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                O



          H           H
    σ+                    σ+



Atoms and Bonding
         Intro to Chemistry
                 MrT
                               staylor@canacad.ac.jp
It has electrons and
                                  protons in the nucleus
                                  and neutrons outside.



                                      The electrons are the
                                      heaviest part, which is
                                       why they’re outside.



                                                The nucleus is overall
                                              positive and the electrons
                                               are negatively charged.




Clipart people from: http://www.clker.com/search/krug/1
Atoms and Bonding
  Unit Questions: “How can we know what we cannot see?”
  Enduring Understandings:
       •    Patterns and structures lead to predictability
  Areas of interaction:
      Human Ingenuity
      The Periodic Table is an amazing feat of the scientific method and reason.


Criterion                             Assessment Tasks
B: Communication                      Sports Drinks Lab
C: Knowledge & Understanding          Mystery elements bonding task (test conditions)

  Quia Review Quizzes:
      • 2.1 Atoms, ions, isotopes
      • 2.2 Periodic Table and structure
      • 2.3 Ionic and Covalent Bonding
      • 2.4 Intermolecular forces
Atoms and Bonding
Assessment Statements
                                                  •   Define valence electrons and outline the duet
•   Describe the components of the atom
                                                      and octet rules.
    (protons, neutrons, electrons), in terms of
                                                  •   Draw Lewis dot structures for the valence
    size and charge.
                                                      electrons of elements on the periodic table.
•   Outline the structure of the atom.
                                                  •   Deduce whether two elements will form an
•   Distinguish between atomic number, mass
    number and atomic mass.
                                                      ionic or covalent compounds from their
                                                      position on the periodic table
•   Deduce the atomic number and mass
                                                  •   Explain the formation of ionic bonds.
    number of an element from its position on
                                                  •   Describe the properties of ionic compounds.
    the periodic table.
                                                  •   Describe metallic bonds and their properties.
•   Outline the formation of isotopes, using
                                                  •   Define molecule.
    examples.
                                                  •   Explain the formation of covalent bonds,
•   Distinguish between atoms and ions.
                                                      using Lewis dot structures.
•   Explain how cations and anions are formed,
                                                  •   Describe the properties of covalently bonded
    with examples.
                                                      molecules.
•   Outline the organisation of the periodic
                                                  •   Outline how covalent bonding leads to polar
    table in terms of groups, periods and
                                                      bonds and molecules.
    families.
                                                  •   Explain hydrogen bonding in water as an
•   Describe the trend in atomic structure
    through the periodic table.
                                                      example of dipole-dipole attractions.
                                                  •   Describe Van der Waal's Forces.
Build an Atom
Run the simulation and build the following:
1. a hydrogen atom.
2. the hydrogen cation.
3. helium.
4. a stable isotope of helium.
5. an unstable istotope of helium.

Answer the following:
1. Which subatomic particle determines
   the element’s atomic number?               Build an Atom, from PhET. Click Run Now.
                                              http://phet.colorado.edu/en/simulation/build-an-atom
2. Which two subatomic particles
   determine the element’s mass number?                         If you’re done:
3. How is ionic charge (net charge)                             What level can you reach on the game?
   determined and what makes an ion?
4. What is an isotope and how is it made?


Then test yourself (and research further):
http://www.quia.com/quiz/3320413.html
(firstnamelastname230, milk)
-                                          Atom
                                                                   Nucleus and electron cloud
                              Electron (e-)
                       (mass = negligible, charge: -1)




                                              Neutron (n0)
                                    +         (mass = 1amu*, charge: 0)
                 Nucleus
          contains nucleons             +     Proton (p+)
                                              (mass = 1amu, charge: +1)

                Mass number is the          Atomic number is              Atomic mass is the
                   total number of          the number of                 mean mass of an
                      protons plus          protons. This                 element’s atom
                          neutrons.         defines the                   based on isotopes.
                                            element.

                                        -
*atomic mass unit (neutrons are slightly more than 1amu)
-
                                      Atomic number
                                  is the number of protons.


                                              2
                                          He
+                                        helium
        +
                                           4.00
                                        Atomic mass
                                     is the mean mass of an
                                    element’s atom based on
                                            isotopes.



            Different periodic tables place the atomic
            number, atomic mass and mass number in
    -       different positions, so pay attention to the key.
What’s this?


               ?
           +   ?
               ?
               ?
What’s this?                       An atom of hydrogen has one
                                   proton and one electron only.


                                                                       1
                       +                                              H
                                                                 hydrogen
                                                                     1.01
                                                                Why the 1.01?
                                      In nature some isotopes of hydrogen exist.
 These have 1 neutron (deuterium, mass 2amu) or 2 neutrons (tritium, mass 3amu)
              How would you change the diagram to show each of these isotopes?
What’s the mean number
of legs per person in:
• this class?
• the world?




                                         Image: 'Stacked'
 http://www.flickr.com/photos/17731548@N00/2153132167
                                     Found on flickrcc.net
What’s the mean number
of legs per person in:
• this class?
• the world?


Slightly less than one!
Why?




                                         Image: 'Stacked'
 http://www.flickr.com/photos/17731548@N00/2153132167
                                     Found on flickrcc.net
What’s this?


               ?
           +   ?
               ?
               ?
What’s this?    This ion of hydrogen has one proton
                only. An electron has been lost.


                                           1
           +                               H +
                                        hydrogen
                                           1.01

               The overall charge of this ion is +1.
               It is a cation.
-                   What do you
                                         think?
            +
    +
        +


    It has 2 e-, but 3n0, so it must
-       be an isotope of helium

            It has 3 p+, so it must
             be an ion of lithium
        It has 2 e-, so it must
              be helium
-

  +                +
                    +
                               -



What do these represent?
               -
                   +
  +                 +
                           -
-

              +                                           +
                                                           +
                                                                              -
An atom of hydrogen has one proton   An atom of helium has two protons,
and one electron only.               two neutrons and two electrons.




                                                -
                                                            +
              +                                              +
                                                                          -
An ion of hydrogen has one            This isotope of helium has two protons,
proton only – and therefore an        one neutron and two electrons.
overall charge of +1
mass number =    12                 13                      What do you
                       ?                  ?                    think?
atomic number =   6     Charge = 0   6     Charge = 0



                       They are both the same element,
                       but have different mass numbers,
                            so one must be an ion.


                               The atomic mass of the
                             second element is 13, so it
                                 must be aluminium


                           Its atomic number is 6, so they
                                 must both be carbon
Marshmallow Isotopes
                                                                              neutrons
  1. Make a hydrogen nucleus (a proton).                       nucleons
  2. Make an alpha particle (helium nucleus)                                  protons
     Use a lick to stick.
     Sticking forces in nuclei are weak. What are they?                                           You need white and
                                                                                                  pink marshmallows
  This is called helium-4, as it has four nucleons.
  3. Make a particle of the isotope helium-3.                             +
     What is different?                                                       +
  4. He-5 is an unstable isotope.                 The alpha-particle
     Make it and then suggest why it is unstable.

  5. C-12 is the main stable isotope of carbon. Make it.
     What other isotopes of carbon are there? What are their uses?

  6. In the first few minutes of the universe, alpha particles formed.
     New elements can be made from combining alpha particles.
     Combine your He-4 with a C-12. What element have you made?


