm: P qrrtrrion.D oDeries. $rr.t crnd !s.solborrzotc. dih.doe
axrboD Frniil_v Stuorrrc.nd pmpdrics.lg'{|ncxoddrmond Pr.rJxr('r. p opefi.r
rnJ !r.i.1 11tr.r.., b.tr( r,l i.rl.r
Hrlo8ens lnerhxlog.rs P.cDr.!rior. propcrries. Srrctrr'.r.dusetolinrc'hxLor.ns ol
r.rpLhP,oq
Pseudo hxlLr!. : Ocp ation dl l]n)D. .s ol.trnrgcn. rhio._Mro!.n&a
2. Cbrhicil Bonding: Izl]rs
r,!rir hond: I inice cDcrgt. B..n Hrb.r!)clc. Eorn |lnde cquxnon (neriur on Dot
(qun.l. nmbl.nN.d B.rn Ixrdcer)lsrof r.ber.rk.d.url arLculxlioD. xr[r
.nc !ies.lNaCLxddNIgO .llcctol rlric.cncllr !nntubilrr!ot ionccont.n.d
Co.l.nrBoDd:'.lcn..bonarDDroadl[]brdizdiorrtuldr.cLioDrlchxrru.rrj.sor
sD. sDr. trr. strd. rif shapcs olEccLr.llt, sictr Patr.sFivstipttrlr.o:rhaf.soi
Cllr.H..NH r. H.o. BrFi.lClr.
Nlol..uLx.o.hilxl lircoN llr. H.r. ts.r. r. or.o.. al.'. or .ndco (b.ndo'ic'.
nrbililyrnd nrr!nerr rropcnicr n,b. d(u5.1). Poh.iz.rion .otr..fl. F{!n s nrte. b.Dd
lcngli. bond a.gl. ind b..d cncrB!. polr' )nLl non-polr niol..ulc. di$nc nroircnt '.rk
lllJ'!,g..brnl: I rrnrolecrixrxrd lfierioL..ulxrrypcr rnonrlo0s
t()t.iri.s !J HF. HrO. Nllr. al.oh.ls. ci'1r) i. x.rJ!. nrio |hcro s rid bio d!n..ul.
NTcrrllic b!nJ: Delirir or.chi,IdiTrrni..r i.rrllir {I.s..cctun S.i N o,t.t
ll l: ll: ORG.N lC CIH ENT ISTRY 2lHr
l. Alklner: {)t ttr:
,lt)n. Slnrh.sis b! d.rldrohrli)gc rhon oL i!nrrl dihr i.lcs. d.hxtogcnrli!n fL rctr
hrlidrs. lciLlily of r kyics rhcnricrl .crcrions ol i klrc$rddirn,n !l hr olcr .cid
.lcr. forn[rion o]nr.hLrcc!l[]cs. Sr-n(hcs s.id uscs.l djldoD.nc
2 Arones.nd otorticitr: 0t ll]
,runc, Nonrercaturc ol b.f/.f. d.r r.r rcs. nod.m conc.tr or rh'crurc ol h.rcnc
rncluding 14.o I Rcsonxncc er.r!r. i'cchinnii olclc.r!nhilrc $Ltri( i.i 'rr.r
of ot
b.n/cnc Nil..tior. ll.logcDxll! . S l rulion d Fri.d.l - Cmlr r.x.r!n. Fli.ct ol
srbiilr lon oi n.tro suhnit|l.d bcn,cnc- o, p- oricmin.s !'!!r! ( cDlxn b takl.!
12. cl.crron d.nft groufr ). m{ne.ling erolo(cxplarn b! rakin-! el.'ron Bilhdrawl'e
gdlps I xnd an! ixloui h.hrio!r!r chlorine
A.oDrri.i,r.- llefi nition. crildia l ItNkcL ixle
3. Alkr_l.ndi4lhilides :
Alktl hrLid.s onienrlxtue. cla$iticatnn th
r.r.rnrd rith nre.hrii!ns
05Fhs,
.xmples. m.thods ortnnf ation !nd
Adhilnbs Nlelhodsoflonnation n!clcoDliiLlcdisth.m.nttur'Iionslr'hNaOll
Ni..Kal!,Ull,lxnrfurction.lnrigrerdni.xndwun2Fiftigrexdi'n(Cfi'Clnlaken
'{. Stereocbe.ist,t olorglnic mol..!les: o?Hrs
aif..i^ .l in)nr.r i$. rcrcois.rncrirn Nd t!!cs
G{mdrtrrlrNr.rkD Dctiiitor (;conrenrrxl isonefin rn
'raleic
rnd tumd' {ids
a r rrd tnns svstcn.lnonrctrclinN
. .. ,t, - "a I
ii) nr.rliir.lcrn;n F txrkiicr.id rdz br.nio_r chltntbtri'nc:
Fnmi)n.s !l dix$ere.iicr. R rnd S slienr olioni.nclrrdrt
I Nl l: lll: Plll$C.LCHtllSTR ?lHK
l. lherdodln!mics _ l:
R.!isioi.l ;Ni.1.!nN.l'lrnlrwol LL.nnod]ra']i's ('r'n]'nr'delfrlirnol
r'f ' " r o'
CalNldlon oi;. q. dLr. dll. i(' 11,. crp!n!.. olidealsr md" n'rb'Nilrd rdllbxlic
tundi{l.nstbrr.vuiiblelrli..$!olrrherl.xpr.itics.rsrr'sdc'nd't}olu cdid
r *-r"nt o,.**" .,it."l"rlon h.trlc$ rlr. i Nunrcrrcrl froblcn} Joulc Tht x'n
.l'ii.i l(trLlc lho ns.tr co.llici.nL. nc'sior rcnrnc'irtrc.7cn h ol drc'moilnxnrl's
Absoluc s.xl. oltctrf, rN(
1 Chctrlicn|k ctics: lrqH's
n-.tl,r, .r,t" -""",rr. tr," ,xre. ddcr dnd rol.culx'nl
'l
rciclon xfd Br!l litt
f.,i.d S{. d ordc ca.lr!ns $ith crriirfles. Dc'i io0 ol sfc'ilic rirc
'onslrnrtlI'.-,-,1 .4" ,-"
"
,
"
r""
"+
11{ru( or ddctrniruion ol odr !l J r'rdio r diffe' e nirl
tnii lltc mt g,"ptric"L dlli lbeo[ .r re.clro' m{'i r]!rlnxr e tr'dncnl oi
coll,siu, rlro,r ol br rolccrlf ercr.ns Thc'rl
'f
uni'ro1'cuLrr rexcrrons
;ind an.sh rdG . xl rm.l! htc princL c). An.lcmcnra rcctunt oflnnsnion shle
ir,".'' ,""i"r onlD* rG rcldiot nirh thcanodvnroric tun'tirns llcl
^ll+'
'i.i;l. r-.,lr.l '-t-,. "
,t, *.r,pL.s. .onieruti'. ie.crirn nh !uni01cs Nrdicical
p ohlcdr .ls..ond Drd.r r{t.riors
3. Solid statc: rl5llr
( ,!r lin. slile. ldus or.'vsr.llocrathv (dciinior nnd cpLnnrro ) si.nnn'r'! oD
" i; -*',,r .*t-" , p1",. i,l slN ,]cs!. xxls or !!nN.l, r-. .cntd or sr nn'!r ''irs
.ndli!Lci hnli;.r.le'ivrridrorB.rg!cquxrioD Problc'N
'jr. fani.!cs: lntodrcti0i duliDxrion ol nnio pr(i'lcs ClGsili!xtion !l nano
p,,ii"li. ,"o a--'... rtol.lrl.Lll) stadrrcs oIca$on
'x'o
nrbcs AtfLic'rions or
13. t
I
CIIP:021: L{BORATORY COI'RSE tr
Oigdic qMlitative mal)sis of shgle coDpoudjdflritcation of d orgmic compoud
lhrolgh nature of conpound, phlsical constanl, elemmtal dalrsis, tunctlonal group
mal6is md prepmtion ofsuilable de.ivarives.
