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Appendices
Appendix A

Summary of Site Soil and Sediment
Data Used in the Risk Assessment
APPENDIX A
                                                                                                               SUMMARY OF SITE SOIL DATA USED IN RISK ASSESSMENT
                                                                                                                    KOPPERS INC. WOOD-TREATING FACILITY
                                                                                                                             GAINESVILLE, FLORIDA

             Sample ID                                B1              B3              B-4             B5           DT           GA-Soil-001   GA-Soil-004   GA-Soil-005   GA-Soil-011   GA-Soil-033   GA-Soil-034       GA-Soil-035       GA-Soil-036       GA-Soil-037       GA-Soil-038
             Sample Date                           15-Aug-95       16-Aug-95       17-Aug-95       17-Aug-95    24-Aug-95        11-Aug-98     13-Aug-98     13-Aug-98     13-Aug-98     13-Aug-98    11-Aug-98          11-Aug-98         11-Aug-98         11-Aug-98        11-Aug-98
             Sample Depth (feet)                    2.5-2.5           2-2             3-3             5-5         0-0.5            0-0.7          0-1           0-1           0-1           0-1         0.5-0.5           0.5-0.5           0.5-0.5           0.5-0.5           0.5-0.5
             Concentration Units                     mg/kg           mg/kg           mg/kg           mg/kg        mg/kg            mg/kg         mg/kg         mg/kg         mg/kg         mg/kg        mg/kg              mg/kg             mg/kg             mg/kg            mg/kg
71-55-6      1,1,1-Trichloroethane
79-34-5      1,1,2,2-Tetrachloroethane
79-00-5      1,1,2-Trichloroethane
75-34-3      1,1-Dichloroethane
75-35-4      1,1-Dichloroethylene
120-82-1     1,2,4-Trichlorobenzene
96-12-8      1,2-Dibromo-3-chloropropane
106-93-4     1,2-Dibromoethane
95-50-1      1,2-Dichlorobenzene
107-06-2     1,2-Dichloroethane
78-87-5      1,2-Dichloropropane
106-46-7     1,4-Dichlorobenzene
95-95-4      2,4,5-Trichlorophenol
88-06-2      2,4,6-Trichlorophenol
120-83-2     2,4-Dichlorophenol
105-67-9     2,4-Dimethylphenol
51-28-5      2,4-Dinitrophenol
121-14-2     2,4-Dinitrotoluene
606-20-2     2,6-Dinitrotoluene
91-58-7      2-Chloronaphthalene
95-57-8      2-Chlorophenol
91-57-6      2-Methylnaphthalene                      2.3            0.75      U     400                           58       J
95-48-7      2-Methylphenol (o-cresol)
88-74-4      2-Nitroaniline
88-75-5      2-Nitrophenol
91-94-1      3,3'-Dichlorobenzidine
78-59-1      3,5,5-Trimethyl-2-cyclohexene-1-one
99-09-2      3-Nitroaniline
534-52-1     4,6-Dinitro-2-Methylphenol
101-55-3     4-Bromophenyl phenyl ether
59-50-7      4-Chloro-3-methylphenol
7005-72-3    4-Chlorophenyl phenyl ether
106-44-5     4-Methylphenol (m/p-cresol)
100-02-7     4-Nitrophenol
83-32-9      Acenaphthene                            0.95      U      0.2      J      450                         130                                                                                     2         U       20        U       0.2       U       20        U       0.2       U
208-96-8     Acenaphthylene                          0.95      U      0.3      J     0.022     J                  38.5      U                                                                             1         U       10        U       0.1       U       10        U       0.1       U
67-64-1      Acetone
120-12-7     Anthracene                               3.9            0.54      J     440                          180                                                                                    0.04       U      0.81             0.004       U       0.4       U     0.004       U
7440-36-0    Antimony
7440-38-2    Arsenic                                  7.2             8.1             11              3.1                                                                                                 10        U      30.3               10        U       10        U       10        U
7440-39-3    Barium
71-43-2      Benzene
56-55-3      Benzo(a)anthracene                      0.95      U     1.7             220                          180                                                                                    0.08       U        3              0.033               2.9             0.008       U
50-32-8      Benzo(a)pyrene                          2.8             1.6             120                           77                                                                                    0.05       U       4.4             0.068               7.3             0.021
205-99-2     Benzo(b)fluoranthene                    7.3             2.1             220                          160                                                                                    0.18               6.6             0.088               9.2              0.04
191-24-2     Benzo(g,h,i)perylene                    2.1             0.82             37                           43       J                                                                            0.08       U       4.4             0.068               6.1              0.02
207-08-9     Benzo(k)fluoranthene                    2.4             0.82             48                           55       J                                                                            0.1                4.1             0.049               5.7              0.02
85-68-7      Benzyl butyl phthalate
92-52-4      Biphenyl
111-91-1     Bis(2-chlorethoxy)methane
111-44-4     Bis(2-chloroethyl)ether
39638-32-9   Bis(2-chloroisopropyl) ether
117-81-7     Bis(2-ethylhexyl)phthalate
75-27-4      Bromodichloromethane
74-83-9      Bromomethane
7440-43-9    Cadmium
86-74-8      Carbazole
75-15-0      Carbon disulfide
56-23-5      Carbon tetrachloride
108-90-7     Chlorobenzene
124-48-1     Chlorodibromomethane
75-00-3      Chloroethane
67-66-3      Chloroform
74-87-3      Chloromethane
7440-47-3    Chromium                                100              12              33              8.4                                                                                                1.2               22.7             11.6               13.7                7
218-01-9     Chrysene                                0.95      U      2.2            210                          190                                                                                    0.33               3.6             0.037               3                0.01       U
156-59-2     cis-1,2-Dichloroethylene
10061-01-5   cis-1,3-Dichloropropene
APPENDIX A
                                                                                                                   SUMMARY OF SITE SOIL DATA USED IN RISK ASSESSMENT
                                                                                                                        KOPPERS INC. WOOD-TREATING FACILITY
                                                                                                                                 GAINESVILLE, FLORIDA

            Sample ID                                     B1               B3           B-4              B5            DT           GA-Soil-001   GA-Soil-004   GA-Soil-005   GA-Soil-011   GA-Soil-033   GA-Soil-034       GA-Soil-035       GA-Soil-036       GA-Soil-037       GA-Soil-038
            Sample Date                                15-Aug-95       16-Aug-95     17-Aug-95       17-Aug-95      24-Aug-95        11-Aug-98     13-Aug-98     13-Aug-98     13-Aug-98     13-Aug-98    11-Aug-98          11-Aug-98         11-Aug-98         11-Aug-98        11-Aug-98
            Sample Depth (feet)                         2.5-2.5           2-2           3-3             5-5           0-0.5            0-0.7          0-1           0-1           0-1           0-1         0.5-0.5           0.5-0.5           0.5-0.5           0.5-0.5           0.5-0.5
            Concentration Units                          mg/kg           mg/kg         mg/kg           mg/kg          mg/kg            mg/kg         mg/kg         mg/kg         mg/kg         mg/kg        mg/kg              mg/kg             mg/kg             mg/kg            mg/kg
7440-50-8   Copper                                        4.5             1.25   U       47             1.25   U
110-82-7    Cyclohexane
53-70-3     Dibenzo(a,h)anthracene                       0.95      U     0.32   J      0.025     U                     18       J                                                                             0.2       U       2         U      0.02       U       2         U      0.02       U
132-64-9    Dibenzofuran
75-09-2     Dichloromethane
84-66-2     Diethyl phthalate
131-11-3    Dimethyl phthalate
84-74-2     di-n-Butyl-phthalate
117-84-0    di-n-Octyl-phthalate
100-41-4    Ethylbenzene
206-44-0    Fluoranthene                                 0.95      U     0.54          990                            780                                                                                     1.8               7.6             0.053               8               0.046
86-73-7     Fluorene                                     0.95      U     0.2    J      480                            170                                                                                     0.2       U        2        U     0.02        U       2         U      0.02       U
87-68-3     Hexachloro-1,3-butadiene
118-74-1    Hexachlorobenzene
77-47-4     Hexachlorocyclopentadiene
67-72-1     Hexachloroethane
193-39-5    Indeno(1,2,3-cd)pyrene                        2.4            0.77           41                             42       J                                                                             0.1       U       5.5             0.073               7.1             0.023
98-82-8     Isopropylbenzene
7439-92-1   Lead
136777-61-2 m,p-Xylenes
541-73-1    m-Dichlorobenzene
7439-97-6   Mercury
79-20-9     Methyl acetate
78-93-3     Methyl ethyl ketone
108-10-1    Methyl isobutyl ketone
591-78-6    Methyl n-butyl ketone
108-88-3    Methylbenzene
108-87-2    Methylcylohexane
91-20-3     Naphthalene                                  0.95      U     0.19   J      530                             62       J                                                                             1         U       10        U       0.1       U       10        U       0.1       U
98-95-3     Nitrobenzene
621-64-7    n-Nitroso-di-n-Propylamine
86-30-6     n-Nitrosodiphenylamine
95-47-6     o-Xylene
106-47-8    p-Chloroaniline
87-86-5     Pentachlorophenol                            0.95      U     0.11   J       32                             50       J                                                                           0.003             0.094             0.028               0.7             0.006
85-01-8     Phenanthrene                                 0.95      U     0.19          2000                           620                                                                                    1.1               2.9              0.018               1.8              0.02
108-95-2    Phenol
100-01-6    p-Nitroaniline
129-00-0    Pyrene                                       0.95      U     0.56          740                            490                                                                                     1.1               7.3             0.051               8.7             0.042
7782-49-2   Selenium
7440-22-4   Silver
100-42-5    Styrene (monomer)
1634-04-4   tert-Butyl methyl ether
127-18-4    Tetrachloroethylene
156-60-5    trans-1,2-Dichloroethene
10061-02-6 trans-1,2-Dichloropropene
75-25-2     Tribromomethane
79-01-6     Trichloroethylene
7440-62-2   Vanadium
75-01-4     Vinyl chloride
67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran        0.0831                                                        0.0324
35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin                                                                   0.272
55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran        0.0153                                                       0.00158
70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran                                                                       0.000267    U
39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin                                                                   0.000772
57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran                                                                       0.000158    U
57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin                                                                    0.00511
72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran                                                                       0.000185    U
19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin                                                                    0.00218
57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran                                                                        0.0002125   U
40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin                                                                    0.0002285   U
60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran
57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran
51207-31-9 2,3,7,8-Tetrachlorodibenzofuran                                                                         0.00002725   U
1746-01-6   2,3,7,8-Tetrachlorodibenzo-p-dioxin                                                                     0.0000218   U
39001-02-0 Octachlorodibenzofuran                      0.000771                                                       0.264
3268-87-9   Octachlorodibenzo-p-dioxin                   0.418                                                         2.92
APPENDIX A
                                                                                                    SUMMARY OF SITE SOIL DATA USED IN RISK ASSESSMENT
                                                                                                         KOPPERS INC. WOOD-TREATING FACILITY
                                                                                                                  GAINESVILLE, FLORIDA

             Sample ID                                NL              PA              PL              SL           SS001AA          SS001BA          SS001CA          SS001DA          SS002AA          SS002AC          SS002BA          SS003AA
             Sample Date                           24-Aug-95       24-Aug-95       24-Aug-95       24-Aug-95       07-Dec-06        07-Dec-06        07-Dec-06        07-Dec-06        05-Dec-06        05-Dec-06        05-Dec-06        08-Dec-06
             Sample Depth (feet)                     0-0.5           0-0.5           0-0.5           0-0.5           0-0.25          0.25-0.5           0.5-2             2-6            0-0.25           0-0.25          0.25-0.5          0-0.25
             Concentration Units                     mg/kg           mg/kg           mg/kg           mg/kg           mg/kg            mg/kg            mg/kg            mg/kg            mg/kg            mg/kg            mg/kg            mg/kg
71-55-6      1,1,1-Trichloroethane                                                                                  0.00007    U     0.00007    U    0.000075    U    0.000065    U    0.000075    U    0.000075    U     0.00007    U    0.000075    U
79-34-5      1,1,2,2-Tetrachloroethane                                                                             0.000036    U    0.0000385   U    0.000041    U    0.0000355   U     0.00004    U    0.0000395   U    0.0000385   U    0.0000395   U
79-00-5      1,1,2-Trichloroethane                                                                                 0.000075    U     0.00008    U    0.000085    U     0.00007    U     0.00008    U     0.00008    U     0.00008    U     0.00008    U
75-34-3      1,1-Dichloroethane                                                                                    0.0000345   U    0.0000365   U    0.000039    U    0.0000335   U    0.0000385   U    0.0000375   U    0.0000365   U    0.000038    U
