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Green Chemistry / Biomimicry [email_address] Mark Dorfman
Common synthetic chemical-based products: Fire retardants Synthetic fabrics Adhesives, paints, solvents, and coatings Plastics and synthetic rubber Detergents and cleaning chemicals Electronics chemicals Fuels
Agricultural insecticides and fertilizers Artificial flavors and fragrances Personal care products Pharmaceuticals Meat processing hormones and antibiotics
There’s no such thing... as a FREE LUNCH
[object Object],[object Object],[object Object],Products do not come to the home or market without a “price”: … at any point along the  Commercial Chemical Chain
The Commercial Chemical Chain ,[object Object]
Raw Material Extraction ,[object Object],[object Object],[object Object],[object Object]
Refining / Purification ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Synthesis / Formulation ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Generic Chemical Synthesis Compound “A” Compound “B” Product “C” By-products Reaction Vessel This is just to cover
Some products require multiple steps to get from raw materials to final product.  Each step may release potentially toxic or hazardous substances.
Consumption / Utilization  of Final Product ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
The next slide lists quantities of potentially toxic and hazardous substances released to the environment in a single year.  They are limited to: ,[object Object],[object Object],[object Object],[object Object],RELEASES TO THE ENVIRONMENT
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Releases to:
Product Use and Disposal ,[object Object],[object Object],[object Object],[object Object]
Potential Environmental and Public Health Impacts from Exposure to Commercial Chemicals ,[object Object],[object Object]
Emerging Picture ,[object Object],[object Object],[object Object],[object Object]
Impacts on the Human Fetus? ,[object Object],[object Object],[object Object]
[object Object],This 1940’s Mobil gas ad (as well as the following 1920s quote)  illustrate the perspective during most of the 20 th  century that petroleum and the chemical laboratory could improve the world… …how ironic that the ad shows the earth coated with oil.
… and into the  Nano-Bio-Technology Age As we step out of the Petro-Chem-Technology Age…
BEWARE! ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
HAVE WE LEARNED ANY LESSONS? If so, the following 12  “ GREEN CHEMISTRY PRINCIPLES ” offer a means to enjoy  the fruits of an industrial society  while reducing their impacts  on public and environmental health
Green Chemistry Principle ,[object Object]
Green Chemistry Principle ,[object Object]
Green Chemistry Principle ,[object Object]
Green Chemistry Principle ,[object Object]
Green Chemistry Principle ,[object Object]
Green Chemistry Principle ,[object Object]
Green Chemistry Principle ,[object Object]
Green Chemistry Principle ,[object Object]
Green Chemistry Principle ,[object Object]
Green Chemistry Principle ,[object Object]
Green Chemistry Principle ,[object Object]
Green Chemistry Principle ,[object Object],[object Object]
The general public tends to assume that “chemicals” are man-made, and that nature is something other than chemical. This section is designed to show that the natural world is indeed a chemical one.