Adapted from: http://www.lbl.gov/abc/marsh-nuclei/index.html          Image from http://www.hancocks.co.uk/
Neutrons determine nuclear properties
Have a go at this at home if you need more consolidation on isotopes, neutrons and mass number.

                                                                  Recreate some of the atoms and isotopes you
                                                                  made in the marshmallow activity.

                                                                  How does neutron number affect mass
                                                                  number of the atom?

                                                                  Are all isotopes of an element equally
                                                                  abundant in nature?

                                                                  What is nuclear ‘stability’?


Isotopes & Atomic Mass, from PhET. Click Run Now.
http://phet.colorado.edu/en/simulation/isotopes-and-atomic-mass




 The number of neutrons does not always equal the number of protons in a stable
 element. As proton number increases, an increasing number of neutrons is needed
 to keep the atom stable. If there are too many or too few neutrons, it is unstable.
Not all periodic    atomic number

tables organise the
numbers around the
elements in the same
way.                  mass number
                                      symbol




You must pay                        name


attention to the key!
mass number =    127                 131                   What do you
                       ?                   ?                  think?
atomic number =   53     Charge = 0   53    Charge = 0



Check the key!          They are both isotopes of iodine.
                         They have different numbers of
                             neutrons and protons.


                               They are both isotopes of
                              iodine. They have different
                                 numbers of neutrons.


                              They have the same atomic
                              numbers but different mass
                               numbers. They are ions.
Iodine has many isotopes.
 mass number =    127                   131
                       I                     I
atomic number =   53       Charge = 0   53       Charge = 0

                     Iodine-127           Iodine-131
         Protons:       53              Protons:        53
         Neutrons:      74              Neutrons:       78


                   Stable               Unstable              Radioisotope used in treating
                  Abundant              Artifical             thyroid cancer.




The number of neutrons does not always equal the number of protons in a stable
element. As proton number increases, an increasing number of neutrons is needed
to keep the atom stable. If there are too many or too few neutrons, it is unstable.
mass number =    12                Atom, Ion or
                       C              Isotope?
atomic number =    6   Charge = 0


  1
       ?
  1      Charge = +1
mass number =    12                      Atom, Ion or
                       C                    Isotope?
atomic number =    6    Charge = 0


  1                    238
       H                    ?
  1      Charge = +1   92    Charge = 0

       H+ ion
mass number =    12                                          Atom, Ion or
                       C                                        Isotope?
atomic number =    6    Charge = 0


  1                    238                 235
       H                     U                  ?
  1      Charge = +1   92     Charge = 0   92    Charge = 0

       H+ ion               Uranium
mass number =    12                                           Atom, Ion or
                       C                                         Isotope?
atomic number =    6    Charge = 0


  1                    238                 235                60
       H                     U                  U                  ?
  1      Charge = +1   92     Charge = 0   92    Charge = 0   27   Charge = 0

       H+ ion               Uranium        Uranium isotope
mass number =     12                                           Atom, Ion or
                        C                                         Isotope?
atomic number =    6     Charge = 0


  1                     238                 235                60
       H                      U                  U                  Co
  1      Charge = +1    92     Charge = 0   92    Charge = 0   27     Charge = 0

       H+ ion                Uranium        Uranium isotope     Cobalt isotope



  16
       ?
  8      Charge = 2-
mass number =      12                                            Atom, Ion or
                         C                                          Isotope?
atomic number =     6     Charge = 0


  1                      238                  235                60
        H                      U                   U                  Co
  1       Charge = +1    92     Charge = 0    92    Charge = 0   27     Charge = 0

       H+ ion                 Uranium         Uranium isotope     Cobalt isotope



  16                     238
        O                       ?
  8       Charge = 2-    94      Charge = 0

      Oxygen ion
mass number =      12                                              Atom, Ion or
                         C                                            Isotope?
atomic number =     6       Charge = 0


  1                      238                  235                  60
        H                      U                   U                    Co
  1       Charge = +1    92      Charge = 0   92    Charge = 0     27     Charge = 0

       H+ ion                 Uranium         Uranium isotope       Cobalt isotope



  16                     238                  40
        O                     Pu                   ?
  8       Charge = 2-    94      Charge = 0   20     Charge = 2+

      Oxygen ion         Plutonium isotope
mass number =      12                                              Atom, Ion or
                         C                                            Isotope?
atomic number =     6       Charge = 0


  1                      238                  235                  60
        H                      U                   U                    Co
  1       Charge = +1    92      Charge = 0   92    Charge = 0     27     Charge = 0

       H+ ion                 Uranium         Uranium isotope       Cobalt isotope



  16                     238                  40                   47
        O                     Pu                   Ca                   ?
  8       Charge = 2-    94      Charge = 0   20     Charge = 2+   20     Charge = 0

      Oxygen ion         Plutonium isotope      Calcium ion
mass number =      12                                              Atom, Ion or
                         C                                            Isotope?
atomic number =     6       Charge = 0


  1                      238                  235                  60
        H                      U                   U                    Co
  1       Charge = +1    92      Charge = 0   92    Charge = 0     27     Charge = 0

       H+ ion                 Uranium         Uranium isotope       Cobalt isotope



  16                     238                  40                   47
        O                     Pu                   Ca                   Ca
  8       Charge = 2-    94      Charge = 0   20     Charge = 2+   20     Charge = 0

      Oxygen ion         Plutonium isotope      Calcium ion        Calcium isotope
What are they?
                       How do we draw them?




                    IONS
How do we name them?



                         How do they make bonds?
Electrons determine chemical properties
 An atom of helium has two protons, two
 neutrons and two electrons.                               -
 It is a small atom, with an electron ‘shell’ which                  2p+
 can hold only 2 electrons.                                          2n0

 Because the ‘shell’ is full, He is stable and                             -
 unreactive – it is a noble gas.
 The inner shells ‘fill’ first, as the electrons are           - -
 attracted to the positive nucleus.                             -

 Larger atoms have bigger shells. However, the
 outermost shell holds maximum 8 electrons.                    9p+             -
                                                       -       9n0             -
 What is this atom?

 How might it become more stable?
                                                                 -
                                                               - -
Ions have unbalanced protons and electrons
                                    -
            H atom                            1p+
                                              0n0




                                        - -
                                         -
            F atom
                                        9p+         -
                              -         9n0         -


                                          -
                                        - -
Ions have unbalanced protons and electrons


                H+   ion                          1p+
                                                  0n0

   Positively charged ions are cations.
   (Think: cats make old ladies happy)
                                            - -
                                             -
                F- ion
                                        -   9p+         -
    Negatively charged ions are anions.
                                        -   9n0         -
    (Think: A Negative ION)

                                              -
                                            - -
Octet Rule
 Atoms in a compound will tend to have the
    electron configuration of a noble gas:
 Eight electrons in the outer (valence) shell.