Cdboxylic acidsr Benoic aci4 Cimanic acid, Salicylic acid md
NLho compounds. N'mbenzene Jnd m D n bobepene
Ph6ol, Crsols, lNaphthol and 2 Naphthol
Edylmelhylkctone,Acelophenone mdAcelone
Naphlhalene and Diphenyl
Anilin.,nn T.fi,idines
Ealogen conpouds: ChlorcbeMene d Bronoben?ene
Calibdtion olftaoional weighrs. pipcttcs and breftes.
PGpution ofsldded solutions. dilution - 0,2M to 0.001M solulio.s
mermo chenisll.y.- To detmine dre solubility orbenzoic acid at diffe€nt tefrpeEtures
and lo delemine AH of the disso l ionproces.
To deremine lrc cnthalpy ot solnion of solid calciur chloide dd calculate tbe lanice
energy of calciufr chloride rrotu ils enthalph dala usins Born tlber crcle.
N,te: O.ly oHanic malrsis is 10 be siven ror $e exminal@n.
14. 1'HIRD SENI'STER
C}IT : 03I : CHENIISfRY
UlT: I: I N ORGAIC CH E NllSTRl
rnt.,lu.tior. ..mprutn. $udy ol pr!pcr(ics .l rrtrn{nonal elenr'ns oi ld cries rilh
,r-.i ri.r' ' J'r' { r'i
,,1 .".. .i'. p'r' or'' rrii- ' IrJ '
Dtr)tcties. rnagnelic lopeas. cmtyic acinY. inresriial
'ompoon{l
nrnl(nr' md
2, i-Block Elcdenis: oiHa
l.anrlianidcvl.ro.lurion elc.tumc ..DliguBlild. oidrli!' nxrej aldnrc ud i'nrc
r foPir' r'-' Iol.- i ' '' r''i '
.,,,,,t ,,. i.i '.1 ' o' i
lrnthand.s by ion crdr.nq. drethod
nl i"i,r* r.,i"a""i,-, a""-"ic coDti!nrarion. oidnrion slrr': doin c xtrd ionic radii
coldr chrfuctrnir f,.pe1io'. nia-sroli. froperlics md conrol' turnring rbilrr ol
x.ri,rid.s Acr nLd. ; ;dnm si iihnricJ md diffcr'n"s betr"' lxnlhnoidcs trnd
l. Cuu'{linrriun rl'e
'i!rtr:IrtrodlcLon, dcfinrnon oi rltr t nn, Llgaftls do 06 accctt'6 cot'Jin'lion slhcF
.."iai""i., .*,r* li|15 ol islnds. I'n'oclaturc
'l coordrlrtn
'onrrands
''o ' 'r1r
'+ '
r'. ' .,. .,
;d.'. o.bir"l ..irplc.s trilr crrmp c
cr"r'eorurrcs..fririineora_orbilrl lD sq!.( flxtro !nd o'klicdrrL'tnrp cci lLNSpln
rndhishstinconnl..s.aFsLand.l.irnlrq tr'rlncnt
't.Slabitirl ol llclrl Compltles:
Thc.nodlnlnr nrbilit] rnl liinelic
c.dipLcxc, c|. 11. cttccl. dc(er nrirli!n
0lllrs.
{xblli(r. li.toE rfl.rlns rlr. i.bilil} rl mcl.L
or..nr;osilnn of conPlc b) lob r nrerlxrd .id
Llll: lt : nRC NIC C llENIll R!
'
ii,.ilr:.u.. rilh .atrrplc! ionrcrclatu. (tlit''l iv' rods !l i!nrhc( ol
rlcoiroh (br h!d ion or.lt.;es. rcducrion
'laldehll'
rnd lcion's ad'if!nolR1s
i."l,l"l'"rJ."iAro...l.ni.tiDsunhinsresrlirtrinari- .ccondlrrrdtcnix'txkohols
br d;hr''d.,{ni imd !m6 *dh;d Nl.ihin(n ol csierifi.rl'i iarctn belNcc crh}L
ninrarlc ]romls, 1crh!ds ol lor iatloi ol .1hlcnc gl)tol ir"hxnitrr ol Pi|acol
pmr..loncExrrargcr. r'
15. _t
Classlfcrion $ith da.rpl.. naDulicture ol phenoL by .uri.n. xnd
AriliLy o nhrn!], D.chlnisnr !l R.id,.. li.nr. anJ KoLbc rcdiors
pherol conrerstun ol phenol inro I Asfirn l. i'lelh)l sahc)lare L Sxlol.
5 Phcnoli.k.toncs(Fr.rcrnng.ni.nt)6PhenoLphdrxlein.
I
^ldrhvdei.nd
Krl ne :
Nonicn.litur€ (lLiPACl ol .liphilic nllehyde rnil k€! cs, leferxl nrelhods ol
pr.0aratlon bt al..hok. gcdr dihrlides. rlkyies rnd crlcnN iah 0l jifty r.ids
txc.laldchl{lc and rr.!)n. nr!) b. r*ctr .s .xtr]plct. 1cc|anisn .l nucl.otlilli.
dnion nilh llCN rnd condensrtior r.&hon snh adnn.oix d.rnltn. R NH.IR OH.
NHr NHPb) ol rldehtd.s ind kerooes.lV.!htLniinr rl alllol condcn!alr!n rlrl
rc.rxlachydr i11is r$!riL,n Mxnnirh r.x.tion. tsicrrr- 'iL1ie$ oxidrthr ol L{.toncs
^'!Darl.
aldchl-des: I echaDlsnr ol Bcn/oin cofn.'sriln ucrtun rn{l C!nnr/4.o s
rrxction (bcnzxld.hldc G tak.D xs exanplel
'1. Heteroclclic Compo! ds: olll's.
Dcliniror !nd classrlicrlior. mcrlrod o1 yorhcsn ol tux. rl,i.tlrnc Dy'dc rnd
rrrdi. AmmIc clrrder olthe trLrove lonrNrds (w(h
'folscullr
o.LrilrL nicruE).
Fl.c(!thili. b*itLtion r.i.tbns ol p_vtroLc rnd p)ridinc
lilT: III : PHlSlClLCllEllslRY
l. l hormodrnrmic II :
L nrihtnir orFi'sr N (needoIse.on{llr{) sNnrxnc.us rd)..ss
'irh crmDl.s Dillircnr s1lrcnrcnl! 0l c$od Lr ol (trc.nod!nr n. Cx.nn s
.J-cl...tlicieicy.lrbe helr eng ne. run{! 1he.r r,r)nr.n(flrnr,f!icnron!rtrn.re
liLn.r.D, fhtsi.xl sigDincincc !lcntropl. cnr op! chxnlcs olrn ciL !as N rh drugcs iI
F. V rrd T. rrl.ulxlio..1 . !ooy ch.igcs in lv.rsiLrlc. notroim ind r.crslblc
riLirbxli. Do..i Pfuble rbf,.d. .llicicn.! L'qu.lion.