75-35-4      1,1-Dichloroethylene                                                                                  0.000095    U      0.0001    U     0.00011    U    0.000095    U    0.000105    U    0.000105    U      0.0001    U    0.000105    U
120-82-1     1,2,4-Trichlorobenzene                                                                                0.000085    U     0.00009    U    0.000095    U     0.00008    U    0.000095    UJ    0.00009    UJ    0.00009    U     0.00009    U
96-12-8      1,2-Dibromo-3-chloropropane                                                                            0.00027    U    0.000285    U    0.000305    U    0.000265    U      0.0003    UJ   0.000295    UJ   0.000285    U    0.000295    U
106-93-4     1,2-Dibromoethane                                                                                     0.0000305   U    0.0000325   U    0.000035    U     0.00003    U    0.000034    U    0.0000335   U    0.0000325   U    0.0000335   U
95-50-1      1,2-Dichlorobenzene                                                                                   0.0000425   U    0.0000455   U    0.0000485   U    0.0000415   U    0.0000475   UJ   0.0000465   UJ   0.0000455   U    0.000047    U
107-06-2     1,2-Dichloroethane                                                                                    0.000055    U     0.00006    U    0.000065    U    0.000055    U    0.000065    U     0.00006    U     0.00006    U     0.00006    U
78-87-5      1,2-Dichloropropane                                                                                   0.0000295   U    0.0000315   U    0.0000335   U    0.000029    U    0.000033    U    0.0000325   U    0.0000315   U    0.0000325   U
106-46-7     1,4-Dichlorobenzene                                                                                   0.0000475   U    0.000055    U    0.000055    U    0.0000465   U    0.000055    UJ   0.000055    UJ   0.000055    U    0.000055    U
95-95-4      2,4,5-Trichlorophenol                                                                                   0.0075    U       0.007    U      0.0085    U       0.007    U      0.0075    U      0.0075    U      0.0075    U       0.008    U
88-06-2      2,4,6-Trichlorophenol                                                                                    0.02     U      0.0195    U      0.0225    U      0.0195    U       0.02     U       0.02     U       0.02     U      0.0215    U
120-83-2     2,4-Dichlorophenol                                                                                      0.0095    U      0.0095    U      0.0105    U      0.0095    U      0.0095    U      0.0095    U      0.0095    U      0.0105    U
105-67-9     2,4-Dimethylphenol                                                                                      0.0105    U      0.0105    U       0.012    U      0.0105    U      0.0105    U       0.011    U      0.0105    U      0.0115    U
51-28-5      2,4-Dinitrophenol                                                                                        0.007    U      0.0065    U      0.0075    U      0.0065    U       0.007    U       0.007    U       0.007    U      0.0075    U
121-14-2     2,4-Dinitrotoluene                                                                                      0.0055    U      0.0055    U      0.0065    U      0.0055    U      0.0055    U      0.0055    U      0.0055    U       0.006    U
606-20-2     2,6-Dinitrotoluene                                                                                       0.02     U      0.0195    U      0.0225    U      0.0195    U       0.02     U       0.02     U       0.02     U      0.0215    U
91-58-7      2-Chloronaphthalene                                                                                      0.009    U       0.009    U       0.01     U       0.009    U       0.009    U       0.009    U       0.009    U       0.01     U
95-57-8      2-Chlorophenol                                                                                           0.01     U       0.01     U      0.0115    U       0.01     U       0.01     U       0.01     U       0.01     U       0.011    U
91-57-6      2-Methylnaphthalene                      68       J     120       J     10.5      U      9        U     0.0085    U      0.0085    U     0.00095    U      0.0008    U       0.042    J       0.044    J       0.052    J       0.009    U
95-48-7      2-Methylphenol (o-cresol)                                                                                0.007    U      0.0065    U      0.0075    U      0.0065    U       0.007    U       0.007    U       0.007    U      0.0075    U
88-74-4      2-Nitroaniline                                                                                           0.012    UJ      0.012    UJ      0.014    U       0.012    U      0.0125    UJ     0.0125    UJ      0.012    U      0.0135    U
88-75-5      2-Nitrophenol                                                                                            0.008    U       0.008    U       0.009    U      0.0075    U       0.008    U       0.008    U       0.008    U      0.0085    U
91-94-1      3,3'-Dichlorobenzidine                                                                                  0.0185    U      0.0185    U       0.021    U      0.0185    U       0.019    UJ      0.019    UJ      0.019    U      0.0205    U
78-59-1      3,5,5-Trimethyl-2-cyclohexene-1-one                                                                     0.0075    U       0.007    U      0.0085    U       0.007    U      0.0075    UJ     0.0075    UJ     0.0075    U       0.008    U
99-09-2      3-Nitroaniline                                                                                          0.0095    U      0.0095    U      0.0105    U      0.0095    U      0.0095    U      0.0095    U      0.0095    U      0.0105    U
534-52-1     4,6-Dinitro-2-Methylphenol                                                                              0.0055    U      0.0055    U       0.006    U       0.005    U      0.0055    U      0.0055    U      0.0055    U       0.006    U
101-55-3     4-Bromophenyl phenyl ether                                                                              0.0055    U      0.0055    U      0.0065    U      0.0055    U      0.0055    U      0.0055    U      0.0055    U       0.006    U
59-50-7      4-Chloro-3-methylphenol                                                                                  0.009    U       0.009    U       0.01     U       0.009    U       0.009    U       0.009    U       0.009    U       0.01     U
7005-72-3    4-Chlorophenyl phenyl ether                                                                              0.012    U       0.012    U       0.014    U       0.012    U      0.0125    U      0.0125    U       0.012    U      0.0135    U
106-44-5     4-Methylphenol (m/p-cresol)                                                                             0.0145    U       0.014    U      0.0165    U       0.014    U      0.0145    U      0.0145    U      0.0145    U      0.0155    U
100-02-7     4-Nitrophenol                                                                                           0.0095    UJ     0.0095    UJ     0.0105    U      0.0095    U      0.0095    UJ     0.0095    UJ     0.0095    UJ     0.0105    U
83-32-9      Acenaphthene                            430              30       J     2.05      U     1.15             0.015    U       0.015    U      0.0017    U     0.00145    U       0.03     U       0.03     U      0.0295    U      0.0165    U
208-96-8     Acenaphthylene                          7.6       J      39       U     0.32      J     0.51      J      0.094           0.0145    U     0.00165    U      0.0014    U       0.35             0.37             0.48             0.36
67-64-1      Acetone                                                                                                 0.0014    U     0.00145    U     0.00155    U     0.00135    U     0.00155    U      0.0015    U       0.04     J      0.0015    U
120-12-7     Anthracene                              390              64       J     0.91      J      3.1      J      0.13             0.015    J      0.0011    J    0.000325    U       0.78             0.86              1.1              0.3
7440-36-0    Antimony                                                                                                 0.46     J       0.37     J       0.195    U       0.18     U       0.185    UJ      0.39     J       0.37     J       0.195    UJ
7440-38-2    Arsenic                                                                                                    20               99              100              8.6              4.1     J        5.9     J        6.9               6      J
7440-39-3    Barium                                                                                                     13              5.6              5.7               12               11     J         15     J         16               42
71-43-2      Benzene                                                                                               0.000215    U     0.00023    U    0.000245    U     0.00021    U     0.00024    U    0.000235    U     0.00023    U    0.000235    U
56-55-3      Benzo(a)anthracene                      120              98              3.1      J      11              0.89             0.032    J      0.0031    J     0.00085    J       0.68             0.71             0.92             0.18
50-32-8      Benzo(a)pyrene                           33       J      28       J      4.2             7.1             0.77             0.041           0.0033    J      0.0006    U         1               1.1              1.4             0.31
205-99-2     Benzo(b)fluoranthene                     74              90              10              16                1              0.059           0.0055           0.0018    J        1.8              1.9              2.5             0.47
191-24-2     Benzo(g,h,i)perylene                     36       U      16              3.7      J      5.7             0.43             0.033    J       0.003    J     0.00099    J       0.73             0.77             0.95              0.6
207-08-9     Benzo(k)fluoranthene                     24       J      30       J      2.6      J      4.1             0.92             0.052           0.0047           0.0014    J        1.3              1.4              1.7             0.36
85-68-7      Benzyl butyl phthalate                                                                                   0.01     U       0.01     U      0.0115    U       0.01     U       0.01     U       0.01     U       0.01     U       0.011    U
92-52-4      Biphenyl                                                                                                 0.085    U       0.085    U       0.095    U       0.08     U       0.085    U       0.085    U       0.085    U       0.09     U
111-91-1     Bis(2-chlorethoxy)methane                                                                               0.0095    U      0.0095    U      0.0105    U      0.0095    U      0.0095    U      0.0095    U      0.0095    U      0.0105    U
111-44-4     Bis(2-chloroethyl)ether                                                                                 0.0085    U      0.0085    U      0.0095    U       0.008    U      0.0085    U      0.0085    U      0.0085    U       0.009    U
39638-32-9   Bis(2-chloroisopropyl) ether                                                                            0.0115    UJ     0.0115    UJ      0.013    UJ     0.0115    UJ      0.012    UJ      0.012    UJ     0.0115    UJ     0.0125    U
117-81-7     Bis(2-ethylhexyl)phthalate                                                                               0.009    U       0.009    U       0.01     U       0.009    U       0.009    U       0.02     J       0.029    J       0.01     U
75-27-4      Bromodichloromethane                                                                                   0.00016    U     0.00017    U     0.00018    U    0.000155    U     0.00018    U    0.000175    U     0.00017    U    0.000175    U
74-83-9      Bromomethane                                                                                          0.000175    U    0.000185    U      0.0002    U     0.00017    U    0.000195    UJ    0.00019    UJ    0.00019    UJ   0.000195    UJ
7440-43-9    Cadmium                                                                                                  0.145    U       0.15     U       0.17     U       0.155    U       0.16     U       0.16     U       0.15     U       0.17     U
86-74-8      Carbazole                                                                                                0.032    J       0.009    U       0.01     U       0.009    U       0.075    J       0.08     J       0.13     J       0.03     J
75-15-0      Carbon disulfide                                                                                       0.0009 U        0.00095 U         0.001 U         0.00085 U           0.001    U     0.00095    U    0.00095 U         0.001 U
56-23-5      Carbon tetrachloride                                                                                   0.00019    U    0.000205    U     0.00022    U     0.00019    U    0.000215    U     0.00021    U    0.000205    U     0.00021    U
108-90-7     Chlorobenzene                                                                                          0.00022    U    0.000235    U     0.00025    U    0.000215    U    0.000245    U     0.00024    U    0.000235    U     0.00024    U
124-48-1     Chlorodibromomethane                                                                                   0.00014    U    0.000145    U    0.000155    U    0.000135    U    0.000155    U     0.00015    U    0.000145    U     0.00015    U
75-00-3      Chloroethane                                                                                            0.0002    U     0.00021    U    0.000225    U    0.000195    U     0.00022    U    0.000215    U     0.00021    U     0.00022    U
67-66-3      Chloroform                                                                                            0.000185    U      0.0002    U    0.000215    U    0.000185    U     0.00021    U    0.000205    U      0.0002    U    0.000205    U
74-87-3      Chloromethane                                                                                         0.000245    U     0.00026    U     0.00028    U     0.00024    U    0.000275    U     0.00027    U    0.000265    U     0.00027    U
7440-47-3    Chromium                                                                                                  6.4              2.8              2.5              7.3              4.5     J        6.7     J        6.4               13     J
218-01-9     Chrysene                                120             120              5.4             13               1.2             0.046           0.0045           0.0015    J         1               1.1              1.3             0.24
156-59-2     cis-1,2-Dichloroethylene                                                                              0.000145    U    0.000155    U    0.000165    U     0.00014    U     0.00016    U    0.000155    U    0.000155    U     0.00016    U
10061-01-5   cis-1,3-Dichloropropene                                                                                0.00016    U     0.00017    U     0.00018    U    0.000155    U     0.00018    U    0.000175    U     0.00017    U    0.000175    U
APPENDIX A
                                                                                                          SUMMARY OF SITE SOIL DATA USED IN RISK ASSESSMENT
                                                                                                               KOPPERS INC. WOOD-TREATING FACILITY
                                                                                                                        GAINESVILLE, FLORIDA

            Sample ID                                     NL              PA               PL               SL             SS001AA            SS001BA            SS001CA            SS001DA           SS002AA           SS002AC            SS002BA            SS003AA