                     Duet Rule
The inner shell can hold a maximum two electrons
          – the configuration of helium.
Atoms and the                                periodic table
                                                 Group 1: Alkali metals
               columns                           Group 2: Alkaline earth metals
              are groups                         Group 7: Halogens (sometimes called 17)
                                                 Group 8: Noble gases (sometimes 18 or 0)

    orphan
  hydrogen




rows are
 periods




           Lanthanides
              Actinoids


             Interactive periodic table from: http://www.ptable.com/
Ions have unbalanced protons and electrons
   Common ions:




     Positively charged ions are cations. Negatively charged ions are anions.
     (Think: cats make old ladies happy) (Think: A Negative ION)

 What’s the difference between the ions in purple and those in black?
 Compare the elemental ions to the periodic table. Can you describe a trend?
 Can you explain why the elements above form these specific ions?
What’s the relationship between atomic structure and the periodic table?


   +1 +2        Ionic charges are in red.                                   +3       -3   -2   -1

                                                                   metals   non-metals


                                               transition metals




Periodic Table from the IBDP Chemistry Data Booklet
What’s the relationship between atomic structure and the periodic table?




Interactive periodic table from: http://www.footprints-science.co.uk/flash/periodic2.swf
Atoms and the                                periodic table
                                                 Group 1: Alkali metals
               columns                           Group 2: Alkaline earth metals
              are groups                         Group 17: Halogens
                                                 Group 18: Noble gases

    orphan
  hydrogen




rows are
 periods




           Lanthanides
              Actinoids


             Interactive periodic table from: http://www.ptable.com/
Valence Electrons & Configurations
In the first period (H and He), there is one
small electron shell. It can hold up to two
electrons – a duet.

As we move down each period, we
add an electron shell.
The outer shell can hold
up to 8 electrons.




                               4 shells, 1 valence
                                    electron

Valence electrons are the electrons in
the outer shell only. They are used in
bonding.

Once the outer shell is full, the atom is
stable. This is the octet rule.

                             Interactive periodic table from: http://www.ptable.com/
Complete the pattern…
 H                                                          He

 Li          Be             B          C        N   O   F   Ne
What do the dots represent?

What is the relationship with periodic table?


Can you predict the pattern for aluminium?
Lewis dot configurations
             These dots show the number of valence electrons in an atom.
 H           We can use them to predict bond types as well as the                                    He
             structure of a compound.


 Li          Be             B          C           N                O              F                 Ne
What is the relationship with periodic table?
Elements in the same group have the same        All the Lewis dots:
number of valence electrons.

Can you predict the pattern for aluminium?



                Al

                                                http://www.roymech.co.uk/Related/Chemistry/Lewis_dot_structure.html
What’s in your sports drinks?
  Sports drinks contain ions to help with rehydration (if you really need it).
  Two of their main ingredients are sugar (sucrose) and salt (sodium chloride).

  In this investigation we will:
  • Determine whether sugar or salt is ionic
  • Compare the ion concentrations of two drinks




                                              https://docs.google.com/presentation/d/1Hqs6AMjlx5KBGWWSzOLBSBbO2mzDqw17CkMSdB
                                                                                                                       hSAcQ
Pocari Sweat and Aquarius bottles from
http://jin.jcic.or.jp/en/ranking/near_water_small_pet_bottle_pouch/
Bonding is the attraction between atoms.
   Atoms are stable when they have a full valence shell.
   In ionic bonds, electrons are transferred to achieve this.
   In covalent, electrons are shared.
   The result are forces of attraction.

   Bonds:
       • Ionic
       • Covalent
       • Metallic

   Inter-molecular forces:
        • Dipole-dipole bonds
        • Hydrogen bonds
        • Van der Waal’s forces




http://www.kentchemistry.com/links/bonding/bondingflashes/bond_types.swf
Ionic or covalent bonds?
                  Binary compounds contain two elements.
                  Metal + non-metal, the bonding will be ionic.
                  If both are non-metals, bonding is covalent.
                                                                         non-metals

                                                    metals




                        So what about these compounds?

                lithium fluoride _____________        nitrogen dioxide   _____________
                carbon dioxide _____________          water              _____________
                magnesium oxide ____________          methane (CH4)          _____________
                sodium chloride _____________         lead iodide        _____________

Periodic table from the BBC. http://goo.gl/1rrCk
Ionic or covalent bonds?
                  Binary compounds contain two elements.
                  Metal + non-metal, the bonding will be ionic.
                  If both are non-metals, bonding is covalent.
                                                                         non-metals

                                                    metals




                        So what about these compounds?

                lithium fluoride         ionic        nitrogen dioxide   covalent
                carbon dioxide           covalent     water              covalent
                magnesium oxide ionic                 methane (CH4)              covalent
                sodium chloride          ionic        lead iodide        ionic

Periodic table from the BBC. http://goo.gl/1rrCk
Octet Rule
 Atoms in a compound will tend to have the
    electron configuration of a noble gas:
 Eight electrons in the outer (valence) shell.

                     Duet Rule
The inner shell can hold a maximum two electrons
          – the configuration of helium.
Ionic Bonding
   Forms between a metal and a non-metal.
   Metal cations(+) donate electron(s) to non-
   metal anions(-).


             Li                F
                    +                   -
   cation     Li                F       anion


   The metal has lost its lone electron and the
   non-metal has gained. They each now have
   filled outer valence shells.
   Cations attract anions – the atoms are held
   together by this attraction – the ionic bond.
                     +              -
               Li           F
http://www.footprints-science.co.uk/ionic.htm
Almost full? Get some more. Almost empty? Get rid.
Draw the electron arrangements on these shells.
State the number of valence electrons and draw a Lewis dot configuration.
Deduce whether they will form an anion or a cation.

                     Oxygen                           Chlorine




                        Aluminium                   Beryllium
Almost full? Get some more. Almost empty? Get rid.
Draw the electron arrangements on these shells.
State the number of valence electrons and draw a Lewis dot configuration.
Deduce whether they will form an anion or a cation.

                     Oxygen                                   Chlorine
                        8 protons, 8 electrons,
                        6 valence electrons.

                        Lewis dot:     O
                            2-
                      O           Almost full- gain two electrons
                                  and form an anion.



                        Aluminium                          Magnesium



          Al
Almost full? Get some more. Almost empty? Get rid.
Draw the electron arrangements on these shells.
State the number of valence electrons and draw a Lewis dot configuration.
Deduce whether they will form an anion or a cation.

                     Oxygen                                    Chlorine
                        8 protons, 8 electrons,
                        6 valence electrons.

                        Lewis dot:      O
                             2-
                      O            Almost full- gain two electrons
                                   and form an anion.



                        Aluminium                           Magnesium

                           13 protons, 13 electrons,
          Al               3 valence electrons.

