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1. Joint Entrance Exam/IITJEE-2016
Paper Code - F
3rd
April 2016 | 9.30 AM – 12.30 PM
CHMISTRY, MATHEMATICS & PHYSICS
Important Instructions:
1. Immediately fill in the particulars on this page of Test Booklet with only Blue / Black Ball Point Pen
provided by the Board.
2. The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet, take out
the Answer Sheet and fill in the particulars carefully.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 360.
5. There are three parts in the question paper A, B, C, consisting of Chemistry, Mathematics and Physics
having 30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for each correct
response.
6. Candidates will be awarded ,marks as stated above in instruction No. 5 for correct response of each
question. ¼ (one fourth) marks will be deducted for indicating incorrect response for each question. No
deduction from the total score will be made if no response is indicated for an item in the answer sheet.
7. There is only one correct response for each question. Filling up more than one response in each question will
be treated as wrong response and marks for wrong response will be deducted accordingly as per instruction 6
above.
8. For writing particulars/marking responses on Side -1 and Side-2 of the Answer Sheet use only Blue / Black
Ball Point Pen provided by the Board.
9. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone,
any electronic device, etc. except the Admit Card inside the examination room/hall.
10. Rough work is not to be done on the space provided for this purpose in the Test Booklet only.
11. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
12. The CODE for this booklet is F. Make sure that the CODE printed on Side – 2 of the Answer Sheet and
also tally the serial number of the Test Booklet and Answer Sheet are the same as that on this booklet. In case of
discrepancy, the candidate should immediately report the matter to the Invigilator for replacement of both the
Test Booklet and the Answer Sheet.
13. Do not fold or make any stray mark on the Answer Sheet.
2. IIT JEE-2016 2 JEE Entrance Examination
PART-A CHEMISTRY
1. A stream of electrons from a heated filament was passed between two charged plates kept at a potential
difference V esu. If e and m are charge and mass of an electron, respectively, then the value of
h
(where is
wavelength associated with electron wave) is given by :
(1) 2 meV (2) meV (3) 2meV (4) meV
1.(3) de-Broglie wavelength,
h h
P
P
and
2
1 P h
eV P 2meV
2 m
2. 2-chloro-2-methylpentane on reaction with sodium methoxide in methanol yields :
(a)
3
2 5 2 3
3
CH
|
C H CH C OCH
|
CH
(b) 2 5 2 2
3
C H CH C CH
|
CH
(c) 2 5 3
3
C H CH C CH
|
CH
(1) (a) and (c) (2) (c) only (3) (a) and (b) (4) All of these
2.(4) 3
3
3 3 3
CH O Na
3 2 2 3 3 2 2 3 3 2 3CH OH
3
CH CH CH
| | |
CH C CH CH CH CH C CH CH CH CH C CH CH CH
| |
Cl OCH
N(S 1 product) ( product)E1 and E2
3
2 2 2 3
CH
|
CH C CH CH CH
3. Which of the following compounds is metallic and ferromagnetic ?
(1) CrO2 (2) VO2 (3) MnO2 (4) TiO2
3.(1) CrO2 is metallic and ferromagnetic substance (fact).
Read NCERT (XIIth) - Chapter-1/The Solid State-Page-28
4. Which of the following statements about low density polythene is FALSE ?
(1) It is a poor conductor of electricity
(2) Its synthesis requires dioxygen or a peroxide initiator as a catalyst
(3) It is used in the manufacture of buckets, dust-bins etc
(4) Its synthesis requires high pressure
4.(3) Low density polythene is chemically inert and tough but flexible and a poor conductor of electricity. Hence, it is
used in the insulation of electricity carrying wires and manufacture of squeeze bottles, toys and flexible pipes.
5. For a linear plot of log (x/m) versus log p in Freundlich adsorption isotherm, which of the following statements is
correct ? (k and n are constants)
(1) 1/n appears as the intercept (2) Only 1/n appears as the slope
(3) log (1/n) appears as the intercept (4) Both k and 1/n appear in the slope term
5.(2)
x 1
log log k log P
m n
(NCERT (XIIth-Chapter-5/Surface Chemistry-Page-125)
6. The heats of combustion of carbon and carbon monoxide are 393.5 and 1
283.5kJ mol
, respectively. The
heat of formation (in kJ) of carbon monoxide per mole is :
(1) 676.5 (2) 676.5 (3) 110.5 (4) 110.5
3. IIT JEE-2016 3 JEE Entrance Examination
6.(3)
2 2
2 2
C O CO [i]
1
CO O CO [ii]
2
2 f CO (i) (ii)
1
C O CO H ( H H ) 393.5 ( 283.5) 110.0
2
7. The hottest region of Bunsen flame shown in the figure below is :
(1) region 2 (2) region 3 (3) region 4 (4) region 1
7.(1)
8. Which of the following is an anionic detergent?
(1) Sodium lauryl sulphate (2) Cetyltrimethyl ammonium bromide
(3) Glyceryl oleate (4) Sodium stearate
8.(1)
2 4
3
H SO NaOH aq
3 2 2 3 2 2 3 3 2 210 10 10
CH CH CH OH CH CH CH OSO H CH CH CH OSO Na
Sodium lauryl sulphate (Anionic detergent)
(Read NCERT-XIIth-Chapter 16-Chemistry in Every day life/Page-452)
9. 18 g glucose 6 12 6C H O is added to 178.2 g water. The vapor pressure of water (in torr) for this aqueous
solution is:
(1) 76.0 (2) 752.4 (3) 759.0 (4) 7.6
9.(2) C H O 206 12 6
n
18 178.2
n 0.1, n 9.9
180 18
6 12 6C H O B
A
0.1 0.1 p p
0.01, Now 0.01 P 7.6 torr
0.1 9.9 10 760P
n watersol
P P P 760 7.6 752.4 torr
10. The distillation technique most suited for separating glycerol from spent-lye in the soap industry is:
(1) Fractional distillation (2) Steam distillation
(3) Distillation under reduced pressure (4) Simple distillation
10.(3) Steam distillation is preferred for separation of substances which are steam volatile and are immiscible with
water.
Fractional distillation is used if the difference in boiling points of two liquids is not much. This technique is used
to separate different fractions of crude oil in petroleum industry.
