Cd2SnO4 دراسة تأثير التلدين على الخواص التركيبية والبصرية لأغشية
by: Thikra Abbas Mujbil Al- Hilfi, ذكرى عباس مجبل الحلفي
Supervised By: prof. Sabria Alioui
22. 1-
(Interatomic Spacing (d)
(d)
2dsinθ = nλ
(d)(CdO)
(d)
(Cd2SnO4)
dÅ(Theory.)
dÅ
(Measured)
2θ(hkl)
Temperatu
re
T(°C)
Type of
thin film
2.717362.71735732.9353(111)300CdO
2.352462.352464538.2274(200)
1.662761.6627655.1961(220)
2.709562.70955933.0328(111)400
2.346472.34647438.3288(200)
1.659311.659312455.3206(220)
2.709722.70971933.0308(111)500
2.347492.34748838.3115(200)
1.661491.661487155.242(220)
2.726752.72672632.8186(111)300Cd:5%Sn
2.361182.36143538.0808(200)
1.669181.66912254.9659(220)
3.302393.30175726.9776(001)400
Cd2SnO4
2.867022.86702131.171(130)
2.088742.24460643.2817(131)
3.307283.30728626.937(001)500
2.868412.86845331.1555(130)
2.400792.40078837.429(121)
2.093492.09348543.1786(131)
23. 2-(Lattice Constant (a))
(a)(ASTM)
1/d2 = (h2+k2+l2)/a2
(CdO)(4.7066Å)(Cd2SnO4)
(9.0663Å)
aÅ (Measured)(hkl)
Temperature
T(°C)
Type of thin
film
4.706601(111)300CdO
4.693094(111)400
4.693371(111)500
4.722827(111)300Cd:5%Sn
9.066316(130)400Cd2SnO4
9.070844(130)500
24. 3-(Grain Size (G.s))
(G.s)
(CdO)
(Cd2SnO4)
G.s Å
β(FWHM)
(deg.)
2θ(hkl)
Temperature
T(°C)
Type of thin
film
201.6460.456732.9353(111)300CdO
225.00120.464633.0328(111)400
228.80030.402633.0308(111)500
149.50380.615832.8186(111)300Cd:5%Sn
268.32260.341731.171(130)400Cd2SnO4
224.10760.409131.1555(130)500
cos
kG.s
27. 2-(Dislocation Density ( ))
δ = 1/ (G.s) 2
(CdO)
( )
(Cd2SnO4)
×10-5
Line/Å2
Temperature
T(°C)
Type of thin
film
2.4564300CdO
1.9751400
1.91024500
4.474300Cd:5%Sn
1.38895400Cd2SnO4
1.99107500
28. 3-(Number of Crystals (M)
M=t/ (G.s) 3
(CdO)
(Cd2SnO4)
4-Number of Layers (NL)
NL=t/G.s
(CdO)(Cd2SnO4)
NLM/Å2
Temperature
T(°C)
Type of
thin film
9.91840.00024300CdO
8.8890.0001756400
8.741250.00017500
13.377590.000599300Cd:5%Sn
7.4537130.000104400Cd2SnO4
8.9242840.000178500
29. 5-Integral Breadth (∆))
(XRD)
∆=Area/Imax
(∆)(β)
(Δ)
β
Shape
Factor (Φ)
Integral
Breadth
(∆)(deg.)
β(FWHM)
(deg.)
Temperature
T(°C)
Type of thin
film
0.91340.50.4567300CdO
0.84470.550.4646400
1.17980.4750.4026500
0.87970.70.6158300Cd:5%Sn
0.91120.3750.3417400Cd2SnO4
0.90910.450.4091500
6-Shape Factor (Φ))
Φ= β/∆