GHS HazCom for South Davis Metro Fire
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OSHA labels and SDS explanation for firefighters.
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GHS HazCom for South Davis Metro Fire
- 1. HAZARD COMMUNICATION The Globally Harmonized System of Classification and Labeling of Chemicals Ryan Putman, B.S. Environmental Management Hazardous Materials Training Coordinator, South Davis Metro Fire Agency
- 2. BACKGROUND • The Globally Harmonized System of Classification and Labeling of Chemicals (GHS) was conceived during the 1992 United Nations Conference on Environment and Development (commonly referred to as the Rio Conference). • It was recognized that there were many differing standards between separate nations and regions of how chemicals were classified, labeled, and how information was made available regarding their characteristics to workers, consumers, and emergency responders. • In 2012 OSHA adopted the newest revision of the GHS as part of the Hazard Communication regulation (29 CFR 1910.1200), to take effect June 1, 2015.
- 3. GHS HAZCOM IN TWO PARTS Labels Safety Data Sheets
- 4. REQUIRED PARTS OF A GHS COMPLIANT LABEL Chemical Identifier • Proper chemical or trade name • Including individual ingredients for solutions, mixtures, or alloys • Other identification method • CAS# • UN/NA #
- 5. REQUIRED PARTS OF A GHS COMPLIANT LABEL Pictograms
- 6. Oxidizers
- 9. •Acutely Toxic (Severe) •LD50 <300 mg/kg
- 10. •Corrosive
- 13. •Irritant •Dermal Sensitizer •Acute Toxicity (Harmful) •LD50 >300 mg/kg •Narcotic Effects •Respiratory Tract
- 14. •Environmental Toxicity Not required by OSHA, but supplier may include to meet requirements in other nations.
- 15. REQUIRED PARTS OF A GHS COMPLIANT LABEL Signal Words •Danger •Warning
- 16. REQUIRED PARTS OF A GHS COMPLIANT LABEL Hazard Statements •Physical •Health •Environment
- 17. REQUIRED PARTS OF A GHS COMPLIANT LABEL Precautionary Statements •General •Prevention •Response •Storage •Disposal
- 18. REQUIRED PARTS OF A GHS COMPLIANT LABEL First Aid Statements
- 19. REQUIRED PARTS OF A GHS COMPLIANT LABEL Supplier or Manufacturer Information
- 20. REQUIRED PARTS OF A GHS COMPLIANT LABEL Supplemental Information •Is not a required part of the GHS label. •Is allowed if is necessary to provide important information not covered in a required part. •Recommended PPE •May be Pictogram •Exposure Limits •Cannot contradict or cast doubt to the validity of a required part.
- 21. GHS SAFETY DATA SHEET (SDS) Old MSDS New SDS
- 22. SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
- 23. SECTION 2 HAZARDS IDENTIFICATION
- 24. SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS
- 25. SECTION 4 FIRST-AID MEASURES
- 26. SECTION 5 FIREFIGHTING MEASURES
- 27. SECTION 6 ACCIDENTAL RELEASE MEASURES
- 28. SECTION 7 HANDLING AND STORAGE
- 29. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
- 30. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
- 31. SECTION 10 STABILITY AND REACTIVITY
- 32. SECTION 11 TOXICOLOGICAL INFORMATION
- 33. SECTION 12 ECOLOGICAL INFORMATION
- 34. SECTION 13 DISPOSAL CONSIDERATIONS
- 35. SECTION 14 TRANSPORT INFORMATION
- 36. SECTION 15 REGULATORY INFORMATION
- 37. SECTION 16 OTHER INFORMATION
Hinweis der Redaktion
- Toxic
- Should not appear with Skull and Crossbones, Toxic, or Corrosive Pictogram
- OSHA does not have any regulatory authority over the Environment. EPA has the authority in this area, and has so far not fully adopted GHS in its regulatory requirements.
- These are the only signal words allowed. Warning should not appear if Danger does.
- These PPE Pictograms are European Union approved. OSHA has not officially recognized PPE Pictograms, but they are allowed.
- GHS product identifier. Other means of identification. Recommended use of the chemical and restrictions on use. Supplier's details (including name, address, phone number etc). Emergency phone number.
- GHS classification of the substance/mixture and any regional information. GHS label elements, including precautionary statements. (Hazard symbols may be provided as a graphical reproduction of the symbols in black and white or the name of the symbol, e.g., flame, skull and crossbones.) Other hazards which do not result in classification (e.g., dust explosion hazard) or are not covered by the GHS.
- Substance Chemical identity Common name, synonyms, etc. CAS number, EC number, etc. Impurities and stabilizing additives which are themselves classified and which contribute to the classification of the substance. Mixture The chemical identity and concentration or concentration ranges of all ingredients which are hazardous within the meaning of the GHS and are present above their cut-off levels. Cut-off level for reproductive toxicity, carcinogenicity and category 1 mutagenicity is 0.1% Cut-off level for all other hazard classes is 1%
- Description of necessary measures, subdivided according to the different routes of exposure, i.e., inhalation, skin and eye contact and ingestion. Most important symptoms/effects, acute and delayed. Indication of immediate medical attention and special treatment needed, if necessary.
- Suitable (and unsuitable) extinguishing media. Specific hazards arising from the chemical (e.g., nature of any hazardous combustion products). Special protective equipment and precautions for fire-fighters.
- Personal precautions, protective equipment and emergency procedures. Environmental precautions. Methods and materials for containment and cleaning up.
- Precautions for safe handling. Conditions for safe storage, including any incompatibilities.
- Control parameters (e.g., occupational exposure limit values or biological limit values). Appropriate engineering controls. Individual protection measures, such as personal protective equipment.
- Appearance (physical state, color, etc.) Odor Odor threshold pH melting point/freezing point initial boiling point and boiling range flash point: evaporation rate flammability (solid, gas) upper/lower flammability or explosive limits vapor pressure vapor density relative density: solubility(ies) partition coefficient: n-octanol/water auto-ignition temperature decomposition temperature
- Chemical stability. Possibility of hazardous reactions. Conditions to avoid (e.g., static discharge, shock or vibration). Incompatible materials, Hazardous decomposition products.
- Concise but complete and comprehensible description of the various toxicological (health) effects and the available data used to identify those effects, including: Information on the likely routes of exposure (inhalation, ingestion, skin and eye contact); Symptoms related to the physical, chemical and toxicological characteristics; Delayed and immediate effects and also chronic effects from short- and long-term exposure;. Numerical measures of toxicity (such as acute toxicity estimates).
- Ecotoxicity (aquatic and terrestrial, where available). Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects
- Description of waste residues and information on their safe handling and methods of disposal, including any contaminated packaging.
- UN number. UN Proper shipping name. Transport Hazard class(es). Packing group, if applicable. Marine pollutant (Y/N). Special precautions which a user needs to be aware of or needs to comply with in connection with transport or conveyance either within or outside their premises.
- Safety, health and environmental regulations specific for the product in question.
- Other information including information on preparation and revision of the SDS.