Distillation under reduced pressure is used to purify liquids having very high boiling points and those, which
decompose at or below their boiling points. Glycerol can be separated from spent-lye in soap industry by using
this technique
4. -2016 4 JEE Entrance Examination
Simple distillation This technique is used to separate volatile liquids from nonvolatile impurities or liquids
having sufficient difference in their boiling points.
11. The species in which the N atom is in a state of sp hybridization is :
(1) 2
NO
(2) 3NO
(3) 2NO (4) 2NO
11.(4)
12. Decomposition of 2 2H O follows a first order reaction. In fifty minutes the concentration of 2 2H O decreases
from 0.5 to 0.125 M in one such decomposition. When the concentration of 2 2H O reaches 0.05 M, the rate of
formation of 2O will be:
(1) 4 1
6.93 10 molmin
(2) 1
2.66Lmin atSTP
(3) 2 1
1.34 10 molmin
(4) 2 1
6.93 10 molmin
12.(1) In fifty minutes the concentration of H2O2 decreases from 0.5 to 0.125 M.
It means two half lives must have passed
1/ 22 50t minutes
1/2 25t minutes
10.693
min
25
k
Also 2 2
2 2
d[H O ]
k[H O ]
dt
10.693
(0.05)mol min
25
As per reaction
2 2 2 22H O 2H O O
2 2 2d[O ] 1 d[H O ]
dt 2 dt
11 0.693
0.05 mol min
2 25
4 1
6.93 10 mol min
13. The pair having the same magnetic moment is : At.No.: Cr 24,Mn 25,Fe 26,Co 27
(1)
2
2 6
Cr H O
and
2
2 6
Fe H O
(2)
2
2 6
Mn H O
and
2
2 6
Cr H O
(3) 2
4CoCl
and
2
2 6
Fe H O
(4)
2
2 6
Cr H O
and 2
4CoCl
13.(1) 2 2 4
2 6[Cr(H O) ] Cr , [Ar] 3d
2 2 6
2 6[Fe(H O) ] Fe , [Ar]3d
2 2 5
2 6[Mn(H O) ] Mn , [Ar]3d
2 2 7
4[CoCl ] Co , [Ar]3d
5. IIT JEE-2016 5 JEE Entrance Examination
14. The absolute configuration of
(1) (2S, 3R) (2) (2S, 3S) (3) (2R, 3R) (4) (2R, 3S)
14.(1) Order of priority of substituent of C-2 is OH > CH(Cl)(CH3) > COOH
(Z)
Order of priority is in anti-clockwise direction hence, its configuration is S.
Order of priority of substituent of C-3 is Cl > CH(OH)COOH > CH3
(Z )
Order of priority is in clockwise direction hence, its configuration is R.
15. The equilibrium constant at 298 K for a reaction A B C D is 100. If the initial concentration of all the
four species were 1M each, then equilibrium concentration of D (in 1
mol L
) will be :
(1) 0.818 (2) 1.818 (3) 1.182 (4) 0.182
15.(2) Initially at equilibrium
eqA B C D K 100
1 1 1 1 Q 1
(1 x) (1 x) 1 x 1 x
2
eq 2
[C][D] (1 x)(1 x) (1 x)
K
[A][B] (1 x)(1 x) (1 x)
1 x
10
1 x
On solving
9
x
11
[D] 1.818
16. Which one of the following ores is best concentrated by froth floatation method ?
(1) Siderite (2) Galena (3) Malachite (4) Magnetite
16.(2) Sulphide ores are concentrated by forth floatation process
Galena PbS Siderite 3FeCO Malachite 3 2CuCO . Cu(OH) Magnetite 3 4Fe O
17. At 300 K and 1 atm, 15 mL of a gaseous hydrocarbon requires 375 mL air containing 20% O2 by volume for
complete combustion. After combustion the gases occupy 330 mL. Assuming that the water formed is in liquid
form and the volumes were measured at the same temperature and pressure, the formula of the hydrocarbon is :
6. IIT JEE-2016 6 JEE Entrance Examination
(1) C3H8 (2) C4H8 (3) C4H10 (4) C3H6
17.(None) x y 2 2 2
y y
C H (g) x O (g) xCO (g) H O(l)
4 2
15 ml
y
15 x ml
4
15 x ml
2O used = 20% of 375 = 75 ml
Inert part of air = 80% of 375 = 300 ml
Total volume of gases = CO2 + Inert part of air = 330 ml
Vol of CO2 = 30 ml
Two equations are x = 2, y = 12
None of the option matches.
18. The pair in which phosphorous atoms have a formal oxidation state of +3 is :
(1) Pyrophosphorous and hypophosphoric acids (2) Orthophosphorous and hypophosphoric acids
(3) Pyrophosphorous and pyrophosphoric acids (4) Orthophosphorous and pyrophosphorous acids
18.(4) 3 3H PO is orthophosphorous acid :
O
||
HO P OH
|
H
4 2 5H P O is pyrophosphorous acid :
O O
|| ||
HO P O P OH
| |
H H
Read NCERT (XIIth)-Chapter-7/p-Block Elements-Page-179
19. Which one of the following complexes shows optical isomerism ?
(1) cis [Co(en)2Cl2]Cl (2) trans [Co(en)2Cl2]Cl
(3) [Co(NH3)4Cl2]Cl (4) [Co(NH3)3Cl3]
(en = ethylenediamine)
19.(1)
3 4 2[Co(NH ) Cl ]Cl can exist in both cis and trans form and both are optically inactive.
Read NCERT (XIIth)-Chapter-9/Co-ordination Compounds-Page-259
trans cis
3 3 3[Co(NH ) Cl ] exist in fac and Mer forms and both are optically inactive.
7. IIT JEE-2016 7 JEE Entrance Examination
20. The reaction of zinc with dilute and concentrated nitric acid, respectively, produces:
(1) 2NO and NO (2) NO and N2O (3) 2NO and 2N O (4) 2N O and 2NO
20.(4) 3 3 2 2 2
conc.