                             Lewis dot:     Al
                              3+
                        Al         Almost empty- lose three
                                   electrons and form a cation.
Ionic Bonding
                                                       Cations                          Anions
                                               +1        +2          +3         -3        -2        -1
                                                 +          2+        3+         3-        2-           -
                                               H        Mg          Al          N         O         Cl
                                               Li+      Ca2+        Fe3+        P3-       S2-       Br-
In an ionic bond, the charges must balance.       +        2+                      3-         2-      -
                                              Na        Fe                     PO4       CO3         I
Ions can be elemental or polyatomic – it is    K
                                                 +
                                                        Cu
                                                           2+
                                                                                         SO4
                                                                                             2-
                                                                                                   NO3
                                                                                                          -

the charge which matters.                     NH4
                                                   +
                                                        Zn
                                                           2+
                                                                                                   HCO3
                                                                                                            -

                                                             2+                                           -
                                                        Pb                                          OH
What combinations of ions are needed to
make the following compounds?
    • Sodium chloride
                                                                           one of each ion gives a
    • Lithium iodide                          Na+             Cl-          balanced charge
    • Calcium carbonate
    • Sodium hydroxide
    • Iron (III) oxide


                         Ionic bonding works in 3-D, so
                         ionic compounds form crystal
                         structures. They are strong and
                         can form aqueous solutions. They
                         are good electrical conductors
                         when dissolved or molten.
Ionic Bonding
                                                             Cations                            Anions
                                                     +1        +2            +3         -3        -2          -1
                                                       +          2+          3+         3-        2-             -
                                                     H        Mg            Al          N         O           Cl
                                                     Li+      Ca2+          Fe3+        P3-       S2-         Br-
In an ionic bond, the charges must balance.             +        2+                        3-         2-        -
                                                    Na        Fe                       PO4       CO3           I
Ions can be elemental or polyatomic – it is          K
                                                       +
                                                              Cu
                                                                 2+
                                                                                                 SO4
                                                                                                     2-
                                                                                                             NO3
                                                                                                                    -

the charge which matters.                           NH4
                                                         +
                                                              Zn
                                                                 2+
                                                                                                             HCO3
                                                                                                                      -

                                                                   2+                                               -
                                                              Pb                                              OH
What combinations of ions are needed to
make the following compounds?
    • Sodium chloride
    • Lithium iodide                             Na+                Cl-                    Fe3+            Fe3+
    • Calcium carbonate
    • Sodium hydroxide
                                 balance the charges: 6+ and 6-
    • Iron (III) oxide                                                                  O2-       O2-          O2-

                           Ionic bonding works in 3-D, so
                           ionic compounds form crystal
                           structures. They are strong
                           and can form aqueous
                           solutions. They are good
                           electrical conductors when
                           dissolved or molten.


                                                                        http://en.wikipedia.org/wiki/Iron(III)_oxide
Ionic Bonding
                                                     Cations                    Anions
                                             +1        +2        +3     -3        -2        -1
                                               +          2+      3+     3-        2-           -
                                             H        Mg        Al      N         O         Cl
                                             Li+      Ca2+      Fe3+    P3-       S2-       Br-
Practice drawing Lewis dot structures for       +        2+                3-         2-      -
                                            Na        Fe               PO4       CO3         I
these ionic bonds:                           K
                                               +
                                                      Cu
                                                         2+
                                                                                 SO4
                                                                                     2-
                                                                                           NO3
                                                                                                  -

                                                 +       2+                                         -
                                            NH4       Zn                                   HCO3
    • hydrogen chloride                               Pb
                                                           2+
                                                                                            OH
                                                                                                  -




    • iron (II) oxide

    • potassium iodide

    • copper sulphide (CuS)

    • potassium nitride
Metallic Bonding
In bonds between metal atoms, electrons
become delocalised and move freely.

This makes them very malleable and
ductile. Freely-moving electrons makes
them very good electrical conductors.



                                          From GCSE Bitesize: http://goo.gl/tJlVP




                                          Animation from:
                                          http://www.drkstreet.com/resources/m
                                          etallic-bonding-animation.swf
The duet and octet rules
 Hydrogen and helium follow the duet rule –
 two valence electrons. They have a small             H   H
 outer electron shell.


            H2 (H-H)                          H H             H       H
              Single covalent bond             shared     the line represents
                                              electrons   a pair of electrons.
The duet and octet rules
   Hydrogen and helium follow the duet rule –
   two valence electrons. They have a small                 H        H
   outer electron shell.


                 H2 (H-H)                           H H                  H         H
                  Single covalent bond               shared            the line represents
                                                    electrons          a pair of electrons.
Other elements follow the octet rule.
They will gain, lose or share electrons
until the outer shell has a full set of 8.
                                                          O         O
We can work out how bonds will form by
adding up the total number of valence
                                                                        O2 (O=O)
electrons and distributing them.
                                                O O                    O O
Two oxygen atoms have a total of 12 valence
electrons. By sharing them in covalent bonds,      shared               shared
they can make up the 8 needed.                    electrons            electrons
                                 Double covalent bond each line represents a pair of electrons.
Diatomic molecules
              These are molecules which are found as pairs of atoms,
 H H          sharing electrons. They can be elements or compounds.

     H2       See if you can draw Lewis dot configurations
              for these diatomic molecules.
 H        H
                  F          F        Cl            Cl       Br Br
 O O                    F2                 Cl2                   Br
                                                                 2
     O2

 O O          N                       I         I
              NN                           I2
                    2
Covalent Bonding
Forms between non-metals.
Atoms share valence electrons in the outer shell.
They do not form large crystals like ionic compounds.
                                                                  http://www.visionlearning.com/library/m
A single bond is the force between                                odule_viewer.php?mid=55 (animation)
two atoms which are sharing two electrons, e.g. H-H.
Double bonds are formed when
two atoms share four electrons, such as O=O.

Water is an example of a polar covalent bond.
Oxygen has more protons and pulls the shared
electrons more strongly.
The electrons are not                 σ-
shared equally.
                                                        http://www.allthingsscience.com/video/849/Ionic-

The oxygen side is slightly              O              and-covalent-bonding-animation

negative and the
hydrogens are
slightly positive.            H                  H       σ+
                                    σ+
                                                                           σ = “slightly”
Only covalently-bonded compounds
can be accurately called ‘molecules’.

Ionic compounds interact in crystals.
Covalent Bonding               Non-metals will share electrons
                               when they bond.

          How many electrons does oxygen have in total?


    O     How many of these are valence electrons?


          How about hydrogen?


          Draw them on. Draw a Lewis Dot structure for each.
    H
Covalent Bonding              Non-metals will share electrons
                              when they bond.

           Oxygen: 8 electrons, 6 valence electrons.
           Hydrogen: 1 electron, 1 valence electron.
    O
                 O                           H
            Oxygen follows the octet rule and needs eight valence
            electrons to be stable.

    H       Hydrogen follows the duet rule and needs two.
            It has one already, so will share it with oxygen.
Covalent Bonding             Non-metals will share electrons
                             when they bond.




                             H O
           Oxygen follows the octet rule and needs eight valence
           electrons to be stable.
  H
       O
           Hydrogen follows the duet rule and needs two.
           It has one already, so will share it with oxygen.

           Now the hydrogen has a full valence shell…

           … but the oxygen is one short.
Covalent Bonding                Non-metals will share electrons
                                when they bond.



                                  H
                                H O
           H

               Another hydrogen atom can share the final electron
               needed to fill the valence shell of oxygen.
  H
       O
               This gives water – H2O!
Polar Bonds                Larger atoms exert a greater pull on shared electrons.



                               Oxygen has more protons than hydrogen.
                               This means there is a stronger attraction between
                               the shared electrons and oxygen than there is
                               with the nucleus of hydrogen.

