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A Technical Presentation on
   Ceramic Composites



               By
DESHPANDE JAYDEEP SANJEEV

        T.E. Mechanical
      PVG’S COET, PUNE.

      Under the guidance of
      Prof. P.G.Kulkarni
Contents:

 Introduction
 Monolithic vs. Composite
 Composites and applications
 Advantages
 Case Study
Introduction

 A ceramic is an inorganic, nonmetallic
 solid prepared by the action of heat and
 subsequent cooling.
 The word "ceramic" comes from the Greek
 word κεραμικός (keramikos), "of pottery"
 or "for pottery",from κέραμος (keramos),
 "potter's clay, tile, pottery"
Introduction




 Base matrix + reinforcement = composite!
Composite -v- Monolithic Ceramics
         Interphase
                                            LOAD




                                         matrix

                                                  fiber
                      crack
                                                              crack
                                                              arrest


              Fiber    Composite materials, whether platelet, chopped
Matrix                 fiber, or continuous fiber reinforced are superior
                       “engineering”materials to monolithics:

                          • generally higher strength, especially in tension
                          • much higher damage tolerance (fracture toughness)
Composite -v- Monolithic Ceramics
                                                            200
                                                                        Carbon
                                                                         Fiber
                                                            150        Composite




                                           Strength (MPa)
                                                            100
                                                                                               Graphite


                                                             50



                              Toughness                       0
                               MPa/m-1/2                          0    0.2      0.4     0.6      0.8        1
                                                                        Displacement (mm)
           Steel                 >50

    Monolithic Ceramic            3                                      Monolithic             Composite
Platelet Reinforced Ceramic       6                                    Strength (MPa)         Strength (MPa)
                                                              SiC            100 ± 50            220 ± 20
 Chopped Fiber Reinforced        10

Continuous Fiber Reinforced     25-30                       Graphite         107 ± 20            176 ± 20
         Ceramic
Why Composites
Advantages:

 Increased strength per unit volume
 Lesser weight
 Higher impact resistance
 Greater through thickness strength
Ceramic Composites




Composite Examples
Structural Composites in Aerospace Applications




• Thermal protection system for a re-entry space vehicle:
  Nose corn, leading edge, …
• Rocket engine: Extendable nozzle, aerospike engine, …
• Scram-jet engine for a future space vehicle.
Exhaust Tail-cone




                Weaving / 2D Cloth + Stitching
Successfully engine demonstrated at gas temperature 1573K (1998)
SiC/SiC Thrust chamber




                 Weaving / 3-Axial Braiding
Successfully hot firing tested at gas temperature 2073K (1998)
Short History of Materials
10000 bc    5000 bc      0       1000 1500 1600        1900       1940      1960      1980     1990     2000

    GOLD COPPER
             BRONZE
                IRON               METALS
                                      CAST IRON
     POLYMERS/                                STEELS                                                           ODS STEELS
     ELASTOMER
      WOOD
                                                                LIGHT ALLOYS             NEW SUPERALLOYS
      SKIN
      FIBERS
                             GLUES                                 SUPER ALLOYS         GLASSY METALS


                                            RUBBER               TITANIUM,
    COMPOSITES                                                   ZIRCONIUM
                                                                 etc. ALLOYS                     HIGH TEMPERATURE
     STRAW-BRICK         HORSEHAIR
                                                                                                 POLYMERS
                         PLASTER
    STONE                                                                                 HIGH MODULUS
      FLINT                                             BAKELITE                          POLYMERS
              POTTERY                                         NYLON                    POLYESTERS     CERAMIC
                   GLASS                                         P.E.               EPOXIES           MATRIX
                                                                                                METAL
                                 CEMENT                                    PMMA    ACRYLICS     MATRIX
                                          REFRACTORIES
     CERAMICS/                                   PORTLAND                             C/C
     GLASSES                                                                   GFRE
                                                 CEMENT   FUSED
                                                          SILICA             PYROLITIC TOUGHENED
                                                                     CERMETS CERAMICS CERAMICS


 10000 bc      5000 bc       0     1000 1500 1600        1900       1940       1960    1980     1990       2000


                                                                Date
Yield Strength Strength of Various Materials
                                  Yield of Various Structural Materials


                         600

                         500
                                                   Superalloy
                                                                                 C/C Composite
                                                                                 Ceramic Composites
                         400
Yield Strength (MPa)