Zn 4HNO Zn(NO ) 2H O 2NO
3 3 2 2 24Zn 10HNO 4Zn(NO ) N O 5H O
dil
21. Which one of the following statements about water is FALSE?
(1) Water can act both as an acid and as a base
(2) There is extensive intramolecular hydrogen bonding in the condensed phase
(3) Ice formed by heavy water sinks in normal water
(4) Water is oxidized to oxygen during photosynthesis
21.(2) Water shows only intermolecular H-bond in the condensed phase
22. The concentration of fluoride, lead, nitrate and iron in a water sample from an underground lake was found to be
1000 ppb, 40 ppb, 100 ppm and 0.2 ppm, respectively. This water is unsuitable for drinking due to high
concentration of :
(1) Lead (2) Nitrate (3) Iron (4) Fluoride
22.(2) In drinking water maximum permissible concentration of
Lead about 50 ppb
Nitrate about 50 ppm
Iron about 0.2 ppm
Fluoride about < 1 ppm
High concentration of nitrate in drinking water can cause disease such as methemoglobinemia.
Read NCERT (XIth)-Chapter-14/Environmental Chemistry-Page-412
23. The main oxides formed on combustion of Li, Na and K in excess of air are, respectively:
(1) 2 2 2 2LiO , Na O and K O (2) Li2O2, Na2O2 and KO2
(3) 2 2 2 2Li O, Na O and KO (4) 2 2 2Li O,Na O and KO
23.(3) Li mainly forms 2Li O Na mainly forms 2 2Na O K mainly forms 2KO
24. Thiol group is present in:
(1) Cystine (2) Cysteine (3) Methionine (4) Cytosine
24.(2) Cysteine is amino acid having thiol group
2
2
HS CH CH COOH
|
NH
Read NCERT (XIIth)-Chapter-14/Biomolecules-Page-413
25. Galvanization is applying a coating of:
(1) Cr (2) Cu (3) Zn (4) Pb
25. (3) Galvanization means applying a coating of zinc metal to prevent corrosion.
26. Which of the following atoms has the highest first ionization energy?
(1) Na (2) K (3) Sc (4) Rb
26.(3) NaIE 496 kJ / mol ; ScIE 633 kJ / mol
It is relatively difficult to remove on e
from 4s orbital of Sc as compared to 3S of Na due to poor shielding of
d-orbital.
8. IIT JEE-2016 8 JEE Entrance Examination
27. In the Hofmann bromamide degradation reaction, the number of moles of NaOH and 2Br used per mole of
amine produced are:
(1) Four moles of NaOH and two moles of 2Br (2) Two moles of NaOH and two moles of 2Br
(3) Four moles of NaOH and one mole of 2Br (4) One mole of NaOH and one mole of 2Br
27.(3) 2 2 2 2 3 2RCONH 4NaOH Br RNH Na CO 2NaBr 2H O
Read NCERT (XIIth)-Chapter-13/Amines-Page-386
28. Two closed bulbs of equal volume (V) containing an ideal gas initially at pressure ip and temperature 1T are
connected through a narrow tube of negligible volume as shown in the figure below. The temperature of one of
the bulbs is then raised to 2T . The final pressure fp is:
(1) 1
1 2
2
i
T
p
T T
(2) 2
1 2
2
i
T
p
T T
(3) 1 2
1 2
2
i
T T
p
T T
(4) 1 2
1 2
i
T T
p
T T
28.(2)
Number of mol of gases in each container
1
ip V
RT
Total mol of gases in both containers
1
2 ip V
RT
In left chamber 1
1
fp V
n
RT
and In right chamber, 2
2
fp V
n
RT
Total moles of gases should remain constant 2
1 1 2 1 2
2
2
f fi
f i
p V p Vp V T
p p
RT RT RT T T
29. The reaction of propene with HOCl 2 2(Cl H O) proceeds through the intermediate:
(1) 3 2CH CH CH Cl
(2) 3 2CH CH(OH) CH
(3) 3 2CH CHCl CH
(4) 3 2CH CH CH OH
29.(1)
HO Cl OH
3 2 3 2 3 2Electrophilic addition
Intermediate
CH — CH CH CH — CH — CH — Cl CH — CH— CH — Cl
|
OH
30. The product of the reaction given below is:
(1) (2) (3) (4)
9. IIT JEE-2016 9 JEE Entrance Examination
30.(1)
PART-C MATHEMATICS
31. Two sides of a rhombus are along the lines, 1 0x y and 7 5 0x y . If its diagonals intersect at
1, 2 , then which one of the following is a vertex of this rhombus ?
(1) 3, 8 (2)
1 8
,
3 3
(3)
10 7
,
3 3
(4) 3, 9
31.(2)
32. If the 2nd
, 5th
and 9th
terms of a non-constant A.P. are in G.P., then the common ratio of this G.P. is :
(1)
4
3
(2) 1 (3)
7
4
(4)
8
5
32.(1) 4 8a d , a d, a d
2
4 8a d a d a d
2 2 2 2
16 8 9 8a d ad a ad d
2
8d ad
8 0a d, d
4 12 4
9 3
a d d
r
a d d
33. Let P be the point on the parabola, 2