            Sample Date                                24-Aug-95       24-Aug-95        24-Aug-95        24-Aug-95        07-Dec-06          07-Dec-06          07-Dec-06          07-Dec-06         05-Dec-06          05-Dec-06         05-Dec-06          08-Dec-06
            Sample Depth (feet)                          0-0.5           0-0.5            0-0.5            0-0.5             0-0.25            0.25-0.5            0.5-2               2-6              0-0.25            0-0.25            0.25-0.5            0-0.25
            Concentration Units                          mg/kg           mg/kg            mg/kg            mg/kg             mg/kg              mg/kg              mg/kg              mg/kg             mg/kg             mg/kg              mg/kg              mg/kg
7440-50-8   Copper                                                                                                             6.8                1.6              0.175     U         0.38     J         5.1     J         7.3     J          7.6                9.1     J
110-82-7    Cyclohexane                                                                                                     0.00021    U       0.00022    U      0.000235    U      0.000205    U      0.00023    U      0.00023    U       0.00022    U       0.00023    U
53-70-3     Dibenzo(a,h)anthracene                        36       U      39        U      1.4       J      1.6      J        0.15              0.0083    J       0.00032    U      0.000275    U        0.23              0.25               0.32               0.11
132-64-9    Dibenzofuran                                                                                                    0.0075     U         0.007    U       0.0085     U        0.007     U        0.02     J        0.023    J         0.03     J        0.008     U
75-09-2     Dichloromethane                                                                                                0.000215    U       0.00023    U      0.000245    U       0.00021    U      0.00024    U     0.000235    U       0.00023    U      0.000235    U
84-66-2     Diethyl phthalate                                                                                                0.007     U        0.0065    U       0.0075     U       0.0065     U       0.007     U        0.007    U         0.007    U       0.0075     U
131-11-3    Dimethyl phthalate                                                                                              0.0055     U        0.0055    U       0.0065     U       0.0055     U      0.0055     U       0.0055    U        0.0055    U        0.006     U
84-74-2     di-n-Butyl-phthalate                                                                                            0.0335     U         0.033    U        0.038     U       0.0325     U       0.034     U        0.034    U        0.0335    U       0.0365     U
117-84-0    di-n-Octyl-phthalate                                                                                            0.0085     U        0.0085    U       0.0095     U        0.008     U      0.0085     U       0.0085    U        0.0085    U        0.009     U
100-41-4    Ethylbenzene                                                                                                    0.00023    U      0.000245    U       0.00026    U      0.000225    U     0.000255    U      0.00025    U      0.000245    U      0.000255    U
206-44-0    Fluoranthene                                 620              600               6.4             28                 1.1               0.06             0.0059            0.000315    U         0.7              0.73               0.91               0.22
86-73-7     Fluorene                                     450               34       J      2.05      U     1.05             0.0085     U        0.0085    U       0.00095    U       0.0008     U      0.0165     U        0.017    U         0.038    J        0.022     J
87-68-3     Hexachloro-1,3-butadiene                                                                                        0.0095     U        0.0095    U       0.0105     U       0.0095     U      0.0095     U       0.0095    U        0.0095    U       0.0105     U
118-74-1    Hexachlorobenzene                                                                                               0.00455    U        0.0045    U       0.0055     U       0.00445    U      0.0046     U      0.00465    U       0.00455    U       0.00495    U
77-47-4     Hexachlorocyclopentadiene                                                                                        0.006     U         0.006    U        0.007     U        0.006     U      0.0065     U       0.0065    U         0.006    U        0.007     U
67-72-1     Hexachloroethane                                                                                                0.0095     U        0.0095    U       0.0105     U       0.0095     U      0.0095     U       0.0095    U        0.0095    U       0.0105     U
193-39-5    Indeno(1,2,3-cd)pyrene                        36       U      17        J      3.5       J      4.8               0.53               0.035    J       0.0034     J       0.0011     J        0.96                1                 1.3               0.43
98-82-8     Isopropylbenzene                                                                                                0.00025    U       0.00027    U      0.000285    U      0.000245    U      0.00028    UJ    0.000275    UJ      0.00027    U       0.00028    U
7439-92-1   Lead                                                                                                               35      J           12     J          2.6     J          6.8     J         18      J          25     J           27                6.9     J
136777-61-2 m,p-Xylenes                                                                                                    0.000475    U       0.00055    U       0.00055    U      0.000465    U      0.00055    U      0.00055    U       0.00055    U       0.00055    U
541-73-1    m-Dichlorobenzene                                                                                             0.0000275    U      0.000029    U      0.000031    U      0.000027    U    0.0000305    UJ     0.00003    UJ     0.000029    U       0.00003    U
7439-97-6   Mercury                                                                                                           0.12               0.029             0.026     J        0.027              0.41              0.32               0.46              0.039     J
79-20-9     Methyl acetate                                                                                                 0.000105    U       0.00011    U       0.00012    U      0.000105    U      0.0021     J     0.000115    U       0.00011    U      0.000115    U
78-93-3     Methyl ethyl ketone                                                                                             0.0006     U       0.00065    U       0.0007     U       0.0006     U      0.0007     U       0.0007    U        0.0022    J       0.0007     U
108-10-1    Methyl isobutyl ketone                                                                                         0.000385    U      0.000415    U       0.00044    U       0.00038    U      0.00043    U     0.000425    U      0.000415    U      0.000425    U
591-78-6    Methyl n-butyl ketone                                                                                           0.00055    U        0.0006    U       0.00065    U       0.00055    U      0.00065    U       0.0006    U        0.0006    U       0.0006     UJ
108-88-3    Methylbenzene                                                                                                   0.00023    U      0.000245    U       0.00026    U      0.000225    U     0.000255    U      0.00025    U       0.00062    J      0.000255    U
108-87-2    Methylcylohexane                                                                                                0.00024    U      0.000255    U      0.000275    U      0.000235    U      0.00027    U     0.000265    U      0.000255    UJ     0.000265    U
91-20-3     Naphthalene                                  250              39        U      2.05      U     0.35      J      0.0028     U        0.0028    U       0.00032    U      0.000275    U        0.07     J        0.075    J         0.092             0.018     J
98-95-3     Nitrobenzene                                                                                                     0.011     UJ        0.011    UJ      0.0125     U        0.011     U       0.011     U       0.0115    U         0.011    U        0.012     U
621-64-7    n-Nitroso-di-n-Propylamine                                                                                        0.01     U         0.01     U       0.0115     U         0.01     U        0.01     UJ       0.01     UJ        0.01     U        0.011     U
86-30-6     n-Nitrosodiphenylamine                                                                                           0.006     U         0.006    U        0.007     U        0.006     U      0.0065     U       0.0065    U         0.006    U        0.007     U
95-47-6     o-Xylene                                                                                                        0.00022    U      0.000235    U       0.00025    U      0.000215    U     0.000245    U      0.00024    U      0.000235    U       0.00024    U
106-47-8    p-Chloroaniline                                                                                                 0.0145     U         0.014    U       0.0165     U        0.014     U      0.0145     U       0.0145    U        0.0145    U       0.0155     UJ
87-86-5     Pentachlorophenol                            240               39       U      2.05      U     1.75      U        0.12     J         0.11     J      0.000435    U      0.000375    U        0.15              0.17     J         0.21     J         0.15     J
85-01-8     Phenanthrene                                 830              550              0.59      J      6.6                0.2               0.018    U       0.00205    U       0.0018     U        0.14     J        0.15     J         0.19              0.059     J
108-95-2    Phenol                                                                                                           0.009     U         0.009    U         0.01     U        0.009     U       0.009     U        0.009    U         0.009    U         0.01     U
100-01-6    p-Nitroaniline                                                                                                   0.007     U        0.0065    U       0.0075     U       0.0065     U       0.007     U        0.007    U         0.007    U       0.0075     U
129-00-0    Pyrene                                       400              370              8.7              27                  1                0.056            0.0054             0.0021     J         1.1               1.1                1.4               0.28
7782-49-2   Selenium                                                                                                         0.425     U         0.435    U        0.485     U        0.445     U        0.46     U        0.46     U         0.425    U        0.485     U
7440-22-4   Silver                                                                                                           0.195     U         0.195    U         0.22     U          0.2     U       0.205     U        0.21     U         0.195    U         0.22     U
100-42-5    Styrene (monomer)                                                                                              0.000235    U       0.00025    U       0.00027    U       0.00023    U      0.00026    U     0.000255    U       0.00025    U       0.00026    U
1634-04-4   tert-Butyl methyl ether                                                                                        0.000175    U      0.000185    U       0.0002     U       0.00017    U     0.000195    U      0.00019    U       0.00019    U      0.000195    U
127-18-4    Tetrachloroethylene                                                                                             0.00022    U      0.000235    U       0.00025    U      0.000215    U     0.000245    U      0.00024    U      0.000235    U       0.00024    U
156-60-5    trans-1,2-Dichloroethene                                                                                        0.00021    U       0.00022    U      0.000235    U      0.000205    U      0.00023    U      0.00023    U       0.00022    U       0.00023    U
10061-02-6 trans-1,2-Dichloropropene                                                                                       0.000165    U      0.000175    U       0.00019    U       0.00016    U     0.000185    U      0.00018    U      0.000175    U       0.00018    U
75-25-2     Tribromomethane                                                                                                0.000215    U       0.00023    U      0.000245    U       0.00021    U      0.00024    U     0.000235    U       0.00023    U      0.000235    U
79-01-6     Trichloroethylene                                                                                               0.00022    U      0.000235    U       0.00025    U      0.000215    U     0.000245    U      0.00024    U      0.000235    U       0.00024    U
7440-62-2   Vanadium                                                                                                           4.2                1.7                0.5     UJ          4                1.6     J         2.3     J          2.5                18
75-01-4     Vinyl chloride                                                                                                 0.000135    U       0.00014    U       0.00015    U       0.00013    U     0.000145    U     0.000145    U       0.00014    U      0.000145    U
67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran         0.0125          0.0661         0.00003695   U   0.000756        0.000095769        0.000017532        0.000003269   J    0.000004166   J     0.000552          0.000516         0.000251552        0.000865786
35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin      0.142           0.45             0.0115          0.0123        0.000746826        0.000192404        0.000026107        0.000028925          0.00555           0.00533         0.002877368   J    0.010366933
55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran        0.00148         0.00285           0.00008    U   0.0000715   U   0.000006065        0.00000128    J    0.000000205   J    0.000000245   J    0.0000333          0.000032         0.000018079        0.000051434
70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran          0.0002695   U   0.0001395    U    0.0002805   U    0.00025    U   0.000002742   J    0.000001434   J    0.000000058   U      3.15E-08    U    0.0000112          0.0000105        0.000005384   J    0.000013745
39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin      0.000209    U    0.00146          0.0002175   U   0.000194    U   0.00000618         0.000001058   J    0.000000202   J    0.000000051   U     0.000026          0.0000255        0.000010005        0.000037265
57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran          0.0001595   U   0.0001095    U    0.000166    U   0.000148    U   0.000002384   J    0.00000075    J    0.000000033   U    0.000000036   U   0.00000697         0.00000593        0.000002665   J    0.000006566
57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin        0.0015           0.011           0.00028        0.0001175   U   0.00001672         0.000004784   J    0.000000684   J    0.000001058   J    0.0000947          0.0000962        0.000051217        0.000164222
72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran          0.000187    U   0.000141     U    0.0001945   U   0.0001735   U     5.15E-08    U    0.000000095   U      4.25E-08    U      4.55E-08    U   0.00000259         0.00000233   J     1.605E-07    U    0.000000215   U
