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CARBONATING MAGNESIA
FOR SOIL STABILIZATION
1
2
RELEVANCE OF STABILISATION
 To improve the engineering properties of soil
 Bearing capacity of soil may be inadequate
 Decrease permeability, compressibility
 To obtain adequate strength
 To control swelling and shrinkage
CHEMICAL STABILIZATION?
 The chemicals undergo various reactions
 Increases the binding property between the soil
particles
 changes surface molecular properties
3
STABILIZING CHEMICALS
•Lime
• Calcium and sodium chloride
•Lignin
•Water proofers like siliconates ,
amines
•Natural and synthetic polymers
•Dispersants and aggregants
 An alternative solution for Stabilization by ordinary
Portland cement
Reasons
 Less energy consumption
 CO2 sequestration
 Higher compressive strength
4
BASIC REACTIONS
MgO+H2O→Mg(OH) 2 (brucite)
Mg(OH) 2 +CO 2 +2H2O→ MgCO3.3H2O (Nesquehonite)
5 Mg(OH) 2 +4 CO 2 +H2O →(Mg) 5(CO3 ) 4(OH) 2 .5H2O
(dypingite)
5 Mg(OH) 2 +4 CO 2 →(Mg) 5(CO3 ) 4(OH) 2 .4H2O
(hydromagnesite)
•Expansive reactions (3.8 - 6.7)
5
6
SCANNING
ELECTRON
MICROSCOPE
STUDIES
Courtesy:Yaolin Yi,
Martin Liska
7
 Slightly clayey
silty sand (90%
sharp sand , 5%
kaolin clay, 5%
silica flour )
 organic clayey
silt (82% silica
flour ,15% kaolin
clay , 3% peat )
 Confining pressure 400 KPa
 CO 2 Pressures 200 Kpa,100 KPa, 50 KPa
 carbonation period 0.5-7 hours
LABORATORY SET -UP
Water content Vs Dry density
GRAPHS AND RESULTS
8
Optimum water
content for maximum
dry density is more
than that of OPC –
Rapid hydration
Contd…
Water content Vs UCS
9
optimum water
content for
maximum UCS
is lesser than
that of OPC –
enough
carbonation
Contd…
UCS Of MgO treated soil after a carbonation period of 3
Hours= UCS of PC stabilized soil at 28 days
10
Lower the MgO content and Higher the
carbonation period cracks will be more
o Lower MgO ,Higher water content
o MgO impurities like dead burnt MgO
COLUMN INSTALATION & CARBONATION
11
Column installation
 Laboratory scale auger set up
 MgO grout is pumped into grout inject
 Three switch travel stop mechanism
12
•Auger penetration and
withdrawal-5.2 mm/sec
at 50 rpm
• grout pumped at 7.2
g/sec
Column carbonation
Method 1
•Pumping gaseous CO 2 through the auger
• Auger is connected to CO 2 canister
•Method 2
• perforated plastic pipe system
• More homogeneous carbonation
• Pipe Diameter 20 mm
13
Real Life Applications
CARBONATION IS ACHIEVED THROUGH
 Deep mixing carbonation method
Injected reactive MgO powder is mixed with soil by
an auger followed by carbonation(Through perforated
pipe)
14
15
DEEP MIXING CARBONATION
 Auger with hollow drill
 Mixing tool at the bottom
 Grout is passed through the drill rod
16
CONCLUSION
 Adequately carbonated MgO treated soil in few hours reach 28 day
strength of PC stabilised soil
 Reactive MgO – A promising stabilisation binder through the
sequestration of CO 2
 Magnesium oxide has less environmental impact compared
with PC, in which the production process is conducted at a
temperature far less than that of PC.