                               The result is a polar bond. Electrons are pulled
                               slightly closer to the oxygen, making it slightly
                               negatively charged overall. The hydrogen ends up
                      σ+       slightly positively charged.
σ = “slightly”
                               This will happen in any covalently-bonded
                               molecule where there is a big difference in atomic
   σ+                          numbers. The bigger the difference, the stronger
                               the effect.
                 σ-
Hydrogen Bonding
                            This is really an inter-molecular force
           σ-               between polar molecules.
                            It is a dipole-dipole attraction
            O               involving H-O, H-F or H-N bonds.

                                     Electrons in covalent bonds
                                     can be unevenly shared,                         Animation from Sumanas:
  H                    H                                                             http://goo.gl/rblz1
                                     making the molecule polar.
 σ+                    σ+
                                             These slight charges will attract opposites,
                                             such as in water and DNA!
           hydrogen bond
      σ = “slightly”            σ-




                                                         http://dna.microbiologyguide.com/s/10002/pics/dnabases.gif
Water molecules are attracted to each other with hydrogen bonds.



                                           σ-
                                            O



                                  H                    H
                                 σ+                    σ+

                                           hydrogen bond
                                      σ = “slightly”        σ-
The polar nature of water allows it to act as a solvent for ionic solids.
Annotate this model of water dissolving NaCl.
Carbon dioxide

                         C
           C



                     O       O

                 O
     O
Carbon dioxide: double bonds

                                                   O C O
                         C                       Two double bonds are formed.
                                                 These are shorter and stronger
             shared                      O             than single bonds.
            electrons
                              shared
                             electrons
                                                    O C O
                                                Bonds and electrons can also be
 By forming a double bond with each oxygen        represented with these lines.
 atom, carbon has shared four more electrons   Each line represents two electrons.
 in its valence shell and is stable.
Carbon monoxide: triple bonds

                           C                      O          C
                                                 One triple bond is formed. These
                                                  are shorter and stronger than
                                                    single and double bonds.
 The oxygen atom shares four electrons and
 the carbon shares two. This gives six shared
 electrons – a triple bond.                                O C
                                                 Bonds and electrons can also be
                                                   represented with these lines.
                                                Each line represents two electrons.
Van der Waal’s Forces
When non-polar molecules come in very close contact with
each other, an attractive force called Van der Waal’s force can
be created. This is because an induced dipole is created.

It is is a very weak inter-molecular force,
but the cumulative total of Van der Waal’s
forces can be quite strong.

Gecko feet are thought to use VdW’s forces.
They have thousands of tiny hairs called spatulae,
which maximise the surface area for forces to act.




                                                                            1μm
                                          Read about how geckoes use Van der Waal’s forces here:
                                          http://news.bbc.co.uk/2/hi/science/nature/781611.stm
Assessment: Knowledge and Understanding
MrT will give you two elements and the conclusion of a fictitious student.
Using all of your knowledge from Atoms and Bonding, explain how they will bond.
Analyse and evaluate the student’s conclusion.

Work through these steps:
         • Draw atomic structure diagrams of each
         • Identify the number of valence electrons
         • Draw Lewis dot structures
         • State whether they will bond ionically or covalently and why.
         • If they bond ionically, explain which will form an anion and which will forma
           cation and why.
         • Draw diagrams to show how they will bond
         • Show the final Lewsis Dot structures and state whether the bonds are single,
           double or triple and why.
         • If they bond covalently, try to determine if they will form a polar bond and
           identify which part will be positive and which negative, and why.

Submit this on a separate piece of paper, along with this worksheet. It will be assessed for
criterion C: Knowledge and Understanding.
A           H           B           C
                                                O O
                          H
H
            O           H O                 D
                                                H H

E                   F           G           +   H
                                                        2-
        H               H           H               O
σ-
           O



 H                    H
σ+                    σ+

          hydrogen bond
     σ = “slightly”        σ-
One World Issues: Group Poster Task
Explain the problem and outline how the use of       Explain how the A-bomb worked
the bomb was thought to be a solution.               and was used.

Identify the stakeholders.                           Evaluate and discuss the
Who are all the people or groups who were            implications of the bomb.
affected in some way by the use of the bomb?

 Discuss the use of the bomb, from multiple perspectives,
 for each of these One World issues:
        social             moral                 ethical                  political

            environmental                  economic              cultural



                                                 This will help you write your own personal
                                                 essay on One World in Chemistry…
How do we use these radioisotopes?
 Quick research and presentation:
 - What is it and how is it an isotope?
 - What is it used for?
 - HOW is it used for this purpose?

                                               Uranium-235
         Cesium-137


                                   Cobalt-60
Criterion A: One World                                         “The role of radioisotopes in Science.”
Level   Level descriptor
  0     The student does not reach a standard described by any of the descriptors below.

 1–2    The student states how science is applied and how it may be used to address a specific problem or issue in a local or global context.
        The student states the effectiveness of science and its application in solving the problem or issue.

 3–4    The student describes how science is applied and how it may be used to address a specific problem or issue in a local or global context.
        The student describes the effectiveness of science and its application in solving the problem or issue.
        The student describes the implications of the use and application of science interacting with at least one of the following factors: moral,
        ethical, social, economic, political, cultural and environmental.

 5–6    The student explains how science is applied and how it may be used to address a specific problem or issue in a local or global context.
        The student discusses the effectiveness of science and its application in solving the problem or issue.
        The student discusses and evaluates the implications of the use and application of science interacting with at least two of the following
        factors: moral, ethical, social, economic, political, cultural and environmental.


Criterion B: Communication in Science
Level   Level descriptor
  0     The student does not reach a standard described by any of the descriptors below.

 1–2    The student uses a limited range of scientific language correctly.
        The student communicates scientific information with limited effectiveness.
        When appropriate to the task, the student makes little attempt to document sources of information.

 3–4    The student uses some scientific language correctly.
        The student communicates scientific information with some effectiveness.
        When appropriate to the task, the student partially documents sources of information.

 5–6    The student uses sufficient scientific language correctly.
        The student communicates scientific information effectively.
        When appropriate to the task, the student fully documents sources of information correctly.
Ions have unbalanced protons and electrons
   Common ions:
                  Cations                             Anions
        +1          +2           +3         -3          -2          -1
          +            2+         3+         3-          2-             -
        H          Mg           Al          N           O           Cl
        Li+        Ca2+         Fe3+        P3-         S2-         Br-
           +          2+                       3-           2-        -
       Na          Fe                      PO4         CO3           I
          +           2+                                   2-             -
        K          Cu                                  SO4         NO3
            +         2+                                                    -
       NH4         Zn                                              HCO3
                         2+                                               -
                    Pb                                              OH
     Positively charged ions are cations. Negatively charged ions are anions.
     (Think: cats make old ladies happy) (Think: A Negative ION)

 What’s the difference between the ions in purple and those in black?
 Compare the elemental ions to the periodic table. Can you describe a trend?
 Can you explain why the elements above form these specific ions?
What do you think?




                                    Ideas based on
                               Concept Cartoons:
                             http://www.conceptcartoons.com




Clipart people from: http://www.clker.com/search/krug/1
South-West A   South-West B
South-East A   South-East B
North-East A   North-East B
North-West A   North-West B
 MrT’s Chemistry Shop
@IBiologyStephen                                         Please consider a donation to charity via Biology4Good.
                                         Click here for more information about Biology4Good charity donations.
                   This is a Creative Commons presentation. It may be linked and embedded but not sold or re-hosted.

