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Presented By ,
Miss. Janhavi Shirish Zope
M Pharmacy 1st year
Department : Pharmaceutics
R . G . SAPKAL COLLEGE OF PHARMACY
1
CONTENTS
 Introduction
 Types of Polymer
 Classification of Polymer
 Characteristics of Polymer
 Application
 References
2
INTRODUCTION
 Polymers are very large molecules made when hundreds
of monomers join together to form long chains .
 The word POLYMER comes from the Greek words poly
means many and mer means parts .
 Polymer is used as a synonym for plastic .
 All plastics are polymers , but not all polymers are plastics
N(CH2-CH2) (-CH2-CH2-)s
Ethylene Polyethylene
3
TYPES OF POLYMER
 Natural Polymers
 Homopolymer
 Copolymer
 Thermoplastics
 Thermosets
 Long chain Polymers
4
NATURAL POLYMERS
 Definition : Natural polymer is a polymer that results from
only raw materials that are found in nature .
 Some of these natural polymers include DNA and RNA
 Cotton , DNA , Wool , Wood are some of the naturally
occurring polymers .
5
HOMOPOLYMER
 Homopolymers are synthesized from a single type of
monomer .
 Homopolymers are consists of chains with identical
bonding linkages to each monomer unit .
 This usually implies that the polymer is made from all
identical monomer molecules .
6
COPOLYMER
 When two or more different monomers together to
polymerize their result is called as copolymer .
 This process is called as copolymerization .
 Types of Copolymer :
1) Statistical copolymer
2) Alternating copolymer
3) Block copolymer
4) Graft copolymer
7
THERMOPLASTIC
 A type of plastic that can be softened by heat , hardened
by cooling , and then softened by heat over and over again
 Thermoplastic are not cross – linked polymer .
 Examples : Polyethylene , Nylon , Polyvinyl chloride .
8
THERMOSETS
 Thermoset having the property of becoming permanently
hard and rigid when heated .
 Thermosets are hard and rigid at room temperature and do
not soften on heating .
 Examples : Epoxy resins , Phenolic resins , Unsaturated
polyester resins .
9
LONG CHAIN POLYMERS
 A very long strand of repeating molecules linked together
by primary bond .
 Polymer chains are orient themselves in lines as they
enter a mold but may be annealed so they can recoil .
10
CLASSIFICATION OF POLYMER
11
BASED ON ORIGIN OF SOURCE
 Natural Polymer :- Polymers which are isolated from
natural materials are called as Natural Polymers . E.g. :
Cotton , silk , wool , rubber .
 Synthetic Polymer :- Polymers which are synthesized
from low molecular weight compounds are called as
Synthetic Polymers . E.g. : Polyethylene , nylon , terylene.
 Semisynthetic Polymers :- These polymers are mostly
derived from naturally occurring polymers by chemical
modification . E.g. : Rayon
12
BASED ON STRUCTURE
 Linear Polymer : Molecules
form long chains without
branches.
 Branched Polymer : Molecules
having branch points that
connect 3 or more segments .
 Cross-Linked Polymer : It
includes interconnections
between chains .
 Network Polymer : A cross
linked polymer that includes
numerous interconnections
between chains .
13
BASED ON MODE OF POLYMERISATION
 Additional Polymerization :
Same kind of monomers are straight forwardly added .
It is rapid chain reaction having chemically activated mers
.
Each reaction sets up the condition for another to proceed
.
It consists of 3 stages :
Initiation
(Birth)
Propagation
(Growth)
Termination
(Death)
14
CONT…
 Condensation Polymerization :
It involves a polymerization reaction between two
monomers with the expulsion of a simple by product .
A + B AB + Simple by product
It involves individual chemical reaction between reactive
mer .
By product is formed and condensed out .
This reaction is slower than additional polymerization.
Need reactive functional groups .
15
CHARACTERISTICS OF POLYMER
 Low density
 Low coefficient of friction
 Good corrosion resistance
 Good mould ability
 Poor tensile strength
 Low mechanical properties
 Poor temperature resistance
 Can be produced transparent or different colours 16
APPLICATION
 Medicine : Many biomaterials especially heart valve
replacements and blood vessels are made up of polymers
like dacron , teflon .
 Consumer Science : Plastic containers of all shapes and
sizes are light weight and economically less expensive
than more traditional containers .
 Industry : Automobile parts , pipes , tanks , packing
material , adhesives are all polymer application used in
industrial market .
 Sports : Playground equipment , golf clubs , swimming
pools and protective helmets are produced from polymers.
17
REFERENCES
 Robinson J R and Lee V H ; Controlled Drug Delivery –
Fundamentals and Applications ; Marcel Dekker .
 Jain N K ; Controlled and Novel Drug Delivery ; CBS
publication .