19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin      0.000943         0.00892          0.000377        0.000112    U   0.000015977        0.000003758   J    0.000000648   J    0.000000517   J    0.0000443          0.0000419        0.000012274        0.000159479
57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran           0.0002145   U   0.000046     U    0.000223    U   0.000199    U   0.000000312   J    0.00000037    J      1.75E-08    U      1.25E-08    U   0.000000925   J    0.00000082   J    0.000000545   J     2.625E-07    U
40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin       0.000231    U   0.0000655    U     0.00024    U   0.000214    U   0.000002012   J    0.000000548   J    0.00000002    U    0.000000022   U   0.00000801         0.00000792        0.000004292   J    0.000005989   J
60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran                                                                            0.000001688   J    0.000000754   J      3.25E-08    U      3.65E-08    U    0.0000116          0.0000108        0.000002355   J    0.000008114   J
57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran                                                                             0.00000068    J    0.00000071    J      1.85E-08    U    0.000000014   U   0.00000276         0.00000265        0.000000812   J    0.000000713   J
51207-31-9 2,3,7,8-Tetrachlorodibenzofuran             0.0000275   U   0.00003615   U   0.0000286    U   0.0000255   U    4.325E-07    U    0.000000594   U    0.000000019   U      2.65E-08    U    0.0000013         0.00000135        0.000000535   U     2.745E-07    U
1746-01-6   2,3,7,8-Tetrachlorodibenzo-p-dioxin        0.000022    U    0.000044    U   0.0000229    U   0.0000204   U   0.000000099   U    0.000000034   U      1.15E-08    U    0.000000013   U   0.00000108         0.00000111        0.00000032    U    0.000000394   J
39001-02-0 Octachlorodibenzofuran                        0.0795         0.0002805   U    0.00551          0.00632        0.000458957        0.000082162        0.000014049         0.0000232           0.00321           0.00307         0.001968873        0.00556771
3268-87-9   Octachlorodibenzo-p-dioxin                    0.933            8.2            0.108            0.118         0.006956787   J    0.001730716        0.000240163        0.000316932           0.053             0.0519         0.028365185   J    0.087059257   J
APPENDIX A
                                                                                                      SUMMARY OF SITE SOIL DATA USED IN RISK ASSESSMENT
                                                                                                           KOPPERS INC. WOOD-TREATING FACILITY
                                                                                                                    GAINESVILLE, FLORIDA

             Sample ID                             SS003BA          SS003CA          SS003CB             SS003DA          SS004AA          SS004BA          SS004BB          SS005AA          SS005BA          SS005CA          SS005DA          SS006AA
             Sample Date                           08-Dec-06        08-Dec-06        08-Dec-06           08-Dec-06        05-Dec-06        05-Dec-06        05-Dec-06        08-Dec-06        08-Dec-06        08-Dec-06        08-Dec-06        05-Dec-06
             Sample Depth (feet)                    0.25-0.5           0.5-2            0.5-2                2-6            0-0.25          0.25-0.5         0.25-0.5          0-0.25          0.25-0.5           0.5-2             2-6            0-0.25
             Concentration Units                     mg/kg            mg/kg            mg/kg               mg/kg            mg/kg            mg/kg            mg/kg            mg/kg            mg/kg            mg/kg            mg/kg            mg/kg
71-55-6      1,1,1-Trichloroethane                   0.0001    U     0.00007    U     0.00007    U       0.000065    U     0.00012    U    0.000085    U      0.0001    U     0.00007    U     0.00007    U     0.00008    U    0.000075    U    0.000065    U
79-34-5      1,1,2,2-Tetrachloroethane             0.000055    U    0.000036    U    0.000038    U       0.000035    U    0.000065    U    0.000047    U    0.000055    U    0.0000365   U    0.000037    U    0.0000435   U    0.000039    U    0.0000355   U
79-00-5      1,1,2-Trichloroethane                  0.00011    U    0.000075    U    0.000075    U        0.00007    U    0.000125    U    0.000095    U     0.00011    U    0.000075    U    0.000075    U     0.00009    U     0.00008    U     0.00007    U
75-34-3      1,1-Dichloroethane                    0.000055    U    0.0000345   U    0.000036    U       0.0000335   U    0.000065    U    0.0000445   U    0.000055    U    0.0000345   U    0.0000355   U    0.0000415   U    0.0000375   U    0.000034    U
75-35-4      1,1-Dichloroethylene                  0.000145    U    0.000095    U      0.0001    U       0.000095    U    0.000165    U    0.000125    U     0.00014    U    0.000095    U    0.000095    U    0.000115    U    0.000105    U    0.000095    U
120-82-1     1,2,4-Trichlorobenzene                0.000125    U    0.000085    U     0.00009    U        0.00008    U    0.000145    U     0.00011    U    0.000125    U    0.000085    U    0.000085    U      0.0001    U     0.00009    U    0.000085    U
96-12-8      1,2-Dibromo-3-chloropropane            0.00041    U     0.00027    U     0.00028    U        0.00026    U    0.000475    U     0.00035    U      0.0004    U     0.00027    U    0.000275    U    0.000325    U     0.00029    U    0.000265    U
106-93-4     1,2-Dibromoethane                     0.000047    U    0.0000305   U    0.000032    U        0.00003    U    0.000055    U     0.00004    U    0.000046    U    0.000031    U    0.0000315   U    0.000037    U    0.000033    U    0.0000305   U
95-50-1      1,2-Dichlorobenzene                   0.000065    U    0.0000425   U    0.0000445   U       0.0000415   U    0.000075    U     0.00006    U    0.000065    U    0.000043    U    0.0000435   U    0.000055    U    0.000046    U    0.000042    U
107-06-2     1,2-Dichloroethane                    0.000085    U    0.000055    U     0.00006    U       0.000055    U      0.0001    U    0.000075    U    0.000085    U    0.000055    U     0.00006    U     0.00007    U     0.00006    U    0.000055    U
78-87-5      1,2-Dichloropropane                   0.000045    U    0.0000295   U    0.000031    U       0.000029    U    0.000055    U    0.0000385   U    0.000044    U     0.00003    U    0.0000305   U    0.0000355   U    0.000032    U    0.0000295   U
106-46-7     1,4-Dichlorobenzene                   0.000075    U    0.0000475   U    0.0000495   U       0.0000465   U    0.000085    U    0.000065    U    0.000075    U    0.000048    U    0.0000485   U     0.00006    U    0.000055    U    0.000047    U
95-95-4      2,4,5-Trichlorophenol                   0.0085    U      0.0075    U       0.007    U          0.007    U      0.0085    U      0.0085    U      0.009     U      0.0075    U      0.0075    U       0.007    U       0.008    U       0.007    U
88-06-2      2,4,6-Trichlorophenol                   0.0225    U       0.02     U      0.0195    U         0.0195    U      0.0235    U       0.023    U      0.024     U       0.02     U       0.02     U      0.0195    U      0.0215    U      0.0195    U
120-83-2     2,4-Dichlorophenol                       0.011    U      0.0095    U      0.0095    U         0.0095    U       0.011    U       0.011    U      0.0115    U      0.0095    U      0.0095    U      0.0095    U       0.01     U      0.0095    U
105-67-9     2,4-Dimethylphenol                       0.012    U      0.0105    U      0.0105    U         0.0105    U      0.0125    U      0.0125    U      0.0125    U      0.0105    U       0.032    J      0.0105    U      0.0115    U      0.0105    U
51-28-5      2,4-Dinitrophenol                       0.0075    U       0.007    U      0.0065    U         0.0065    U       0.008    U       0.008    U      0.008     U       0.007    U       0.007    U      0.0065    U      0.0075    U      0.0065    U
121-14-2     2,4-Dinitrotoluene                      0.0065    U      0.0055    U      0.0055    U         0.0055    U      0.0065    U      0.0065    U      0.0065    U      0.0055    U      0.0055    U      0.0055    U       0.006    U      0.0055    U
606-20-2     2,6-Dinitrotoluene                      0.0225    U       0.02     U      0.0195    U         0.0195    U      0.0235    U       0.023    U      0.024     U       0.02     U       0.02     U      0.0195    U      0.0215    U      0.0195    U
91-58-7      2-Chloronaphthalene                      0.01     U       0.009    U       0.009    U          0.009    U      0.0105    U      0.0105    U      0.0105    U       0.009    U       0.009    U       0.009    U      0.0095    U       0.009    U
95-57-8      2-Chlorophenol                          0.0115    U       0.01     U       0.01     U          0.01     U       0.012    U      0.0115    U      0.012     U       0.01     U       0.01     U       0.01     U       0.011    U       0.01     U
91-57-6      2-Methylnaphthalene                      0.085            0.038            0.049              0.0045            0.076    J       0.067    J      0.099     J       0.03     J       0.66             0.11             0.013            0.099
95-48-7      2-Methylphenol (o-cresol)               0.0075    U       0.007    U      0.0065    U         0.0065    U       0.008    U       0.008    U      0.008     U       0.007    U       0.007    U      0.0065    U      0.0075    U      0.0065    U
88-74-4      2-Nitroaniline                           0.014    U       0.012    U       0.012    U          0.012    U      0.0145    UJ      0.014    UJ     0.0145    UJ     0.0125    U      0.0125    U       0.012    U       0.013    U       0.012    UJ
88-75-5      2-Nitrophenol                            0.009    U       0.008    U       0.008    U         0.0075    U       0.009    U       0.009    U      0.0095    U       0.008    U       0.008    U       0.008    U      0.0085    U      0.0075    U
91-94-1      3,3'-Dichlorobenzidine                  0.0215    U      0.0185    U      0.0185    U         0.0185    U       0.022    UJ      0.022    UJ     0.0225    UJ      0.019    U       0.019    U      0.0185    U       0.02     U      0.0185    UJ
78-59-1      3,5,5-Trimethyl-2-cyclohexene-1-one     0.0085    U      0.0075    U       0.007    U          0.007    U      0.0085    UJ     0.0085    UJ     0.009     UJ     0.0075    U      0.0075    U       0.007    U       0.008    U       0.007    UJ
99-09-2      3-Nitroaniline                           0.011    U      0.0095    U      0.0095    U         0.0095    U       0.011    U       0.011    U      0.0115    U      0.0095    U      0.0095    U      0.0095    U       0.01     U      0.0095    U
534-52-1     4,6-Dinitro-2-Methylphenol               0.006    U      0.0055    U      0.0055    U          0.005    U      0.0065    U       0.006    U      0.0065    U      0.0055    U      0.0055    U      0.0055    U       0.006    U      0.0055    U
101-55-3     4-Bromophenyl phenyl ether              0.0065    U      0.0055    U      0.0055    U         0.0055    U      0.0065    U      0.0065    U      0.0065    U      0.0055    U      0.0055    U      0.0055    U       0.006    U      0.0055    U
59-50-7      4-Chloro-3-methylphenol                  0.01     U       0.009    U       0.009    U          0.009    U      0.0105    U      0.0105    U      0.0105    U       0.009    U       0.009    U       0.009    U      0.0095    U       0.009    U
7005-72-3    4-Chlorophenyl phenyl ether              0.014    U       0.012    U       0.012    U          0.012    U      0.0145    U       0.014    U      0.0145    U      0.0125    U      0.0125    U       0.012    U       0.013    U       0.012    U
106-44-5     4-Methylphenol (m/p-cresol)             0.0165    U      0.0145    U       0.014    U          0.014    U       0.017    U       0.017    U      0.0175    U      0.0145    U      0.0145    U       0.014    U      0.0155    U       0.014    U
100-02-7     4-Nitrophenol                            0.011    U      0.0095    U      0.0095    U         0.0095    U       0.011    UJ      0.011    UJ     0.0115    UJ     0.0095    U      0.0095    U      0.0095    U       0.01     U      0.0095    UJ
83-32-9      Acenaphthene                             0.062    J       0.015    U       0.015    U         0.0041    J       0.035    U       0.039    J      0.0355    U       0.015    U       0.58             0.14             0.01             0.064    J
208-96-8     Acenaphthylene                           0.91             0.075    J       0.051    J          0.016            0.64             0.46     J       0.72     J       0.33              1.9             0.34             0.06              0.9
67-64-1      Acetone                                 0.0021    U      0.0014    U     0.00145    U        0.00135    U     0.00245    U      0.0018    U     0.00205    U      0.0014    U      0.0014    U     0.00165    U      0.0015    U     0.00135    U
120-12-7     Anthracene                                1.8              0.2     J       0.11     J          0.023            0.76             0.52     J       0.84     J       0.37              6.4             0.34             0.13              1.8
7440-36-0    Antimony                                 0.205    UJ      0.17     UJ      0.18     UJ         0.17     UJ      0.215    UJ      0.215    UJ     0.215     UJ      0.17     U       0.185    U       0.175    UJ      0.185    UJ      0.18     UJ
7440-38-2    Arsenic                                    22     J         19     J         14     J           5.4     J        5.8              4.8              5.1               5      J         12     J        4.3     J         14     J         17
7440-39-3    Barium                                     51               12               11                 8.1               30               33              31                16               32               23               12               18
71-43-2      Benzene                               0.000325    U    0.000215    U    0.000225    U        0.00021    U    0.000375    U     0.00028    U     0.00032    U    0.000215    U     0.00022    U     0.00026    U     0.00023    U     0.00021    U
56-55-3      Benzo(a)anthracene                        2.8             0.41     J       0.15     J          0.02             0.73             0.71     J        1.1     J       0.71              5.6             0.57             0.088              1
50-32-8      Benzo(a)pyrene                            6.1             0.36     J        0.2     J          0.037             1.2             0.93     J        1.4     J       0.69              6.5             0.66             0.13              1.3
205-99-2     Benzo(b)fluoranthene                       12             0.63     J       0.36     J          0.075             1.9              1.5     J        2.2     J        1.4               13             0.84             0.26              2.5
191-24-2     Benzo(g,h,i)perylene                      2.9             0.21             0.16                0.049             1.2             0.88     J        1.4     J       0.75              5.5             0.39             0.11              1.8
207-08-9     Benzo(k)fluoranthene                      5.9             0.52     J       0.25     J          0.033             1.5              1.1     J        1.7     J       0.81              6.5             0.68             0.12              1.6
85-68-7      Benzyl butyl phthalate                  0.0115    U       0.01     U       0.01     U          0.01     U       0.012    U      0.0115    U      0.012     U       0.01     U       0.01     U       0.01     U       0.011    U       0.01     U
92-52-4      Biphenyl                                 0.095    U       0.085    U       0.085    U          0.08     U        0.1     U        0.1     U        0.1     U       0.085    U       0.085    U       0.085    U       0.09     U       0.085    U
111-91-1     Bis(2-chlorethoxy)methane                0.011    U      0.0095    U      0.0095    U         0.0095    U       0.011    U       0.011    U      0.0115    U      0.0095    U      0.0095    U      0.0095    U       0.01     U      0.0095    U