 Compared to CaCO3 it is resistant to sulphate attack
 More stable than CaCO3
17
REFERENCES
1. "Physical properties, Electrical Resistivity and strength characteristics of
Carbonated silty soil admixed with reactive Magnesia" - Devendra Narain Singh,
Guang Hua Cai: Canadian geotechnical journal(April 2015)
2. "Carbonating magnesia for soil stabilization" - Yaolin Yi, Martin Liska, Cise
Uniuer: Canadian geotechnical journal (June 2013)
3. "Soil stabilization using Lime: Advantages, Disadvantages and proposing a
potential alternative" -Ibtehaj Taha Jawad, Mohd Raihan Taha, Zaid Hameed
Majeed , Tanveer A .Khan: Research journal of applied sciences, Engineering and
technology (May 10,2014)
4. "Strength and deformation characteristics of carbonated reactive magnesia
treated silt soil" -CAI Guang-hua , LIU Song-Yu, DU Yan-jun, ZHANG Ding-wen,
ZHENG Xu:Central south University press and Springer (2015)
5. "Preliminary Laboratory-scale model Auger installation and testing of
carbonated soil-MgO columns" - Yaolin Yi, Martin Liska, Cise Uniuer:
Geotechnical testing journal (March 2013)
18
THANK YOU

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CARBONATING MAGNESIA FOR SOIL STABILIZATION

  • 2. 2 RELEVANCE OF STABILISATION  To improve the engineering properties of soil  Bearing capacity of soil may be inadequate  Decrease permeability, compressibility  To obtain adequate strength  To control swelling and shrinkage
  • 3. CHEMICAL STABILIZATION?  The chemicals undergo various reactions  Increases the binding property between the soil particles  changes surface molecular properties 3 STABILIZING CHEMICALS •Lime • Calcium and sodium chloride •Lignin •Water proofers like siliconates , amines •Natural and synthetic polymers •Dispersants and aggregants
  • 4.  An alternative solution for Stabilization by ordinary Portland cement Reasons  Less energy consumption  CO2 sequestration  Higher compressive strength 4
  • 5. BASIC REACTIONS MgO+H2O→Mg(OH) 2 (brucite) Mg(OH) 2 +CO 2 +2H2O→ MgCO3.3H2O (Nesquehonite) 5 Mg(OH) 2 +4 CO 2 +H2O →(Mg) 5(CO3 ) 4(OH) 2 .5H2O (dypingite) 5 Mg(OH) 2 +4 CO 2 →(Mg) 5(CO3 ) 4(OH) 2 .4H2O (hydromagnesite) •Expansive reactions (3.8 - 6.7) 5
  • 7. 7  Slightly clayey silty sand (90% sharp sand , 5% kaolin clay, 5% silica flour )  organic clayey silt (82% silica flour ,15% kaolin clay , 3% peat )  Confining pressure 400 KPa  CO 2 Pressures 200 Kpa,100 KPa, 50 KPa  carbonation period 0.5-7 hours LABORATORY SET -UP
  • 8. Water content Vs Dry density GRAPHS AND RESULTS 8 Optimum water content for maximum dry density is more than that of OPC – Rapid hydration Contd…
  • 9. Water content Vs UCS 9 optimum water content for maximum UCS is lesser than that of OPC – enough carbonation Contd…
  • 10. UCS Of MgO treated soil after a carbonation period of 3 Hours= UCS of PC stabilized soil at 28 days 10 Lower the MgO content and Higher the carbonation period cracks will be more o Lower MgO ,Higher water content o MgO impurities like dead burnt MgO
  • 11. COLUMN INSTALATION & CARBONATION 11
  • 12. Column installation  Laboratory scale auger set up  MgO grout is pumped into grout inject  Three switch travel stop mechanism 12 •Auger penetration and withdrawal-5.2 mm/sec at 50 rpm • grout pumped at 7.2 g/sec
  • 13. Column carbonation Method 1 •Pumping gaseous CO 2 through the auger • Auger is connected to CO 2 canister •Method 2 • perforated plastic pipe system • More homogeneous carbonation • Pipe Diameter 20 mm 13
  • 14. Real Life Applications CARBONATION IS ACHIEVED THROUGH  Deep mixing carbonation method Injected reactive MgO powder is mixed with soil by an auger followed by carbonation(Through perforated pipe) 14
  • 15. 15 DEEP MIXING CARBONATION  Auger with hollow drill  Mixing tool at the bottom  Grout is passed through the drill rod
  • 16. 16 CONCLUSION  Adequately carbonated MgO treated soil in few hours reach 28 day strength of PC stabilised soil  Reactive MgO – A promising stabilisation binder through the sequestration of CO 2  Magnesium oxide has less environmental impact compared with PC, in which the production process is conducted at a temperature far less than that of PC.  Compared to CaCO3 it is resistant to sulphate attack  More stable than CaCO3
  • 17. 17 REFERENCES 1. "Physical properties, Electrical Resistivity and strength characteristics of Carbonated silty soil admixed with reactive Magnesia" - Devendra Narain Singh, Guang Hua Cai: Canadian geotechnical journal(April 2015) 2. "Carbonating magnesia for soil stabilization" - Yaolin Yi, Martin Liska, Cise Uniuer: Canadian geotechnical journal (June 2013) 3. "Soil stabilization using Lime: Advantages, Disadvantages and proposing a potential alternative" -Ibtehaj Taha Jawad, Mohd Raihan Taha, Zaid Hameed Majeed , Tanveer A .Khan: Research journal of applied sciences, Engineering and technology (May 10,2014) 4. "Strength and deformation characteristics of carbonated reactive magnesia treated silt soil" -CAI Guang-hua , LIU Song-Yu, DU Yan-jun, ZHANG Ding-wen, ZHENG Xu:Central south University press and Springer (2015) 5. "Preliminary Laboratory-scale model Auger installation and testing of carbonated soil-MgO columns" - Yaolin Yi, Martin Liska, Cise Uniuer: Geotechnical testing journal (March 2013)