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Properties, Synthesis, Reactions & Uses of Heterocycles

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Heterocyclic compounds organic chemistry for pharmacy

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Amit Z Chaudhari
CONTENT 2018 2 Properties, synthesis, reactions & medicinal uses of…
Properties 1. Aromaticity PYRROLE 2018 3
Properties 1. Aromaticity 2018 4 PYRROLE
Properties 2018 5 PYRROLE
Synthesis 1. From Furans 2018 6 PYRROLE
Synthesis 2. Paal-Knorr synthesis 2018 7 PYRROLE
Synthesis 2. Paal-Knorr synthesis 2018 8 PYRROLE
Synthesis 3. Hantzsch Pyrrole synthesis 2018 9 PYRROLE
Synthesis 3. Hantzsch Pyrrole synthesis 2018 10 PYRROLE
Synthesis 4. Knorr synthesis 2018 11 PYRROLE
Synthesis 4. Knorr synthesis Mechanism 2018 12 PYRROLE
Reactions 1. Electrophilic substitution 2018 13 PYRROLE
Reactions 1. Electrophilic substitution Pyrrole undergoes electrophilic substitution reaction at 2nd position 2018 14 PYRROLE
Reactions 1. Electrophilic substitution 2018 15 PYRROLE
Reactions 2. Reduction 2018 16 PYRROLE
Reactions 3. Reimer Tiemann reaction 2018 17 PYRROLE
Reactions 2018 18 PYRROLE
2018 Medicinal uses 19 PYRROLE
Properties 1. Aromaticity FURAN 2018 20
Properties 1. Aromaticity 2018 21 FURAN
Synthesis 1. Paal-Knorr synthesis of furan 2018 22 FURAN
Synthesis 1. Paal-Knorr synthesis of furan 2018 23 FURAN
Synthesis 2. Feist – Benary Synthesis 2018 24 FURAN
Synthesis 2. Feist – Benary Synthesis Mechanism 2018 25 FURAN
Synthesis 3. From carbohydrate 2018 26 FURAN
Reactions 1. Electrophilic substitution furan undergoes electrophilic substitution reaction at 2nd position 2018 27 FURAN
Reactions 1. Electrophilic substitution 2018 28 FURAN
Reactions 1. Electrophilic substitution 2018 29 FURAN
Reactions 2. Reduction 2018 30 FURAN
Reactions 3. Diels-Alder reaction 2018 31 FURAN
Reactions 3. Diels-Alder reaction 2018 32 FURAN
Reactions 4. Pyrrole synthesis 2018 33 FURAN
2018 Medicinal uses 34 FURAN
Properties 1. Aromaticity THIOPHENE 2018 35
Properties 1. Aromaticity 2018 36 THIOPHENE
Properties 1. Aromaticity 2018 37 THIOPHENE
Synthesis 1. Paal-Knorr synthesis of thiophene 2018 38 THIOPHENE
Synthesis 1. Paal-Knorr synthesis of furan Mechanism 2018 39 THIOPHENE
Synthesis 2. From sod. succinate 2018 40 THIOPHENE
Synthesis 3. Hinsberg Synthesis 2018 41 THIOPHENE
Reactions 1. Electrophilic substitution thiophene undergoes electrophilic substitution reaction at 2nd position 2018 42 THIOPHENE
Reactions 1. Electrophilic substitution 2018 43 THIOPHENE
Reactions 1. Electrophilic substitution 2018 44 THIOPHENE
Reactions 2. Reduction 2018 45 THIOPHENE
Reactions 3. reaction 2018 46 THIOPHENE
2018 Medicinal uses 47 THIOPHENE
2018 Medicinal uses 48 THIOPHENE
Properties 1. Aromaticity PYRAZOLE 2018 49
Properties 1. Aromaticity PYRAZOLE 2018 50
Properties PYRAZOLE 2018 51
Synthesis 1. From pyrimidine PYRAZOLE 2018 52
Synthesis 1. From pyrimidine PYRAZOLE 2018 53
Synthesis 2. Knorr pyrazole synthesis - . PYRAZOLE 2018 54
Synthesis 2. Knorr pyrazole synthesis mechanism PYRAZOLE 2018 55
Synthesis 2. Knorr pyrazole synthesis Examples PYRAZOLE 2018 56
Synthesis 3. From Nitrile Imines PYRAZOLE 2018 57