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Atoms and Bonding

  • 1. σ- O H H σ+ σ+ Atoms and Bonding Intro to Chemistry MrT staylor@canacad.ac.jp
  • 2. It has electrons and protons in the nucleus and neutrons outside. The electrons are the heaviest part, which is why they’re outside. The nucleus is overall positive and the electrons are negatively charged. Clipart people from: http://www.clker.com/search/krug/1
  • 3. Atoms and Bonding Unit Questions: “How can we know what we cannot see?” Enduring Understandings: • Patterns and structures lead to predictability Areas of interaction: Human Ingenuity The Periodic Table is an amazing feat of the scientific method and reason. Criterion Assessment Tasks B: Communication Sports Drinks Lab C: Knowledge & Understanding Mystery elements bonding task (test conditions) Quia Review Quizzes: • 2.1 Atoms, ions, isotopes • 2.2 Periodic Table and structure • 2.3 Ionic and Covalent Bonding • 2.4 Intermolecular forces
  • 4. Atoms and Bonding Assessment Statements • Define valence electrons and outline the duet • Describe the components of the atom and octet rules. (protons, neutrons, electrons), in terms of • Draw Lewis dot structures for the valence size and charge. electrons of elements on the periodic table. • Outline the structure of the atom. • Deduce whether two elements will form an • Distinguish between atomic number, mass number and atomic mass. ionic or covalent compounds from their position on the periodic table • Deduce the atomic number and mass • Explain the formation of ionic bonds. number of an element from its position on • Describe the properties of ionic compounds. the periodic table. • Describe metallic bonds and their properties. • Outline the formation of isotopes, using • Define molecule. examples. • Explain the formation of covalent bonds, • Distinguish between atoms and ions. using Lewis dot structures. • Explain how cations and anions are formed, • Describe the properties of covalently bonded with examples. molecules. • Outline the organisation of the periodic • Outline how covalent bonding leads to polar table in terms of groups, periods and bonds and molecules. families. • Explain hydrogen bonding in water as an • Describe the trend in atomic structure through the periodic table. example of dipole-dipole attractions. • Describe Van der Waal's Forces.
  • 5. Build an Atom Run the simulation and build the following: 1. a hydrogen atom. 2. the hydrogen cation. 3. helium. 4. a stable isotope of helium. 5. an unstable istotope of helium. Answer the following: 1. Which subatomic particle determines the element’s atomic number? Build an Atom, from PhET. Click Run Now. http://phet.colorado.edu/en/simulation/build-an-atom 2. Which two subatomic particles determine the element’s mass number? If you’re done: 3. How is ionic charge (net charge) What level can you reach on the game? determined and what makes an ion? 4. What is an isotope and how is it made? Then test yourself (and research further): http://www.quia.com/quiz/3320413.html (firstnamelastname230, milk)
  • 6. - Atom Nucleus and electron cloud Electron (e-) (mass = negligible, charge: -1) Neutron (n0) + (mass = 1amu*, charge: 0) Nucleus contains nucleons + Proton (p+) (mass = 1amu, charge: +1) Mass number is the Atomic number is Atomic mass is the total number of the number of mean mass of an protons plus protons. This element’s atom neutrons. defines the based on isotopes. element. - *atomic mass unit (neutrons are slightly more than 1amu)
  • 7. - Atomic number is the number of protons. 2 He + helium + 4.00 Atomic mass is the mean mass of an element’s atom based on isotopes. Different periodic tables place the atomic number, atomic mass and mass number in - different positions, so pay attention to the key.
  • 8. What’s this? ? + ? ? ?
  • 9. What’s this? An atom of hydrogen has one proton and one electron only. 1 + H hydrogen 1.01 Why the 1.01? In nature some isotopes of hydrogen exist. These have 1 neutron (deuterium, mass 2amu) or 2 neutrons (tritium, mass 3amu) How would you change the diagram to show each of these isotopes?
  • 10. What’s the mean number of legs per person in: • this class? • the world? Image: 'Stacked' http://www.flickr.com/photos/17731548@N00/2153132167 Found on flickrcc.net
  • 11. What’s the mean number of legs per person in: • this class? • the world? Slightly less than one! Why? Image: 'Stacked' http://www.flickr.com/photos/17731548@N00/2153132167 Found on flickrcc.net
  • 12. What’s this? ? + ? ? ?
  • 13. What’s this? This ion of hydrogen has one proton only. An electron has been lost. 1 + H + hydrogen 1.01 The overall charge of this ion is +1. It is a cation.
  • 14. - What do you think? + + + It has 2 e-, but 3n0, so it must - be an isotope of helium It has 3 p+, so it must be an ion of lithium It has 2 e-, so it must be helium
  • 15. - + + + - What do these represent? - + + + -
  • 16. - + + + - An atom of hydrogen has one proton An atom of helium has two protons, and one electron only. two neutrons and two electrons. - + + + - An ion of hydrogen has one This isotope of helium has two protons, proton only – and therefore an one neutron and two electrons. overall charge of +1
  • 17. mass number = 12 13 What do you ? ? think? atomic number = 6 Charge = 0 6 Charge = 0 They are both the same element, but have different mass numbers, so one must be an ion. The atomic mass of the second element is 13, so it must be aluminium Its atomic number is 6, so they must both be carbon
  • 18. Marshmallow Isotopes neutrons 1. Make a hydrogen nucleus (a proton). nucleons 2. Make an alpha particle (helium nucleus) protons Use a lick to stick. Sticking forces in nuclei are weak. What are they? You need white and pink marshmallows This is called helium-4, as it has four nucleons. 3. Make a particle of the isotope helium-3. + What is different? + 4. He-5 is an unstable isotope. The alpha-particle Make it and then suggest why it is unstable. 5. C-12 is the main stable isotope of carbon. Make it. What other isotopes of carbon are there? What are their uses? 6. In the first few minutes of the universe, alpha particles formed. New elements can be made from combining alpha particles. Combine your He-4 with a C-12. What element have you made? Adapted from: http://www.lbl.gov/abc/marsh-nuclei/index.html Image from http://www.hancocks.co.uk/
  • 19. Neutrons determine nuclear properties Have a go at this at home if you need more consolidation on isotopes, neutrons and mass number. Recreate some of the atoms and isotopes you made in the marshmallow activity. How does neutron number affect mass number of the atom? Are all isotopes of an element equally abundant in nature? What is nuclear ‘stability’? Isotopes & Atomic Mass, from PhET. Click Run Now. http://phet.colorado.edu/en/simulation/isotopes-and-atomic-mass The number of neutrons does not always equal the number of protons in a stable element. As proton number increases, an increasing number of neutrons is needed to keep the atom stable. If there are too many or too few neutrons, it is unstable.