Gitrhs lnl H.lrnhollT tilr.ocrgt_ tud(ioN. Cibbs i.e cNr-ly lur.tion - rsclirl n.rk.
rlnrli..nce ol llce .ncrs), lhrngc ..it$i. t.' torhnciq d cquiLibria in tcrrN ol
U.ll.S.A and C Llenirliof ol Gibb Hcl,!hrh7 cquxtidr clxli.j_ror Clrusns.qurtiir
ed ns ,rrpil.xtions llidlx'.fthe nod{ranrio. Ncm{ h.rt il!.rnr. {rlrnrcnLnd .u.+t
2. lolulionr: 0gl l!:
l)ifteEnr Llt.s of nnrri!f i1h .rnrpL.s Llinary mirtuc ol conrpl.r.ly nircibl.
liqLrids. liiollrs hr. Trl$l rnrL nonid.xl sDlut.is(b.s.d ol Raon rs LarL). Doire.rd
mg n. dcvi.rioDs nlm RftNLrs lu q h dr!|L.s vat.nr pK$n. ci n0$itnni rDd
borlnrSD!rnt contorilnin dir!rrxnN lbraboc rlp.s Iti'rcr colliiclionrl diiiLl.lior,
Azcohoprc nrixtrL cs I'rnirlll nrisclhl. liluld n tn$. cr rcxl solLfon tcmp.ratu.
lcs-l) nr renrsr rol.) $r10r Dhcnrl s)rl.r (b) ricLhlLrnii'rc rx(dsr{.r.xrd(r)
l.Drltrc - r.l.r slsr.ni lllicr ol .ddrior oJ iilr rn CST 01 nh.nol xo -tcn
l. ,
'd
li I
3. Colloidllslat.: 01H
C.nr$(..L..ricxl 0rofc,1i.s olsoLs. orig r ol chrqc on 0oll!irhl f l clcs. rhco,t ol
clc.riLc do!bLc lryc.. Tcrx !orcn{ixl clcrmr osn.si. clcct o|rofsis.gcnoxlaDp ]. ior
16. EDu!sions - rlpes. Preparations emuLsilyins ae.nt a.d appljcati'ni
G.ls .lasiication.pqmtion Mda rhcrh. s
CIIP: 011: I,ARORAIoRY COURSI- III
lnorgamcscJni micoqualilalrrcanxLlsis.ontaiDiDg nro
A!L{lradili CUr.C P NO dndSOl
H.,rLnLLrs:au BL ' cJ-' cu: Al . Far ln I 7.-r ca r.
sir. Bxi:. Nts
r. r'
,n.,'- .! L.i,, 1 .l. r |r'll 1d I rr
"
r ll" t. , j
".1
d ' ' I i
Bcnzoi. i.id li oni F.rc.. D..olourisxlio. ud.rvnilhzarion usin! dra'c'rl
Decolorrn.iion or bro$ sugxr (suc,.scl *ilh rnin[l chrcoa! using grlrrt i!'ilion
CosralhTrrion rml J.coloo;isxtion ol l.rfuE n.phtlrt!cD. (100s
'l
naplrrlulcn' mixed
wiih 0.3g oJ coDgo.cd nsin! lg d.colonTtg crrbon) r'o'r
'nnnol
! Totreparors.nn,u!llhidc{nnli{rnrnd..mprrcihcPrccilihringn'ncrol
mono. hi rnd tr nlcnt ani0s
2. Dcrcnninxtion ol txnsirnrntenrDrtufutofthe gr'.n srb$o'c bv re'n'dr'lricl
dialomcti. ni.tho{i (e
-q
tnCl2.lll:O.. srBrr'rH:O )
3 -locon{tucttht Phxse{lrrgrmror'tr.c.mpon.nr(c.g diph'n)_lanline
bcnzophcnlnc)sln.tr, by cooli,lg crn. nrclbod
N.t:only,oorgxi c cDi niicr!qnri1trLi!.anal-YsG is gncn i ihr rtdrinilio'
17. DeftritioD .l xc d aDd
.Dnc.pt rdd Lur ljkn,d th.orv.
2, Non lqu.ou Sollcnts:
lin.du.rioD. Dhyicrl |IoFft,. .l a
.ha.r.r..isi.: R.r.ri,)n,n nonaqucous
nrlphtr.l!)xnLe. hqr H:SOa rdrO!
.1. Orgini. Conipounds of
nro .orrfourdr: (i.DoxL
..Ju.lon ol nit!bcu/.nc iI
rm.ri.is.lnir,.).n/.i.
FOTJRTH SF:IESTER
(HT:0Jl : (HENIISTRY
IiI l: I : INORG^rCCtlFlISTRv 2lHrs.
05llrs
' 09llr.
ol nir.rlkxr.s xnd nrtro r'!ncs.
r.! unr Flcd.ophilrc subirtr( or
h!s.s. ,^dhcnils ttic.,]. J Nry Brc*rd
HSAB Dnncitne and iDDlicxrion
0lltrs.
l.cnrrrffn. F,fenidj. s'1,ctui€ rrd bordrngofnxronucle ctuhonls nh [tn'cd.. tr
Fc(( o)r Ni(co),addc,(Co)i tr rcrc|(trb.hnr!,.l.rrbonrror e. s}fe,-sic efti.r
i-',ll r
06Hrs
d.nt. r)lics .r rl!cnL rnd the; lenemt
$iL h.clcrcncc b liqLL rDrnir. liqrid
.l Rerctiri6 ofNtrrxl ComDlcros:
Lrbi[ ]d incn .onrdexes, ligaDd sub{n ion rcx.tioN s rld SN:
r.actioDs ofsquxrc pLxnnr.o fl..s Tnns cltc.t rdd its tr0nh!rr!'s
LIIT: ll: ORG IC Cll!MIS I RI
l. Ethr6 rnd F.Foidr i
).lnrnnnr n.n.f.lxitr. n.ilnls .l
wilixnson erh.i svnh.sn. h.xriig xLkvl
.nhrid, xil (:{r li.r,lr .rNa. n trnN
c'.qr.rh.r: lfiDdn(ni. wi{h cr r .
LFid.sr D.ll ion dd slnrhris oi EfoiJ. (. rylcn. orir x xr .tr nnc) rcd afd
br,.crtrlyrcil rin! o|!nin! rcd onl
?. CrrboJlir lcid! : ljH,.
Dcliniirln. cLrssilicrlron nilh crnrplc5. nr.llrods ol stnthcsis ol taty ar rl bt
rlcohoLs.cy r es .nd Cr -!i1d rcrgefr Ac ily!lc.rboxrLc..ds..ni.totsLb{tu(nin
on icid str..glh. C.trDxr. tuid sotr-!ths.niong lorniic a.id. rccti. ncid. ffunrnoi. rrrd.
b..7.1. !.id .l'lrru llu.r). Lron.!..ri. r!ids x.cti. r.id. rino di rn{l hrchlooic.l c
rriih H.ll 1)lhanl TrlirLkr.crchof ol cr.hrli. r.ids
pr.p.r.tion h! dchydnli{ni .i xkrl,ol.
hxld. r nh drr sin.r.id.. RirlnB rulo
11 ir h!.Jlrriltilnf . i..it. c ri ,.i.,.
' I ,)'5
cr r. ketoiej xidcxn d.s.
Dctinirion Nith cditl.s sydrlicsh .l a.idchlordcs (rc.t}l .hl.ridc) mJ ndn)n
lh)d.or!. rlcoho!Ji. nnnonollrir
'.drrlion.
Ror.nnund r!du!liof. Frrcdel Cmfts
xc!hr on: Acid anhrdrid.s (accri. xnhrdr c) r.x.1 0ns (hl.drolrrG. i.x.lio. s dr rlfuh.l.
.irnofix)r Anid.s (rcctxDrid.) icr.to (hydrol!r. r.ductior. llouir[n d.eriiL,(irn.
rci(!. xlkrllr. !nJ..!tal
18. AmD.s: Dciritron. cLbsni.rtion {ith .rrnplls a;.n.r.l d'th'ds ol s}tlhcsi oi
l,l'.".r'
n''n '
. r,-o cl ) 'l
d r''l' ' o iir
1r cH,NII..1CHi)NH & lallJrN
h) ClH.llr, C.H;llCH. and CiHiN (Cllr)l
c) Anihn., P_nntuaniline rnd P_TolurJinc
'o r ' 'F
' r' 'v
i ' I
hldr oxyrTobenzcnc and I dnnerlrl'!dlin'47'bcnz'ne)
L NII ' III ' PIt I5I' L CHTIIsTR
I t .e'n.nrr' (ru^ntL'n 1.(h
'ni'
l:"
R ' ro B. l
4,,',hr' posnrlrrcs ulqurunr rncchdi.s Bl&k b.d-r tudir(iorr. Plxn'ks radirtnr' lxN
'.".1 t L' P I I o', l' Ii-
n'.,. ni l' | _ '' ir
''l{| .