Synthesis PYRAZOLE 2018 58
Reactions PYRAZOLE 2018 59
Reactions PYRAZOLE 2018 60
Reactions PYRAZOLE 2018 61
Reactions PYRAZOLE 2018 62
Reactions PYRAZOLE 2018 63
Reactions PYRAZOLE 2018 64
Reactions PYRAZOLE 2018 65
Reactions PYRAZOLE 2018 66
Medicinal Use PYRAZOLE 2018 67
Properties 1. Aromaticity IMIDAZOLE 2018 68
IMIDAZOLE 2018 Properties 1. Aromaticity 69
IMIDAZOLE 2018 Properties 70
IMIDAZOLE 2018 Synthesis 71
IMIDAZOLE 2018 Synthesis 2. From an α- Halo - Carbonyl Component What is α- Halo - Carbonyl Compound ???? 72
IMIDAZOLE 2018 Synthesis 3. From Dehydrogenation of Imidazoline 73
Reactions 1. Electrophilic addition to N 2018 IMIDAZOLE ??? 74
Reactions 1. Electrophilic addition to N 2018 IMIDAZOLE 75
Reactions 1. Electrophilic addition to N 2018 IMIDAZOLE 76
Reactions 2. Electrophilic substitution to C 2018 IMIDAZOLE ??? ??? 77
Reactions 2. Electrophilic substitution to C 2018 IMIDAZOLE 78
Reactions 3. Imidazole catalyzed ester HL 2018 IMIDAZOLE Slow reaction due to weak Nu: (H2O) 79
Reactions 3. Imidazole catalyzed ester HL 2018 IMIDAZOLE 80
Medicinal uses 2018 IMIDAZOLE 81
Medicinal uses 2018 IMIDAZOLE 82
Properties 1. Aromaticity OXAZOLE 2018 83
2018 Properties 1. Aromaticity OXAZOLE 84
2018 Synthesis 1. Robinson-Gabriel synthesis OXAZOLE 85
2018 Synthesis 1. Robinson-Gabriel synthesis Mechanism OXAZOLE 86
2018 Synthesis 2. From an α- Hydroxy - Carbonyl Component OXAZOLE α- Hydroxy - Carbonyl Component ???? 87
2018 Synthesis 2. From an α- Hydroxy - Carbonyl Component E.g. OXAZOLE 88
2018 Synthesis 3. From Isocyanides E.g. OXAZOLE 89
2018 OXAZOLE Reactions 1. Electrophilic addition to N 90
2018 OXAZOLE Reactions 2. Electrophilic substitution to C 91
2018 OXAZOLE Reactions 3. Diels-Alder Reaction 92
2018 OXAZOLE Reactions 3. Diels-Alder Reaction 93
2018 OXAZOLE Reactions 3. Diels-Alder Reaction (2) Kondrat'eva pyridine synthesis 94
2018 OXAZOLE Reactions 3. Diels-Alder Reaction (2) Kondrat'eva pyridine synthesis 95
2018 OXAZOLE Medicinal uses 96
Properties 1. Aromaticity THIAZOLE 2018 97
Properties 1. Aromaticity THIAZOLE 2018 98
2018 Synthesis 1. Gabriel synthesis THIAZOLE 99
2018 Synthesis 1. Gabriel synthesis Mechanism THIAZOLE 100
2018 Synthesis 2. From an α- Hydroxy - Carbonyl Component ( Hantzsch Thiazole Synthesis) THIAZOLE 101
2018 Synthesis 2. From an α- Hydroxy - Carbonyl Component ( Hantzsch Thiazole Synthesis) Mechanism THIAZOLE 102
2018 Synthesis 3. From an thiocyanate salts THIAZOLE 103
2018 THIAZOLE Reactions 1. Electrophilic addition to N a. Protonation (basic property) 104
2018 THIAZOLE Reactions 2. Electrophilic substitution to C 105
2018 THIAZOLE Reactions 2. Electrophilic substitution to C 106
2018 THIAZOLE Reactions 107
2018 THIAZOLE Medicinal uses 108
2018 THIAZOLE Medicinal uses 109
Properties 1. Aromaticity P Y R I D I N E 2018 110
2018 Properties 1. Aromaticity P Y R I D I N E 111
2018 Properties 2. Basicity P Y R I D I N E 112
2018 Properties 2. Basicity Pyridine is more basic than pyrrole P Y R I D I N E 113
2018 Properties 2. Basicity P Y R I D I N E 114
2018 Properties 2. Basicity P Y R I D I N E 115
2018 Properties 3. Tautomerism P Y R I D I N E 116
2018 P Y R I D I N E Synthesis 1. Hantzsch pyridine synthesis 117