18
19

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Types, Classification and Applications of Polymers

  • 1. Presented By , Miss. Janhavi Shirish Zope M Pharmacy 1st year Department : Pharmaceutics R . G . SAPKAL COLLEGE OF PHARMACY 1
  • 2. CONTENTS  Introduction  Types of Polymer  Classification of Polymer  Characteristics of Polymer  Application  References 2
  • 3. INTRODUCTION  Polymers are very large molecules made when hundreds of monomers join together to form long chains .  The word POLYMER comes from the Greek words poly means many and mer means parts .  Polymer is used as a synonym for plastic .  All plastics are polymers , but not all polymers are plastics N(CH2-CH2) (-CH2-CH2-)s Ethylene Polyethylene 3
  • 4. TYPES OF POLYMER  Natural Polymers  Homopolymer  Copolymer  Thermoplastics  Thermosets  Long chain Polymers 4
  • 5. NATURAL POLYMERS  Definition : Natural polymer is a polymer that results from only raw materials that are found in nature .  Some of these natural polymers include DNA and RNA  Cotton , DNA , Wool , Wood are some of the naturally occurring polymers . 5
  • 6. HOMOPOLYMER  Homopolymers are synthesized from a single type of monomer .  Homopolymers are consists of chains with identical bonding linkages to each monomer unit .  This usually implies that the polymer is made from all identical monomer molecules . 6
  • 7. COPOLYMER  When two or more different monomers together to polymerize their result is called as copolymer .  This process is called as copolymerization .  Types of Copolymer : 1) Statistical copolymer 2) Alternating copolymer 3) Block copolymer 4) Graft copolymer 7
  • 8. THERMOPLASTIC  A type of plastic that can be softened by heat , hardened by cooling , and then softened by heat over and over again  Thermoplastic are not cross – linked polymer .  Examples : Polyethylene , Nylon , Polyvinyl chloride . 8
  • 9. THERMOSETS  Thermoset having the property of becoming permanently hard and rigid when heated .  Thermosets are hard and rigid at room temperature and do not soften on heating .  Examples : Epoxy resins , Phenolic resins , Unsaturated polyester resins . 9
  • 10. LONG CHAIN POLYMERS  A very long strand of repeating molecules linked together by primary bond .  Polymer chains are orient themselves in lines as they enter a mold but may be annealed so they can recoil . 10
  • 12. BASED ON ORIGIN OF SOURCE  Natural Polymer :- Polymers which are isolated from natural materials are called as Natural Polymers . E.g. : Cotton , silk , wool , rubber .  Synthetic Polymer :- Polymers which are synthesized from low molecular weight compounds are called as Synthetic Polymers . E.g. : Polyethylene , nylon , terylene.  Semisynthetic Polymers :- These polymers are mostly derived from naturally occurring polymers by chemical modification . E.g. : Rayon 12
  • 13. BASED ON STRUCTURE  Linear Polymer : Molecules form long chains without branches.  Branched Polymer : Molecules having branch points that connect 3 or more segments .  Cross-Linked Polymer : It includes interconnections between chains .  Network Polymer : A cross linked polymer that includes numerous interconnections between chains . 13
  • 14. BASED ON MODE OF POLYMERISATION  Additional Polymerization : Same kind of monomers are straight forwardly added . It is rapid chain reaction having chemically activated mers . Each reaction sets up the condition for another to proceed . It consists of 3 stages : Initiation (Birth) Propagation (Growth) Termination (Death) 14
  • 15. CONT…  Condensation Polymerization : It involves a polymerization reaction between two monomers with the expulsion of a simple by product . A + B AB + Simple by product It involves individual chemical reaction between reactive mer . By product is formed and condensed out . This reaction is slower than additional polymerization. Need reactive functional groups . 15
  • 16. CHARACTERISTICS OF POLYMER  Low density  Low coefficient of friction  Good corrosion resistance  Good mould ability  Poor tensile strength  Low mechanical properties  Poor temperature resistance  Can be produced transparent or different colours 16
  • 17. APPLICATION  Medicine : Many biomaterials especially heart valve replacements and blood vessels are made up of polymers like dacron , teflon .  Consumer Science : Plastic containers of all shapes and sizes are light weight and economically less expensive than more traditional containers .  Industry : Automobile parts , pipes , tanks , packing material , adhesives are all polymer application used in industrial market .  Sports : Playground equipment , golf clubs , swimming pools and protective helmets are produced from polymers. 17
  • 18. REFERENCES  Robinson J R and Lee V H ; Controlled Drug Delivery – Fundamentals and Applications ; Marcel Dekker .  Jain N K ; Controlled and Novel Drug Delivery ; CBS publication . 18
  • 19. 19