111-44-4     Bis(2-chloroethyl)ether                 0.0095    U      0.0085    U      0.0085    U          0.008    U       0.01     U       0.01     U       0.01     U      0.0085    U      0.0085    UJ     0.0085    U       0.009    U      0.0085    U
39638-32-9   Bis(2-chloroisopropyl) ether            0.0135    U      0.0115    U      0.0115    U         0.0115    U      0.0135    UJ     0.0135    UJ     0.014     UJ      0.012    U       0.012    U      0.0115    U      0.0125    U      0.0115    UJ
117-81-7     Bis(2-ethylhexyl)phthalate               0.03     J       0.009    U       0.009    U          0.009    U      0.0105    U      0.0105    U      0.0105    U       0.24             0.094    J       0.05     J      0.0095    U       0.021    J
75-27-4      Bromodichloromethane                  0.000245    U     0.00016    U    0.000165    U       0.000155    U     0.00028    U    0.000205    U     0.00024    U     0.00016    U    0.000165    U     0.00019    U    0.000175    U     0.00016    U
74-83-9      Bromomethane                           0.00027    UJ   0.000175    UJ   0.000185    UJ       0.00017    UJ    0.00031    UJ    0.00023    UJ   0.000265    UJ    0.00018    UJ    0.00018    UJ    0.00021    UJ    0.00019    UJ   0.000175    UJ
7440-43-9    Cadmium                                  0.175    U       0.145    U       0.15     U          0.145    U       0.185    U       0.18     U      0.185     U       0.145    U       0.16     U       0.15     U       0.155    U       0.155    U
86-74-8      Carbazole                                0.54             0.042    J       0.034    J          0.009    U       0.044    J       0.043    J       0.05     J       0.06     J       0.57             0.047    J      0.0095    U       0.22
75-15-0      Carbon disulfide                      0.00135 U          0.0009    U     0.00095    U       0.00085 U        0.00155 U         0.00115    U     0.00135    U     0.0009 U         0.0009 U        0.00105 U        0.00095 U         0.0009 U
56-23-5      Carbon tetrachloride                  0.000295    U    0.000195    U      0.0002    U        0.00019    U     0.00034    U     0.00025    U    0.000285    U    0.000195    U    0.000195    U     0.00023    U     0.00021    U     0.00019    U
108-90-7     Chlorobenzene                         0.000335    U     0.00022    U     0.00023    U       0.000215    U    0.000385    U    0.000285    U     0.00033    U     0.00022    U    0.000225    U    0.000265    U     0.00024    U    0.000215    U
124-48-1     Chlorodibromomethane                   0.00021    U     0.00014    U    0.000145    U       0.000135    U    0.000245    U     0.00018    U    0.000205    U     0.00014    U     0.00014    U    0.000165    U     0.00015    U    0.000135    U
75-00-3      Chloroethane                            0.0003    U      0.0002    U    0.000205    U       0.000195    U     0.00035    U    0.000255    U    0.000295    U      0.0002    U    0.000205    U     0.00024    U    0.000215    U    0.000195    U
67-66-3      Chloroform                            0.000285    U    0.000185    U    0.000195    U       0.000185    U     0.00033    U    0.000245    U     0.00028    U     0.00019    U     0.00019    U    0.000225    U    0.000205    U    0.000185    U
74-87-3      Chloromethane                         0.000375    U    0.000245    U     0.00026    U        0.00024    U    0.000435    U     0.00032    U     0.00037    U     0.00025    U    0.000255    U    0.000295    U     0.00027    U    0.000245    U
7440-47-3    Chromium                                   10     J        3.4     J        3.6     J           3.9     J         16               14              15                11     J         12     J        9.8     J        5.6     J         20
218-01-9     Chrysene                                  4.9             0.59     J       0.25     J          0.03              0.9             0.88     J        1.2     J        0.9              7.2              0.7             0.11              1.3
156-59-2     cis-1,2-Dichloroethylene               0.00022    U    0.000145    U     0.00015    U        0.00014    U     0.00025    U    0.000185    U    0.000215    U    0.000145    U    0.000145    U    0.000175    U    0.000155    U     0.00014    U
10061-01-5   cis-1,3-Dichloropropene               0.000245    U     0.00016    U    0.000165    U       0.000155    U     0.00028    U    0.000205    U     0.00024    U     0.00016    U    0.000165    U     0.00019    U    0.000175    U     0.00016    U
APPENDIX A
                                                                                                               SUMMARY OF SITE SOIL DATA USED IN RISK ASSESSMENT
                                                                                                                    KOPPERS INC. WOOD-TREATING FACILITY
                                                                                                                             GAINESVILLE, FLORIDA

            Sample ID                                   SS003BA            SS003CA            SS003CB              SS003DA          SS004AA          SS004BA          SS004BB            SS005AA           SS005BA            SS005CA            SS005DA           SS006AA
            Sample Date                                 08-Dec-06         08-Dec-06          08-Dec-06            08-Dec-06         05-Dec-06        05-Dec-06        05-Dec-06         08-Dec-06          08-Dec-06         08-Dec-06          08-Dec-06          05-Dec-06
            Sample Depth (feet)                          0.25-0.5            0.5-2              0.5-2                 2-6             0-0.25          0.25-0.5         0.25-0.5            0-0.25           0.25-0.5            0.5-2               2-6              0-0.25
            Concentration Units                           mg/kg              mg/kg              mg/kg                mg/kg            mg/kg            mg/kg            mg/kg              mg/kg             mg/kg              mg/kg              mg/kg             mg/kg
7440-50-8   Copper                                           13     J          2.1     J          2.1     J            1.1     J         11              9.1              9.8                6.7     J          14     J          5.8     J          1.6     J          18
110-82-7    Cyclohexane                                  0.00069    J       0.00021    U       0.00022    U        0.000205    U     0.00037    U     0.00027    U     0.00031    U       0.00021    U     0.000215    U       0.00025    U      0.000225    U     0.000205    U
53-70-3     Dibenzo(a,h)anthracene                          1.2              0.074     J        0.043     J          0.013             0.31             0.22     J       0.35     J         0.21               1.2               0.24              0.037              0.49
132-64-9    Dibenzofuran                                   0.21     J        0.022     J        0.024     J          0.007     U       0.048    J       0.053    J      0.089     J        0.032     J        0.88              0.029     J        0.008     U        0.11     J
75-09-2     Dichloromethane                             0.000325    U      0.000215    U      0.000225    U         0.00021    U    0.000375    U     0.00028    U     0.00032    U      0.000215    U      0.00022    U       0.00026    U       0.00023    U      0.00021    U
84-66-2     Diethyl phthalate                             0.0075    U        0.007     U       0.0065     U         0.0065     U       0.008    U       0.008    U      0.008     U        0.007     U        0.007    U       0.0065     U       0.0075     U       0.0065    U
131-11-3    Dimethyl phthalate                            0.0065    U       0.0055     U       0.0055     U         0.0055     U      0.0065    U      0.0065    U      0.0065    U       0.0055     U       0.0055    U       0.0055     U        0.006     U       0.0055    U
84-74-2     di-n-Butyl-phthalate                          0.0385    U       0.0335     U        0.033     U         0.0325     U      0.0395    U       0.039    U       0.04     U        0.034     U        0.034    U        0.033     U        0.036     U        0.033    U
117-84-0    di-n-Octyl-phthalate                          0.0095    U       0.0085     U       0.0085     U          0.008     U       0.01     U       0.01     U       0.01     U       0.0085     U       0.0085    U       0.0085     U        0.009     U       0.0085    U
100-41-4    Ethylbenzene                                 0.00035    U       0.00023    U       0.00024    U        0.000225    U    0.000405    U      0.0003    U    0.000345    U       0.00023    U     0.000235    U       0.00028    U       0.00025    U      0.00023    U
206-44-0    Fluoranthene                                    6.5               0.94     J         0.34     J          0.036              1.1             0.94     J        1.7     J           1                 12                1.1               0.15               1.7
86-73-7     Fluorene                                       0.089             0.023     J       0.0085     U         0.0065             0.055    J       0.029    J      0.066     J        0.027     J        0.56               0.17               0.01              0.074
87-68-3     Hexachloro-1,3-butadiene                       0.011    U       0.0095     U       0.0095     U         0.0095     U       0.011    U       0.011    U      0.0115    U       0.0095     U       0.0095    U       0.0095     U         0.01     U       0.0095    U
118-74-1    Hexachlorobenzene                             0.0055    U       0.00455    U       0.0045     U         0.00445    U      0.0055    U      0.0055    U      0.0055    U       0.0046     U      0.00465    U       0.0045     U       0.0049     U      0.00445    U
77-47-4     Hexachlorocyclopentadiene                      0.007    U        0.006     U        0.006     U          0.006     U      0.0075    U       0.007    U      0.0075    U       0.0065     U       0.0065    UJ       0.006     U       0.0065     U        0.006    U
67-72-1     Hexachloroethane                               0.011    U       0.0095     U       0.0095     U         0.0095     U       0.011    U       0.011    U      0.0115    U       0.0095     U       0.0095    U       0.0095     U         0.01     U       0.0095    U
193-39-5    Indeno(1,2,3-cd)pyrene                          5.2               0.25     J         0.18     J          0.039              1.4             0.99     J        1.6     J         0.55               5.5               0.49               0.11               2.1
98-82-8     Isopropylbenzene                            0.000385    U      0.000255    U      0.000265    U        0.000245    U    0.000445    U    0.000325    U    0.000375    U      0.000255    U      0.00026    U      0.000305    U      0.000275    U      0.00025    U
7439-92-1   Lead                                             13     J          6.3     J          5.1     J            3.1     J         14               13              14                 14      J          37     J          13      J          5.5     J          16
136777-61-2 m,p-Xylenes                                  0.00075    U      0.000475    U      0.000495    U        0.000465    U     0.00085    U     0.00065    U     0.00075    U       0.00048    U     0.000485    U       0.0006     U       0.00055    U      0.00047    U
541-73-1    m-Dichlorobenzene                           0.000042    U     0.0000275    U     0.0000285    U       0.0000265    U    0.0000485   U    0.0000355   U    0.000041    U     0.0000275    U     0.000028    U      0.000033    U     0.0000295    U     0.000027    U
7439-97-6   Mercury                                        0.25     J        0.024     J        0.022     J          0.015     J        0.2              0.2             0.27              0.066     J        0.32     J        0.069     J        0.049     J        0.095
79-20-9     Methyl acetate                               0.00016    U      0.000105    U       0.00011    U        0.000105    U    0.000185    U    0.000135    U    0.000155    U      0.000105    U      0.00011    U      0.000125    U      0.000115    U     0.000105    U
78-93-3     Methyl ethyl ketone                           0.0024    J       0.0006     U       0.00065    U         0.0006     U      0.0011    U      0.0008    U      0.0009    U       0.00065    U      0.00065    U       0.00075    U       0.00065    U       0.0006    U
108-10-1    Methyl isobutyl ketone                        0.0006    U       0.00039    U      0.000405    U         0.00038    U      0.0007    U     0.00055    U      0.0006    U       0.00039    U       0.0004    U       0.00047    U       0.00042    U     0.000385    U
591-78-6    Methyl n-butyl ketone                        0.00085    UJ      0.00055    UJ      0.0006     UJ        0.00055    UJ      0.001    U     0.00075    U     0.00085    U       0.00055    UJ      0.0006    UJ      0.0007     UJ      0.0006     UJ     0.00055    U
108-88-3    Methylbenzene                                 0.0029    J       0.00023    U       0.00024    U        0.000225    U    0.000405    U      0.0003    U    0.000345    U       0.00023    U     0.000235    U       0.00028    U       0.00025    U      0.00023    U
108-87-2    Methylcylohexane                              0.0015    J       0.00024    U      0.000255    U        0.000235    U    0.000425    U    0.000315    U     0.00036    UJ     0.000245    U     0.000245    U       0.00029    U       0.00026    U      0.00024    U
91-20-3     Naphthalene                                    0.15              0.038              0.042               0.0061             0.079    J       0.07     J        0.1     J        0.049              0.92               0.11               0.02              0.11
98-95-3     Nitrobenzene                                  0.0125    U        0.011     U        0.011     U          0.011     U       0.013    U       0.013    U      0.0135    U        0.011     U       0.0115    U        0.011     U        0.012     U        0.011    U
621-64-7    n-Nitroso-di-n-Propylamine                    0.0115    U         0.01     U         0.01     U           0.01     U       0.012    UJ     0.0115    UJ     0.012     UJ        0.01     U        0.01     U         0.01     U        0.011     U        0.01     UJ
86-30-6     n-Nitrosodiphenylamine                         0.007    U        0.006     U        0.006     U          0.006     U      0.0075    U       0.007    U      0.0075    U       0.0065     U       0.0065    U        0.006     U       0.0065     U        0.006    U
95-47-6     o-Xylene                                    0.000335    U       0.00022    U       0.00023    U        0.000215    U    0.000385    U    0.000285    U     0.00033    U       0.00022    U     0.000225    U      0.000265    U       0.00024    U     0.000215    U
106-47-8    p-Chloroaniline                               0.0165    U       0.0145     UJ       0.014     UJ         0.014     UJ      0.017    U       0.017    U      0.0175    U       0.0145     UJ      0.0145    U        0.014     UJ      0.0155     UJ       0.014    U
87-86-5     Pentachlorophenol                             0.0044    UJ      0.00385    UJ      0.0038     UJ        0.0025     J       0.056    J       0.051    J      0.054     J         0.19     J        0.43     J         0.28     J        0.012     J        0.48     J
85-01-8     Phenanthrene                                   0.83                0.2     J        0.095     J          0.028             0.23             0.17     J       0.26     J         0.19               2.8                0.3              0.051              0.56
108-95-2    Phenol                                         0.01     U        0.009     U        0.009     U          0.009     U      0.0105    U      0.0105    U      0.0105    U        0.009     U        0.009    U        0.009     U       0.0095     U        0.009    U
100-01-6    p-Nitroaniline                                0.0075    UJ       0.007     U       0.0065     U         0.0065     U       0.008    U       0.008    U      0.008     U        0.007     U        0.007    U       0.0065     U       0.0075     U       0.0065    U