                                                                                         SiC/SiC
                         300
                                                   Carbon Ste e l
                                     Zircaloy
                         200

                                                                    Stainle ss Ste e l
                         100
                                                                                           Graphite
                           0



                               0.0              400.0           800.0               1200.0            1600.0
                                                        Temperature (°C)
CERAMIC COMPOSITES

 Latest and the most advanced material in
 the market
 Provide very high strength
 Reduce weight greatly
 Better impact properties
 Higher in plane properties
 Very high operating temperatures
CASE STUDY
Impact on 12mm steel plate




        Muzzle Velocity=500m/s
Case Study: Ballistic Impact

 Ceramic tiles are a good replacement for
 steel armor plates




   Weight                 Strength
Impact on ceramic tile




       Muzzle velocity =1200m/s
Impact Characteristics

 Monolithic ceramic tiles crumble under
 impact loading
 In plane properties are weak
 Yet impact resistance is good because of
 the failure mechanism of ceramic
Failure Mechanism

 Under high energy impact ceramic
 material fails, forming fine ceramic dust
 This dust is confined by surrounding
 ceramic structure
 Thus it provides no route for failed
 material to escape
 As a result penetrating projectile faces
 great resistance and loses out energy
Failure of monolithic ceramic




       Muzzle velocity =1200m/s
Failure of monolithic ceramic




       Muzzle velocity =1200m/s
Monolithic Ceramic: Problem

 During the course of impact, layers of the
 ceramic stacking move parallel to each
 other due to inter-laminar shear stress
 This causes delamination of the
 monolithic crystal
 Also monolithic crystal allows for easy
 through thickness crack propagation
Effects of reinforcement

 Reinforcement in the monolithic ceramic
 tile improves ILSS properties
 It prevents delamination to some extent
 Through thickness crack propagation is
 reduced
 Reinforcing fibres take the impact loading
 and prevent the matrix from cracking
 Fibres help in holding the matrix together
SiC Whisker Reinforced Ceramic Tiles
Popular reinforcements


 Glass fibre
 Carbon fibre
 Silicon carbide
 Kevlar™
Popular Matrix Materials


 Alumina
 Zirconia
 Zirconia toughened Alumina (ZTA)
 Cr3C2
 CeO2
 TiN
Conclusion


 Thus wherever weight constraints hinder
 the use of thick steel plates, Ceramic
 composites provide the best solution.
 In defense applications ceramic
 composite tiles are popularly used in
 ballistic impact protection tiles and vests.
 Ceramic composites are also popularly
 used in high temperature applications
 such as rocket nozzles and reactors.

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[2024]Digital Global Overview Report 2024 Meltwater.pdf
 