8y x which is at a minimum distance from the centre C of the
circle, 22
6 1x y . Then the equation of the circle, passing through C and having its centre at P is:
(1) 2 2
4 12 0x y x y (2) 2 2
2 24 0
4
x
x y y
(3) 2 2
4 9 18 0x y x y (4) 2 2
4 8 12 0x y x y
33.(4) 2
2 4 0 6t , t ,
24
4 4 6F t t t
P
A B(1, 2)
3 6, D 1 8
3 3
C ,
7 15 0x y
7 5 0x y
1 0x y
10. IIT JEE-2016 10 JEE Entrance Examination
= 4 2
4 4 9 12t t t
= 4 2
4 4 12 9t t t
3
4 4 8 12 0F' t t t
3
2 3 0t t
1t
2 2
4 8 12 0x y x y
34. The system of linear equations
0x y z
0x y z
0x y z
has a non-trivial solution for :
(1) exactly one value of (2) exactly two values of
(3) exactly three values of (4) infinitely many values of
34.(3)
1 1
1 1 0
1 1
2
1 1 1 0
1 1 1 1 0
1 0 1or or
35. If
1
2 3 , 0f x f x x
x
and :S x R f x f x ; then S :
(1) contains exactly one element (2) contains exactly two elements
(3) contains more than two elements (4) is an empty set
35.(2)
1
2 3 0f x f x, x
x
1 3
2f f x
x x
6
3 3f x x
x
2
f x x
x
2 2
f x f x x x
x x
4
2x
x
2
2 2x x
36. Let
1
2 2
0
lim 1 tan x
x
p x
then log p is equal to :
11. IIT JEE-2016 11 JEE Entrance Examination
(1) 1 (2)
1
2
(3)
1
4
(4) 2
36.(2) 21 11
tan
2 2 22
0 0
lim 1 tan lim
x
xx
x x
p x e e
1
log
2
e p
37. A value of for which
2 3 sin
1 2 sin
i
i
is purely imaginary, is :
(1)
6
(2) 1 3
sin
4
(3) 1 1
sin
3
(4)
3
37.(3) 2
Re 2 3 sin 1 2 sin 2 6sin 0i i
2 1
sin
3
38. The eccentricity of the hyperbola whose length of the latus rectum is equal to 8 and the length of its
conjugate axis is equal to half of the distance between its foci, is :
(1)
4
3
(2)
2
3
(3) 3 (4)
4
3
38.(2)
2
2
8
b
a
2b ae
2 2 2
4b a e
2 2 2 2
4 1a e a e
2
3 4e
2
3
e
39. If the standard deviation of the numbers 2, 3, a and 11 is 3.5, then which of the following is true :
(1) 2
3 32 84 0a a (2) 2
3 34 91 0a a
(3) 2
3 23 44 0a a (4) 2
3 26 55 0a a
39.(1) Variance
22 22
4 9 121 16
4 4
i ix x a a
n n
2 2
4 134 256 32
16
a a a
2
2 7
3 32 280 16 4 49
2
a a
2
3 32 84 0a a
40. The integral
12 9
3
5 3
2 5
1
x x
dx
x x
is equal to :
12. IIT JEE-2016 12 JEE Entrance Examination
(Where C is an arbitrary constant)
(1)
10
25 3
2 1
x
C
x x
(2)
5
25 3
2 1
x
C
x x
(3)
10
2
5 3
2 1
x
C
x x
(4)
5
2
5 3
1
x
C
x x
40. (1)
12 9
3
5 3
2 5
1
x x
dx
x x
12 9
3
15 2 5
2 5
1
x x
dx
x x x
3 6
35 2
2 5
1
x x
dx
x x
5 2
1x x t
6 3
5 2x x dx dt
2 10
3 2 25 3
1
2 2 2 1
dt t x
C C C
t t x x
41. If the line,
3 2 4
2 1 3
x y z
lies in the plane, 2 2
9 thenlx my z , l m is equal to:
(1) 18 (2) 5 (3) 2 (4) 26
3 2 5m …… (i)
2 3 0m
2 3m …… (ii)
4 2 6m …… (iii)
(iii) – (i)
1
1m 2 2
2m
42. If 0 2x , then the number of real values of x, which satisfy the equation cosx + cos2x + cos3x +
cos4x = 0, is :
(1) 5 (2) 7 (3) 9 (4) 3
5 3 5
2cos cos 2cos cos 0
2 2 2 2
x x x x
5 3
2cos cos cos 0
2 2 2
x x x
5
2cos 2cos cos 0
2 2
x x
x
3
cos 0 ,
2 2
x x
cos 0
2
x
x
5 3 7 9
cos 0 , , ,
2 5 5 5 5
x
x
5
isrepeated
5
13. IIT JEE-2016 13 JEE Entrance Examination
43. The area (in sq. units) of the region 2 2 2
2 and 4 0 0x, y : y x x y x, x ,y is :
(1)
8
3
(2)
4 2
3
(3)
2 2
2 3
(4)
4
3
43.(1) 2 2
4 0x y x
2
2y x
2
2 4 0x x x
2
2 0x x
2 0x x
0, 2x x
Area
2 2
22 2
0 0
4 2 2 2 2x x x dx x x dx
23
2 1 2
0
2 4 2 2 2 2
4 sin 2 2 2 2
2 2 2 3 3 2
x x
x x x
8
3
44. Let anda , b c
be three unit vectors such that 3
2
a b c b c
. If b
is not parallel to c
, then
the angle between anda b
is:
(1)
2
(2)
2
3
(3)
5
6
(4)
3
4
44.(3) 3
2
a b c b c
3 3
2 2
a . c b a · b c b c
3 3
and
2 2
a · c a · b
Angle between 30a & c
5
150
6
a & b
45. A wire of length 2 units is cut into two parts which are bent respectively to form a square of side = x
units and a circle of radius = r units. If the sum of the areas of the square and the circle so formed is
minimum, then:
(1) 4 x r (2) 2x r
(3) 2x = r (4) 2 4x r
45.(2) 4 2 2 2 1x r x r
1 2x
r
2 2
f x x r
14. -2016 14 JEE Entrance Examination
=
2
2
2
1 2x
x
2
2 1 2x
f x x
2 1 2 2
2 0
x
f ' x x
2 1 2x
x
2 4x x
1
2 4
2
r
x
2 2 1x r
2 2 2x r
2x r .