2018 P Y R I D I N E Synthesis 1. Hantzsch pyridine synthesis 118
2018 P Y R I D I N E Synthesis 1. Hantzsch pyridine synthesis 119
2018 P Y R I D I N E Synthesis 2. The Guareschi Synthesis 120
2018 P Y R I D I N E Synthesis 3. From 1,5 - Dicarbonyl Compounds 121
2018 P Y R I D I N E Synthesis 4. From Oxazoles Kondrat'eva pyridine synthesis 122
2018 Reactions 1. Electrophilic addition to N P Y R I D I N E 123
2018 Reactions P Y R I D I N E 124
2018 P Y R I D I N E C2 C3 C4 Reactions 2. Electrophilic substitution to C 125
2018 P Y R I D I N E Reactions 2. Electrophilic substitution to C 126
2018 P Y R I D I N E Reactions 2. Electrophilic substitution to C 127
2018 P Y R I D I N E Reactions 3. Nucleophilic substitution Why pyridine undergoes nucleophilic substitution reaction at 2-position. 128 C3 C2
2018 P Y R I D I N E Reactions 3. Nucleophilic substitution 129
2018 P Y R I D I N E Reactions 4. Pyridine as Nucleophilic catalyst 130
2018 P Y R I D I N E Reactions 5. Reduction 131
2018 P Y R I D I N E Medicinal uses 132
2018 P Y R I D I N E Medicinal uses 133
2018 P Y R I D I N E Medicinal uses 134
Properties 1. Aromaticity A Z E P I N E S 2018 135
Properties 2. Tautomerism A Z E P I N E S 2018 136
A Z E P I N E S 2018 Synthesis 1. Valence-bond Isomerization 137
A Z E P I N E S 2018 Synthesis 2. From Phenylazide 138
A Z E P I N E S 2018 Synthesis 3. From Nitrobenzene 139
A Z E P I N E S 2018 Reactions 140
A Z E P I N E S 2018 Reactions 3. Diels-Alder reaction - 6+2 π electron reaction 141
A Z E P I N E S 2018 Medicinal Uses 142
2018 Properties 1. Aromatic Q U I N O L I N E 143
2018 Synthesis 1. Skraup Quinoline synthesis Q U I N O L I N E 144
2018 Synthesis 1. Skraup Quinoline synthesis Mechanism Q U I N O L I N E 145
2018 Q U I N O L I N E Synthesis 1. Skraup Quinoline synthesis 146
2018 Synthesis 2. Doebner-Miller Synthesis Q U I N O L I N E 147
2018 Synthesis 3. Friedlander Synthesis Q U I N O L I N E 148
2018 Reactions 1. Electrophilic addition to N Q U I N O L I N E 149
2018 Q U I N O L I N E Reactions 2. Electrophilic aromatic substitution 150
2018 Reactions 3. Reduction reactions Q U I N O L I N E 151
2018 Reactions 4. Oxidation Q U I N O L I N E 152
2018 Q U I N O L I N E Reactions 5. Nucleophilic substitution 153
2018 Medicinal uses Q U I N O L I N E 154
2018 Medicinal uses Q U I N O L I N E 155
2018 Properties 1. Aromatic I S O Q U I N O L I N E 156
2018 Synthesis 1. Bischler-Napieralski Isoquinoline synthesis I S O Q U I N O L I N E 157
2018 Synthesis 2. The Pictet – Gams synthesis I S O Q U I N O L I N E 158
2018 Synthesis 3. Pomeranz–Fritsch synthesis I S O Q U I N O L I N E 159
2018 I S O Q U I N O L I N E Reactions 1. Electrophilic addition to N 160
2018 I S O Q U I N O L I N E Reactions 2. Electrophilic aromatic substitution 161
2018 I S O Q U I N O L I N E Reactions 3. Reduction reactions 162
2018 I S O Q U I N O L I N E Reactions 4. Oxidation 163
2018 I S O Q U I N O L I N E Reactions 5. Nucleophilic substitution 164
2018 I S O Q U I N O L I N E Medicinal uses 165
2018 I S O Q U I N O L I N E Medicinal uses 166
2018 Properties 1. Aromatic A C R I D I N E 167
2018 Synthesis 1. From diphenyl amine-2-carboxylic acid A C R I D I N E 168