Composites

  • 1. A Technical Presentation on Ceramic Composites By DESHPANDE JAYDEEP SANJEEV T.E. Mechanical PVG’S COET, PUNE. Under the guidance of Prof. P.G.Kulkarni
  • 2. Contents: Introduction Monolithic vs. Composite Composites and applications Advantages Case Study
  • 3. Introduction A ceramic is an inorganic, nonmetallic solid prepared by the action of heat and subsequent cooling. The word "ceramic" comes from the Greek word κεραμικός (keramikos), "of pottery" or "for pottery",from κέραμος (keramos), "potter's clay, tile, pottery"
  • 4. Introduction Base matrix + reinforcement = composite!
  • 5. Composite -v- Monolithic Ceramics Interphase LOAD matrix fiber crack crack arrest Fiber Composite materials, whether platelet, chopped Matrix fiber, or continuous fiber reinforced are superior “engineering”materials to monolithics: • generally higher strength, especially in tension • much higher damage tolerance (fracture toughness)
  • 6. Composite -v- Monolithic Ceramics 200 Carbon Fiber 150 Composite Strength (MPa) 100 Graphite 50 Toughness 0 MPa/m-1/2 0 0.2 0.4 0.6 0.8 1 Displacement (mm) Steel >50 Monolithic Ceramic 3 Monolithic Composite Platelet Reinforced Ceramic 6 Strength (MPa) Strength (MPa) SiC 100 ± 50 220 ± 20 Chopped Fiber Reinforced 10 Continuous Fiber Reinforced 25-30 Graphite 107 ± 20 176 ± 20 Ceramic
  • 8. Advantages: Increased strength per unit volume Lesser weight Higher impact resistance Greater through thickness strength
  • 10. Structural Composites in Aerospace Applications • Thermal protection system for a re-entry space vehicle: Nose corn, leading edge, … • Rocket engine: Extendable nozzle, aerospike engine, … • Scram-jet engine for a future space vehicle.
  • 11. Exhaust Tail-cone Weaving / 2D Cloth + Stitching Successfully engine demonstrated at gas temperature 1573K (1998)
  • 12. SiC/SiC Thrust chamber Weaving / 3-Axial Braiding Successfully hot firing tested at gas temperature 2073K (1998)
  • 13. Short History of Materials 10000 bc 5000 bc 0 1000 1500 1600 1900 1940 1960 1980 1990 2000 GOLD COPPER BRONZE IRON METALS CAST IRON POLYMERS/ STEELS ODS STEELS ELASTOMER WOOD LIGHT ALLOYS NEW SUPERALLOYS SKIN FIBERS GLUES SUPER ALLOYS GLASSY METALS RUBBER TITANIUM, COMPOSITES ZIRCONIUM etc. ALLOYS HIGH TEMPERATURE STRAW-BRICK HORSEHAIR POLYMERS PLASTER STONE HIGH MODULUS FLINT BAKELITE POLYMERS POTTERY NYLON POLYESTERS CERAMIC GLASS P.E. EPOXIES MATRIX METAL CEMENT PMMA ACRYLICS MATRIX REFRACTORIES CERAMICS/ PORTLAND C/C GLASSES GFRE CEMENT FUSED SILICA PYROLITIC TOUGHENED CERMETS CERAMICS CERAMICS 10000 bc 5000 bc 0 1000 1500 1600 1900 1940 1960 1980 1990 2000 Date
  • 14. Yield Strength Strength of Various Materials Yield of Various Structural Materials 600 500 Superalloy C/C Composite Ceramic Composites 400 Yield Strength (MPa) SiC/SiC 300 Carbon Ste e l Zircaloy 200 Stainle ss Ste e l 100 Graphite 0 0.0 400.0 800.0 1200.0 1600.0 Temperature (°C)
  • 15. CERAMIC COMPOSITES Latest and the most advanced material in the market Provide very high strength Reduce weight greatly Better impact properties Higher in plane properties Very high operating temperatures
  • 17. Impact on 12mm steel plate Muzzle Velocity=500m/s
  • 18. Case Study: Ballistic Impact Ceramic tiles are a good replacement for steel armor plates Weight Strength
  • 19. Impact on ceramic tile Muzzle velocity =1200m/s
  • 20. Impact Characteristics Monolithic ceramic tiles crumble under impact loading In plane properties are weak Yet impact resistance is good because of the failure mechanism of ceramic
  • 21. Failure Mechanism Under high energy impact ceramic material fails, forming fine ceramic dust This dust is confined by surrounding ceramic structure Thus it provides no route for failed material to escape As a result penetrating projectile faces great resistance and loses out energy
  • 22. Failure of monolithic ceramic Muzzle velocity =1200m/s
  • 23. Failure of monolithic ceramic Muzzle velocity =1200m/s
  • 24. Monolithic Ceramic: Problem During the course of impact, layers of the ceramic stacking move parallel to each other due to inter-laminar shear stress This causes delamination of the monolithic crystal Also monolithic crystal allows for easy through thickness crack propagation
  • 25. Effects of reinforcement Reinforcement in the monolithic ceramic tile improves ILSS properties It prevents delamination to some extent Through thickness crack propagation is reduced Reinforcing fibres take the impact loading and prevent the matrix from cracking Fibres help in holding the matrix together
  • 26. SiC Whisker Reinforced Ceramic Tiles
  • 27. Popular reinforcements Glass fibre Carbon fibre Silicon carbide Kevlar™
  • 28. Popular Matrix Materials Alumina Zirconia Zirconia toughened Alumina (ZTA) Cr3C2 CeO2 TiN
  • 29. Conclusion Thus wherever weight constraints hinder the use of thick steel plates, Ceramic composites provide the best solution. In defense applications ceramic composite tiles are popularly used in ballistic impact protection tiles and vests. Ceramic composites are also popularly used in high temperature applications such as rocket nozzles and reactors.