46. The distance of the point 1 5 9, , from the plane 5x y z measured along the line x = y = z is :
(1) 10 3 (2)
10
3
(3)
20
3
(4) 3 10
46.(1) Equation of line:
1 5 9
1 1 1
x y z
Any point is 1 5 9, ,
It lies on plane
1 5 9 5
1 5 9 5
10 0
10
Point is 9 15 1 another is 1 5 9, , , , ,
Distance = 100 100 100 10 3
47. If a curve y = f (x) passes through the point 1 1, and satisfies the differential equation,
y (1 + xy) dx = xdy, then
1
2
f
is equal to :
(1)
4
5
(2)
2
5
(3)
4
5
(4)
2
5
47.(3) 1y xy dx xdy
2dy y
y
dx x
2dy y
y
dx x
Bernaulli’s DE
2n
I.F
1 1
1 2
e e
dx dx x
x x
, Solution 1 2
1 2 1y x x dx
2
2
x x
C
y
Given 1 1f
15. IIT JEE-2016 15 JEE Entrance Examination
1 1 1
1 2 2
C C
equation
2
1
2 2
x x
y
When
1 1 1 1
, we have
2 2 4 2 2
x
y
1 5 4
4 5
y
y
48. If the number of terms in the expansion of 2
2 4
1 0
n
, x
x x
, is 28, then the sum of the coefficients
of the terms in this expansion, is :
(1) 2187 (2) 243 (3) 729 (4) 64
48.(3)
2
2 4
1
n
x x
Assuming all dissimilar terms
2
2 28n
C
6n
Sum of all coefficients 6
3 729
49. Consider 1 1
0
1 2
sin x
f x tan , x ,
sin x
. A normal to at
6
y f x
also passes through the
point :
(1)
2
0
3
,
(2) 0
6
,
(3) 0
4
,
(4) (0, 0)
49.(1) 1 1 sin
tan ; 0,
1 sin 2
x
f x x
x
2
1 sin cos 1 sin cos1 1
1 sin 1 sin 1 sin1 2
1 sin 1 sin
x x x x
f x
x x x
x x
At
6
x
2
1 1 2 3 / 2 1 1 3 1 1
4 3
1 16 1 3 4 21 2 3 2 311 1
2 421 221 11 1
2 2
f
Slope of normal 2
Point at
6
x
1 1
1
1
2tan tan 3
16 31
2
f
equation 2
3 6
y x
2
3 3
y x
2
2
3
y x
16. IIT JEE-2016 16 JEE Entrance Examination
50. For 2 andx R , f x |log sin x| g x f f x , then :
(1) 0 2g' cos log
(2) 0 2g' cos log
(3) g is differentiable at x = 0 and 0 2g' sin log
(4) g is not differentiable at x = 0
0 0 0g f f f
For 0, log 2 sinx x
log 2 sinf x x cos 0 1f x x f
Also, log 2, log2 sin log2 sinx x f x x
cos log 2 cos log 2f x x f
0 cos log2 1 cos log2g
51. Let two fair six-faced dice A and B be thrown simultaneously. If 1E is the event that die A shows up four,
2E is the event that die B shows up two and 3E is the event that the sum of numbers on both dice is odd,
then which of the following statements is NOT true ?
(1) 2 3andE E are independent (2) 1 3andE E are independent
(3) 1 2 3, andE E E are independent (4) 1 2andE E are independent
51.(3) 1
1
6
P E
2
1
6
P E
3
2 4 6 4 2 1
36 2
P E
2 3 2 3
1 1
6 2
P E E P E P E
1 3 1 3
1 1
6 2
P E E P E P E
1 2 3 1 2 30P E E E P E P E P E
52. If
5
3 2
a b
A
and T
A adj A AA , then 5a b is equal to :
(1) 5 (2) 4 (3) 13 (4) 1
52.(1) T
nA adj A A I AA [Given]
10 3A a b
5 3
2
T a
A
b
5 5 3 10 3 0
3 2 2 0 10 3
T a b a a b
AA
b a b
2 2 10 3 025 15 2
0 10 315 2 13
a ba b a b
a ba b
15 2 0a b
2
15
b
a & 10 3 13a b
13 3
10
b
a
17. IIT JEE-2016 17 JEE Entrance Examination
2 13 3
15 10
b b
4 39 9b b 13 39b 3b
2 6 2
3
15 15 5
a 5 2a
5 2 3 5a b
53. The Boolean Expression p q q p q is equivalent to :
(1) p q (2) p q (3) p q (4) p q
53.(2) p q q p q
p q q q p q
p q t p q
p q p q
p q p p q q
t q p q t p q p q
54. The sum of all real values of x satisfying the equation
2
4 602
5 5 1
x x
x x
is :
(1) 4 (2) 6 (3) 5 (4) 3
54.(4)
2
4 60
2
5 5 1
x x
x x
Case – I
2
4 60 0x x
10x
6x
Case – II
2
5 5 1x x
2
5 4 0x x
1x
4x
Case – III
2
5 5 1x x
2
5 6 0x x
2 or 3x
For 2x
2
4 60 48x x
For 3x
2
4 60 39x x
2x
Sum of all real value 3
18. IIT JEE-2016 18 JEE Entrance Examination
55. The centres of those circles which touch the circle, 2 2
8 8 4 0x y x y , externally and also touch
the x-axis, lie on :
(1) an ellipse which is not a circle. (2) a hyperbola
(3) a parabola (4) a circle
55.(3) 2 2
8 8 4 0x y x y
4 4 6C , r
Let centre be (x1, y1)
Radius = |y1| C1 C2 = r1 + r2
2 2
1 1 14 4 6x y | y |
2 2 2
1 1 1 14 4 36 12x y y | y |
2
1 1 11 8 8 4 12x x y | y |
1 0y 2
1 1 1 18 8 4 12x x y y
2
1 1 18 4 20x x y
2
1 14 20 20x y
2
1 14 20 1x y Parabola
y1 < 0 2
1 1 1 18 8 4 12x x y y
2
1 1 18 4 4x x y
2 2
1 1 14 20 4 4 4 5 parabolax y x y
56. If all the words (with or without meaning) having five letters, formed using the letters of the word
SMALL and arranged as in a dictionary ; then the position of the word SMALL is :
(1) 59th
(2) 52nd
(3) 58th
(4) 46th
56.(3)
4
12
2
A
4 24L
4
12
2
M
3
3
2
SA
3 6SL
Total 57
Next word is SMALL.
57.
1
2
1 2 3
/ n
nn
n n . ....... n
lim
n
is equal to :
(1) 2
27
e
(2) 2
9
e
(3) 3 3 2log (4) 4
18
e
57.(1)
1
1 2 3 2
/ n
n n n n n
. . . . .......
n n n n
1 1 2 2n n n n
log log log ........ log
n n n n
19. IIT JEE-2016 19 JEE Entrance Examination
2
0
1log log x dx 1 + x = t
3
1
log log t dt
1
log t log t . t dt
t
1log t log t
3 3 1 1 1 1log log log
= 3 3 2log
= 2
27log log e
= 2
27
log log
e
2
27
e
58. If the sum of the first ten terms of the series
2 2 2 2
23 2 1 4 16
1 2 3 4 4 is
5 5 5 5 5
..., m
, then
m is equal to :
(1) 101 (2) 100 (3) 99 (4) 102
58.(1)
2 2 2 2
8 12 16 20
5 5 5 5
nS
2 2 2 21
8 12 16 20
25
nS ......
