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josefsaenz@gmail.com
José Francisco Sáenz C., Ph. D.
Dept. de Ingegneria Elettrica ed Elettronica– Università di Cagliari (Italia)
Fabricating conductive yarns/fabrics
for e-textiles applications
• Relatively cheap fibers
• Good mechanical properties
• Obtained from the cultivation of
plants (potentially unlimited
supply)
• Almost never cause allergic
reactions or other dermatological
issues
• Unfortunately: cellulose is
electrically insulating.
Using natural fibers (as cotton) for electronics
Using Conductive Polymers (CP)
• They are usually π-conjugated polymers, that can be
easily produced in aqueous solutions.
• After immersion in the polymerisation bath, materials
are coated with an even and uniform layer of CP, and
the presence of doping agents improves the electrical
conductivity of the layer itself.
• Most common types of CP:
• Nitrogen-containing aromatics
• poly(pyrrole)s (PPY)
• polyanilines (PANI)
• Sulfur-containing aromatics
• poly(thiophene)s (PT)
• poly(3,4-ethylenedioxythiophene) (PEDOT)
How to make conductive cotton?
• Common textile materials like cotton,
polyester and Lycra are treated with the
conductive polymer PEDOT:PSS,
transforming normally insulating materials
into conductors.
• Conductive textiles can be manufactured into
many shapes, printed, sewn, or knitted into
fabrics, or even woven in fiber forms directly
into textile structures
Mechanical properties of treated and
non-treated cotton yarns
Elongation to
break (%)
Stress at
break (MPa)
Young's modulus
(MPa)
Non treated 6.23 ± 0.98 170.9 ± 7.5 3711 ± 318
PEDOD:PSS+EG
treated 4.58 ± 0.39 69.1 ± 14.6 2987 ± 149
Treating cotton yarns with PEDOT:PSS
Cotton-based organic field
effect transistor (OFET)
Cotton-based organic
electrochemical transistor
(OECT)
In the cotton-based OFET the gate electrode is
represented by a conductive yarn; the gate dielectric,
semiconductor and drain/source contacts are deposited
around the yarn.
Cotton-based OFET Cotton-based OECT
G. Mattana, P. Cosseddu et al., Organic Electronics, 12, 2033-2039, 2011
Non-treated
polyester fabric
PEDOT:PSS-
treated polyester
fabric
Conductive fabrics
• It’s possible to treat a wide range of
textile materials including yarns and
fabric made of cotton, polyester,
polyamide, spandex, silk, etc.
• “Low cost” treatment based in the
deposition of a conductive polymer
and other organic solutions in liquid
phase.
• Minimum surface resistance obtained
with a fabric so far (fabric of mix fibers
polyester, viscosa, spandex):
o 15 Ohm/sq
Electronic textiles for wearable
sensors and large area applications
Textile bio-electrodes
Electrode comparison
• Commercial Ag/AgCl ECG electrode
with gel: Standard disposable electrode for
clinical applications
• Sewed Ag-coated Nylon yarn electrode:
State of the art approach for fabricating dry
textile electrodes1
• Conductive polymer treated fabric
electrode: Our proposed solution using
conventional textile fabrics (like cotton,
polyester or polyamide) treated with a
conducting polymer
Commercial ECG
Ag/AgCl with gel
Sewed Ag-coated
Nylon yarn
PEDOT:PSS
treated fabric
By directly treating common textile materials we
obtain very conductive fabrics that, when used as dry
surface electrodes, have shown a performance
comparable to standard gelled-Ag/AgCl electrodes.
Textile bio-electrodes
Conductive fabric electrodes with 16cm2 of active area were used to acquire the
ECG signals from a human volunteer at rest and while walking.
For further info: jose.saenz@nano.cnr.it; annalisa@diee.unica.it
Textile bio-electrodes
Textile strain sensors
DeltaR/Ro = (R-R@0N)/R@0Nx100%
Resistance of conductive Spandex (Lycra) fabric
with tensile stress
Textile pressure sensors
• An all-textile sensor for measuring the pressure distribution between two
contacting surfaces.
• The force sensing elements consist in a conductive-polymer treated fabric
sandwiched between to two pads of highly conductive yarn sewed on a non
conductive fabric.
Example of the new textile tactile sensor
Non-conductive fabric
Semi-conductive fabric
(Conductive-polymer-
treated textile)
Highly conductive yarn sewed on the
non-conductive fabric
Contact pad
Detail of the sensing elements
Textile pressure sensors
• Tactile sensors with square sensing elements of 1cm spaced 3cm
were used for the experiments
• Data is shown for sensors with thin sensing layer (cotton fabric).
Other applications
Resistive heatingEMI shielding
Attenuation: ~26 dβ @ 2,5GHz
Summary of applications
• Active electronic devices
o Organic field effect transistors (OFET)
o Organic electrochemical transistors (OECT)
• Biopotential electrodes
o Textile electrodes allow recording biopotentials from the skin surface as for
instance Electrocardiographic (ECG) signals.
• Strain/pressure sensors
o Sensors entirely based on textile materials allow recording pressure or
tension applied on the textile itself with a high sensitivity.
• Electromagnetic interference (EMI) shielding
o This technology allows realizing electromagnetic shields entirely made of
fabric, on large and ultra-large areas.
• Heating textiles
o Patches entirely based on conductive textile materials can be inserted in
garments for providing heating effect with a simple battery.
• Humidity/temperature sensors
• Color changing textiles (electrochromic)
o Conductive textiles can change color from light blue to dark blue using an
electrical signal and be used as displays, indicators or color changing
garments.
