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Reactivity and Rates of Reaction
By : Albert Ng
THE MYSTERY
OF
SPONTANEOUS
COMBUSTION
Learning Objectives
 How metals react with oxygen
 How metals react with water
 How metals react with acids
 Displacement reactions
 The reactivity series
 Measuring rate of reaction by change in mass of the
reactants
 Measuring rate of reaction by the change in volume of
the product
 The effect of concentration
 The effect of particles size
 The effect of temperature
 Catalysts
Metal
 Mostly active
 Combined readily with non metals such as oxygen to
form stable compounds
 Example of Metals:
 Aluminium
 Iron
 Lead
 Tin
 Silver
 Gold
 Nickel
Sodium
 Silver-white, highly reactive metal
 Need to be kept under a layer of oil because it
readily react wit water and oxygen in the air to
produce flames
 Very soft metal
 Shiny surface of small cut sodium quickly tarnished
soon it react with air
Comparatively, iron take much longer to react with
air ( Rusting of Iron )
 INDICATION:
Different metals have different speeds at which they react
with other chemicals = Different Reactivity
Reaction of metals with oxygen
 Why most metals lose their lustre over time?
 Metals react with oxygen in the air to form metal oxide.
This process is called oxidation
Metal + Oxygen  Metal Oxide
Example:
Iron + Oxygen  Iron Oxide
When metals heated with oxygen
 A) Copper develop a covering of black powder
without glowing or bursting into flame
 B) Iron glows and produces yellow sparks, a black
powder is left behind
 C) Sodium only needs a little heat to make it burst
into yellow flame and burn quickly to leave a white
powder behind
 D) Gold is not changed after it has been heated and
then left to cool
Reaction of metals with water
 Pg 147
Rocksil wool
soaked in water
Metal
Sample
Rubber Bung
Hydrogen
Water
Heat
Calcium
 A) In COLD water
 Sink
 Form bubble of hydrogen on its surface
 Bubbles increase over time
 Water become cloudy as calcium hydroxide formed
B) Test tube filled with water over fizzing metal
 Gas pushes water out of the test tube
 Tube filled with gas and raised out from water with a light
splint held beneath its mouth
 Popping sound heard because hydrogen in tube react
with oxygen in the air
Copper
 Sink in cold water and does not react with it
 Does not react with steam
Sodium
 Floats on surface of the water
 Bubbles of hydrogen produced around it (Fizzing)
 Gas produced push the metal across the surface
 Metals burst into flame
 Clear solution of sodium hydroxide formed
 VIDEO
Iron
 Sinks in water
 No bubbles of hydrogen formed
 When steamed, hydrogen produced slowly
Magnesium
 Sinks in water
 Bubbles of hydrogen produced very slowly
 Magnesium hydroxide solution formed
 When heated with steam, hydrogen is produced
quickly
Potassium
 Floats on water
 Bursts into flames immediately
 Hydrogen bubbles rapidly produced around the
metal
 Clear solution of potassium hydroxide formed
Reaction of metals with acids
 Pg 149
 Piece of metal placed in tube
 Acid was poured into the tube
 Bubble of hydrogen gas observed
 Reactivity of Metals can be compared by comparing the amount of
hydrogen gas produced in the reaction between acid and different
metals
 Metal+ Hydrochloric Acid  Metal Chloride + Hydrogen
Apparatus used in investigating the reaction of some
metals (Not sodium or potassium) and hydrochloric acid
Refer to Page 149
Reaction of metals with dilute HCL and Concentrated HCL
 Lead
 Did not react with dilute HCL
 Bubbles of hydrogen gas produced slowly
 Zinc
 React slowly with dilute HCL to produce bubbles of hydrogen
 Copper
 Did not react with either dilute or concentrated HCL
 Magnesium
 React quickly with dilute HCL to produce bubbles of hydrogen
Reactivity Series

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Reactivity and rates of reaction

  • 1. Reactivity and Rates of Reaction By : Albert Ng
  • 3. Learning Objectives  How metals react with oxygen  How metals react with water  How metals react with acids  Displacement reactions  The reactivity series  Measuring rate of reaction by change in mass of the reactants  Measuring rate of reaction by the change in volume of the product  The effect of concentration  The effect of particles size  The effect of temperature  Catalysts
  • 4. Metal  Mostly active  Combined readily with non metals such as oxygen to form stable compounds  Example of Metals:  Aluminium  Iron  Lead  Tin  Silver  Gold  Nickel
  • 5. Sodium  Silver-white, highly reactive metal  Need to be kept under a layer of oil because it readily react wit water and oxygen in the air to produce flames  Very soft metal  Shiny surface of small cut sodium quickly tarnished soon it react with air
  • 6. Comparatively, iron take much longer to react with air ( Rusting of Iron )  INDICATION: Different metals have different speeds at which they react with other chemicals = Different Reactivity
  • 7. Reaction of metals with oxygen  Why most metals lose their lustre over time?  Metals react with oxygen in the air to form metal oxide. This process is called oxidation Metal + Oxygen  Metal Oxide Example: Iron + Oxygen  Iron Oxide
  • 8. When metals heated with oxygen  A) Copper develop a covering of black powder without glowing or bursting into flame  B) Iron glows and produces yellow sparks, a black powder is left behind  C) Sodium only needs a little heat to make it burst into yellow flame and burn quickly to leave a white powder behind  D) Gold is not changed after it has been heated and then left to cool
  • 9. Reaction of metals with water  Pg 147 Rocksil wool soaked in water Metal Sample Rubber Bung Hydrogen Water Heat
  • 10. Calcium  A) In COLD water  Sink  Form bubble of hydrogen on its surface  Bubbles increase over time  Water become cloudy as calcium hydroxide formed B) Test tube filled with water over fizzing metal  Gas pushes water out of the test tube  Tube filled with gas and raised out from water with a light splint held beneath its mouth  Popping sound heard because hydrogen in tube react with oxygen in the air
  • 11. Copper  Sink in cold water and does not react with it  Does not react with steam
  • 12. Sodium  Floats on surface of the water  Bubbles of hydrogen produced around it (Fizzing)  Gas produced push the metal across the surface  Metals burst into flame  Clear solution of sodium hydroxide formed  VIDEO
  • 13. Iron  Sinks in water  No bubbles of hydrogen formed  When steamed, hydrogen produced slowly
  • 14. Magnesium  Sinks in water  Bubbles of hydrogen produced very slowly  Magnesium hydroxide solution formed  When heated with steam, hydrogen is produced quickly
  • 15. Potassium  Floats on water  Bursts into flames immediately  Hydrogen bubbles rapidly produced around the metal  Clear solution of potassium hydroxide formed
  • 16. Reaction of metals with acids  Pg 149  Piece of metal placed in tube  Acid was poured into the tube  Bubble of hydrogen gas observed  Reactivity of Metals can be compared by comparing the amount of hydrogen gas produced in the reaction between acid and different metals  Metal+ Hydrochloric Acid  Metal Chloride + Hydrogen
  • 17. Apparatus used in investigating the reaction of some metals (Not sodium or potassium) and hydrochloric acid Refer to Page 149
  • 18. Reaction of metals with dilute HCL and Concentrated HCL  Lead  Did not react with dilute HCL  Bubbles of hydrogen gas produced slowly  Zinc  React slowly with dilute HCL to produce bubbles of hydrogen  Copper  Did not react with either dilute or concentrated HCL  Magnesium  React quickly with dilute HCL to produce bubbles of hydrogen