129-00-0    Pyrene                                          7.1                1.1     J         0.37     J           0.04              1.1              1.1     J        1.6     J          1.5                12                1.3               0.17               1.6
7782-49-2   Selenium                                        0.5     U         0.42     U         0.44     U          0.415     U       0.55     U       0.55     U       0.55     U        0.425     U        0.455    U         0.44     U        0.455     U        0.445    U
7440-22-4   Silver                                         0.23     U         0.19     U          0.2     U           0.19     U       0.24     U       0.24     U       0.24     U         0.19     U        0.205    U          0.2     U        0.205     U         0.2     U
100-42-5    Styrene (monomer)                            0.00036    U      0.000235    U      0.000245    U         0.00023    U    0.000415    U    0.000305    U    0.000355    U       0.00024    U      0.00024    U      0.000285    U      0.000255    U     0.000235    U
1634-04-4   tert-Butyl methyl ether                      0.00027    U      0.000175    U      0.000185    U         0.00017    U     0.00031    U     0.00023    U    0.000265    U       0.00018    U      0.00018    U       0.00021    U       0.00019    U     0.000175    U
127-18-4    Tetrachloroethylene                         0.000335    U       0.00022    U       0.00023    U        0.000215    U    0.000385    U    0.000285    U     0.00033    U       0.00022    U     0.000225    U      0.000265    U       0.00024    U     0.000215    U
156-60-5    trans-1,2-Dichloroethene                     0.00032    U       0.00021    U       0.00022    U        0.000205    U     0.00037    U     0.00027    U     0.00031    U       0.00021    U     0.000215    U       0.00025    U      0.000225    U     0.000205    U
10061-02-6 trans-1,2-Dichloropropene                     0.00025    U      0.000165    U      0.000175    U         0.00016    U     0.00029    U    0.000215    U    0.000245    U      0.000165    U      0.00017    U       0.0002     U       0.00018    U     0.000165    U
75-25-2     Tribromomethane                             0.000325    U      0.000215    U      0.000225    U         0.00021    U    0.000375    U     0.00028    U     0.00032    U      0.000215    U      0.00022    U       0.00026    U       0.00023    U      0.00021    U
79-01-6     Trichloroethylene                           0.000335    U       0.00022    U       0.00023    U        0.000215    U    0.000385    U    0.000285    U     0.00033    U       0.00022    U     0.000225    U      0.000265    U       0.00024    U     0.000215    U
7440-62-2   Vanadium                                        9.6                2.4     J          3.3     J            1.7              7.5              7.8               9                 5.6               7.6                6.2                2.6               3.9
75-01-4     Vinyl chloride                                0.0002    U      0.000135    U       0.00014    U         0.00013    U    0.000235    U     0.00017    U      0.0002    U      0.000135    U     0.000135    U       0.00016    U      0.000145    U      0.00013    U
67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran        0.000674         0.00002271          1.425E-07    U      0.000029113                                                           0.001007751          0.00311    J    0.000615288        0.000124468          0.00494
35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin     0.00558         0.000223149        0.000147144          0.000213096                                                           0.007383233           0.0425         0.005481337        0.001228708           0.0371
55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran        0.000054         0.000002917   J    0.000001223   J      0.000001031   J                                                       0.000066966         0.000225         0.00004336         0.000006619   U     0.000295
70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran           0.0000185        0.000000538   J    0.000001434   J      0.000000541   J                                                       0.000028905         0.0000652        0.000016659        0.000003126   J     0.000122
39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin       0.0000263        0.000001074   J    0.000000659   J      0.000001014   J                                                       0.000074532         0.000181         0.000042411        0.000007061         0.000366
57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran            0.00001         0.000000162   U    0.000000743   J      0.000000377   J                                                       0.000027546         0.0000347        0.000012897        0.000002282   J     0.000103
57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin       0.000118         0.000004099   J    0.000002875   J      0.000003748   J                                                       0.000196911         0.000756         0.000119628        0.000024077         0.000911
72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran          0.00000356         1.735E-07    U    0.000000749   J        6.85E-08    U                                                        1.985E-07    U     0.0000117         1.355E-07    U    0.000000117   U     0.0000271
19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin       0.0000436        0.000004312   J    0.000001831   J      0.000002295   J                                                       0.000143555   J     0.000347         0.000081824   J    0.000013317   J     0.000634
57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran           0.00000235   J      2.55E-08    U    0.000000598   J      0.00000024    J                                                       0.000002258   J    0.00000401        0.000001309   J    0.000000324   J    0.00000944
40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin       0.00000625        0.000000152   U    0.000000045   U      0.000000331   J                                                       0.000023769         0.0000483        0.000011592        0.000002151   J     0.000119
60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran           0.0000203        0.000000067   U     2.855E-07    U      0.000000422   J                                                       0.000023235         0.0000643        0.000009601   J    0.000001915   J     0.000194
57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran           0.00000608        0.00000016    J    0.000000466   J      0.000000229   J                                                       0.00000329    J     0.0000143        0.000001773   J    0.000000299   J     0.0000374
51207-31-9 2,3,7,8-Tetrachlorodibenzofuran             0.00000165        0.000000022   U    0.000000509   J      0.000000015   U                                                       0.000000672   J    0.00000186        0.000000279   U    0.000000176   U    0.00000223
1746-01-6   2,3,7,8-Tetrachlorodibenzo-p-dioxin                     U    0.000000022   U      2.25E-08    U      0.000000014   U                                                       0.000001096   J    0.00000584        0.000000599   J    0.000000012   U    0.00000643
39001-02-0 Octachlorodibenzofuran                       0.00373          0.000119868        0.000079273          0.00011289                                                            0.004225438           0.0175         0.003389941        0.000704675           0.0198
3268-87-9   Octachlorodibenzo-p-dioxin                  0.0564           0.002061955        0.001403442          0.001930378   J                                                       0.05433963    J        0.412         0.047246051   J    0.011326673   J        0.35
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1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010
1658 amec beazer updated human health risk assessment koppers appendices   5 10-2010

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1658 amec beazer updated human health risk assessment koppers appendices 5 10-2010

  • 2. Appendix A Summary of Site Soil and Sediment Data Used in the Risk Assessment
  • 3. APPENDIX A SUMMARY OF SITE SOIL DATA USED IN RISK ASSESSMENT KOPPERS INC. WOOD-TREATING FACILITY GAINESVILLE, FLORIDA Sample ID B1 B3 B-4 B5 DT GA-Soil-001 GA-Soil-004 GA-Soil-005 GA-Soil-011 GA-Soil-033 GA-Soil-034 GA-Soil-035 GA-Soil-036 GA-Soil-037 GA-Soil-038 Sample Date 15-Aug-95 16-Aug-95 17-Aug-95 17-Aug-95 24-Aug-95 11-Aug-98 13-Aug-98 13-Aug-98 13-Aug-98 13-Aug-98 11-Aug-98 11-Aug-98 11-Aug-98 11-Aug-98 11-Aug-98 Sample Depth (feet) 2.5-2.5 2-2 3-3 5-5 0-0.5 0-0.7 0-1 0-1 0-1 0-1 0.5-0.5 0.5-0.5 0.5-0.5 0.5-0.5 0.5-0.5 Concentration Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 71-55-6 1,1,1-Trichloroethane 79-34-5 1,1,2,2-Tetrachloroethane 79-00-5 1,1,2-Trichloroethane 75-34-3 1,1-Dichloroethane 75-35-4 1,1-Dichloroethylene 120-82-1 1,2,4-Trichlorobenzene 96-12-8 1,2-Dibromo-3-chloropropane 106-93-4 1,2-Dibromoethane 95-50-1 1,2-Dichlorobenzene 107-06-2 1,2-Dichloroethane 78-87-5 1,2-Dichloropropane 106-46-7 1,4-Dichlorobenzene 95-95-4 2,4,5-Trichlorophenol 88-06-2 2,4,6-Trichlorophenol 120-83-2 2,4-Dichlorophenol 105-67-9 2,4-Dimethylphenol 51-28-5 2,4-Dinitrophenol 121-14-2 2,4-Dinitrotoluene 606-20-2 2,6-Dinitrotoluene 91-58-7 2-Chloronaphthalene 95-57-8 2-Chlorophenol 91-57-6 2-Methylnaphthalene 2.3 0.75 U 400 58 J 95-48-7 2-Methylphenol (o-cresol) 88-74-4 2-Nitroaniline 88-75-5 2-Nitrophenol 91-94-1 3,3'-Dichlorobenzidine 78-59-1 3,5,5-Trimethyl-2-cyclohexene-1-one 99-09-2 3-Nitroaniline 534-52-1 4,6-Dinitro-2-Methylphenol 101-55-3 4-Bromophenyl phenyl ether 59-50-7 4-Chloro-3-methylphenol 7005-72-3 4-Chlorophenyl phenyl ether 106-44-5 4-Methylphenol (m/p-cresol) 100-02-7 4-Nitrophenol 83-32-9 Acenaphthene 0.95 U 0.2 J 450 130 2 U 20 U 0.2 U 20 U 0.2 U 208-96-8 Acenaphthylene 0.95 U 0.3 J 0.022 J 38.5 U 1 U 10 U 0.1 U 10 U 0.1 U 67-64-1 Acetone 120-12-7 Anthracene 3.9 0.54 J 440 180 0.04 U 0.81 0.004 U 0.4 U 0.004 U 7440-36-0 Antimony 7440-38-2 Arsenic 7.2 8.1 11 3.1 10 U 30.3 10 U 10 U 10 U 7440-39-3 Barium 71-43-2 Benzene 56-55-3 Benzo(a)anthracene 0.95 U 1.7 220 180 0.08 U 3 0.033 2.9 0.008 U 50-32-8 Benzo(a)pyrene 2.8 1.6 120 77 0.05 U 4.4 0.068 7.3 0.021 205-99-2 Benzo(b)fluoranthene 7.3 2.1 220 160 0.18 6.6 0.088 9.2 0.04 191-24-2 Benzo(g,h,i)perylene 2.1 0.82 37 43 J 0.08 U 4.4 0.068 6.1 0.02 207-08-9 Benzo(k)fluoranthene 2.4 0.82 48 55 J 0.1 4.1 0.049 5.7 0.02 85-68-7 Benzyl butyl phthalate 92-52-4 Biphenyl 111-91-1 Bis(2-chlorethoxy)methane 111-44-4 Bis(2-chloroethyl)ether 39638-32-9 Bis(2-chloroisopropyl) ether 117-81-7 Bis(2-ethylhexyl)phthalate 75-27-4 Bromodichloromethane 74-83-9 Bromomethane 7440-43-9 Cadmium 86-74-8 Carbazole 75-15-0 Carbon disulfide 56-23-5 Carbon tetrachloride 108-90-7 Chlorobenzene 124-48-1 Chlorodibromomethane 75-00-3 Chloroethane 67-66-3 Chloroform 74-87-3 Chloromethane 7440-47-3 Chromium 100 12 33 8.4 1.2 22.7 11.6 13.7 7 218-01-9 Chrysene 0.95 U 2.2 210 190 0.33 3.6 0.037 3 0.01 U 156-59-2 cis-1,2-Dichloroethylene 10061-01-5 cis-1,3-Dichloropropene
  • 4. APPENDIX A SUMMARY OF SITE SOIL DATA USED IN RISK ASSESSMENT KOPPERS INC. WOOD-TREATING FACILITY GAINESVILLE, FLORIDA Sample ID B1 B3 B-4 B5 DT GA-Soil-001 GA-Soil-004 GA-Soil-005 GA-Soil-011 GA-Soil-033 GA-Soil-034 GA-Soil-035 GA-Soil-036 GA-Soil-037 GA-Soil-038 Sample Date 15-Aug-95 16-Aug-95 17-Aug-95 17-Aug-95 24-Aug-95 11-Aug-98 13-Aug-98 13-Aug-98 13-Aug-98 13-Aug-98 11-Aug-98 11-Aug-98 11-Aug-98 11-Aug-98 11-Aug-98 Sample Depth (feet) 2.5-2.5 2-2 3-3 5-5 0-0.5 0-0.7 0-1 0-1 0-1 0-1 0.5-0.5 0.5-0.5 0.5-0.5 0.5-0.5 0.5-0.5 Concentration Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 7440-50-8 Copper 4.5 1.25 U 47 1.25 U 110-82-7 Cyclohexane 53-70-3 Dibenzo(a,h)anthracene 0.95 U 0.32 J 0.025 U 18 J 0.2 U 2 U 0.02 U 2 U 0.02 U 132-64-9 Dibenzofuran 75-09-2 Dichloromethane 84-66-2 Diethyl phthalate 131-11-3 Dimethyl phthalate 84-74-2 di-n-Butyl-phthalate 117-84-0 di-n-Octyl-phthalate 100-41-4 Ethylbenzene 206-44-0 Fluoranthene 0.95 U 0.54 990 780 1.8 7.6 0.053 8 0.046 86-73-7 Fluorene 0.95 U 0.2 J 480 170 0.2 U 2 U 0.02 U 2 U 0.02 U 87-68-3 Hexachloro-1,3-butadiene 118-74-1 Hexachlorobenzene 77-47-4 Hexachlorocyclopentadiene 67-72-1 Hexachloroethane 193-39-5 Indeno(1,2,3-cd)pyrene 2.4 0.77 41 42 J 0.1 U 5.5 0.073 7.1 0.023 98-82-8 Isopropylbenzene 7439-92-1 Lead 136777-61-2 m,p-Xylenes 541-73-1 m-Dichlorobenzene 7439-97-6 Mercury 79-20-9 Methyl acetate 78-93-3 Methyl ethyl ketone 108-10-1 Methyl isobutyl ketone 591-78-6 Methyl n-butyl ketone 108-88-3 Methylbenzene 108-87-2 Methylcylohexane 91-20-3 Naphthalene 0.95 U 0.19 J 530 62 J 1 U 10 U 0.1 U 10 U 0.1 U 98-95-3 Nitrobenzene 621-64-7 n-Nitroso-di-n-Propylamine 86-30-6 n-Nitrosodiphenylamine 95-47-6 o-Xylene 106-47-8 p-Chloroaniline 87-86-5 Pentachlorophenol 0.95 U 0.11 J 32 50 J 0.003 0.094 0.028 0.7 0.006 85-01-8 Phenanthrene 0.95 U 0.19 2000 620 1.1 2.9 0.018 1.8 0.02 108-95-2 Phenol 100-01-6 p-Nitroaniline 129-00-0 Pyrene 0.95 U 0.56 740 490 1.1 7.3 0.051 8.7 0.042 7782-49-2 Selenium 7440-22-4 Silver 100-42-5 Styrene (monomer) 1634-04-4 tert-Butyl methyl ether 127-18-4 Tetrachloroethylene 156-60-5 trans-1,2-Dichloroethene 10061-02-6 trans-1,2-Dichloropropene 75-25-2 Tribromomethane 79-01-6 Trichloroethylene 7440-62-2 Vanadium 75-01-4 Vinyl chloride 67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 0.0831 0.0324 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 0.272 55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 0.0153 0.00158 70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 0.000267 U 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 0.000772 57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 0.000158 U 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 0.00511 72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 0.000185 U 19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 0.00218 57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 0.0002125 U 40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 0.0002285 U 60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 0.00002725 U 1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 0.0000218 U 39001-02-0 Octachlorodibenzofuran 0.000771 0.264 3268-87-9 Octachlorodibenzo-p-dioxin 0.418 2.92
