THE CENTRAL QUESTION ...
Since the battery is pivotal to my EV, what are the core issues that will allow me to understand battery technology?
COURSE ABSTRACT
A discussion of battery components and fabrication approach, the reasons that building higher capacity batteries are constrained by geometry and technological factors, the key characteristics to assess when comparing battery chemistries, and new battery tech that may lead to significant improvements in those characteristics. To obtain a copy of the EVU study guide for this and other available EVU courses, please complete the form on this page.
Course level: Intermediate
2. 2
EV Battery
Technology,
part 3
EV-210c
This course is presented as part of
Evannex University—a free, open
learning environment that presents
concise, video-based mini-courses for
those who have interest in electric
vehicles (EVs) …
3. A look back
the basic elements of an EV battery
the battery production process
the metrics by which we compare one battery chemistry
to another
the cost drivers for EV batteries
3
4. Is it reasonable to expect lower cost?
Technical advances in the
design and fabrication of
anodes, cathodes and
electrolytes are likely
cell capacity improvements
of 40%
overall increase in battery
capacity by 80 to 110 percent
4
Source: http://theconversation.com/affordable-
batteries-for-green-energy-are-closer-than-we-think-
28772
5. The Battery Landscape
5
Source: Electric
Vehicle Integration
into Modern Power
Networks,
Electric Vehicle
Battery Technologies
(Ch. 2), Young, K. et
al,
Springer, 2013
6. Batteries vs. Gasoline
6
Source: McKinsey&Co from DoE data,
http://www.mckinsey.com/insights/energy_resources_materials/battery_
technology_charges_ahead
7. Battery Research—Components
Graphene and carbon nanotubes for supercapacitors that
would reduce charging time to minutes, rather than hours
problem: fabrication and cost
problem: relatively low energy density
lithium rather than graphite electrodes have the potential to
increase capacity by 100 - 300%
problem: left cycle and safety concerns
super-thin batteries can be spread over then entire vehicle
surface
problem: early stages
7
Graphene photomicrograph
8. Battery Research—Chemistry
Lithium-Vanadium-Phosphate (LVP)—faster charging and
longer life expectancy than Li-Ion.
Lithium sulphur—increase energy density by a factor of 4
Lithium air—potential to achieve energy density of
gasoline, but is not suitable for the heavy loads of
automotive applications, possibly could supplement a Li-
Ion battery
8
9. Supercapacitors
two carbon electrodes sandwich and electrolyte to
for the super capacitor
thin film, with high power density, but lower
specific energy
able to charge very quickly,
very thin (body panel applications)
supplement EV battery—does not replace it
provides burst of power for acceleration, allowing
battery to provide steady state power
9
Source: IEEE Spectrum,
http://spectrum.ieee.org/nanoclast/tra
nsportation/advanced-
cars/graphenebased-supercapacitors-
take-another-crack-at-allelectric-
vehicles
10. Summary
battery components form cells, organized into modules,
and built as a pack
building higher capacity batteries is constrained by
geometry, weight, and technology
six characteristics must be considered when evaluating a
battery pack—specific energy, specific power, life span,
cost, safety and performance
new technology may enable improvements in all six
characteristics
10
11. 11
… a free study guide for
all EVU mini-courses is
available for download
from our website …
For a complete list of mini-
courses and the study guide,
visit: www.evannex.com
Hinweis der Redaktion
In the preceding parts of this EVU mini-course you learned about:
>> the basic elements of an EV battery
>> the battery production process
>> the technological characteristics by which we compare one battery chemistry to another
>> the cost drivers for EV batteries
Now it time to look at Battery trends going forward.
No one has a crystal ball, but recent trends indicate a few key facts:
>> Technical advances in the design and fabrication of anodes, cathodes and electrolytes are likely
These will result in:
>> cell capacity improvements of 40%
>> overall increase in battery capacity by 80 to 110 percent
in the 2020 - 2025 timeframe
The graph on the right of your screen shows battery cost projections of 10 different studies of battery cost. You’ll note that all converge on 200/kWh in the time range of 2020 to 2030. In the last few decades, technology has tended to progress more rapidly that most projections indicate, so the $200/kWh projection in the 2020 to 2025 timeframe seems reasonable and achievable.