'll.v
I q' .il
i.i.r;.'r ,."*"1 eDlii.irnnL tr rndial wavc rLLr&on xai rn3ulxr tra' iricrion
Qudnm nt;nbes md ricniqronxn..(.nL!quiihrne)
r Ph!.r I ouilftrL
, ." t,, "io nii.,rrtui.nr srsrcni(rd.'
"nl
sutN).1rinh 0oinl r|rlicnlion b nvo connon' t
' ! h. ir " J 1 1 "i " ' l:
t- , ,. t{tr ,...i
i rtrnt*t'"-i.tty,
lncn.tion ol r;di.ti,t1 rh rrlrc. iLirTarcr.c bcN"D lrc'fxl aid flrotochcnri'xl
'u D{ lJl ' r
Li . ", ,,." ",t " il:r
;,;
"- ",
rr 'r,,i iJ' r"
ti, or r'' "nr''-, l'i '.
phltxensiri/ci] rarlidN I rttr Ndn0l.
CHP:0ll: L,tloR.ToR! COLRSE l' ')6Hrs
L Snthrv JntlAnrlsi:
o,. 11. ",. ,.' o, r'o l'
D. nlArnoil.rry'
iL) tr+ar.ri,n ol^_i DN1(j curpLc
r rl !ntrnLUrir.urF! tctr I ' 'c.!nn!IJ t' I o
2, Insoumcntition : (.lo.ndrl
il Delcrfriralion of tun usine l. l0 |h.nrftltuLiIc'sxrc'geitb)colori'n'nr_'rl rj.*t."." "t,,. -",r.!tnnr oilhc tirD!' con c b! JoLr's iicLhod rnd
19. t nole latio nethod.
3.W!ter rnd Efituent malysis.
I Esiimalion ofwarer sohble carboxylic acid tiraton nethod
2, Estinadon ofslucose by tihimery ne&od
3. Estination ofphmol /aniline by brcninaiion method
4. Eslimaiion ofAldehyde sd ketone
5. Esdnation ofamino acid
o . n.m0.or olianrl co) I I n.n merhoo
' n or o_ 'rosel b (.eldal-l1e hoo
Non-instrume.trl l{ethods of analysis :
L Det€mine the specific dte constal ofhydrclysis ofmethyl ac€tate by IJCj al rcom
2. Compare the strengrh ofHcl mdH:SOa in rhe hydrolysis ofdhyl acerare ([ for onc
3. Detemine L€ aciivarion enersy in the hydrclysis of m€thyl a*ule (k vnlne For one
Tenpemnr€ is to be siven)
4. Deremine rhe padition coefEcienr ofiodine bciqccn carbon retmcbloride ad
5
6.
Deremine ne equilibdm consht of Kl+I2-KI3bt disrribuiio.
stldy the adsorption of aeti. acid by activared chrcoal
9. Detcminc the ritical solution tenpemtuE ofwaier - phcnol s)6lem
I0. Deteminc rhe lercenrase ofNaCL solurion Bine solubilit, of plenol in water,
I l. Detemine dre mledld weight ofnon volatile solute by R6t method
12. Detennine rbe noledltr Neight olno. volatile solute by ebullioscopy hethod.
13. Detemine tne heat of neuh alization of stong acid and stong base.
14. Detemine tne h.at of neut alizatior of aceti c acid md sodiun hydioxi de and alcu late
15. tie heal.li..i7rti.n ofscdic acid
Detennine the specinc 6re consunt ol a second oder rcaciion betwecn Kl
Derenninc &e specinc Ftc constart of s.ponincaiion of cthyl acetate
Note: Either orgmic cstimaiions or phlsical expenhen6 n b be given for
20. Dcinjln,n $!es ol i..nrrnic l vmc!s. rlasnli.ati.tr comparnr)n h'Neen
'rsr'''
rn,L inolgorc lilyineA Stnnl.sL {rururaL xspccG rnd xppicdnr' ot iLrconcs'
Ph!.n
'J ozene,Jn!prosn inhlir!h ,iL
'''' j i
cychcsli.dcs, chrinsih{r.s aml shc.rsil.ares.
I Bnsic Concepts olChronritoguphl:
c.ndxl d*sinrr.n. delin(ntr. tems lnd Fr.nrerc s uscd ln chranrxtog'anhv
Cl|sirti.ation ;l ch,omrlosrafhi. rerlro.]s Crircrix tnr seLe.tion ol a nrlLomrl x'd
mobiLc fliN. ixtrtrt rladsorbcnLs, trctos infucn.rdg dre idsorbcnts .x re rnd lvNs ol
Th n lricrah.odrro-! rph) (TLC) I,rir!Ld...rnro{l0l!-qv. d.r.Nirrrlior !l R,rxLue and
,r orill.i{e u.ixbles rlur ,tlid R, vrhL. 1.d .DDlrcdions.
l. l, 'r'r ",n '
r
' 'J ''lr'd,oo' -iJ ' '
'.f
-..1 r,r ' r '' ir'r' ", , ' '.r'
FIfTH SEIES'I ER
CHT: 05I : CLIENIISTRY
UII: I: INORC I IC CHEITSTRY
I. Inorg!nicPollnrers:
!llla
ntc. piu.rtior aDd pr!lc!1ir.
xDr!icrlion ol nr.firl n g csiun (inlc
|2H
.hc nicil rcr!tnnr ol I riolJ (E(lixnc 1lr ol n y
[rl'a: lI: ORG.lC CHF.tISl RY l6llrs.
Ji or n1
l ll .' ovPn olL
, ,1 '
r"'
crdrdes. Fr;.tional !tuup ail lni!c$ri'r r.s$.s. l-vDes !T rb!!rions nrd guns
. I' P "" '
NlR rdroscopr NNIR sncctrx ol nnrplc or-larrc mrl.Nl.r ch r Fdrvl brunnlc
D.firirbr. th$,ics. rcac{nns. ficlor xLlicling co.!nJn
Frhanol. Acctxldch-rlc r d lohLcnc
2. orgrnomelrllicConPounds :
Th. (lrign.d rcxgcnt slDrLicsis aid
3. Orgrno Sulphu, conrpounds :
Nonrcr.lxtuc. u.$ods o lDrnxtn xnd
ThiLrctlreiJ N!.rcrclnkc n.!h!ds ol pilpx.xtior rnd
suhliLd. ni]' bc rxkcn rs crandc)
!h!ntr.1 cr.r'!l ln !rhl
21. 4. Resrrang€nent reactions :
Backman[ ]-osscn ed Cunius, dienone and Bcnzidine
02Hrs
UNIT: III : flIYSICAL Cq64lgIRY
Dofinnion anrl exanples
osmosis and Osmolic Prcssu.er Semi permeable membran€, nalurat and anincjal
semi p$meable examples. Osmosis and osfroric pressurc- delemination ot osmotjc
pre$ure by Berkel€y and Hertlerit mclhod. Theo.y oi dilute eLulions. Las of osmotic
plestrre, relalionship berw€en molecul.r ma$ and asnotic pressrc, isoronic sotutions.
Loweine of vapour PEssurs : Concopr ol vapou. p.essure, Raoutt's LaB, retarive
lowerine ofvap.ur pressure ofsolvent, ils dererniiatioo by dynamic methdd (OsMtds
& walker). Calculalion ol moleoular ma$ lron relarive Lowrins ol vapour pEsur!.
D
obh 1,
Elcqion in boilins point: definirion add irs rtlarionship wlth rclative Lo*erins otlapour
toT ' l.pc)rcn- lr . r- cq dir I l.bt |,o.cop' .on..a; o
solvent, relationship between mola. mass and elevation in boilins poinr Dddinarion of
nole nrN otuolute by L{d Bergers herhod. trcblems
Depre$ion in lreezing point Definnion and irs El ionship to thc toNering otlapo r
pre$ure, cryoscopicconstantolthe solvent,relation berween depression in lrcozing poirt
dd molecular ma$ ol solute(ro be derived from CLcpelrdn Clau$ius cquarion),
deternination otmolecular mds olso!lre by cryoscopic method. Probtems
AdsoDrion ol cases by Solids: Adsoqlion isothems, deavation ofFrundtich adsorption
isolhermandilslimilarions.De.iralioDofLansmunsadsorptionisothens,BlTequadon
(no derivation) and ns appllcadon in the dderminstion of surlrce area ol adsorbc .