  • 5. APPENDIX A SUMMARY OF SITE SOIL DATA USED IN RISK ASSESSMENT KOPPERS INC. WOOD-TREATING FACILITY GAINESVILLE, FLORIDA Sample ID NL PA PL SL SS001AA SS001BA SS001CA SS001DA SS002AA SS002AC SS002BA SS003AA Sample Date 24-Aug-95 24-Aug-95 24-Aug-95 24-Aug-95 07-Dec-06 07-Dec-06 07-Dec-06 07-Dec-06 05-Dec-06 05-Dec-06 05-Dec-06 08-Dec-06 Sample Depth (feet) 0-0.5 0-0.5 0-0.5 0-0.5 0-0.25 0.25-0.5 0.5-2 2-6 0-0.25 0-0.25 0.25-0.5 0-0.25 Concentration Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 71-55-6 1,1,1-Trichloroethane 0.00007 U 0.00007 U 0.000075 U 0.000065 U 0.000075 U 0.000075 U 0.00007 U 0.000075 U 79-34-5 1,1,2,2-Tetrachloroethane 0.000036 U 0.0000385 U 0.000041 U 0.0000355 U 0.00004 U 0.0000395 U 0.0000385 U 0.0000395 U 79-00-5 1,1,2-Trichloroethane 0.000075 U 0.00008 U 0.000085 U 0.00007 U 0.00008 U 0.00008 U 0.00008 U 0.00008 U 75-34-3 1,1-Dichloroethane 0.0000345 U 0.0000365 U 0.000039 U 0.0000335 U 0.0000385 U 0.0000375 U 0.0000365 U 0.000038 U 75-35-4 1,1-Dichloroethylene 0.000095 U 0.0001 U 0.00011 U 0.000095 U 0.000105 U 0.000105 U 0.0001 U 0.000105 U 120-82-1 1,2,4-Trichlorobenzene 0.000085 U 0.00009 U 0.000095 U 0.00008 U 0.000095 UJ 0.00009 UJ 0.00009 U 0.00009 U 96-12-8 1,2-Dibromo-3-chloropropane 0.00027 U 0.000285 U 0.000305 U 0.000265 U 0.0003 UJ 0.000295 UJ 0.000285 U 0.000295 U 106-93-4 1,2-Dibromoethane 0.0000305 U 0.0000325 U 0.000035 U 0.00003 U 0.000034 U 0.0000335 U 0.0000325 U 0.0000335 U 95-50-1 1,2-Dichlorobenzene 0.0000425 U 0.0000455 U 0.0000485 U 0.0000415 U 0.0000475 UJ 0.0000465 UJ 0.0000455 U 0.000047 U 107-06-2 1,2-Dichloroethane 0.000055 U 0.00006 U 0.000065 U 0.000055 U 0.000065 U 0.00006 U 0.00006 U 0.00006 U 78-87-5 1,2-Dichloropropane 0.0000295 U 0.0000315 U 0.0000335 U 0.000029 U 0.000033 U 0.0000325 U 0.0000315 U 0.0000325 U 106-46-7 1,4-Dichlorobenzene 0.0000475 U 0.000055 U 0.000055 U 0.0000465 U 0.000055 UJ 0.000055 UJ 0.000055 U 0.000055 U 95-95-4 2,4,5-Trichlorophenol 0.0075 U 0.007 U 0.0085 U 0.007 U 0.0075 U 0.0075 U 0.0075 U 0.008 U 88-06-2 2,4,6-Trichlorophenol 0.02 U 0.0195 U 0.0225 U 0.0195 U 0.02 U 0.02 U 0.02 U 0.0215 U 120-83-2 2,4-Dichlorophenol 0.0095 U 0.0095 U 0.0105 U 0.0095 U 0.0095 U 0.0095 U 0.0095 U 0.0105 U 105-67-9 2,4-Dimethylphenol 0.0105 U 0.0105 U 0.012 U 0.0105 U 0.0105 U 0.011 U 0.0105 U 0.0115 U 51-28-5 2,4-Dinitrophenol 0.007 U 0.0065 U 0.0075 U 0.0065 U 0.007 U 0.007 U 0.007 U 0.0075 U 121-14-2 2,4-Dinitrotoluene 0.0055 U 0.0055 U 0.0065 U 0.0055 U 0.0055 U 0.0055 U 0.0055 U 0.006 U 606-20-2 2,6-Dinitrotoluene 0.02 U 0.0195 U 0.0225 U 0.0195 U 0.02 U 0.02 U 0.02 U 0.0215 U 91-58-7 2-Chloronaphthalene 0.009 U 0.009 U 0.01 U 0.009 U 0.009 U 0.009 U 0.009 U 0.01 U 95-57-8 2-Chlorophenol 0.01 U 0.01 U 0.0115 U 0.01 U 0.01 U 0.01 U 0.01 U 0.011 U 91-57-6 2-Methylnaphthalene 68 J 120 J 10.5 U 9 U 0.0085 U 0.0085 U 0.00095 U 0.0008 U 0.042 J 0.044 J 0.052 J 0.009 U 95-48-7 2-Methylphenol (o-cresol) 0.007 U 0.0065 U 0.0075 U 0.0065 U 0.007 U 0.007 U 0.007 U 0.0075 U 88-74-4 2-Nitroaniline 0.012 UJ 0.012 UJ 0.014 U 0.012 U 0.0125 UJ 0.0125 UJ 0.012 U 0.0135 U 88-75-5 2-Nitrophenol 0.008 U 0.008 U 0.009 U 0.0075 U 0.008 U 0.008 U 0.008 U 0.0085 U 91-94-1 3,3'-Dichlorobenzidine 0.0185 U 0.0185 U 0.021 U 0.0185 U 0.019 UJ 0.019 UJ 0.019 U 0.0205 U 78-59-1 3,5,5-Trimethyl-2-cyclohexene-1-one 0.0075 U 0.007 U 0.0085 U 0.007 U 0.0075 UJ 0.0075 UJ 0.0075 U 0.008 U 99-09-2 3-Nitroaniline 0.0095 U 0.0095 U 0.0105 U 0.0095 U 0.0095 U 0.0095 U 0.0095 U 0.0105 U 534-52-1 4,6-Dinitro-2-Methylphenol 0.0055 U 0.0055 U 0.006 U 0.005 U 0.0055 U 0.0055 U 0.0055 U 0.006 U 101-55-3 4-Bromophenyl phenyl ether 0.0055 U 0.0055 U 0.0065 U 0.0055 U 0.0055 U 0.0055 U 0.0055 U 0.006 U 59-50-7 4-Chloro-3-methylphenol 0.009 U 0.009 U 0.01 U 0.009 U 0.009 U 0.009 U 0.009 U 0.01 U 7005-72-3 4-Chlorophenyl phenyl ether 0.012 U 0.012 U 0.014 U 0.012 U 0.0125 U 0.0125 U 0.012 U 0.0135 U 106-44-5 4-Methylphenol (m/p-cresol) 0.0145 U 0.014 U 0.0165 U 0.014 U 0.0145 U 0.0145 U 0.0145 U 0.0155 U 100-02-7 4-Nitrophenol 0.0095 UJ 0.0095 UJ 0.0105 U 0.0095 U 0.0095 UJ 0.0095 UJ 0.0095 UJ 0.0105 U 83-32-9 Acenaphthene 430 30 J 2.05 U 1.15 0.015 U 0.015 U 0.0017 U 0.00145 U 0.03 U 0.03 U 0.0295 U 0.0165 U 208-96-8 Acenaphthylene 7.6 J 39 U 0.32 J 0.51 J 0.094 0.0145 U 0.00165 U 0.0014 U 0.35 0.37 0.48 0.36 67-64-1 Acetone 0.0014 U 0.00145 U 0.00155 U 0.00135 U 0.00155 U 0.0015 U 0.04 J 0.0015 U 120-12-7 Anthracene 390 64 J 0.91 J 3.1 J 0.13 0.015 J 0.0011 J 0.000325 U 0.78 0.86 1.1 0.3 7440-36-0 Antimony 0.46 J 0.37 J 0.195 U 0.18 U 0.185 UJ 0.39 J 0.37 J 0.195 UJ 7440-38-2 Arsenic 20 99 100 8.6 4.1 J 5.9 J 6.9 6 J 7440-39-3 Barium 13 5.6 5.7 12 11 J 15 J 16 42 71-43-2 Benzene 0.000215 U 0.00023 U 0.000245 U 0.00021 U 0.00024 U 0.000235 U 0.00023 U 0.000235 U 56-55-3 Benzo(a)anthracene 120 98 3.1 J 11 0.89 0.032 J 0.0031 J 0.00085 J 0.68 0.71 0.92 0.18 50-32-8 Benzo(a)pyrene 33 J 28 J 4.2 7.1 0.77 0.041 0.0033 J 0.0006 U 1 1.1 1.4 0.31 205-99-2 Benzo(b)fluoranthene 74 90 10 16 1 0.059 0.0055 0.0018 J 1.8 1.9 2.5 0.47 191-24-2 Benzo(g,h,i)perylene 36 U 16 3.7 J 5.7 0.43 0.033 J 0.003 J 0.00099 J 0.73 0.77 0.95 0.6 207-08-9 Benzo(k)fluoranthene 24 J 30 J 2.6 J 4.1 0.92 0.052 0.0047 0.0014 J 1.3 1.4 1.7 0.36 85-68-7 Benzyl butyl phthalate 0.01 U 0.01 U 0.0115 U 0.01 U 0.01 U 0.01 U 0.01 U 0.011 U 92-52-4 Biphenyl 0.085 U 0.085 U 0.095 U 0.08 U 0.085 U 0.085 U 0.085 U 0.09 U 111-91-1 Bis(2-chlorethoxy)methane 0.0095 U 0.0095 U 0.0105 U 0.0095 U 0.0095 U 0.0095 U 0.0095 U 0.0105 U 111-44-4 Bis(2-chloroethyl)ether 0.0085 U 0.0085 U 0.0095 U 0.008 U 0.0085 U 0.0085 U 0.0085 U 0.009 U 39638-32-9 Bis(2-chloroisopropyl) ether 0.0115 UJ 0.0115 UJ 0.013 UJ 0.0115 UJ 0.012 UJ 0.012 UJ 0.0115 UJ 0.0125 U 117-81-7 Bis(2-ethylhexyl)phthalate 0.009 U 0.009 U 0.01 U 0.009 U 0.009 U 0.02 J 0.029 J 0.01 U 75-27-4 Bromodichloromethane 0.00016 U 0.00017 U 0.00018 U 0.000155 U 0.00018 U 0.000175 U 0.00017 U 0.000175 U 74-83-9 Bromomethane 0.000175 U 0.000185 U 0.0002 U 0.00017 U 0.000195 UJ 0.00019 UJ 0.00019 UJ 0.000195 UJ 7440-43-9 Cadmium 0.145 U 0.15 U 0.17 U 0.155 U 0.16 U 0.16 U 0.15 U 0.17 U 86-74-8 Carbazole 0.032 J 0.009 U 0.01 U 0.009 U 0.075 J 0.08 J 0.13 J 0.03 J 75-15-0 Carbon disulfide 0.0009 U 0.00095 U 0.001 U 0.00085 U 0.001 U 0.00095 U 0.00095 U 0.001 U 56-23-5 Carbon tetrachloride 0.00019 U 0.000205 U 0.00022 U 0.00019 U 0.000215 U 0.00021 U 0.000205 U 0.00021 U 108-90-7 Chlorobenzene 0.00022 U 0.000235 U 0.00025 U 0.000215 U 0.000245 U 0.00024 U 0.000235 U 0.00024 U 124-48-1 Chlorodibromomethane 0.00014 U 0.000145 U 0.000155 U 0.000135 U 0.000155 U 0.00015 U 0.000145 U 0.00015 U 75-00-3 Chloroethane 0.0002 U 0.00021 U 0.000225 U 0.000195 U 0.00022 U 0.000215 U 0.00021 U 0.00022 U 67-66-3 Chloroform 0.000185 U 0.0002 U 0.000215 U 0.000185 U 0.00021 U 0.000205 U 0.0002 U 0.000205 U 74-87-3 Chloromethane 0.000245 U 0.00026 U 0.00028 U 0.00024 U 0.000275 U 0.00027 U 0.000265 U 0.00027 U 7440-47-3 Chromium 6.4 2.8 2.5 7.3 4.5 J 6.7 J 6.4 13 J 218-01-9 Chrysene 120 120 5.4 13 1.2 0.046 0.0045 0.0015 J 1 1.1 1.3 0.24 156-59-2 cis-1,2-Dichloroethylene 0.000145 U 0.000155 U 0.000165 U 0.00014 U 0.00016 U 0.000155 U 0.000155 U 0.00016 U 10061-01-5 cis-1,3-Dichloropropene 0.00016 U 0.00017 U 0.00018 U 0.000155 U 0.00018 U 0.000175 U 0.00017 U 0.000175 U
  • 6. APPENDIX A SUMMARY OF SITE SOIL DATA USED IN RISK ASSESSMENT KOPPERS INC. WOOD-TREATING FACILITY GAINESVILLE, FLORIDA Sample ID NL PA PL SL SS001AA SS001BA SS001CA SS001DA SS002AA SS002AC SS002BA SS003AA Sample Date 24-Aug-95 24-Aug-95 24-Aug-95 24-Aug-95 07-Dec-06 07-Dec-06 07-Dec-06 07-Dec-06 05-Dec-06 05-Dec-06 05-Dec-06 08-Dec-06 Sample Depth (feet) 0-0.5 0-0.5 0-0.5 0-0.5 0-0.25 0.25-0.5 0.5-2 2-6 0-0.25 0-0.25 0.25-0.5 0-0.25 Concentration Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 7440-50-8 Copper 6.8 1.6 0.175 U 0.38 J 5.1 J 7.3 J 7.6 9.1 J 110-82-7 Cyclohexane 0.00021 U 0.00022 U 0.000235 U 0.000205 U 0.00023 U 0.00023 U 0.00022 U 0.00023 U 53-70-3 Dibenzo(a,h)anthracene 36 U 39 U 1.4 J 1.6 J 0.15 0.0083 J 0.00032 U 0.000275 U 0.23 0.25 0.32 0.11 132-64-9 Dibenzofuran 0.0075 U 0.007 U 0.0085 U 0.007 U 0.02 J 0.023 J 0.03 J 0.008 U 75-09-2 Dichloromethane 0.000215 U 0.00023 U 0.000245 U 0.00021 U 0.00024 U 0.000235 U 0.00023 U 0.000235 U 84-66-2 Diethyl phthalate 0.007 U 0.0065 U 0.0075 U 0.0065 U 0.007 U 0.007 U 0.007 U 0.0075 U 131-11-3 Dimethyl phthalate 0.0055 U 0.0055 U 0.0065 U 0.0055 U 0.0055 U 0.0055 U 0.0055 U 0.006 U 84-74-2 di-n-Butyl-phthalate 0.0335 U 0.033 U 0.038 U 0.0325 U 0.034 U 0.034 U 0.0335 U 0.0365 U 117-84-0 di-n-Octyl-phthalate 0.0085 U 0.0085 U 0.0095 U 0.008 U 0.0085 U 0.0085 U 0.0085 U 0.009 U 100-41-4 Ethylbenzene 0.00023 U 0.000245 U 0.00026 U 0.000225 U 0.000255 U 0.00025 U 0.000245 U 0.000255 U 206-44-0 Fluoranthene 620 600 6.4 28 1.1 0.06 0.0059 0.000315 U 0.7 0.73 0.91 0.22 86-73-7 Fluorene 450 34 J 2.05 U 1.05 0.0085 U 0.0085 U 0.00095 U 0.0008 U 0.0165 U 0.017 U 0.038 J 0.022 J 87-68-3 Hexachloro-1,3-butadiene 0.0095 U 0.0095 U 0.0105 U 0.0095 U 0.0095 U 0.0095 U 0.0095 U 0.0105 U 118-74-1 Hexachlorobenzene 0.00455 U 0.0045 U 0.0055 U 0.00445 U 0.0046 U 0.00465 U 0.00455 U 0.00495 U 77-47-4 Hexachlorocyclopentadiene 0.006 U 0.006 U 0.007 U 0.006 U 0.0065 U 0.0065 U 0.006 U 0.007 U 67-72-1 Hexachloroethane 0.0095 U 0.0095 U 0.0105 U 0.0095 U 0.0095 U 0.0095 U 0.0095 U 0.0105 U 193-39-5 Indeno(1,2,3-cd)pyrene 36 U 17 J 3.5 J 4.8 0.53 0.035 J 0.0034 J 0.0011 J 0.96 1 1.3 0.43 98-82-8 Isopropylbenzene 0.00025 U 0.00027 U 0.000285 U 0.000245 U 0.00028 UJ 0.000275 UJ 0.00027 U 0.00028 U 7439-92-1 Lead 35 J 12 J 2.6 J 6.8 J 18 J 25 J 27 6.9 J 136777-61-2 m,p-Xylenes 0.000475 U 0.00055 U 0.00055 U 0.000465 U 0.00055 U 0.00055 U 0.00055 U 0.00055 U 541-73-1 m-Dichlorobenzene 0.0000275 U 0.000029 U 0.000031 U 0.000027 U 0.0000305 UJ 0.00003 UJ 0.000029 U 0.00003 U 7439-97-6 Mercury 0.12 0.029 0.026 J 0.027 0.41 0.32 0.46 0.039 J 79-20-9 Methyl acetate 0.000105 U 0.00011 U 0.00012 U 0.000105 U 0.0021 J 0.000115 U 0.00011 U 0.000115 U 78-93-3 Methyl ethyl ketone 0.0006 U 0.00065 U 0.0007 U 0.0006 U 0.0007 U 0.0007 U 0.0022 J 0.0007 U 108-10-1 Methyl isobutyl ketone 0.000385 U 0.000415 U 0.00044 U 0.00038 U 0.00043 U 0.000425 U 0.000415 U 0.000425 U 591-78-6 Methyl n-butyl ketone 0.00055 U 0.0006 U 0.00065 U 0.00055 U 0.00065 U 0.0006 U 0.0006 U 0.0006 UJ 108-88-3 Methylbenzene 0.00023 U 0.000245 U 0.00026 U 0.000225 U 0.000255 U 0.00025 U 0.00062 J 0.000255 U 108-87-2 Methylcylohexane 0.00024 U 0.000255 U 0.000275 U 0.000235 U 0.00027 U 0.000265 U 0.000255 UJ 0.000265 U 91-20-3 Naphthalene 250 39 U 2.05 U 0.35 J 0.0028 U 0.0028 U 0.00032 U 0.000275 U 0.07 J 0.075 J 0.092 0.018 J 98-95-3 Nitrobenzene 0.011 UJ 0.011 UJ 0.0125 U 0.011 U 0.011 U 0.0115 U 0.011 U 0.012 U 621-64-7 n-Nitroso-di-n-Propylamine 0.01 U 0.01 U 0.0115 U 0.01 U 0.01 UJ 0.01 UJ 0.01 U 0.011 U 86-30-6 n-Nitrosodiphenylamine 0.006 U 0.006 U 0.007 U 0.006 U 0.0065 U 0.0065 U 0.006 U 0.007 U 95-47-6 o-Xylene 0.00022 U 0.000235 U 0.00025 U 0.000215 U 0.000245 U 0.00024 U 0.000235 U 0.00024 U 106-47-8 p-Chloroaniline 0.0145 U 0.014 U 0.0165 U 0.014 U 0.0145 U 0.0145 U 0.0145 U 0.0155 UJ 87-86-5 Pentachlorophenol 240 39 U 2.05 U 1.75 U 0.12 J 0.11 J 0.000435 U 0.000375 U 0.15 0.17 J 0.21 J 0.15 J 85-01-8 Phenanthrene 830 550 0.59 J 6.6 0.2 0.018 U 0.00205 U 0.0018 U 0.14 J 0.15 J 0.19 0.059 J 108-95-2 Phenol 0.009 U 0.009 U 0.01 U 0.009 U 0.009 U 0.009 U 0.009 U 0.01 U 100-01-6 p-Nitroaniline 0.007 U 0.0065 U 0.0075 U 0.0065 U 0.007 U 0.007 U 0.007 U 0.0075 U 129-00-0 Pyrene 400 370 8.7 27 1 0.056 0.0054 0.0021 J 1.1 1.1 1.4 0.28 7782-49-2 Selenium 0.425 U 0.435 U 0.485 U 0.445 U 0.46 U 0.46 U 0.425 U 0.485 U 7440-22-4 Silver 0.195 U 0.195 U 0.22 U 0.2 U 0.205 U 0.21 U 0.195 U 0.22 U 100-42-5 Styrene (monomer) 0.000235 U 0.00025 U 0.00027 U 0.00023 U 0.00026 U 0.000255 U 0.00025 U 0.00026 U 1634-04-4 tert-Butyl methyl ether 0.000175 U 0.000185 U 0.0002 U 0.00017 U 0.000195 U 0.00019 U 0.00019 U 0.000195 U 127-18-4 Tetrachloroethylene 0.00022 U 0.000235 U 0.00025 U 0.000215 U 0.000245 U 0.00024 U 0.000235 U 0.00024 U 156-60-5 trans-1,2-Dichloroethene 0.00021 U 0.00022 U 0.000235 U 0.000205 U 0.00023 U 0.00023 U 0.00022 U 0.00023 U 10061-02-6 trans-1,2-Dichloropropene 0.000165 U 0.000175 U 0.00019 U 0.00016 U 0.000185 U 0.00018 U 0.000175 U 0.00018 U 75-25-2 Tribromomethane 0.000215 U 0.00023 U 0.000245 U 0.00021 U 0.00024 U 0.000235 U 0.00023 U 0.000235 U 79-01-6 Trichloroethylene 0.00022 U 0.000235 U 0.00025 U 0.000215 U 0.000245 U 0.00024 U 0.000235 U 0.00024 U 7440-62-2 Vanadium 4.2 1.7 0.5 UJ 4 1.6 J 2.3 J 2.5 18 75-01-4 Vinyl chloride 0.000135 U 0.00014 U 0.00015 U 0.00013 U 0.000145 U 0.000145 U 0.00014 U 0.000145 U 67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 0.0125 0.0661 0.00003695 U 0.000756 0.000095769 0.000017532 0.000003269 J 0.000004166 J 0.000552 0.000516 0.000251552 0.000865786 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 0.142 0.45 0.0115 0.0123 0.000746826 0.000192404 0.000026107 0.000028925 0.00555 0.00533 0.002877368 J 0.010366933 55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 0.00148 0.00285 0.00008 U 0.0000715 U 0.000006065 0.00000128 J 0.000000205 J 0.000000245 J 0.0000333 0.000032 0.000018079 0.000051434 70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 0.0002695 U 0.0001395 U 0.0002805 U 0.00025 U 0.000002742 J 0.000001434 J 0.000000058 U 3.15E-08 U 0.0000112 0.0000105 0.000005384 J 0.000013745 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 0.000209 U 0.00146 0.0002175 U 0.000194 U 0.00000618 0.000001058 J 0.000000202 J 0.000000051 U 0.000026 0.0000255 0.000010005 0.000037265 57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 0.0001595 U 0.0001095 U 0.000166 U 0.000148 U 0.000002384 J 0.00000075 J 0.000000033 U 0.000000036 U 0.00000697 0.00000593 0.000002665 J 0.000006566 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 0.0015 0.011 0.00028 0.0001175 U 0.00001672 0.000004784 J 0.000000684 J 0.000001058 J 0.0000947 0.0000962 0.000051217 0.000164222 72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 0.000187 U 0.000141 U 0.0001945 U 0.0001735 U 5.15E-08 U 0.000000095 U 4.25E-08 U 4.55E-08 U 0.00000259 0.00000233 J 1.605E-07 U 0.000000215 U 19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 0.000943 0.00892 0.000377 0.000112 U 0.000015977 0.000003758 J 0.000000648 J 0.000000517 J 0.0000443 0.0000419 0.000012274 0.000159479 57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 0.0002145 U 0.000046 U 0.000223 U 0.000199 U 0.000000312 J 0.00000037 J 1.75E-08 U 1.25E-08 U 0.000000925 J 0.00000082 J 0.000000545 J 2.625E-07 U 40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 0.000231 U 0.0000655 U 0.00024 U 0.000214 U 0.000002012 J 0.000000548 J 0.00000002 U 0.000000022 U 0.00000801 0.00000792 0.000004292 J 0.000005989 J 60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 0.000001688 J 0.000000754 J 3.25E-08 U 3.65E-08 U 0.0000116 0.0000108 0.000002355 J 0.000008114 J 57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 0.00000068 J 0.00000071 J 1.85E-08 U 0.000000014 U 0.00000276 0.00000265 0.000000812 J 0.000000713 J 51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 0.0000275 U 0.00003615 U 0.0000286 U 0.0000255 U 4.325E-07 U 0.000000594 U 0.000000019 U 2.65E-08 U 0.0000013 0.00000135 0.000000535 U 2.745E-07 U 1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 0.000022 U 0.000044 U 0.0000229 U 0.0000204 U 0.000000099 U 0.000000034 U 1.15E-08 U 0.000000013 U 0.00000108 0.00000111 0.00000032 U 0.000000394 J 39001-02-0 Octachlorodibenzofuran 0.0795 0.0002805 U 0.00551 0.00632 0.000458957 0.000082162 0.000014049 0.0000232 0.00321 0.00307 0.001968873 0.00556771 3268-87-9 Octachlorodibenzo-p-dioxin 0.933 8.2 0.108 0.118 0.006956787 J 0.001730716 0.000240163 0.000316932 0.053 0.0519 0.028365185 J 0.087059257 J
  • 7. APPENDIX A SUMMARY OF SITE SOIL DATA USED IN RISK ASSESSMENT KOPPERS INC. WOOD-TREATING FACILITY GAINESVILLE, FLORIDA Sample ID SS003BA SS003CA SS003CB SS003DA SS004AA SS004BA SS004BB SS005AA SS005BA SS005CA SS005DA SS006AA Sample Date 08-Dec-06 08-Dec-06 08-Dec-06 08-Dec-06 05-Dec-06 05-Dec-06 05-Dec-06 08-Dec-06 08-Dec-06 08-Dec-06 08-Dec-06 05-Dec-06 Sample Depth (feet) 0.25-0.5 0.5-2 0.5-2 2-6 0-0.25 0.25-0.5 0.25-0.5 0-0.25 0.25-0.5 0.5-2 2-6 0-0.25 Concentration Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 71-55-6 1,1,1-Trichloroethane 0.0001 U 0.00007 U 0.00007 U 0.000065 U 0.00012 U 0.000085 U 0.0001 U 0.00007 U 0.00007 U 0.00008 U 0.000075 U 0.000065 U 79-34-5 1,1,2,2-Tetrachloroethane 0.000055 U 0.000036 U 0.000038 U 0.000035 U 0.000065 U 0.000047 U 0.000055 U 0.0000365 U 0.000037 U 0.0000435 U 0.000039 U 0.0000355 U 79-00-5 1,1,2-Trichloroethane 0.00011 U 0.000075 U 0.000075 U 0.00007 U 0.000125 U 0.000095 U 0.00011 U 0.000075 U 0.000075 U 0.00009 U 0.00008 U 0.00007 U 75-34-3 1,1-Dichloroethane 0.000055 U 0.0000345 U 0.000036 U 0.0000335 U 0.000065 U 0.0000445 U 0.000055 U 0.0000345 U 0.0000355 U 0.0000415 U 0.0000375 U 0.000034 U 75-35-4 1,1-Dichloroethylene 0.000145 U 0.000095 U 0.0001 U 0.000095 U 0.000165 U 0.000125 U 0.00014 U 0.000095 U 0.000095 U 0.000115 U 0.000105 U 0.000095 U 120-82-1 1,2,4-Trichlorobenzene 0.000125 U 0.000085 U 0.00009 U 0.00008 U 0.000145 U 0.00011 U 0.000125 U 0.000085 U 0.000085 U 0.0001 U 0.00009 U 0.000085 U 96-12-8 1,2-Dibromo-3-chloropropane 0.00041 U 0.00027 U 0.00028 U 0.00026 U 0.000475 U 0.00035 U 0.0004 U 0.00027 U 0.000275 U 0.000325 U 0.00029 U 0.000265 U 106-93-4 1,2-Dibromoethane 0.000047 U 0.0000305 U 0.000032 U 0.00003 U 0.000055 U 0.00004 U 0.000046 U 0.000031 U 0.0000315 U 0.000037 U 0.000033 U 0.0000305 U 95-50-1 1,2-Dichlorobenzene 0.000065 U 0.0000425 U 0.0000445 U 0.0000415 U 0.000075 U 0.00006 U 0.000065 U 0.000043 U 0.0000435 U 0.000055 U 0.000046 U 0.000042 U 107-06-2 1,2-Dichloroethane 0.000085 U 0.000055 U 0.00006 U 0.000055 U 0.0001 U 0.000075 U 0.000085 U 0.000055 U 0.00006 U 0.00007 U 0.00006 U 0.000055 U 78-87-5 1,2-Dichloropropane 0.000045 U 0.0000295 U 0.000031 U 0.000029 U 0.000055 U 0.0000385 U 0.000044 U 0.00003 U 0.0000305 U 0.0000355 U 0.000032 U 0.0000295 U 106-46-7 1,4-Dichlorobenzene 0.000075 U 0.0000475 U 0.0000495 U 0.0000465 U 0.000085 U 0.000065 U 0.000075 U 0.000048 U 0.0000485 U 0.00006 U 0.000055 U 0.000047 U 95-95-4 2,4,5-Trichlorophenol 0.0085 U 0.0075 U 0.007 U 0.007 U 0.0085 U 0.0085 U 0.009 U 0.0075 U 