This graph of specific energy (a measure of battery capacity) and specific power (a measure of power to weight of a battery) provides yet another view of the current status and future outlook for EV batteries.
The graph shown on your screen provides a compact view of the existing battery landscape,
represented in terms of specific energy and specific power—terms we discussed in part 2 of this mini-course.
As you can see, Li-Ion batteries offer distinct advantages over lead acid and Nickel-metal-hydride batteries,
with super capacitors—a technology we’ll discuss briefly in a few moments—offering significant potential in high power applications.
The stars on the graph indicate goals established by the United States Advanced Battery Consortium.
Note that goals for Hybrid electrics and PHEVs have already been met,
but the goal for BEVs has yet to be achieved with production battery technology.
The dashed diagonal lines indicate the time to discharge at various specific energy and specific power configurations.
From the plot, as power demand increases, the battery discharges more rapidly and the battery will not offer as much total energy.
In 2012, McKinsey & Co. developed a graph that compares the cost of gasoline with the cost of EV batteries in $ / kWh and then depicts the regions in which EV variants and ICE vehicles are competitive. In this case “competitive” means that any electric vehicle price premium associated with battery costs will be offset over a reasonable period of ownership.
The mid-blue shaded region of the graph shows that as battery costs falls below about $350/KwH, BEVs and PHEVs become fully competitive at a gasoline price of about $3.50 a gallon. When battery cost is reduced to $150 /kWh BEVs are competitive regardless of the cost of gasoline.
By 2020, it is likely that batteries will cost about $200 -$300 / kWh, meaning that a gasoline cost of $3.00 per gallon makes BEV fully competitive with ICE vehicles.
But all of this assumes incremental improvements in battery tech.
What if there are disruptive improvements?
Let’s take a quick look at a few research directions.
There are a number of major national research programs, such as the Joint Center for Energy Storage Research, dedicated to the improvement of energy story technology.
In the domain of batteries, this research is focused on a number of important areas including:
>> Graphene and carbon nanotubes that can be used for supercapacitors that would reduce charging time to minutes, rather than hours
>> the problem: fabrication and cost
>> and another problem: relatively low energy density
Another research area is in new electrode materials
>> lithium rather than graphite electrodes have the potential to increase capacity by 100 - 300%
>> problem: life cycle and safety concerns
Finally,
>> super-thin batteries can be spread over the entire vehicle surface
>> problem: research is in its early stages with potential for success uncertain.
Understanding advances in battery chemistry demands a highly technical background and is beyond the scope of this EVU mini-course. For our discussion, suffice it to say that a variety of Lithium based chemistries offer potential:
>> Lithium-Vanadium-Phosphate (LVP) offers faster charging and longer life expectancy than Li-Ion.
>> Lithium sulphur is claimed to increase energy density by a factor of 4
>> Lithium air has the potential to achieve energy density of gasoline, but is not suitable for the heavy loads of automotive applications, but possibly could be used to supplement a Li-Ion battery
Finally, a word about supercapacitors.
If you read about the future of EVs, you’ll often encounter the term and along with it,
statements about supercacitors as a breakthrough technology for EVs.
The future impact of supercacitors is unclear, but it’s worth exploring this energy storage technology briefly,
>> two carbon electrodes sandwich an electrolyte to form the super capacitor that holds an electrical charge
The characteristics of this device are that it can be implemented as a:
>> thin film, with high power density, but lower specific energy
>> it can be charged very quickly,
>> and because it is very thin, it has potential for body panel applications,
that is, the supercapacitor would become part of the vehicle body panels,
thereby accommodating the geometric constraint we discussed earlier in this mini-course
Given the current state of the technology and the immutable laws of physics, a supercacitor would
>> supplement EV battery—but does not replace it
>> It provides burst of power for acceleration, allowing battery to provide steady state power
or alternatively, might be used to supplement a Li-Ion battery to extend it’s capacity
We’ve covered a lot of ground in this EVU mini-course. Let’s summarize:
>> battery components form cells, organized into modules, and built as a pack
>> building higher capacity EV batteries is constrained by geometry. weight, and technology
>> six metrics must be considered when evaluating a battery pack—specific energy, specific power, life span, cost, safety, and performance
>> new technology may enable improvements in all six characteristics
If these improvements are significant (and only time will tell if they are),
EVs will provide the range and performance that will rival ICE vehicles.