10
2
1
1
4 4
25
n
n
S n
=
10
2
1
16
1
25n
n
=
10
2
1
16
2 1 35 11
25n
n n .
=
16 10 11 21 10 11
10
25 6 2
. . .
=
16
385 110 10
25
=
16 16
505 101 101
25 5
m
59. If one of the diameters of the circle, given by the equation, 2 2
4 6 12 0x y x y is a chord of a
circle S, whose centre is at 3 2, , then the radius of S is :
(1) 5 3 (2) 5 (3) 10 (4) 5 2
59.(1)
3 2,
5
50
2 3,
5 3
20. IIT JEE-2016 20 JEE Entrance Examination
60. A man is walking towards a vertical pillar in a straight path, at a uniform speed. At a certain point A on
the path, he observes that the angle of elevation of the top of the pillar is 30
. After walking for 10
minutes from A in the same direction, at a point B, he observes that the angle of elevation of the top of the
pillar is 60
. Then the time taken (in minutes) by him, from B to reach the pillar, is :
(1) 10 (2) 20 (3) 5 (4) 6
60.(3) Let speed be “ v ”
60 3
b
tan
y
3b y …(i)
30
b
tan
x y
1
3
b
x y
3x y b …(ii)
110 3 3v vt y .
110 3v vt y
1 110 3v vt vt
1 110 3t t
12 10t
t1 = 5.
PART-A PHYSICS
61. A uniform string of length 20 m is suspended from a rigid support. A short wave pulse is introduced at its lowest
end. It starts moving up the string. The time taken to reach the support is: (Take g = 10 ms–2
)
(1) 2 s (2) 2 2 s (3) 2 s (4) 2 2 s
61.(2)
Mgx
T
L
Mgx
T LV gx
M
L
dx
gx
dt
0
L
dx
gt
x
A B
C
30
60
x y
b
21. IIT JEE-2016 21 JEE Entrance Examination
20
0
2 10x t
2 20 10t
2 2t s
62. A person trying to lose weight by burning fat lifts a mass of 10 kg upto a height of 1 m 1000 times. Assume that
the potential energy lost each time he lowers the mass is dissipated. How much fat will he use up considering the
work done only when the weight is lifted up? Fat supplies 3.8×107
J of energy per kg which is converted to
mechanical energy with a 20 % efficiency rate. Take g = 9.8 ms–2
.
(1) 3
6.45 10 kg
(2) 3
9.89 10 kg
(3) 3
12.89 10 kg
(4) 3
2.45 10 kg
62.(3) PE = mgh × 1000 10 9 8 1 1000.
4
10 9 8PE . J
If mass lost is m, then
Energy = 72
3 8 10
10
m . J
So, 4 71
9 8 10 3 8 10
5
. m . . 35
10 9 8
3 8
m .
.
2
1 289 10. kg
63. A point particle of mass m, moves along the uniformly rough track PQR as shown in the figure. The coefficient
of friction, between the particle and the rough track equals . The particle is released, from rest, from the point
P and it comes to rest at a point R. The energies, lost by the ball, over the parts, PQ and QR, of the track, are
equal to each other, and no energy is lost when particle changes direction from PQ to QR. The values of the
coefficient of friction and the distance x (=QR) , are, respectively close to :
(1) 0.2 and 3.5 m (2) 0.29 and 3.5 m (3) 0.29 and 6.5 m (4) 0.2 and 6.5 m
63.(2)
2
PQW mg cos .
sin
2
2 3
mg
mg
tan
QRW mg .x 2 3 3 5x . m
P.E. lost = 2mgh mg
2 4 3mg mg
1
0 29
2 3
.
64. Two identical wires A and B, each of length ‘l’ carry the same current I. Wire A is bent into a circle of radius R
and wire B is bent to form a square of side ‘a’. If BA and BB are the values of magnetic field at the centres of the
circle and square respectively, then the ratio A
B
B
B
is:
(1)
2
16 2
(2)
2
16
(3)
2
8 2
(4)
2
8
22. IIT JEE-2016 22 JEE Entrance Examination
64.(3) 2 R
2
R
0 0
2
a
I I
B
R
04 45 45
4
2
B
I
B sin sin
a
08 2
B
I
B
2
8 2
A
B
B
B
65. A galvanometer having a coil resistance of 100 gives a full scale deflection, when a current of 1 mA is passed
through it. The value of the resistance, which can convert this galvanometer into ammeter giving a full scale
deflection for a current of 10 A, is :
(1) 2 (2) 0.1 (3) 3 (4) 0.01
65.(4)
1 100 10 1 .mA mA x
1
10 10x
1
0.01
100
x
66. An observer looks at a distant tree of height 10 m with a telescope of magnifying power of 20. To the observer
the tree appears:
(1) 10 times nearer (2) 20 times taller (3) 20 times nearer (4) 10 times taller.
66.(2) 20 times taller as the angular magnification is 20 and we observe angular magnification.
Option (3) would not be very correct as the telescope can be adjusted to form image anywhere between infinity
and least distance for distinct vision. Suppose that the image is formed at infinity. Then the observer will have to
focus the eyes at infinity to observe the image. Hence it is incorrect to say that the image will appear nearer to
the observer.
67. The temperature dependence of resistances of Cu and undoped Si in the temperature range 300-400K, is best
described by:
(1) Linear increase for Cu, exponential increase for Si
(2) Linear increase for Cu, exponential decrease for Si
(3) Linear decrease for Cu, linear decrease for Si
(4) Linear increase for Cu, linear increase for Si
67.(2) Resistance of conductor increases and resistance of a semiconductor decreases with increase in temperature
68. Choose the correct statement:
23. IIT JEE-2016 23 JEE Entrance Examination
(1) In amplitude modulation the frequency of the high frequency carrier wave is made to vary in proportion
to the amplitude of the audio signal
(2) In frequency modulation the amplitude of the high frequency carrier wave is made to vary in proportion
to the amplitude of the audio signal
(3) In frequency modulation the amplitude of the high frequency carrier wave is made to vary in proportion
to the frequency of the audio signal
(4) In amplitude modulation the amplitude of the high frequency carrier wave is made to vary in proportion
to the amplitude of the audio signal
68.(4) Fact
69. Half – lives of two radioactive elements A and B are 20 minutes and 40 minutes, respectively. Initially the
samples have equal number of nuclei. After 80 minutes, the ratio of decayed numbers of A and B nuclei will be :
(1) 4 : 1 (2) 1 : 4 (3) 5 : 4 (4) 1 : 16
69.(3) For A: Number of half lives = 80/20 = 4
0
4
2
x
A
0 0
1 15
1
16 16
A x x
For B : Number of half lives = 80/40 = 2
0
2
2
x
B
03
4
x
B
15/16
5: 4
3/ 4
A
B
70. ‘n’ mole of an ideal gas undergoes a process A B as shown in the figure.