0.0075 U 0.007 U 0.008 U 0.007 U 88-06-2 2,4,6-Trichlorophenol 0.0225 U 0.02 U 0.0195 U 0.0195 U 0.0235 U 0.023 U 0.024 U 0.02 U 0.02 U 0.0195 U 0.0215 U 0.0195 U 120-83-2 2,4-Dichlorophenol 0.011 U 0.0095 U 0.0095 U 0.0095 U 0.011 U 0.011 U 0.0115 U 0.0095 U 0.0095 U 0.0095 U 0.01 U 0.0095 U 105-67-9 2,4-Dimethylphenol 0.012 U 0.0105 U 0.0105 U 0.0105 U 0.0125 U 0.0125 U 0.0125 U 0.0105 U 0.032 J 0.0105 U 0.0115 U 0.0105 U 51-28-5 2,4-Dinitrophenol 0.0075 U 0.007 U 0.0065 U 0.0065 U 0.008 U 0.008 U 0.008 U 0.007 U 0.007 U 0.0065 U 0.0075 U 0.0065 U 121-14-2 2,4-Dinitrotoluene 0.0065 U 0.0055 U 0.0055 U 0.0055 U 0.0065 U 0.0065 U 0.0065 U 0.0055 U 0.0055 U 0.0055 U 0.006 U 0.0055 U 606-20-2 2,6-Dinitrotoluene 0.0225 U 0.02 U 0.0195 U 0.0195 U 0.0235 U 0.023 U 0.024 U 0.02 U 0.02 U 0.0195 U 0.0215 U 0.0195 U 91-58-7 2-Chloronaphthalene 0.01 U 0.009 U 0.009 U 0.009 U 0.0105 U 0.0105 U 0.0105 U 0.009 U 0.009 U 0.009 U 0.0095 U 0.009 U 95-57-8 2-Chlorophenol 0.0115 U 0.01 U 0.01 U 0.01 U 0.012 U 0.0115 U 0.012 U 0.01 U 0.01 U 0.01 U 0.011 U 0.01 U 91-57-6 2-Methylnaphthalene 0.085 0.038 0.049 0.0045 0.076 J 0.067 J 0.099 J 0.03 J 0.66 0.11 0.013 0.099 95-48-7 2-Methylphenol (o-cresol) 0.0075 U 0.007 U 0.0065 U 0.0065 U 0.008 U 0.008 U 0.008 U 0.007 U 0.007 U 0.0065 U 0.0075 U 0.0065 U 88-74-4 2-Nitroaniline 0.014 U 0.012 U 0.012 U 0.012 U 0.0145 UJ 0.014 UJ 0.0145 UJ 0.0125 U 0.0125 U 0.012 U 0.013 U 0.012 UJ 88-75-5 2-Nitrophenol 0.009 U 0.008 U 0.008 U 0.0075 U 0.009 U 0.009 U 0.0095 U 0.008 U 0.008 U 0.008 U 0.0085 U 0.0075 U 91-94-1 3,3'-Dichlorobenzidine 0.0215 U 0.0185 U 0.0185 U 0.0185 U 0.022 UJ 0.022 UJ 0.0225 UJ 0.019 U 0.019 U 0.0185 U 0.02 U 0.0185 UJ 78-59-1 3,5,5-Trimethyl-2-cyclohexene-1-one 0.0085 U 0.0075 U 0.007 U 0.007 U 0.0085 UJ 0.0085 UJ 0.009 UJ 0.0075 U 0.0075 U 0.007 U 0.008 U 0.007 UJ 99-09-2 3-Nitroaniline 0.011 U 0.0095 U 0.0095 U 0.0095 U 0.011 U 0.011 U 0.0115 U 0.0095 U 0.0095 U 0.0095 U 0.01 U 0.0095 U 534-52-1 4,6-Dinitro-2-Methylphenol 0.006 U 0.0055 U 0.0055 U 0.005 U 0.0065 U 0.006 U 0.0065 U 0.0055 U 0.0055 U 0.0055 U 0.006 U 0.0055 U 101-55-3 4-Bromophenyl phenyl ether 0.0065 U 0.0055 U 0.0055 U 0.0055 U 0.0065 U 0.0065 U 0.0065 U 0.0055 U 0.0055 U 0.0055 U 0.006 U 0.0055 U 59-50-7 4-Chloro-3-methylphenol 0.01 U 0.009 U 0.009 U 0.009 U 0.0105 U 0.0105 U 0.0105 U 0.009 U 0.009 U 0.009 U 0.0095 U 0.009 U 7005-72-3 4-Chlorophenyl phenyl ether 0.014 U 0.012 U 0.012 U 0.012 U 0.0145 U 0.014 U 0.0145 U 0.0125 U 0.0125 U 0.012 U 0.013 U 0.012 U 106-44-5 4-Methylphenol (m/p-cresol) 0.0165 U 0.0145 U 0.014 U 0.014 U 0.017 U 0.017 U 0.0175 U 0.0145 U 0.0145 U 0.014 U 0.0155 U 0.014 U 100-02-7 4-Nitrophenol 0.011 U 0.0095 U 0.0095 U 0.0095 U 0.011 UJ 0.011 UJ 0.0115 UJ 0.0095 U 0.0095 U 0.0095 U 0.01 U 0.0095 UJ 83-32-9 Acenaphthene 0.062 J 0.015 U 0.015 U 0.0041 J 0.035 U 0.039 J 0.0355 U 0.015 U 0.58 0.14 0.01 0.064 J 208-96-8 Acenaphthylene 0.91 0.075 J 0.051 J 0.016 0.64 0.46 J 0.72 J 0.33 1.9 0.34 0.06 0.9 67-64-1 Acetone 0.0021 U 0.0014 U 0.00145 U 0.00135 U 0.00245 U 0.0018 U 0.00205 U 0.0014 U 0.0014 U 0.00165 U 0.0015 U 0.00135 U 120-12-7 Anthracene 1.8 0.2 J 0.11 J 0.023 0.76 0.52 J 0.84 J 0.37 6.4 0.34 0.13 1.8 7440-36-0 Antimony 0.205 UJ 0.17 UJ 0.18 UJ 0.17 UJ 0.215 UJ 0.215 UJ 0.215 UJ 0.17 U 0.185 U 0.175 UJ 0.185 UJ 0.18 UJ 7440-38-2 Arsenic 22 J 19 J 14 J 5.4 J 5.8 4.8 5.1 5 J 12 J 4.3 J 14 J 17 7440-39-3 Barium 51 12 11 8.1 30 33 31 16 32 23 12 18 71-43-2 Benzene 0.000325 U 0.000215 U 0.000225 U 0.00021 U 0.000375 U 0.00028 U 0.00032 U 0.000215 U 0.00022 U 0.00026 U 0.00023 U 0.00021 U 56-55-3 Benzo(a)anthracene 2.8 0.41 J 0.15 J 0.02 0.73 0.71 J 1.1 J 0.71 5.6 0.57 0.088 1 50-32-8 Benzo(a)pyrene 6.1 0.36 J 0.2 J 0.037 1.2 0.93 J 1.4 J 0.69 6.5 0.66 0.13 1.3 205-99-2 Benzo(b)fluoranthene 12 0.63 J 0.36 J 0.075 1.9 1.5 J 2.2 J 1.4 13 0.84 0.26 2.5 191-24-2 Benzo(g,h,i)perylene 2.9 0.21 0.16 0.049 1.2 0.88 J 1.4 J 0.75 5.5 0.39 0.11 1.8 207-08-9 Benzo(k)fluoranthene 5.9 0.52 J 0.25 J 0.033 1.5 1.1 J 1.7 J 0.81 6.5 0.68 0.12 1.6 85-68-7 Benzyl butyl phthalate 0.0115 U 0.01 U 0.01 U 0.01 U 0.012 U 0.0115 U 0.012 U 0.01 U 0.01 U 0.01 U 0.011 U 0.01 U 92-52-4 Biphenyl 0.095 U 0.085 U 0.085 U 0.08 U 0.1 U 0.1 U 0.1 U 0.085 U 0.085 U 0.085 U 0.09 U 0.085 U 111-91-1 Bis(2-chlorethoxy)methane 0.011 U 0.0095 U 0.0095 U 0.0095 U 0.011 U 0.011 U 0.0115 U 0.0095 U 0.0095 U 0.0095 U 0.01 U 0.0095 U 111-44-4 Bis(2-chloroethyl)ether 0.0095 U 0.0085 U 0.0085 U 0.008 U 0.01 U 0.01 U 0.01 U 0.0085 U 0.0085 UJ 0.0085 U 0.009 U 0.0085 U 39638-32-9 Bis(2-chloroisopropyl) ether 0.0135 U 0.0115 U 0.0115 U 0.0115 U 0.0135 UJ 0.0135 UJ 0.014 UJ 0.012 U 0.012 U 0.0115 U 0.0125 U 0.0115 UJ 117-81-7 Bis(2-ethylhexyl)phthalate 0.03 J 0.009 U 0.009 U 0.009 U 0.0105 U 0.0105 U 0.0105 U 0.24 0.094 J 0.05 J 0.0095 U 0.021 J 75-27-4 Bromodichloromethane 0.000245 U 0.00016 U 0.000165 U 0.000155 U 0.00028 U 0.000205 U 0.00024 U 0.00016 U 0.000165 U 0.00019 U 0.000175 U 0.00016 U 74-83-9 Bromomethane 0.00027 UJ 0.000175 UJ 0.000185 UJ 0.00017 UJ 0.00031 UJ 0.00023 UJ 0.000265 UJ 0.00018 UJ 0.00018 UJ 0.00021 UJ 0.00019 UJ 0.000175 UJ 7440-43-9 Cadmium 0.175 U 0.145 U 0.15 U 0.145 U 0.185 U 0.18 U 0.185 U 0.145 U 0.16 U 0.15 U 0.155 U 0.155 U 86-74-8 Carbazole 0.54 0.042 J 0.034 J 0.009 U 0.044 J 0.043 J 0.05 J 0.06 J 0.57 0.047 J 0.0095 U 0.22 75-15-0 Carbon disulfide 0.00135 U 0.0009 U 0.00095 U 0.00085 U 0.00155 U 0.00115 U 0.00135 U 0.0009 U 0.0009 U 0.00105 U 0.00095 U 0.0009 U 56-23-5 Carbon tetrachloride 0.000295 U 0.000195 U 0.0002 U 0.00019 U 0.00034 U 0.00025 U 0.000285 U 0.000195 U 0.000195 U 0.00023 U 0.00021 U 0.00019 U 108-90-7 Chlorobenzene 0.000335 U 0.00022 U 0.00023 U 0.000215 U 0.000385 U 0.000285 U 0.00033 U 0.00022 U 0.000225 U 0.000265 U 0.00024 U 0.000215 U 124-48-1 Chlorodibromomethane 0.00021 U 0.00014 U 0.000145 U 0.000135 U 0.000245 U 0.00018 U 0.000205 U 0.00014 U 0.00014 U 0.000165 U 0.00015 U 0.000135 U 75-00-3 Chloroethane 0.0003 U 0.0002 U 0.000205 U 0.000195 U 0.00035 U 0.000255 U 0.000295 U 0.0002 U 0.000205 U 0.00024 U 0.000215 U 0.000195 U 67-66-3 Chloroform 0.000285 U 0.000185 U 0.000195 U 0.000185 U 0.00033 U 0.000245 U 0.00028 U 0.00019 U 0.00019 U 0.000225 U 0.000205 U 0.000185 U 74-87-3 Chloromethane 0.000375 U 0.000245 U 0.00026 U 0.00024 U 0.000435 U 0.00032 U 0.00037 U 0.00025 U 0.000255 U 0.000295 U 0.00027 U 0.000245 U 7440-47-3 Chromium 10 J 3.4 J 3.6 J 3.9 J 16 14 15 11 J 12 J 9.8 J 5.6 J 20 218-01-9 Chrysene 4.9 0.59 J 0.25 J 0.03 0.9 0.88 J 1.2 J 0.9 7.2 0.7 0.11 1.3 156-59-2 cis-1,2-Dichloroethylene 0.00022 U 0.000145 U 0.00015 U 0.00014 U 0.00025 U 0.000185 U 0.000215 U 0.000145 U 0.000145 U 0.000175 U 0.000155 U 0.00014 U 10061-01-5 cis-1,3-Dichloropropene 0.000245 U 0.00016 U 0.000165 U 0.000155 U 0.00028 U 0.000205 U 0.00024 U 0.00016 U 0.000165 U 0.00019 U 0.000175 U 0.00016 U
  • 8. APPENDIX A SUMMARY OF SITE SOIL DATA USED IN RISK ASSESSMENT KOPPERS INC. WOOD-TREATING FACILITY GAINESVILLE, FLORIDA Sample ID SS003BA SS003CA SS003CB SS003DA SS004AA SS004BA SS004BB SS005AA SS005BA SS005CA SS005DA SS006AA Sample Date 08-Dec-06 08-Dec-06 08-Dec-06 08-Dec-06 05-Dec-06 05-Dec-06 05-Dec-06 08-Dec-06 08-Dec-06 08-Dec-06 08-Dec-06 05-Dec-06 Sample Depth (feet) 0.25-0.5 0.5-2 0.5-2 2-6 0-0.25 0.25-0.5 0.25-0.5 0-0.25 0.25-0.5 0.5-2 2-6 0-0.25 Concentration Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 7440-50-8 Copper 13 J 2.1 J 2.1 J 1.1 J 11 9.1 9.8 6.7 J 14 J 5.8 J 1.6 J 18 110-82-7 Cyclohexane 0.00069 J 0.00021 U 0.00022 U 0.000205 U 0.00037 U 0.00027 U 0.00031 U 0.00021 U 0.000215 U 0.00025 U 0.000225 U 0.000205 U 53-70-3 Dibenzo(a,h)anthracene 1.2 0.074 J 0.043 J 0.013 0.31 0.22 J 0.35 J 0.21 1.2 0.24 0.037 0.49 132-64-9 Dibenzofuran 0.21 J 0.022 J 0.024 J 0.007 U 0.048 J 0.053 J 0.089 J 0.032 J 0.88 0.029 J 0.008 U 0.11 J 75-09-2 Dichloromethane 0.000325 U 0.000215 U 0.000225 U 0.00021 U 0.000375 U 0.00028 U 0.00032 U 0.000215 U 0.00022 U 0.00026 U 0.00023 U 0.00021 U 84-66-2 Diethyl phthalate 0.0075 U 0.007 U 0.0065 U 0.0065 U 0.008 U 0.008 U 0.008 U 0.007 U 0.007 U 0.0065 U 0.0075 U 0.0065 U 131-11-3 Dimethyl phthalate 0.0065 U 0.0055 U 0.0055 U 0.0055 U 0.0065 U 0.0065 U 0.0065 U 0.0055 U 0.0055 U 0.0055 U 0.006 U 0.0055 U 84-74-2 di-n-Butyl-phthalate 0.0385 U 0.0335 U 0.033 U 0.0325 U 0.0395 U 0.039 U 0.04 U 0.034 U 0.034 U 0.033 U 0.036 U 0.033 U 117-84-0 di-n-Octyl-phthalate 0.0095 U 0.0085 U 0.0085 U 0.008 U 0.01 U 0.01 U 0.01 U 0.0085 U 0.0085 U 0.0085 U 0.009 U 0.0085 U 100-41-4 Ethylbenzene 0.00035 U 0.00023 U 0.00024 U 0.000225 U 0.000405 U 0.0003 U 0.000345 U 0.00023 U 0.000235 U 0.00028 U 0.00025 U 0.00023 U 206-44-0 Fluoranthene 6.5 0.94 J 0.34 J 0.036 1.1 0.94 J 1.7 J 1 12 1.1 0.15 1.7 86-73-7 Fluorene 0.089 0.023 J 0.0085 U 0.0065 0.055 J 0.029 J 0.066 J 0.027 J 0.56 0.17 0.01 0.074 87-68-3 Hexachloro-1,3-butadiene 0.011 U 0.0095 U 0.0095 U 0.0095 U 0.011 U 0.011 U 0.0115 U 0.0095 U 0.0095 U 0.0095 U 0.01 U 0.0095 U 118-74-1 Hexachlorobenzene 0.0055 U 0.00455 U 0.0045 U 0.00445 U 0.0055 U 0.0055 U 0.0055 U 0.0046 U 0.00465 U 0.0045 U 0.0049 U 0.00445 U 77-47-4 Hexachlorocyclopentadiene 0.007 U 0.006 U 0.006 U 0.006 U 0.0075 U 0.007 U 0.0075 U 0.0065 U 0.0065 UJ 0.006 U 0.0065 U 0.006 U 67-72-1 Hexachloroethane 0.011 U 0.0095 U 0.0095 U 0.0095 U 0.011 U 0.011 U 0.0115 U 0.0095 U 0.0095 U 0.0095 U 0.01 U 0.0095 U 193-39-5 Indeno(1,2,3-cd)pyrene 5.2 0.25 J 0.18 J 0.039 1.4 0.99 J 1.6 J 0.55 5.5 0.49 0.11 2.1 98-82-8 Isopropylbenzene 0.000385 U 0.000255 U 0.000265 U 0.000245 U 0.000445 U 0.000325 U 0.000375 U 0.000255 U 0.00026 U 0.000305 U 0.000275 U 0.00025 U 7439-92-1 Lead 13 J 6.3 J 5.1 J 3.1 J 14 13 14 14 J 37 J 13 J 5.5 J 16 136777-61-2 m,p-Xylenes 0.00075 U 0.000475 U 0.000495 U 0.000465 U 0.00085 U 0.00065 U 0.00075 U 0.00048 U 0.000485 U 0.0006 U 0.00055 U 0.00047 U 541-73-1 m-Dichlorobenzene 0.000042 U 0.0000275 U 0.0000285 U 0.0000265 U 0.0000485 U 0.0000355 U 0.000041 U 0.0000275 U 0.000028 U 0.000033 U 0.0000295 U 0.000027 U 7439-97-6 Mercury 0.25 J 0.024 J 0.022 J 0.015 J 0.2 0.2 0.27 0.066 J 0.32 J 0.069 J 0.049 J 0.095 79-20-9 Methyl acetate 0.00016 U 0.000105 U 0.00011 U 0.000105 U 0.000185 U 0.000135 U 0.000155 U 0.000105 U 0.00011 U 0.000125 U 0.000115 U 0.000105 U 78-93-3 Methyl ethyl ketone 0.0024 J 0.0006 U 0.00065 U 0.0006 U 0.0011 U 0.0008 U 0.0009 U 0.00065 U 0.00065 U 0.00075 U 0.00065 U 0.0006 U 108-10-1 Methyl isobutyl ketone 0.0006 U 0.00039 U 0.000405 U 0.00038 U 0.0007 U 0.00055 U 0.0006 U 0.00039 U 0.0004 U 0.00047 U 0.00042 U 0.000385 U 591-78-6 Methyl n-butyl ketone 0.00085 UJ 0.00055 UJ 0.0006 UJ 0.00055 UJ 0.001 U 0.00075 U 0.00085 U 0.00055 UJ 0.0006 UJ 0.0007 UJ 0.0006 UJ 0.00055 U 108-88-3 Methylbenzene 0.0029 J 0.00023 U 0.00024 U 0.000225 U 0.000405 U 0.0003 U 0.000345 U 0.00023 U 0.000235 U 0.00028 U 0.00025 U 0.00023 U 108-87-2 Methylcylohexane 0.0015 J 0.00024 U 0.000255 U 0.000235 U 0.000425 U 0.000315 U 0.00036 UJ 0.000245 U 0.000245 U 0.00029 U 0.00026 U 0.00024 U 91-20-3 Naphthalene 0.15 0.038 0.042 0.0061 0.079 J 0.07 J 0.1 J 0.049 0.92 0.11 0.02 0.11 98-95-3 Nitrobenzene 0.0125 U 0.011 U 0.011 U 0.011 U 0.013 U 0.013 U 0.0135 U 0.011 U 0.0115 U 0.011 U 0.012 U 0.011 U 621-64-7 n-Nitroso-di-n-Propylamine 0.0115 U 0.01 U 0.01 U 0.01 U 0.012 UJ 0.0115 UJ 0.012 UJ 0.01 U 0.01 U 0.01 U 0.011 U 0.01 UJ 86-30-6 n-Nitrosodiphenylamine 0.007 U 0.006 U 0.006 U 0.006 U 0.0075 U 0.007 U 0.0075 U 0.0065 U 0.0065 U 0.006 U 0.0065 U 0.006 U 95-47-6 o-Xylene 0.000335 U 0.00022 U 0.00023 U 0.000215 U 0.000385 U 0.000285 U 0.00033 U 0.00022 U 0.000225 U 0.000265 U 0.00024 U 0.000215 U 106-47-8 p-Chloroaniline 0.0165 U 0.0145 UJ 0.014 UJ 0.014 UJ 0.017 U 0.017 U 0.0175 U 0.0145 UJ 0.0145 U 0.014 UJ 0.0155 UJ 0.014 U 87-86-5 Pentachlorophenol 0.0044 UJ 0.00385 UJ 0.0038 UJ 0.0025 J 0.056 J 0.051 J 0.054 J 0.19 J 0.43 J 0.28 J 0.012 J 0.48 J 85-01-8 Phenanthrene 0.83 0.2 J 0.095 J 0.028 0.23 0.17 J 0.26 J 0.19 2.8 0.3 0.051 0.56 108-95-2 Phenol 0.01 U 0.009 U 0.009 U 0.009 U 0.0105 U 0.0105 U 0.0105 U 0.009 U 0.009 U 0.009 U 0.0095 U 0.009 U 100-01-6 p-Nitroaniline 0.0075 UJ 0.007 U 0.0065 U 0.0065 U 0.008 U 0.008 U 0.008 U 0.007 U 0.007 U 0.0065 U 0.0075 U 0.0065 U 129-00-0 Pyrene 7.1 1.1 J 0.37 J 0.04 1.1 1.1 J 1.6 J 1.5 12 1.3 0.17 1.6 7782-49-2 Selenium 0.5 U 0.42 U 0.44 U 0.415 U 0.55 U 0.55 U 0.55 U 0.425 U 0.455 U 0.44 U 0.455 U 0.445 U 7440-22-4 Silver 0.23 U 0.19 U 0.2 U 0.19 U 0.24 U 0.24 U 0.24 U 0.19 U 0.205 U 0.2 U 0.205 U 0.2 U 100-42-5 Styrene (monomer) 0.00036 U 0.000235 U 0.000245 U 0.00023 U 0.000415 U 0.000305 U 0.000355 U 0.00024 U 0.00024 U 0.000285 U 0.000255 U 0.000235 U 1634-04-4 tert-Butyl methyl ether 0.00027 U 0.000175 U 0.000185 U 0.00017 U 0.00031 U 0.00023 U 0.000265 U 0.00018 U 0.00018 U 0.00021 U 0.00019 U 0.000175 U 127-18-4 Tetrachloroethylene 0.000335 U 0.00022 U 0.00023 U 0.000215 U 0.000385 U 0.000285 U 0.00033 U 0.00022 U 0.000225 U 0.000265 U 0.00024 U 0.000215 U 156-60-5 trans-1,2-Dichloroethene 0.00032 U 0.00021 U 0.00022 U 0.000205 U 0.00037 U 0.00027 U 0.00031 U 0.00021 U 0.000215 U 0.00025 U 0.000225 U 0.000205 U 10061-02-6 trans-1,2-Dichloropropene 0.00025 U 0.000165 U 0.000175 U 0.00016 U 0.00029 U 0.000215 U 0.000245 U 0.000165 U 0.00017 U 0.0002 U 0.00018 U 0.000165 U 75-25-2 Tribromomethane 0.000325 U 0.000215 U 0.000225 U 0.00021 U 0.000375 U 0.00028 U 0.00032 U 0.000215 U 0.00022 U 0.00026 U 0.00023 U 0.00021 U 79-01-6 Trichloroethylene 0.000335 U 0.00022 U 0.00023 U 0.000215 U 0.000385 U 0.000285 U 0.00033 U 0.00022 U 0.000225 U 0.000265 U 0.00024 U 0.000215 U 7440-62-2 Vanadium 9.6 2.4 J 3.3 J 1.7 7.5 7.8 9 5.6 7.6 6.2 2.6 3.9 75-01-4 Vinyl chloride 0.0002 U 0.000135 U 0.00014 U 0.00013 U 0.000235 U 0.00017 U 0.0002 U 0.000135 U 0.000135 U 0.00016 U 0.000145 U 0.00013 U 67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 0.000674 0.00002271 1.425E-07 U 0.000029113 0.001007751 0.00311 J 0.000615288 0.000124468 0.00494 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 0.00558 0.000223149 0.000147144 0.000213096 0.007383233 0.0425 0.005481337 0.001228708 0.0371 55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 0.000054 0.000002917 J 0.000001223 J 0.000001031 J 0.000066966 0.000225 0.00004336 0.000006619 U 0.000295 70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 0.0000185 0.000000538 J 0.000001434 J 0.000000541 J 0.000028905 0.0000652 0.000016659 0.000003126 J 0.000122 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 0.0000263 0.000001074 J 0.000000659 J 0.000001014 J 0.000074532 0.000181 0.000042411 0.000007061 0.000366 57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 0.00001 0.000000162 U 0.000000743 J 0.000000377 J 0.000027546 0.0000347 0.000012897 0.000002282 J 0.000103 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 0.000118 0.000004099 J 0.000002875 J 0.000003748 J 0.000196911 0.000756 0.000119628 0.000024077 0.000911 72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 0.00000356 1.735E-07 U 0.000000749 J 6.85E-08 U 1.985E-07 U 0.0000117 1.355E-07 U 0.000000117 U 0.0000271 19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 0.0000436 0.000004312 J 0.000001831 J 0.000002295 J 0.000143555 J 0.000347 0.000081824 J 0.000013317 J 0.000634 57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 0.00000235 J 2.55E-08 U 0.000000598 J 0.00000024 J 0.000002258 J 0.00000401 0.000001309 J 0.000000324 J 0.00000944 40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 0.00000625 0.000000152 U 0.000000045 U 0.000000331 J 0.000023769 0.0000483 0.000011592 0.000002151 J 0.000119 60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 0.0000203 0.000000067 U 2.855E-07 U 0.000000422 J 0.000023235 0.0000643 0.000009601 J 0.000001915 J 0.000194 57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 0.00000608 0.00000016 J 0.000000466 J 0.000000229 J 0.00000329 J 0.0000143 0.000001773 J 0.000000299 J 0.0000374 51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 0.00000165 0.000000022 U 0.000000509 J 0.000000015 U 0.000000672 J 0.00000186 0.000000279 U 0.000000176 U 0.00000223 1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin U 0.000000022 U 2.25E-08 U 0.000000014 U 0.000001096 J 0.00000584 0.000000599 J 0.000000012 U 0.00000643 39001-02-0 Octachlorodibenzofuran 0.00373 0.000119868 0.000079273 0.00011289 0.004225438 0.0175 0.003389941 0.000704675 0.0198 3268-87-9 Octachlorodibenzo-p-dioxin 0.0564 0.002061955 0.001403442 0.001930378 J 0.05433963 J 0.412 0.047246051 J 0.011326673 J 0.35