[object Object]
The BIG BANG 14 Billion Years Ago
Earth 4.5 –3 Billion Years Ago ammonia carbon dioxide hydrogen nitrogen phosphorous sulfur oxygen  ozone layer  water vapor minerals amino acids  heavy metals radio nuclides
Chemicals on the early Earth  interact spontaneously  in   reactions that  take  the path of least resistance,  such as: ,[object Object],[object Object],[object Object]
3 Billion to 350 Million Years Ago ,[object Object],[object Object],[object Object]
350 Million to 10,000 Years Ago ,[object Object],[object Object],[object Object],[object Object]
Bio- and inorganic-chemicals interact with each other, the environment, and living things in cycles such as the CARBON CYCLE
… turning ashes  (burning wood) GLUCOSE  +  OXYGEN   CO 2  + Water + Heat   ,[object Object],[object Object],Biology accomplishes amazing chemical feats, such as…
[object Object],Chalk Both are made of calcium carbonate, but Abalone is…
[object Object],[object Object]
[object Object],[object Object],[object Object],Strength and Resilience of “Nacre” due to:
Nacre micrograph
How Abalone Do It ,[object Object],[object Object],[object Object],[object Object]
How Industry Makes Ceramics ,[object Object],[object Object],[object Object]
Mussel Byssus
Components and Characteristics ,[object Object],[object Object],[object Object],[object Object]
How a Mussel  Makes its Byssus ,[object Object],[object Object],[object Object],[object Object]
Thread   and  Sealant ,[object Object],[object Object],[object Object]
Potential Industrial Applications   ,[object Object],[object Object],[object Object],[object Object]
HOW THE CHEMICAL INDUSTRY MAKES ADHESIVES AND PLASTICS ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Gecko  feet
Synthetic Gecko tape:  Polyimide nanofibers
Mimic  to: ,[object Object],[object Object],[object Object],[object Object],Photosynthesis
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Energy from ATP plus enzyme NADPH is used to build sugar molecules from carbon dioxide. Artificial photosynthetic system
Most Common Human Ways of Generating Power ,[object Object],[object Object],[object Object]
Common Characteristics of Chemistry in Nature ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
VAST UNTAPPED POTENTIAL  ,[object Object],[object Object],[object Object],[object Object],[object Object]
GLOBAL TRENDS Extrapolating current technologies and practices
[object Object],Space   Age Society… GLOBAL TRENDS Utilizing Green Chemistry  and Biomimicry (??)

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Green Chemistry Biomimicry Slideshow Oct 2006

  • 1. Green Chemistry / Biomimicry [email_address] Mark Dorfman
  • 2. Common synthetic chemical-based products: Fire retardants Synthetic fabrics Adhesives, paints, solvents, and coatings Plastics and synthetic rubber Detergents and cleaning chemicals Electronics chemicals Fuels
  • 3. Agricultural insecticides and fertilizers Artificial flavors and fragrances Personal care products Pharmaceuticals Meat processing hormones and antibiotics
  • 4. There’s no such thing... as a FREE LUNCH
  • 5.
  • 6.
  • 7.
  • 8.
  • 9.
  • 10. Generic Chemical Synthesis Compound “A” Compound “B” Product “C” By-products Reaction Vessel This is just to cover
  • 11. Some products require multiple steps to get from raw materials to final product. Each step may release potentially toxic or hazardous substances.
  • 12.
  • 13.
  • 14.
  • 15.
  • 16.
  • 17.
  • 18.
  • 19.
  • 20. … and into the Nano-Bio-Technology Age As we step out of the Petro-Chem-Technology Age…
  • 21.
  • 22. HAVE WE LEARNED ANY LESSONS? If so, the following 12 “ GREEN CHEMISTRY PRINCIPLES ” offer a means to enjoy the fruits of an industrial society while reducing their impacts on public and environmental health
  • 23.
  • 24.
  • 25.
  • 26.
  • 27.
  • 28.
  • 29.
  • 30.
  • 31.
  • 32.
  • 33.
  • 34.
  • 35. The general public tends to assume that “chemicals” are man-made, and that nature is something other than chemical. This section is designed to show that the natural world is indeed a chemical one.
  • 36.
  • 37. The BIG BANG 14 Billion Years Ago
  • 38. Earth 4.5 –3 Billion Years Ago ammonia carbon dioxide hydrogen nitrogen phosphorous sulfur oxygen ozone layer water vapor minerals amino acids heavy metals radio nuclides
  • 39.
  • 40.
  • 41.
  • 42. Bio- and inorganic-chemicals interact with each other, the environment, and living things in cycles such as the CARBON CYCLE
  • 43.
  • 44.
  • 45.
  • 46.
  • 48.
  • 49.
  • 51.
  • 52.
  • 53.
  • 54.
  • 55.
  • 57. Synthetic Gecko tape: Polyimide nanofibers
  • 58.
  • 59.
  • 60.
  • 61.
  • 62.
  • 63. GLOBAL TRENDS Extrapolating current technologies and practices
  • 64.