2018 Synthesis 2. Bernthsen acridine synthesis A C R I D I N E 169
2018 Reactions 1. Electrophilic addition to N A C R I D I N E 170
2018 A C R I D I N E Reactions 2. Electrophilic aromatic substitution 171
2018 A C R I D I N E Reactions 3. Reduction reactions 172
2018 A C R I D I N E Reactions 4. Oxidation 173
2018 A C R I D I N E Reactions 5. Nucleophilic substitution 174
2018 A C R I D I N E Medicinal uses 175
2018 Properties 1. Aromatic I N D O L E 176
2018 I N D O L E Synthesis 1. Fischer indole synthesis 177
2018 I N D O L E Synthesis 1. Fischer indole synthesis Mechanism 178
2018 I N D O L E Synthesis 1. Fischer indole synthesis Mechanism 179
2018 I N D O L E Synthesis 1. Fischer indole synthesis 180
2018 I N D O L E Synthesis 2. Bischler–Möhlau indole synthesis 181
2018 I N D O L E Synthesis 3. Madelung synthesis 182
2018 I N D O L E Synthesis 3. Madelung synthesis E.g. 183
2018 Reactions 1. Electrophilic addition to N I N D O L E 184
2018 Reactions 2. Electrophilic aromatic substitution I N D O L E 185
2018 Reactions 2. Electrophilic aromatic substitution I N D O L E 186
2018 Reactions 2. Electrophilic aromatic substitution I N D O L E 187
2018 Reactions 2. Electrophilic aromatic substitution I N D O L E 188
2018 Reactions 2. Electrophilic aromatic substitution I N D O L E 189
2018 Reactions 3. Reduction reactions I N D O L E 190
2018 Reactions 4. Nucleophilic substitution I N D O L E 191
2018 Medicinal uses (1) Indole alkaloids : I N D O L E 192
2018 Medicinal uses I N D O L E 193
2018 Medicinal uses I N D O L E 194
2018 Properties 1. Aromatic P Y R I M I D I N E 195
2018 Synthesis 1. From 1,3 - Dicarbonyl Compound P Y R I M I D I N E 196
2018 Synthesis 1. From 1,3 - Dicarbonyl Compound P Y R I M I D I N E 197
2018 Synthesis 2. From a , b - Unsaturated Ketones P Y R I M I D I N E 198
2018 Synthesis P Y R I M I D I N E 199
2018 Reactions 1. Electrophilic addition to N P Y R I M I D I N E 200
2018 Reactions 2. Electrophilic aromatic substitution P Y R I M I D I N E 201
2018 Reactions 3. Nucleophilic substitution P Y R I M I D I N E 202
2018 Reactions 3. Nucleophilic substitution P Y R I M I D I N E 203
2018 Medicinal uses P Y R I M I D I N E 204
2018 Medicinal uses P Y R I M I D I N E 205
2018 Medicinal uses P Y R I M I D I N E 206
2018 Properties 1. Aromatic P U R I N E 207
2018 Properties 3. Tautomerism P U R I N E 208
2018 Synthesis 1. Traube Synthesis P U R I N E 209
2018 Synthesis 1. Traube Synthesis P U R I N E 210
2018 Synthesis 2. From formamide P U R I N E 211
2018 Synthesis 3. From substituted imidazole P U R I N E 212
2018 Reactions 1. Electrophilic addition to N P U R I N E 213
2018 P U R I N E Reactions 2. Electrophilic aromatic substitution 214
2018 P U R I N E Reactions 3. Nucleophilic substitution 215
2018 P U R I N E Medicinal uses 216
2018 P U R I N E Medicinal uses 217
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Properties, Synthesis, Reactions & Uses of Heterocycles

Hinweis der Redaktion

  1. In a heterocyclic ring, other things being equal, numbering preferably commences at a saturated rather than at an unsaturated hetero atom
  2. https://www.synarchive.com/named-reactions/hantzsch-thiazole-synthesis