The maximum temperature of the gas during the process will be :
(1) 0 03
2
P V
nR
(2) 0 09
2
P V
nR
(3) 0 09P V
nR
(4) 0 09
4
P V
nR
70.(4) 0
0
0
3
P
P V P
V
PV nRT
20
0
0
1
3
P
T V P V
nR V
For 0max
dT
T ,
dV
0
0
0
2 3 0
P
V P
V
0
3
2
V V
20 0 0
0 0 0
0
1 9 3 9
3
4 2 4
max
P P V
I V P V
nR V nR
Alternate :
Directly by using isotherms we can see that highest temperature will occur at the midpoint.
24. IIT JEE-2016 24 JEE Entrance Examination
71. An arc lamp requires a direct current of 10 A at 80 V to function. If it is connected to a 220 V (rms), 50 Hz AC
supply, the series inductor needed for it to work is close to :
(1) 0.08 H (2) 0.044 H (3) 0.065 H (4) 80 H
71.(3)
80
8
10
R
2
10
64
rms
rms
L
V
i A
X
2 2
22 64 LX 420LX
2 50 420L
420
100
L
2
10
42 6.5 0.065L H
72. A pipe open at both ends has a fundamental frequency f in air. The pipe is dipped vertically in water so that half
of it is in water. The fundamental frequency of the air column in now :
(1)
3
4
f
(2) 2 f (3) f (4)
2
f
72.(3)
Fundamental freq remains same
73. The box of a pin hole camera, of length L, has a hole of radius a, It is assumed that when the hole is illuminated
by a parallel beam of light of wavelength the spread of the spot (obtained on the opposite wall of the camera)
is the sum of its geometrical spread and the spread due to diffraction. The spot would then have its minimum size
minsay b when :
(1)
2
2
and
mina L b
L
(2) and 4 mina L b L
(3)
2
and 4mina b L
L
(4)
2 2
2
and mina b
L L
73.(None) Geometrical spread = a
Diffraction spread =
2 2
L L
a a
Sum (b) =
2
L
a
a
For b to be minimum
2
0 1 0
22
db L L
a
da a
25. IIT JEE-2016 25 JEE Entrance Examination
and 2
2 2
min
L L
b L
No answer is correct.
74. A combination of capacitor is set up as shown in the figure. The magnitude
of the electric field, due to a point charge Q (having a charge equal to the
sum of the sum of the charges on the 4 F and 9 F capacitors), at a
point distant 30 m from it, would equal :
(1) 360 N/C (2) 420 N/C
(3) 480 N/C (4) 240 N/C
74.(2)
Q = 3 8
Q = 24 C
The charges on 4 F and 9 F capacitors are 24 C and 18 C respectively.
Hence,
9
9 10 24 18
420 /
30 30
E N C
75. Arrange the following electromagnetic radiations per quantum in the order of increasing energy :
A : Blue light B : Yellow light C : X-ray D : Radiowave
(1) A, B, D, C (2) C, A B, D (3) B, A, D, C (4) D, B, A, C
75.(4) Energy of one quantum = hv
C A B D D B A C
76. Hysteresis loops for two magnetic materials A and B are given below:
These materials are used to make magnets for electric generators, transformer core and electromagnet core. Then
it is proper to use:
(1) A for electromagnets and B for electric generators.
(2) A for transformers and B for electric generators.
(3) B for electromagnets and transformers.
(4) A for electric generators and transformers.
76.(3) For electromagnets and transformers, energy loss should be low.
26. IIT JEE-2016 26 JEE Entrance Examination
Thin hysteris curves.
Also, 0B when H = 0 and H should be small when B 0.
So option fulfills.
77. A pendulum clock loses 12 s a day if the temperature is 40°C and gains 4 s a day if the temperature is 20°C. The
temperature at which the clock will show correct time, and the co-efficient of linear expansion ( ) of the metal
of the pendulum shaft are respectively:
(1) 4
60 ; 1.85 10 /C C
(2) 3
30 ; 1.85 10 /C C
(3) 2
55 ; 1.85 10 /C C
(4) 5
25 ; 1.85 10 /C C
77.(4) Time loss per day = Δθ 86400
2
1
40 86400 12
2
1
20 86400 4
2
40
3
20
5
25 1 85 10C, . / C
78. The region between two concentric spheres of radii 'a' and 'b',
respectively (see figure), has volume charge density ,
A
r
where A is
a constant and r is the distance from the centre. At the centre of the
spheres is a point charge Q. The value of A such that the electric field in
the region between the spheres will be constant, is: .
(1)
2 2
2
Q
b a
(2)
2 2
2Q
b a
(3)
2
2Q
a
(4)
2
2
Q
a
78.(4) Charge in the region between a and r is calculated as follows :
2
1 4
r
a
A
Q r dr .
r
and 2 2
1 2Q A r a
2 2
12 2
2
K K
E( r ) Q Q Q A r a
r r
2
2 2
2
2
KQ Aa
K A K
r r
For uniform E1 last two terms should cancel
2
2KQ A.a K
2
2
Q
A
a
79. In an experiment for determination of refractive index of glass of a prism by ,i plot, it was found that a ray
incident at angle 35°, suffers a deviation of 40° and that it emerges at angle 79°. In that case which of the
following is closest to the maximum possible value of the refractive index? .
(1) 1.6 (2) 1.7 (3) 1.8 (4) 1.5
79.(4) i e A
40 35 79 A
27. IIT JEE-2016 27 JEE Entrance Examination
74A
Let us put 1 5. and check.