CH?:051: LABOR {TORY COURSE
Quulilotlve analysis olbinary rnixrure containing dvo solid compounds, sepantion using
NaHcOr,NaOH rd HCl. ldenrincation ofmixrure, separation ormixtu.e sndanalysisol
any oie compodent with pEparation olderivatile.
AcidsDenzoic, Salicyiic, Cinnamic and phthalic acid.
Phonols: I Naphtho l, 2-Naphtho land and resorcinoL.
tss es:P-.ol, ro r-O ol oiF-n-lodir-.rcsnli.
NeulDl:Naphthalene. Diphonyl, n dinilrobenane, Aceranilide.
Themi{dreisolA+8, A+N, P+8, P+N add B+N
I scparalionolfreral ionsolsrcup lV byascendinschrofratognphy.
2 separarion olnreralioDs olsrcup ll b] paperchromalosEphy.
3. Separalion olPhenoh on activaEd silicaCel (th)
Note: Qnaiitstivc analysh h given in theexamination.
22. !.IFlII SENlTSTER
cllT: 052: CHI'.'llSTltY
IjNIT: I : iORCAIIC
'tlltNlls
IRY
ITNITT tl : OIICA)lC CHEYIS I RY
Cl.irnrgrdi(n!lsoi0s
'I St thclic Pollmc'r I
. *.lilrlion nh crnPh srdthcns
poLlctlr.nr' Nlv !iill!hLoridc nYLon6 i)
0llh
xDd rses oi lo dcnsiq rid hiSh dcisiil
itr 6.6. b.Lel(c r d rstLrnc
23. 5. SFtheric Dyes : 02Hs.
Introductioq clasinmtion b6ed on sruruq chronophoc thcory ot colou md
coBtitution, SFLhesis ofco4o red, bisntr.kbrown. nElachite gcn Md aliz in.
Revision of conduction in netals md electrollt€ soluii@s. SFEcinc conducrmce, ools
cmducrancE equivalmt onduclane, wiatior of equivaldr condudana &d spsific
conducloce witb dilution. C€ll consiant, deremination of equivslent conductance. tonic
conoucrrnr. roic moo'|iry, Kor zschs ad apDli.d on: Numenral probt.r:
Eirnofs theorelical de ce, transpori nmber, detemitution of liesron nudbd by
l{irimfs method (non-anackable el€ctrcdes). Dcbey Huckel,Onsaer €quation tor srug
€leclrollt$ (€lemenrary ftatnmi oily)
Aoolication of mnductance m{:I@nenls
a) Solubility md soltrbilit prod@t of spdinsly soluble salt
b) DegEe ofdiss@htion ofweak el{trolyd
c) ConducloheEictihtiom{cid-beandprecipiration Etiotrand
2 Phtsi@l propenig an.t not<ullr stdchlre :
Dipole momeni, poldi2ation, induced polarizalioA orienration polarization, m€asurendr
of dipole movefrtrt by tempemtu.e nethod. Classius , Mossotri eqlation ad its
imporiece. Dipolemovd t and structre ol Mo1@ul6 (CC! II,O. BFr NHr ud CCtr
V"gr^ric P'omc. Pdiagrd coin.gr"d.
'
I re oms-e'i s's -r.
' 6t,
CII} : 06t: LABORATORY COURSE,rI
lnstrumental methods oI anilysis - I
l.
2_
3.
5.
9.
t0.
ll
.Conductonetic titraiion of slrong acid Gay HCI ) aeainst stmng b6e (NaOH)
Condudomelric tilration orweak &id (lcetic rcid) asainsi strong bae (l.JaOH)
Condnctonelric titralion ofnixtLre of acids against strong bae
ro'duflonph nec'prh.ror r.larioro .odiu
'Jrlorid"ag,' 'i.r.er
Nit .F
D"er'-, onorhornror. r incl<Or.o triorddvearyBeer Lnb-l dw.
D€temi.e the specific ed nolar rclractivity of nvo given liquids by Abbe
€fractometer md delemine the densities oftwo siven liquids.
lsiimaiion ofHCI bt tirrating wirh srandard NaoHlotemiohetrically.
Estimate the anount of iron in fermns amnoniufr sulplrate by titmtine virh std.
P otassi un di ch romate so luli on pote ntio tuetri call y.
PotentioncFic iitration oldildic acid with strong basc. ,
Dctcmi.ationofamounlofsodiumclloridcinlhogivensolutioo pore.rionetric
ilration asainsr silvcr nnrale
Dctermine lhc spccificrotation of cane sugarsolurionlsingpolrimctcr.
[-INIT: m : PIIAICAL cHEImmY
24. SIXTH SFIvESTER
d 6r CHT:061 CfiEnItSTRY
UNIT : I : AALITIC'L CHEiIISTRY
l. Er!lu.tion olAniltiicrl Dalr:
Ceneral Din.ides. sl.ichnmelr. caLcul8tion ot rc!!h lio ntrnnetrtr drtr. Propcri.!
ol pr.ciInalc Nuclcrln,o rnd o)nal !rotrt. tidor influenci.g ..drtl.ri.n oi
n,€.ipilalrof c. Decr)lrtron xn,l posl precipirarior. purllirx.rn rnd iashns ol
prcipihrcs. Prc.ipndhr lirm honrogcD.ors soLuril,n. r llN clnnon s alim.tric
detnnination+chloridc s siLer chLorldc. sulOhxr. 6 b!.n,n s!ldr.re. rLuniinnN as dr
orin.reandntkcl.sdiD.tlrll gLlorirn.rc
lntndL.h.n, Er.r A.clrx.v. ptucni( ,
'netlrods
olcfrcsnre dcu.a.v rnd Drccisiotr
clriliclliono1e..'r.$$rlicrnlli!u.esx.dcoDrpntxti0nsJnrihurionotru.Jome[ors.
'n3xn
udit xh,d derrn,ns. Eli1b,hry!lresuhs. iu$h.d.r.cponing !nJl!f$Ldxrx.
2. CruYin.rn 'n,hi:
Srn ing ri frenr'lrior olwrler.IretennlnnrloD.lh!'dn.r rlkrliritr. ic ill. rotrl
dissohed soLnh llDsl. Di$flrcd oxv!.r (Do) h $rrnliLer's nredrod ar! doircsir
lllT : Il : OIICANIC CHr IIS I R
l .{lu.rior. c r*Lliri(i,)r Nrh.x!nrp.s. g.ncrrl dicdrrls.lsttrrrd.rl chLrnLrli.n.
H.lnlnn exhln^r nclh)lrion rrLlr Nri.lii. as.aDrln.. Sj-nrlNis xod cluc ltion ol
n,uclrL c or'n roLlncSNrctrL rllornNh xnd u.s ol Q i'ri.c dJ,lurrc
I Terpcnc: !ilt6
Occu Encc. cLisj lir.rLor. lsop'!ic rulc. spccixL kq).n. rl.. iso 11i!r ol Tdtcn.s.
syithej( rnd gcrr nrenl s ortluctu.lcLucid.rion. ntu.rd.rl cLucnh' on ofCnml
SNrctualtomrli dd us$ olmenttul. a- pincn. and .,trrrlir,
L Anrino Acids. poDtid.r xnd DrotcnN:
l r.ducti(r rL.siti.rtiL,r xdlL $rctruc oJ
(lionr rc{l.5hoc[.' )ntl,ci dl (inh'icl
ind islclclrrcl! !ln rn, no r.Ld.
.1. Bio-Orgrhi. Chemhtrt :
!nr l js: Jaeduclil,d.cllsj ft.rionNnh cndr .!
