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Stoichiometry
Stoichiometry is the
study of quantitative
   relationships in
chemical reactions.
The basic idea used in
solving stoichiometric
 problems is the mole
       concept.
A short review
Molecular weight is the
  sum of the atomic
weights of all the atoms
    in a molecule.

  A molecule is the
  smallest unit of a
 covalent compound.
What is a mole?
A mole (mol) is a SI base
unit used to measure the
 amount of material in a
    chemical sample.
1 mole of H2O contains
6.022 x 1023 H2O molecules
   (Avogadro’s number)
A coefficient in a balanced
 chemical equation indicates
   the number of moles of a
chemical compound involved in
     a chemical reaction.


      2H2 + O2  2H2O
The coefficients give you the
mole ration of the compounds
  involved in the reaction.

       2H2 + O2  2H2O

 The mole ratio of hydrogen to
  oxygen is 2:1 (for every one
oxygen put into the reaction, 2
  moles of hydrogen are also
needed to put into the reaction)
The unit of moles
  provides a “bridge” to
 mathematically convert
between several different
   aspects of chemical
       compounds.
Moles link an abstract
chemical equation to a
   concrete unit of
measurement (grams,
  Liters, number of
     molecules)
For example:

1 mole = 6.02 x 1023 molecules

1 mole = molecular mass of a
         substance

1 mole = 22.4 L of a substance
at STP (standard temperature
        and pressure)
For example:

1 mol Cl = 6.02 x 1023 molecules Cl
 1 mol H2O = 6.02 x 1023 molecules
                H 2O

       1 mol Cl = 35.45g Cl
     1 mol H2O = 18.01g H2O

    1 mol Cl = 22.4L Cl @ STP
  1 mol H2O = 22.4L H2O @ ATP
There are several types of
 calculations that can be
  used in Stoichiometry.
Mole – mole
calculations
Involves 1
conversion
  factor
The object of this type of
problem is to calculate the
  moles of one substance
when given the number of
    moles of different
        substance.
Example: Magnesium
hydroxide reacts with carbonic
acid. How many moles of water
     will be produced from
    3.5 moles of magnesium
           hydroxide?
  You are given the moles of one
  substance and asked to find the
    moles of another substance.
Example: How many moles
of ammonia can be produced
from 8.00 moles of hydrogen
   reacting with nitrogen?
Example:
K2Cr2O7 + 6KI + 7H2SO4  Cr2
(SO4)3 + 4K2SO4 + 3I2 + 7H2O
    Calculate the number of moles of
      potassium dichromate that will
    react with 2.0 moles of potassium
     iodide. Calculate the number of
        moles of iodine that will be
       produced from 2.0 moles of
            potassium iodide.
Mole – mass calculations
Involves 2
conversion
  factors
The object of this type of
  problem is to calculate
     the moles of one
substance when given the
     mass of different
        substance.

      Or vise versa
Example:
What mass of hydrogen can be
    produced by reacting
 6.0 moles of aluminum with
     hydrochloric acid?

    You are given the moles of one
    substance and asked to find the
      mass of another substance.
Example: How much
    carbon dioxide is
produced by the complete
combustion of 0.0492 mol
    of propane, C3H8?
Example: How many
 moles of water will be
 produced from 14.6 g
    propane in the
combustion of propane?
Mass – Mass calculations
Involves 3
conversion
  factors
The object of this type of
  problem is to calculate
     the mass of one
substance when given the
     mass of different
        substance.
Example:
How much carbon dioxide is
 produced by the complete
      combustion of
 100.0 g of propane, C3H8?