2
1 5
2
minA
sin
.
Asin
74
3
1 5
37
minsin
.
sin
0 9 37
2
m
. sin
Using calculator, 37 64
2
m
54m
This angle is greater than the 40 deviation angle already given. For greater , deviation will be even higher.
Hence of the given prism should be less than 1.5. Hence the closest option will be 1.5.
Upon solving the given case we get 1 31. .
Note : Upon solving with calculator the exact equations for the given case we get 1 31. .
80. A student measures the time period of 100 oscillations of a simple pendulum four times. The data set is 90s, 91s,
95 s and 92 s. If the minimum division in the measuring clock is 1 s, then the reported mean time should be :
(1) 92 5.0s (2) 92 1.8s (3) 92 3s (4) 92 2s
80.(4)
iX
X
N
= 92
2
(Standard dev ) =
2
iX X
N
=
1 4 9 0
4
= 1.8
But since LC of clock is 1s, rounding off to the correct sign : Time : 92 2s
81. Identify the semiconductor devices whose characteristics are given below, in the order (1), (2), (3), (4):
(1) Zener diode, Simple diode, Light dependent resistance, Solar cell
(2) Solar cell, Light dependent resistance, Zener diode, Simple diode
(3) Zener diode, solar cell, Simple diode, Light dependent resistance
(4) Simple diode, Zener diode, Solar cell, Light dependent resistance
81.(4) Fact based question (From NCERT)
82. Radiation of wavelength , is incident on a photocell. The fastest emitted electron has speed . If the
wavelength is changed to
3
,
4
the speed of the fastest emitted electron will be:
(1)
1
24
3
(2)
1
24
3
(3)
1
23
4
(4)
1
23
4
28. -2016 28 JEE Entrance Examination
82.(4) 0
2 hc
V
m
2 4
3
hc
V
m
4
3
hc
V
hcV
4 3
3 4
hc
hc
We can see that
3
4
1
hc
hc
4
3
VV
83. A particle performs simple harmonic motion with amplitude A. Its speed is trebled at the instant that it is at a
distance
2
3
A
from equilibrium position. The new amplitude of the motion is: .
(1) 3A (2) 3A (3)
7
3
A
(4) 41
3
A
83.(3)
1 2
2 2
/
V A x
At 2 2
1
2 4
3 9
A
x , V A A
1 2
2
5
9
/
A
1 5
3
A
V
13 5newV V A
Now
1 2
2 2
/
new newV A x
5A
2 2 2
5nA x A
2
2 2 4
5
9
n
A
A A
7
3
n
A
A
84. A particle of mass m is moving along the side of square of side 'a', with a uniform speed in the x-y plane as
shown in the figure:
Which of the following statements is false for the angular momentum L
about the origin?
29. -2016 29 JEE Entrance Examination
(1) ˆ
2
R
L m a k
when the particle is moving from C to D.
(2) ˆ
2
R
L m a k
when the particle is moving from B to C.
(3) ˆ
2
m
L Rk
when the particle is moving from D to A.
(4) ˆ
2
m
L Rk
when the particle is moving from A to B.
84.(1, 3)Angular momentum of a particle moving in a straight line is L m r v
Hence, 1 and 3 are false.
85. An ideal gas undergoes a quasi static, reversible process in which its molar heat capacity C remains constant. If
during this process the relation of pressure P and volume V is given by n
PV constant, then n is given by (Here
PC and VC are molar specific heat at constant pressure and constant volume, respectively):
(1) P
V
C C
n
C C
(2) P
V
C C
n
C C
(3) V
P
C C
n
C C
(4) P
V
C
n
C
85.(1)
1
v
R
C C
n
1
p v
v
C C
C C
n
1
p v
v
C C
n
C C
1
p v v p v p
v v v
C C C C C C C C
n
C C C C C C
86. A screw gauge with a pitch of 0.5 mm and a circular scale with 50 divisions is used to measure the thickness of a
thin sheet of Aluminium. Before starting the measurement, it is found that when the two jaws of the screw gauge
are brought in contact, the 45th
division coincides with the main scale line and that the zero of the main scale is
barely visible. What is the thickness of the sheet if the main scale reading is 0.5 mm and the 25th
division
coincides with the main scale line?
(1) 0.80 mm (2) 0.70 mm (3) 0.50 mm (4)
0.75 mm
86.(1) L.C. =
0 5
0 01
50
.
. mm
Zero error 0 5 45 0 01 0 05. . . mm
Measured reading = 0 5 25 0 01 0 75. . . mm
Actual reading = Measured reading - Z,E.
0 75 0 05 0 80. mm . . mm
87. A roller is made by joining, together two cones at their vertices O. It is kept on
two rails AB and CD which are placed asymmetrically (see figure), with its axis
perpendicular to CD and its centre O at the centre of line joining AB and CD (see
figure). It is given a light push so that it starts rolling with its centre O moving
parallel to CD in the direction shown. As it moves, the roller will tend to:
(1) turn right. (2) go straight.
(3) turn left and right alternately. (4) turn left.
30. 2016 30 JEE Entrance Examination
87.(4) As the wheel rolls forward the radius of the wheel decreases along AB hence for the same number of rotations it
moves less distance along AB, hence it turns left.
88. If a, b, c, d are inputs to a gate and x is its output, then, as per the following time graph, the gate is:
(1) AND (2) OR (3) NAND (4) NOT
88.(2) Since 1x if either
a, b, c or d = 1
x a b c d
The gate is OR
89. For a common emitter configuration, if and have their usual meanings, the incorrect relationship between
and
(1)
1
(2)
1
(3)
2
2
1
(4)
1 1
1
89.(1,3) We know that
1
So
1 1
1
and
1
are correct
90. A satellite is revolving in a circular orbit at a height ‘h’ from the earth’s surface (radius or earth R; h<<R). The
minimum increase in its orbital velocity required, so that the satellite could escape from the earth’s gravitational
field, is close to : (Neglect the effect of atmosphere)
(1) gR (2) gR / 2 (3) gR 2 1 (4) 2gR
90.(3) 0
GM
V
R h
2
e
GM
V
R h
Increase required = 0 2 1 2 1e
GM
V V gR
R h