  • 20. Not all periodic atomic number tables organise the numbers around the elements in the same way. mass number symbol You must pay name attention to the key!
  • 21. mass number = 127 131 What do you ? ? think? atomic number = 53 Charge = 0 53 Charge = 0 Check the key! They are both isotopes of iodine. They have different numbers of neutrons and protons. They are both isotopes of iodine. They have different numbers of neutrons. They have the same atomic numbers but different mass numbers. They are ions.
  • 22. Iodine has many isotopes. mass number = 127 131 I I atomic number = 53 Charge = 0 53 Charge = 0 Iodine-127 Iodine-131 Protons: 53 Protons: 53 Neutrons: 74 Neutrons: 78 Stable Unstable Radioisotope used in treating Abundant Artifical thyroid cancer. The number of neutrons does not always equal the number of protons in a stable element. As proton number increases, an increasing number of neutrons is needed to keep the atom stable. If there are too many or too few neutrons, it is unstable.
  • 23. mass number = 12 Atom, Ion or C Isotope? atomic number = 6 Charge = 0 1 ? 1 Charge = +1
  • 24. mass number = 12 Atom, Ion or C Isotope? atomic number = 6 Charge = 0 1 238 H ? 1 Charge = +1 92 Charge = 0 H+ ion
  • 25. mass number = 12 Atom, Ion or C Isotope? atomic number = 6 Charge = 0 1 238 235 H U ? 1 Charge = +1 92 Charge = 0 92 Charge = 0 H+ ion Uranium
  • 26. mass number = 12 Atom, Ion or C Isotope? atomic number = 6 Charge = 0 1 238 235 60 H U U ? 1 Charge = +1 92 Charge = 0 92 Charge = 0 27 Charge = 0 H+ ion Uranium Uranium isotope
  • 27. mass number = 12 Atom, Ion or C Isotope? atomic number = 6 Charge = 0 1 238 235 60 H U U Co 1 Charge = +1 92 Charge = 0 92 Charge = 0 27 Charge = 0 H+ ion Uranium Uranium isotope Cobalt isotope 16 ? 8 Charge = 2-
  • 28. mass number = 12 Atom, Ion or C Isotope? atomic number = 6 Charge = 0 1 238 235 60 H U U Co 1 Charge = +1 92 Charge = 0 92 Charge = 0 27 Charge = 0 H+ ion Uranium Uranium isotope Cobalt isotope 16 238 O ? 8 Charge = 2- 94 Charge = 0 Oxygen ion
  • 29. mass number = 12 Atom, Ion or C Isotope? atomic number = 6 Charge = 0 1 238 235 60 H U U Co 1 Charge = +1 92 Charge = 0 92 Charge = 0 27 Charge = 0 H+ ion Uranium Uranium isotope Cobalt isotope 16 238 40 O Pu ? 8 Charge = 2- 94 Charge = 0 20 Charge = 2+ Oxygen ion Plutonium isotope
  • 30. mass number = 12 Atom, Ion or C Isotope? atomic number = 6 Charge = 0 1 238 235 60 H U U Co 1 Charge = +1 92 Charge = 0 92 Charge = 0 27 Charge = 0 H+ ion Uranium Uranium isotope Cobalt isotope 16 238 40 47 O Pu Ca ? 8 Charge = 2- 94 Charge = 0 20 Charge = 2+ 20 Charge = 0 Oxygen ion Plutonium isotope Calcium ion
  • 31. mass number = 12 Atom, Ion or C Isotope? atomic number = 6 Charge = 0 1 238 235 60 H U U Co 1 Charge = +1 92 Charge = 0 92 Charge = 0 27 Charge = 0 H+ ion Uranium Uranium isotope Cobalt isotope 16 238 40 47 O Pu Ca Ca 8 Charge = 2- 94 Charge = 0 20 Charge = 2+ 20 Charge = 0 Oxygen ion Plutonium isotope Calcium ion Calcium isotope
  • 32. What are they? How do we draw them? IONS How do we name them? How do they make bonds?
  • 33. Electrons determine chemical properties An atom of helium has two protons, two neutrons and two electrons. - It is a small atom, with an electron ‘shell’ which 2p+ can hold only 2 electrons. 2n0 Because the ‘shell’ is full, He is stable and - unreactive – it is a noble gas. The inner shells ‘fill’ first, as the electrons are - - attracted to the positive nucleus. - Larger atoms have bigger shells. However, the outermost shell holds maximum 8 electrons. 9p+ - - 9n0 - What is this atom? How might it become more stable? - - -
  • 34. Ions have unbalanced protons and electrons - H atom 1p+ 0n0 - - - F atom 9p+ - - 9n0 - - - -
  • 35. Ions have unbalanced protons and electrons H+ ion 1p+ 0n0 Positively charged ions are cations. (Think: cats make old ladies happy) - - - F- ion - 9p+ - Negatively charged ions are anions. - 9n0 - (Think: A Negative ION) - - -
  • 36. Octet Rule Atoms in a compound will tend to have the electron configuration of a noble gas: Eight electrons in the outer (valence) shell. Duet Rule The inner shell can hold a maximum two electrons – the configuration of helium.
  • 37. Atoms and the periodic table Group 1: Alkali metals columns Group 2: Alkaline earth metals are groups Group 7: Halogens (sometimes called 17) Group 8: Noble gases (sometimes 18 or 0) orphan hydrogen rows are periods Lanthanides Actinoids Interactive periodic table from: http://www.ptable.com/
  • 38. Ions have unbalanced protons and electrons Common ions: Positively charged ions are cations. Negatively charged ions are anions. (Think: cats make old ladies happy) (Think: A Negative ION) What’s the difference between the ions in purple and those in black? Compare the elemental ions to the periodic table. Can you describe a trend? Can you explain why the elements above form these specific ions?
  • 39. What’s the relationship between atomic structure and the periodic table? +1 +2 Ionic charges are in red. +3 -3 -2 -1 metals non-metals transition metals Periodic Table from the IBDP Chemistry Data Booklet
  • 40. What’s the relationship between atomic structure and the periodic table? Interactive periodic table from: http://www.footprints-science.co.uk/flash/periodic2.swf
  • 41. Atoms and the periodic table Group 1: Alkali metals columns Group 2: Alkaline earth metals are groups Group 17: Halogens Group 18: Noble gases orphan hydrogen rows are periods Lanthanides Actinoids Interactive periodic table from: http://www.ptable.com/
  • 42. Valence Electrons & Configurations In the first period (H and He), there is one small electron shell. It can hold up to two electrons – a duet. As we move down each period, we add an electron shell. The outer shell can hold up to 8 electrons. 4 shells, 1 valence electron Valence electrons are the electrons in the outer shell only. They are used in bonding. Once the outer shell is full, the atom is stable. This is the octet rule. Interactive periodic table from: http://www.ptable.com/
  • 43. Complete the pattern… H He Li Be B C N O F Ne What do the dots represent? What is the relationship with periodic table? Can you predict the pattern for aluminium?
  • 44. Lewis dot configurations These dots show the number of valence electrons in an atom. H We can use them to predict bond types as well as the He structure of a compound. Li Be B C N O F Ne What is the relationship with periodic table? Elements in the same group have the same All the Lewis dots: number of valence electrons. Can you predict the pattern for aluminium? Al http://www.roymech.co.uk/Related/Chemistry/Lewis_dot_structure.html