B !losicrl rNanl.ncc ol irunn . Bl. B2.86. C.
o,l]ls.
.nnr o !.nl. s)nrhcsis ol.r anri{ icidr
rh(lrrhnrmc synrh.sis) Aciil-8asc bcharior
Pcpl l.i clissiiicarior. Dcnfic linkrgr S)n1hcrsol. dipcplidc (Cltcylih ic).I'ror.ins
Clxssllcdon offrorei'rs on ooDrlltrnion Do errl.r nriDe. Prirnrq xnd sc.D Jrrt
Fn/lmcs: Clrsrlicrh!n Chflclcrirric DroDc,!cs ol crzynres. r)cchxrnfr ot cn7_,tuxllc
&ron ll.ock rd Kcr rhco'r' rnd lcnDl.r. hlporh.sk) lracl.F rltrnu r. rrlc ol
erz)nre cxtxlF s. co- cnzlnr.s
llon.ncs: lntudddloi. clx$lllc.liod nh cxnDLs HlNone sec clrng gands
S)nhlsj afd inporlancc orA{l'.IIlnc ind thrr.xin BioLo!ic.l l.rno rn.c !l irulirr
25. Eldronagclic ddiation, Egiom of dre sp{rm. Basic fcares ot difrerent
spectroneters, statenenr of Bom oppenheiner agpbxinatioq d€e6 ofaeedon
Rotarioml specFmi Dialobic noleclle. en€ryy levels of a .igid roraio. (smiJdsi@t
principl6), sp&ing of sp€.tal lines, selection ru16, specnal inr€siry, disiribution using
popdalion distibulion (Mdwell-Boltzmmn distibutio!), deteminatio ofbond length,
quali tative des cripii o n olnon .igid rotatoi, hotopic effeci. NIN
Vibntional speclrun: Inlroed spechn:Energy leveh of sinple hmonic oscillator,
se a rior ru16. ptre .rbmriora pftu r "n, ) detuaiio
'
o ton " conElL
quali0dtite Elation offom consrant and bond enqgi$, etreci of annmonic notion md
isotope on the speclrun. Probltu.
Rman sp{trun: Pure mtational md plre vibrational Raman spectn of diatonric
tJi:IT : m : PEISIqAL CHEMISTRY
1. Moleulrr sDetrIMDv:
2. Rrdi.tion Chmisrryi
Introduction, Dnits of ndiation, ndiolysis
Ceric anph,re dosinieEr koropes - Lrse of Edio
Medicine, Food P6mtim, md orbon .lating,
16HB
04H6,
of walei dosiner6ftche dGineter hd
Isotopes in TEcer technique. Asicultue,
661
Cm : 062 : LABORATORY CoURSE-4I
Cnvimetr'c €stihrtionsr
r Esiimation ofnon 6 f ic oxide infemus m'nonium sulphatesolntion.
2. Eslimalior ofbarium 6 beim sdphatc ir briun chlonde solulion
3. EsLination ofsulphate as b im sulpharc in mmonium sulphate solulion.
4. Eslinadon ofnick€l as hickcl dimcdtl glyorimare in nickel suLphate solution.
5, Estinarion ofMasnesim as oxinatc in magncsiun sulpbate solution.
6. Esrinalion copper a cupos thiocyaate in copper sdphate solulion.
I Prcp@don ofAceranilide fmm aniline
2, Prepdtion of P-Brcnoacetmilide nomAcetdilid€
3, ?repetion ofiodoform f@n acetonc.
4. Prepmtion ofBen2oin fron bwaldehyde
s- Prcpmtion ofm dinifiobeEene Eom rihobwene
6.Prcldation ofp niho aceranilidc fiom accranilidc
7. Pepamtion ofBeMoic acid lrom Bozyl chloridc
8. Peparation of2,4,6 - t ibrofroaniline from aniline.
Note: The $avimetic esdnations arc to bc eivcn in rhe esnrinations
26. SIIH SENfESTER
d LL CHT : 063 : CI IENIISTRY
UIT: l: INDLSTRIAL CHEIlSlRY
htrodudior. {lrlinnl.n. r{ .r)r.riah,
(b! dry xnd nel pro.cst. Nlechnnnn'
grxd.s olcenre.t. lvnnutr.tur. of Ponland cc'ncnr
.l settirig of cemenr l]ocs ri .cmenl and dren
2, Crrlmic! Relia(ortes and gllss:
c.ranricsr INulu.lioD. clrssiliclrion ch definilior. proD.di.snnduses
R, lnnr.rl.( .hs{lication ac . brsc rnd ncuta I Etiacto r e
GLrsi Pturcnies. t)lrcs, rinulxcnre .l sod! rllass Composilion
bomsiliclrj. ctxllic -!
trs. .ntl.rl !lnssls anl DdlranDr e
-!lass.
:1. Prinls. Pignenis rnd Vanishes:
Painrs: Intoducion rcquirenlent ol Fxi cod{itucDlsolparns. n'nrul!rion
turh!e or FL.ls liLnrs {!!x$nt. cnfLsior flos. .r.irhcture ofwhi(c lcrd
PlsDreits: Red igdrnc. htc pignrns.
v!.rishes: SLrir r rod oi1 arilshc
UNIT: II : ORC/NIC CHEIISTRY
L Rcrgenls h or{gxnic s$tlr.sis:
lrc]rrrln,ns x.d rpth[lions oith.lir ]orr rg turg.nF il.r-!ific synth.n
Lnhiun alum,nndr hr_dridc. n,didi borc hyd'de. n,d,un,. Liquid.inonLa
PohssiLLndichnn.t..PolrsnrrfcaningiD.lc.Hllnodi..cid
I'od. ,o' l.r
lita.y.Le. bisic prin.idc olg.ccn cluris.r' Creer ynth.sis olxdipi. a.d.
3. Prote.lion ind d.proleciiotr :
Prorect(n rrd dcpFrccnon.anre iolloring tLndionrl grorD
Critcrir lor thc pmleciion tdd d.p,olcctil'1 , xr.irro. h-rdrovl. rxlboxlL
grorps (trrl.ri tlnc. rrscnl tnrexdr srouf)
J. lledicin,l CheDrtry
Trlt.adflgs: D!linlrid rith Fxnt.s (Ana gesic. Anrilyrctic. Anislhclic. Norc.rics,
Dnrctr.S.Jr1lcs. Cx'diocsc!hr. A lirnalcrill A ihcrldrmt. An(iconl!lsrn1.
,nriscDic. ,ntibiolicr. Sydrhcsn and u6 .l Asflin liracrtm!1. strllhxnihnrmc.
SnLDhrlhrazol.rdchLor nin. T
27. t
I
I
ITNIT : [l: PIISICAL(IIEMISIRY
Elecliolttic dd CaFanic cells, rdeGible od ireydible celLs. T$es of evssible
elechldes, netalmetal ion electrode, n€tal- metal insoluble eleFode, malgm
eledod€, gs elecirode ed edox €l{trode. Electiode @ctio6 in Dmiel cell. Sign
convdrion olelecnode porential Geduction potential is to be adopied) Elnfofine @ll dits
n6uEndt. Slanda.d electode potertial, Nemt eluation for electrode Fotdtial md for
n6uine Emfofthe Cel (to be derived) Ref€rsce elecrrods - calonel eleFod€, Weston
stan.lard .€ll. polatization. ova lolrage dd Hydrogh ove. volllee. Pmblm on Lhe
"lat@epohra and Fd or$e ceu
Concentation cells - Actiriry and Aciivity coeffcient of €l€.rroryt
Concentration celh with ed withoul transtffice, liquidjscid potenrial, $lt 6iidge
Application of Enf nedurem€nts-
Dctemi n tli on of pH of a so lution usi ns qli nh ydrcn and gl ass elccirode
Poientionrelric tiFatiotr - Acid -base ed redox tinaiioG.
1 UecrtuIemic,l serg/ soure.
9, Prepa€ a standard 0.2M NarHPOa and 0.1M cihic acid solulion, hencc prepare
DifeEnt butrer solutions and delemine pKa valrcs of lhcse unknoM solutions.
