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REDOX REACTIONS Oxidation and Reduction
Objectives ,[object Object],[object Object],[object Object]
Redox reactions around us… ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
Introduction ,[object Object],[object Object]
What is oxidation?  A substance is oxidised if one the following happens after a reaction: It  gains oxygen  or It  loses hydrogen  or It  loses electrons  or It  increases  its  oxidation state.
Oxidation — Gain of Oxygen  2Ca(s)  +  O 2 (g)     CaO(s) By the end of the reaction, calcium has gained oxygen. Calcium has been oxidised to calcium oxide .  This process is called  oxidation .
Oxidation — Gain of Oxygen  CH 4 (g) + 2O 2 (g)    CO 2 (g) + 2H 2 O( l ) The  carbon  atom in methane has gained oxygen and  has been  oxidised  to   carbon dioxide . The  hydrogen  atom in methane has also  gained oxygen . Hydrogen has been oxidised to water.
Oxidation — Loss of Hydrogen  A substance is oxidised if it loses hydrogen.  2NH 3 (g)  +  3CuO(s)     N 2 (g)  +  3Cu(s)  +  2H 2 O(g) Ammonia has lost hydrogen. It has been oxidised to nitrogen.
Oxidation — Loss of Electrons When a substance loses electrons during a reaction, it is oxidised. Oxidation reactions can take place  even if there is no oxygen or hydrogen present .  ,[object Object],Look at the equation above. In the next slide, you see how electrons are lost in this reaction.
Oxidation — Loss of Electrons Mg     Mg 2+   +  2e – Each magnesium atom  loses 2 electrons  to form a magnesium ion. ,[object Object],Mg(s)  +  C l 2 (g)     MgC l 2 (s)
Oxidation — Loss of Electrons The copper atom has been oxidised to the copper(II) ion. In the reaction Cu(s)  +  2AgNO 3 (aq)     Cu(NO 3 ) 2 (aq)  +  2Ag(s)  which substance is oxidised? The  ionic equation  for this reaction is Cu(s)  +  2Ag + (aq)     Cu 2+ (aq)  +  2Ag(s) ,[object Object]
Oxidation — Increase in Oxidation State The  oxidation state   is the “ charge ” an atom of an element would have if it existed as an ion in a compound (even if it is actually covalently bonded). The  oxidation state  is also known as  oxidation number .
Various Definitions of Oxidation & Reduction Redox Oxidation Reduction Gain  in Oxygen Loss  in Hydrogen Loss  in Electron (s) Loss  in Oxygen Gain  in Hydrogen   Gain  in Electron (s ) Increase  in Oxidation State Decrease  in Oxidation State 1 2 3 4
Mnemonics for Redox –  OIL - RIG OIL - RIG :  Oxidation is Loss  –  Reduction is Gain Redox Oxidation Reduction Gain   in Oxygen Loss in Hydrogen Loss in Electron (s) Loss   in Oxygen Gain in Hydrogen   Gain in Electron (s )
Test your understanding
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Redox

  • 2.
  • 3.
  • 4.  
  • 5.
  • 6. What is oxidation? A substance is oxidised if one the following happens after a reaction: It gains oxygen or It loses hydrogen or It loses electrons or It increases its oxidation state.
  • 7. Oxidation — Gain of Oxygen 2Ca(s) + O 2 (g)  CaO(s) By the end of the reaction, calcium has gained oxygen. Calcium has been oxidised to calcium oxide . This process is called oxidation .
  • 8. Oxidation — Gain of Oxygen CH 4 (g) + 2O 2 (g)  CO 2 (g) + 2H 2 O( l ) The carbon atom in methane has gained oxygen and has been oxidised to carbon dioxide . The hydrogen atom in methane has also gained oxygen . Hydrogen has been oxidised to water.
  • 9. Oxidation — Loss of Hydrogen A substance is oxidised if it loses hydrogen. 2NH 3 (g) + 3CuO(s)  N 2 (g) + 3Cu(s) + 2H 2 O(g) Ammonia has lost hydrogen. It has been oxidised to nitrogen.
  • 10.
  • 11.
  • 12.
  • 13. Oxidation — Increase in Oxidation State The oxidation state is the “ charge ” an atom of an element would have if it existed as an ion in a compound (even if it is actually covalently bonded). The oxidation state is also known as oxidation number .
  • 14. Various Definitions of Oxidation & Reduction Redox Oxidation Reduction Gain in Oxygen Loss in Hydrogen Loss in Electron (s) Loss in Oxygen Gain in Hydrogen Gain in Electron (s ) Increase in Oxidation State Decrease in Oxidation State 1 2 3 4
  • 15. Mnemonics for Redox – OIL - RIG OIL - RIG : Oxidation is Loss – Reduction is Gain Redox Oxidation Reduction Gain in Oxygen Loss in Hydrogen Loss in Electron (s) Loss in Oxygen Gain in Hydrogen Gain in Electron (s )
  • 17.
  • 18.