   You are given the moles of one
   substance and asked to find the
     mass of another substance.
Example: Magnesium
  chloride reacts with
sulfuric acid. How much
sulfuric acid is needed to
    produce 26.3 g of
  magnesium sulfate?
Calculations
involving Liters
 and number of
   molecules
Example: How many moles
of ammonia can be produced
from 1.03 Liters of hydrogen
  reacting with nitrogen at
            STP?
Example: How many carbon
   dioxide molecules are
 produced by the complete
combustion of 32.00 grams
     of propane, C3H8?
Stoichiometry for online
Stoichiometry for online
Stoichiometry for online

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Stoichiometry for online

  • 2. Stoichiometry is the study of quantitative relationships in chemical reactions.
  • 3. The basic idea used in solving stoichiometric problems is the mole concept.
  • 5. Molecular weight is the sum of the atomic weights of all the atoms in a molecule. A molecule is the smallest unit of a covalent compound.
  • 6. What is a mole?
  • 7. A mole (mol) is a SI base unit used to measure the amount of material in a chemical sample.
  • 8. 1 mole of H2O contains 6.022 x 1023 H2O molecules (Avogadro’s number)
  • 9. A coefficient in a balanced chemical equation indicates the number of moles of a chemical compound involved in a chemical reaction. 2H2 + O2  2H2O
  • 10. The coefficients give you the mole ration of the compounds involved in the reaction. 2H2 + O2  2H2O The mole ratio of hydrogen to oxygen is 2:1 (for every one oxygen put into the reaction, 2 moles of hydrogen are also needed to put into the reaction)
  • 11. The unit of moles provides a “bridge” to mathematically convert between several different aspects of chemical compounds.
  • 12.
  • 13. Moles link an abstract chemical equation to a concrete unit of measurement (grams, Liters, number of molecules)
  • 14. For example: 1 mole = 6.02 x 1023 molecules 1 mole = molecular mass of a substance 1 mole = 22.4 L of a substance at STP (standard temperature and pressure)
  • 15. For example: 1 mol Cl = 6.02 x 1023 molecules Cl 1 mol H2O = 6.02 x 1023 molecules H 2O 1 mol Cl = 35.45g Cl 1 mol H2O = 18.01g H2O 1 mol Cl = 22.4L Cl @ STP 1 mol H2O = 22.4L H2O @ ATP
  • 16. There are several types of calculations that can be used in Stoichiometry.
  • 19. The object of this type of problem is to calculate the moles of one substance when given the number of moles of different substance.
  • 20. Example: Magnesium hydroxide reacts with carbonic acid. How many moles of water will be produced from 3.5 moles of magnesium hydroxide? You are given the moles of one substance and asked to find the moles of another substance.
  • 21. Example: How many moles of ammonia can be produced from 8.00 moles of hydrogen reacting with nitrogen?
  • 22. Example: K2Cr2O7 + 6KI + 7H2SO4  Cr2 (SO4)3 + 4K2SO4 + 3I2 + 7H2O Calculate the number of moles of potassium dichromate that will react with 2.0 moles of potassium iodide. Calculate the number of moles of iodine that will be produced from 2.0 moles of potassium iodide.
  • 23. Mole – mass calculations
  • 25. The object of this type of problem is to calculate the moles of one substance when given the mass of different substance. Or vise versa
  • 26. Example: What mass of hydrogen can be produced by reacting 6.0 moles of aluminum with hydrochloric acid? You are given the moles of one substance and asked to find the mass of another substance.
  • 27. Example: How much carbon dioxide is produced by the complete combustion of 0.0492 mol of propane, C3H8?
  • 28. Example: How many moles of water will be produced from 14.6 g propane in the combustion of propane?
  • 29. Mass – Mass calculations
  • 31. The object of this type of problem is to calculate the mass of one substance when given the mass of different substance.
  • 32. Example: How much carbon dioxide is produced by the complete combustion of 100.0 g of propane, C3H8? You are given the moles of one substance and asked to find the mass of another substance.
  • 33. Example: Magnesium chloride reacts with sulfuric acid. How much sulfuric acid is needed to produce 26.3 g of magnesium sulfate?
  • 34. Calculations involving Liters and number of molecules
  • 35. Example: How many moles of ammonia can be produced from 1.03 Liters of hydrogen reacting with nitrogen at STP?
  • 36. Example: How many carbon dioxide molecules are produced by the complete combustion of 32.00 grams of propane, C3H8?