10. Detemine tie pKa valucs of given acid by pH nelric tilration with strong bse.
1r. Dctcminc the peEenlage ofcane slgar or larrric 4id solution usins polarimcter.
Primary c€U (Dry c.llJ Secondary cell (lead stooge cell ed Nickel-cadmim cell ),
Fuel cells, co.siruction ald workins of ltldross- oxysa tuel cell md ils impdtuce
^a>CHP:oG LABORATORY COURSD - vm 43Hrs.
Insrrnnental methods of Analys's -II
I Detem ination of deerce or dissociation of weak €l€cftol rle.
2. Detemination of dissociation constdl (Ka) of aeak electollt€
3 , Detem inltion o I cquivalenl conduclTce at infnritc dilution of shong cl cchol ye. '
4, Detemltltion ol solubility md solubiliry pmduct ol a spdingly soluble salt Gay
BaSOa, AgCl, AsBt by conduchce medrod.
5. Detennine $e anomt of lron in Feclr solution and vcriry 1be Bed Lmbeft's
6. Detmine the percotage composirion of liquid mixrure (cdbon tetrachloride dd benzeie)
blfomula mclhod using Abbe €iactoderer.
7. Deremine the pe.centag€ @mposnion of hquid toirture(ca$on tetachloride ed bc.4nc)
by graphical netod usins Abbe reftacromelei
8. Detemine Le plt of the folLowins biolosical tuices
(i) niik (ii) otrce jnice
and (!) sodiun ca'tonale
28. I ISI OF RIIIIT,RFCE BOoKS:
I CoLl+.chennst.y B H NlahajrD
I Ie{ b..k.llforganic chcrnidry Puia.dShx.na
I Prulre$nc i..rgxtri. chemistry Slrtrtkr., Than. and Pandil
,1. Scl.ctcdtopics rn r.drgx.i. chenrinD Sd)-!prakrrh, Iuli rnd Madan
5 Chcto,stry olmE errlh DlD.cns Saryerrkish
6. Advanced rno.gtrDic che$inry Pl-s.nl
7. Atcxtbook olinorgrnicchenrislrr, furi. Shr..a and rauhor
8 tndu{ridl.heminr}. B K.S[xrnra
9. lndusrria! .hcniisl,j-. 1NI Lltirl
l0 AnxlyrcJl .h.minry Alkaxnd(jl'flr
'o'n'ol . cJr'
'.1 I
ll Inorgx.i. chctrrinr! ahqi'rlnd Iiapoor
. r-. '. jot.. iBr't.o..Jnr'.
11. Anallricrl ch.nisnl. B.K.sh!.na
l5.Vocelsr(Lro!kolQurntilrlivcAnrLyh.sirdrtdirion. J lerdh.ir.RC Dcnd.J'.
J D.Br ies. iUJK Th!nrxs
!6. A r.tb.ok olr cro&s..ri nid!rtuiln.llveanisisbl
1 7. Ircrgrni. chcniirrry. D.F Shil o & P . Arkirs C.l].I
l8. aoroclrl rnd NlodeLoll|orgrni. Ch.tr]Gt- by Douglas
l!. Crem{R br Rrynrond Chrng 5rlr.dition
A l vogcl. tilih ednnnr
onglirrd FI BS - 2ndcdiiion.
20. Ne'6ui.lc ro N{oJ.ro valen.eTbc..!bycl l. tsrorD - lrdedition
11.coddln .n Co'nNu JsbyBas.loxrdPcx.$.
12 ln.'!rni. Chcnrinq bt Da! .rd Seibil
2:l ln.rgmi. Chem{rybt
^
(;. shrrre- 3 il Fd(i,'l
2.1 Cor.didrli.n Chcmin,) b) A. K. Oc
25. Concicldoreai c Chcm,d't h!1.D. L.c ithcdilion.
16 Thc..ch.trllnorlanic ( hctr,i{ b!Do.ndSeLbn
27.P.i'rcifl..lBloiiroi:uirChciiisn-abyS.l Lippdi
Publishns Co,torlio.. lsiF(ln
28.lnorg ic Ctunristryb) J E. Hul,ccy. .1dr!dn. P.a6on Edrcalion
19 Inshiient.l llerlNJs.lClicmrcd nxlrsis chNtxl and Ar
l0 BasirconccptolAoil,ilcr Chenrinry lnJ cJnlon S Nl Khopkrr
ll.ln{ru rcDh iVeihodrt Ch.Nic.LAnrlyis 6rh.diioi. l d. llerri1t. Dca. xtd
ll Anrlltcrl ch.nrG.l bt,Sklog
ll.ln od!cr,on k, lnnftncnr.l Amlysls R.D llrrur
i.l lnDrgxi c Pollnro b) (j.R.Chrxal Hrnrl!)al'LLblhIingllousc li Fdn 1996
15. Pllytu.rSci.rcc A lcltsoo[ b!V.K. Ahl!Lxlix. Antrradha iU sh.
l6 !n!iron lc.lrlchc'.blry A. K. Dc. jdr Edrlion (N. ngc lDlcrnallorxlpublnh.'jl
rr Enironnrcnlx!( hcnr nry J w lvmraidh.A Nloo'! (Acrd.n1i. Prcs. Ncw
13. Envnln icDhLCh.irinry A K. lllrag rnf C R Ch1(xl (HinaLrlx Puh rihing
l9 In iiuNcilJ I Chcnri* J ll. Krur ln(l Fdirn)n 20ll?. Pr.gtrlrlrxkrllrln N1..tu1.
29. 40. Envircnmenal Chemisny vith Green Chenisrr A. ( Ds , Books dd Atlied (?) Lr4
4l . Modem lnorgaric Chenistry, w' L. Jolly, Mccnw Hill Co.
42. Udve6itt Chenistry, 41h Edition (ISE),B, H. Manan & R J. Mt€n, Addison Wesley,
1989.
43. Essential Trdds ir horgmic Chenistry,C. M. P. Mineos, Oxibd Univ Prss, I998
44. Chenistrt,3rd Edinon,P Atkins &L Jones, w' H. FreeD & Conpby,1997.
45, Modm Chenishy, lthEdnion,D. w' Oiicby, H. P. Cills & N. H. Nachlri€b.
Saud,* Coll€se lublishing, I998.
46. fudm tal Concepts of apFlied Chdislry,Jat€shree Chosh, S Chand Publiqtions.
47, Modm lnorgoic Chetoistiy bt C F Bell and K A K Ijtj
18 Udril) .fl .trJ bJ Ba cev"ltr
r0.lnorgdn rleni.bl b) rlopm dd K€poo
50. Oiganometallic Chenist'y - Al inroduction by R.C.M€holIa and A.Singn
5 L Inorgdic Chenist t by Philips d Willims, ljb Mmuls
52.Introduction to inoBanic Eaclions mechanisms by A.C.Lockhn
53. Cnenical bonding ed moleculd geonery by R.J.Gillepsy and P,L,lopelie.
s4. Adveced lnorgeic Chetristry By Cmdeep Raj
55, Analyical chmisrry by Gary D Ch.isLid, Wiley India
56. Analydcal Chemistry by G.L.David (npadmd, et al, Univ. Press
5?. Selected lopi6 in inorganic chenisrybyW.D.Malik, C..D.Tuli, R.D.Madan
58. Modm lnoryanic Chemistry by Willim L. tolly
s9. Concise coordinati.n chedisl,t' by GoFlan andRmalingah
60. Salyapralah modem inoiganic chenisq by R.D,Madan.
6l . Essential $ends in lnorsanic Chemnq .M.P. Mingos. Oxfo.d Univ. PBs,l998
62, Analytical Chehisty ?nncipls, John H. KenDedy, 2nd ediiion, Sauds CoU€Ce
Prb nhins.C"l.-omia, laao.
63. ?dnciples and Praclicals of Aial)li.al Chcmhi.?, !. w. riteld dd Kcalex 3!d
edition, 2000, Blackweu Sci., Ltd. Malden, USA.