A smart garment
Textile electronics

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Presentation_Elettronica su sustrati tessili_12032014

  • 1. josefsaenz@gmail.com José Francisco Sáenz C., Ph. D. Dept. de Ingegneria Elettrica ed Elettronica– Università di Cagliari (Italia) Fabricating conductive yarns/fabrics for e-textiles applications
  • 2. • Relatively cheap fibers • Good mechanical properties • Obtained from the cultivation of plants (potentially unlimited supply) • Almost never cause allergic reactions or other dermatological issues • Unfortunately: cellulose is electrically insulating. Using natural fibers (as cotton) for electronics
  • 3. Using Conductive Polymers (CP) • They are usually π-conjugated polymers, that can be easily produced in aqueous solutions. • After immersion in the polymerisation bath, materials are coated with an even and uniform layer of CP, and the presence of doping agents improves the electrical conductivity of the layer itself. • Most common types of CP: • Nitrogen-containing aromatics • poly(pyrrole)s (PPY) • polyanilines (PANI) • Sulfur-containing aromatics • poly(thiophene)s (PT) • poly(3,4-ethylenedioxythiophene) (PEDOT) How to make conductive cotton?
  • 4. • Common textile materials like cotton, polyester and Lycra are treated with the conductive polymer PEDOT:PSS, transforming normally insulating materials into conductors. • Conductive textiles can be manufactured into many shapes, printed, sewn, or knitted into fabrics, or even woven in fiber forms directly into textile structures Mechanical properties of treated and non-treated cotton yarns Elongation to break (%) Stress at break (MPa) Young's modulus (MPa) Non treated 6.23 ± 0.98 170.9 ± 7.5 3711 ± 318 PEDOD:PSS+EG treated 4.58 ± 0.39 69.1 ± 14.6 2987 ± 149 Treating cotton yarns with PEDOT:PSS
  • 5. Cotton-based organic field effect transistor (OFET) Cotton-based organic electrochemical transistor (OECT) In the cotton-based OFET the gate electrode is represented by a conductive yarn; the gate dielectric, semiconductor and drain/source contacts are deposited around the yarn.
  • 6. Cotton-based OFET Cotton-based OECT G. Mattana, P. Cosseddu et al., Organic Electronics, 12, 2033-2039, 2011
  • 7. Non-treated polyester fabric PEDOT:PSS- treated polyester fabric Conductive fabrics • It’s possible to treat a wide range of textile materials including yarns and fabric made of cotton, polyester, polyamide, spandex, silk, etc. • “Low cost” treatment based in the deposition of a conductive polymer and other organic solutions in liquid phase. • Minimum surface resistance obtained with a fabric so far (fabric of mix fibers polyester, viscosa, spandex): o 15 Ohm/sq
  • 8. Electronic textiles for wearable sensors and large area applications
  • 10. Electrode comparison • Commercial Ag/AgCl ECG electrode with gel: Standard disposable electrode for clinical applications • Sewed Ag-coated Nylon yarn electrode: State of the art approach for fabricating dry textile electrodes1 • Conductive polymer treated fabric electrode: Our proposed solution using conventional textile fabrics (like cotton, polyester or polyamide) treated with a conducting polymer Commercial ECG Ag/AgCl with gel Sewed Ag-coated Nylon yarn PEDOT:PSS treated fabric By directly treating common textile materials we obtain very conductive fabrics that, when used as dry surface electrodes, have shown a performance comparable to standard gelled-Ag/AgCl electrodes. Textile bio-electrodes
  • 11. Conductive fabric electrodes with 16cm2 of active area were used to acquire the ECG signals from a human volunteer at rest and while walking. For further info: jose.saenz@nano.cnr.it; annalisa@diee.unica.it Textile bio-electrodes
  • 12. Textile strain sensors DeltaR/Ro = (R-R@0N)/R@0Nx100% Resistance of conductive Spandex (Lycra) fabric with tensile stress
  • 13. Textile pressure sensors • An all-textile sensor for measuring the pressure distribution between two contacting surfaces. • The force sensing elements consist in a conductive-polymer treated fabric sandwiched between to two pads of highly conductive yarn sewed on a non conductive fabric. Example of the new textile tactile sensor Non-conductive fabric Semi-conductive fabric (Conductive-polymer- treated textile) Highly conductive yarn sewed on the non-conductive fabric Contact pad Detail of the sensing elements
  • 14. Textile pressure sensors • Tactile sensors with square sensing elements of 1cm spaced 3cm were used for the experiments • Data is shown for sensors with thin sensing layer (cotton fabric).
  • 15. Other applications Resistive heatingEMI shielding Attenuation: ~26 dβ @ 2,5GHz
  • 16. Summary of applications • Active electronic devices o Organic field effect transistors (OFET) o Organic electrochemical transistors (OECT) • Biopotential electrodes o Textile electrodes allow recording biopotentials from the skin surface as for instance Electrocardiographic (ECG) signals. • Strain/pressure sensors o Sensors entirely based on textile materials allow recording pressure or tension applied on the textile itself with a high sensitivity. • Electromagnetic interference (EMI) shielding o This technology allows realizing electromagnetic shields entirely made of fabric, on large and ultra-large areas. • Heating textiles o Patches entirely based on conductive textile materials can be inserted in garments for providing heating effect with a simple battery. • Humidity/temperature sensors • Color changing textiles (electrochromic) o Conductive textiles can change color from light blue to dark blue using an electrical signal and be used as displays, indicators or color changing garments.