64. Moden Anal],rical Cncmistiy, David HNcy, McCraN Hill, New Delhi, 2000.
65. Inorgmic Chenistry. 3ij cdn, C.L. Mie$lcr and D.A. Tar. Pemon Education (2004).
66. lnorgeic Chemistry, 2nd edn, C,E. Housecroft ed A.C. ShaDe, Peanor Education
.Ltd.(2005).
6t. Intoduction ro Modm Ino€mic CheDisFy, K.M. Mackay dd R.A. Mackay, Bl&kie
68. Concepts and Mod.h ofl.o€anic Chemisry 3rd edn. B.E. Dougld. D,H, McDeiel
md Alqmder, Wiley (2001).
69. Chehical Applicltions of Group ft@ry, 3rd edn, F.A. Cor.on, Jobn Wiley and
son(2006).
70. Molmle SFnetry and Group Thcory Robcfi L Cadcr, John Wiley and Sons
(2005).
? I . Physical Inorganic Chemhftr- A Coordinnion ChenGtry Approach- S. F. A. Kclllcl
spektrum, oxfod, (1996).
?2.lnorelnic Chcmislrt 2nd edn, C. E. Hosccrcft and A. G. Sharpe. ?ea6on Educarion
Ltd,(200t.
T3.Inorganic Chenistj' lrd edn, G. L. MisslcrandD. A. Tm, Pearson Educalion,
(2004).
30. 74 B.vcJnorganicChemislr-irdedn,F A.Conon,C.Wilkinsonx.dP.L Cxus..r.hn
'ihtard 5onr, (1002).
75Arrl]licrlCheorislry,GDChri(tan.jrh.d,20llJl,hnWilq&Sons,Inc.lndix.
76 AnaLlicrLChemishl I'nncrplcs.lohn H. Kcrrcdy,5d e{l ron, S LnderCollege
Publishing Calitonrlr. 1990.
7lP.inciDlesx.dlr.cl...l,^.aL]licalChenr{.y,fWlili.ldandKcalcy.lrdcdirion.
2000. ELackn.ll Sci. Lkl. Nlrlil.. USA
Tl. Nl.d.rn .xLyricaL Cheml$ry. lJrr ljmc).lcci.d H,LL,Netr l)elhi. l00a
79 lnhdl.f.. ro lnsltunreDtil Anrbsis. Br n, Phrnn Nled trers lndix.
80 lnsrrnr Nor.sol Anrl!licxL Chcnrnta. Kca1.!aDd llanrs. Vivrb.Dl(sPr. Ltd.. N.n
3L Th.lno'?rni. chcnristrrofBnno8icallrocess 2.tlcditior. NI. N Hughes.lohn
'iLc} and S.o. (19S8)
ll.Brora'gxrNCh.mr{q R. llay. []lisllo$oodLrd.ll9S,1).
31. Bioloeicrl Iruelnic Chc.nsny 1D lntodu.ti... R. R Cri!hbn, ElJc!ic,. (l01l8l
8,1. EioiDorgaDcCheDrist,r A.K D,s.BloksDdAllLcd(Plrd {200i).
8j Br. Lnorgh . chcmiir-- K lln$.il Rcddy. Nc$ Ase I cm.rionxlLrd (l01rll
s6. Bioino srLcChc.rtu) {Suney- hiichiroOchir .Ac.leNic Pr.s. (2tr08)
37. BioinorgrnL0Chcmi{ry A Shofi Couse-:nd .dirloi. R. M. Rort iUrl.ic, Wll.Lt
8ll N ed clnxlAtn i.rf.ni.lC..dina riClrc.risq Chr!I. i.i I.riThfrnr.[
RSc Publlshin-!. (:001).
39 Td.sitrn MctxlConrdees rs Dtugs rrl Ch€rn.lhcrrfelrr AAinls l Fr.cll.
Kldrr Acad.nic l'ublhhcr ll9St)
,r0 Th.Bn,l.gL.alcb.nistry.ldreEeiref(: lhelror-{rricahenri$}olLile-2ml
cililrrn. Jl R Frun. dx Sihi xid lt I li. Wilirns. Oln d Lhncsil! lcjs,(1001).
tl. Tcr book ol o'grni. !lrmi{4 AnD th.land B.S B|xL
01. Alvanc.d orgrntr rhcdris'f. Atur Bhaland B.S BhaL
9i. Rc.dion rcchrn,i! x.d Rcagcns in orgaiic cbc nGtrv Cnrd.cqr.R.Chil,ri
94 Orgxnlcchenisrr! vol l. .1 ll.vol lll lLrkhcrli. Singh and KaF.L
' 1. oo o.oJ !..' r) L l
96 O.gadicrhcDrhtn ,Torinrn rnd Boyd
9? Or$nL. rli.nrhtry L G.Wrdr
O.AxnLr!h.tuistrJ. lol-l,androl ll I.I Finl
08. Anillricrl rhcdrlslry . BK.Shxnni
9t). l'rlncipLer orf jysi.rl.hcnlisq Pnr and Shrmx
liJo Phlsica chernr{ry cci a.dAnand
l0l Ph!!.rl.hcDns1ry. ts.S.Bhr!rndCD.TuliFl.ckoclrcnrishlCLisslon(lhcdri.rl
L0i. Physiclllhc rl{iJ. Ptutoxrd Nlaon
101. Physical chcnn{,r- Glxsbn
!0i Pliysi.rlrhcinrir! R P.'crnr
106. T,h)ic.l chcfidr!. Kund xnd Jain
liJ7. lol.crlxr spcct!5crn) S Brtr$cll
103 Phvsi.al.hcDrinr! C.Nl.Barro$ 5"Edrlion
109 i,lolccuh' {c.hs.oDy. ll.l(our.
31. PR{CTTC{ CEEMISTRY BOOKS :
L Pmciical Physical Chenistry - A.J. Findlay.
2. Experimenral Ph] ical Chedisq F. Daniels et al.
3. Selecled Experinenb in PlDsical Chemntry Lathan.
4. Experinenh in Physical Chenisty James and Prichard.
, 5. Experim€nrs in Physical Chemistry Shoenal<a.
6 AovdnceJ ohy rco .ne ru.rl I /pe .o'er 6 . Ror.
?. PEclical Physical Chenistry S.R.?.lit.
8. Experiments i. Physical Chcmistry - Yadav, Ccol Pubhhins House.
9. Experinenrs in Physical Chemistry Palmer.
10. Experinen( ln Chemisiry D.V. Jahasidar, I.Iimala'€ Publishing House.
I L ExpenDenhl Ph]sical Chdrislly Das. R.C. dd Bebcra B, Tala Mc craw Hill.
12. Adv ced praciical physical ChmistA J,B.Yad!v. Kishna Pmk6hm media(P) Ltd,
13. Adveced pr&tical lnorsanic Chemistry-GuDdeep RE, kishna Pnlasha. nedia(P)
14. Advanced pmctical oreanic Chemhlry-O.P.Agm1, Krisbna Pmlashao neda(P) Ltd,
I I 0. Physical cbdistry . W.LM@rc
General Chemistry Exteriment Anil t Elias (Lhiveaity press).
Quetiiaiive Chemical Analysis S, Sahay (S. Chand & Co.).
Pracii.al chmislrA K.K Shm4 D. S Shanra (vikas Publication).
Voed tcxrbook ol Quantiotive holgeic An.lysis-4lh €dition, Bcssct Dcmey.
Quliotive lnorganic analysis by A.LVogel
Qubtitltilc ADalysis, R.A. Day and A.L. UndeMood, 6ih edition, 1993 prc.rice Hall,
15.
16.
17.
r8.
19.
20.
2 ] Vo8el's Tdtbook of Qudlitative Chemical Anallsis, J. Mtrdnan, R,C. Demey, J.D.
2 Bmcs md M.J.K. Ttona, 6$ edition, ftftj Indim Reprint.2003 Peason lducation