  • 45. What’s in your sports drinks? Sports drinks contain ions to help with rehydration (if you really need it). Two of their main ingredients are sugar (sucrose) and salt (sodium chloride). In this investigation we will: • Determine whether sugar or salt is ionic • Compare the ion concentrations of two drinks https://docs.google.com/presentation/d/1Hqs6AMjlx5KBGWWSzOLBSBbO2mzDqw17CkMSdB hSAcQ Pocari Sweat and Aquarius bottles from http://jin.jcic.or.jp/en/ranking/near_water_small_pet_bottle_pouch/
  • 46. Bonding is the attraction between atoms. Atoms are stable when they have a full valence shell. In ionic bonds, electrons are transferred to achieve this. In covalent, electrons are shared. The result are forces of attraction. Bonds: • Ionic • Covalent • Metallic Inter-molecular forces: • Dipole-dipole bonds • Hydrogen bonds • Van der Waal’s forces http://www.kentchemistry.com/links/bonding/bondingflashes/bond_types.swf
  • 47. Ionic or covalent bonds? Binary compounds contain two elements. Metal + non-metal, the bonding will be ionic. If both are non-metals, bonding is covalent. non-metals metals So what about these compounds? lithium fluoride _____________ nitrogen dioxide _____________ carbon dioxide _____________ water _____________ magnesium oxide ____________ methane (CH4) _____________ sodium chloride _____________ lead iodide _____________ Periodic table from the BBC. http://goo.gl/1rrCk
  • 48. Ionic or covalent bonds? Binary compounds contain two elements. Metal + non-metal, the bonding will be ionic. If both are non-metals, bonding is covalent. non-metals metals So what about these compounds? lithium fluoride ionic nitrogen dioxide covalent carbon dioxide covalent water covalent magnesium oxide ionic methane (CH4) covalent sodium chloride ionic lead iodide ionic Periodic table from the BBC. http://goo.gl/1rrCk
  • 49. Octet Rule Atoms in a compound will tend to have the electron configuration of a noble gas: Eight electrons in the outer (valence) shell. Duet Rule The inner shell can hold a maximum two electrons – the configuration of helium.
  • 50. Ionic Bonding Forms between a metal and a non-metal. Metal cations(+) donate electron(s) to non- metal anions(-). Li F + - cation Li F anion The metal has lost its lone electron and the non-metal has gained. They each now have filled outer valence shells. Cations attract anions – the atoms are held together by this attraction – the ionic bond. + - Li F http://www.footprints-science.co.uk/ionic.htm
  • 51. Almost full? Get some more. Almost empty? Get rid. Draw the electron arrangements on these shells. State the number of valence electrons and draw a Lewis dot configuration. Deduce whether they will form an anion or a cation. Oxygen Chlorine Aluminium Beryllium
  • 52. Almost full? Get some more. Almost empty? Get rid. Draw the electron arrangements on these shells. State the number of valence electrons and draw a Lewis dot configuration. Deduce whether they will form an anion or a cation. Oxygen Chlorine 8 protons, 8 electrons, 6 valence electrons. Lewis dot: O 2- O Almost full- gain two electrons and form an anion. Aluminium Magnesium Al
  • 53. Almost full? Get some more. Almost empty? Get rid. Draw the electron arrangements on these shells. State the number of valence electrons and draw a Lewis dot configuration. Deduce whether they will form an anion or a cation. Oxygen Chlorine 8 protons, 8 electrons, 6 valence electrons. Lewis dot: O 2- O Almost full- gain two electrons and form an anion. Aluminium Magnesium 13 protons, 13 electrons, Al 3 valence electrons. Lewis dot: Al 3+ Al Almost empty- lose three electrons and form a cation.
  • 54. Ionic Bonding Cations Anions +1 +2 +3 -3 -2 -1 + 2+ 3+ 3- 2- - H Mg Al N O Cl Li+ Ca2+ Fe3+ P3- S2- Br- In an ionic bond, the charges must balance. + 2+ 3- 2- - Na Fe PO4 CO3 I Ions can be elemental or polyatomic – it is K + Cu 2+ SO4 2- NO3 - the charge which matters. NH4 + Zn 2+ HCO3 - 2+ - Pb OH What combinations of ions are needed to make the following compounds? • Sodium chloride one of each ion gives a • Lithium iodide Na+ Cl- balanced charge • Calcium carbonate • Sodium hydroxide • Iron (III) oxide Ionic bonding works in 3-D, so ionic compounds form crystal structures. They are strong and can form aqueous solutions. They are good electrical conductors when dissolved or molten.
  • 55. Ionic Bonding Cations Anions +1 +2 +3 -3 -2 -1 + 2+ 3+ 3- 2- - H Mg Al N O Cl Li+ Ca2+ Fe3+ P3- S2- Br- In an ionic bond, the charges must balance. + 2+ 3- 2- - Na Fe PO4 CO3 I Ions can be elemental or polyatomic – it is K + Cu 2+ SO4 2- NO3 - the charge which matters. NH4 + Zn 2+ HCO3 - 2+ - Pb OH What combinations of ions are needed to make the following compounds? • Sodium chloride • Lithium iodide Na+ Cl- Fe3+ Fe3+ • Calcium carbonate • Sodium hydroxide balance the charges: 6+ and 6- • Iron (III) oxide O2- O2- O2- Ionic bonding works in 3-D, so ionic compounds form crystal structures. They are strong and can form aqueous solutions. They are good electrical conductors when dissolved or molten. http://en.wikipedia.org/wiki/Iron(III)_oxide
  • 56. Ionic Bonding Cations Anions +1 +2 +3 -3 -2 -1 + 2+ 3+ 3- 2- - H Mg Al N O Cl Li+ Ca2+ Fe3+ P3- S2- Br- Practice drawing Lewis dot structures for + 2+ 3- 2- - Na Fe PO4 CO3 I these ionic bonds: K + Cu 2+ SO4 2- NO3 - + 2+ - NH4 Zn HCO3 • hydrogen chloride Pb 2+ OH - • iron (II) oxide • potassium iodide • copper sulphide (CuS) • potassium nitride
  • 57. Metallic Bonding In bonds between metal atoms, electrons become delocalised and move freely. This makes them very malleable and ductile. Freely-moving electrons makes them very good electrical conductors. From GCSE Bitesize: http://goo.gl/tJlVP Animation from: http://www.drkstreet.com/resources/m etallic-bonding-animation.swf
  • 58. The duet and octet rules Hydrogen and helium follow the duet rule – two valence electrons. They have a small H H outer electron shell. H2 (H-H) H H H H Single covalent bond shared the line represents electrons a pair of electrons.
  • 59. The duet and octet rules Hydrogen and helium follow the duet rule – two valence electrons. They have a small H H outer electron shell. H2 (H-H) H H H H Single covalent bond shared the line represents electrons a pair of electrons. Other elements follow the octet rule. They will gain, lose or share electrons until the outer shell has a full set of 8. O O We can work out how bonds will form by adding up the total number of valence O2 (O=O) electrons and distributing them. O O O O Two oxygen atoms have a total of 12 valence electrons. By sharing them in covalent bonds, shared shared they can make up the 8 needed. electrons electrons Double covalent bond each line represents a pair of electrons.
  • 60. Diatomic molecules These are molecules which are found as pairs of atoms, H H sharing electrons. They can be elements or compounds. H2 See if you can draw Lewis dot configurations for these diatomic molecules. H H F F Cl Cl Br Br O O F2 Cl2 Br 2 O2 O O N I I NN I2 2
  • 61. Covalent Bonding Forms between non-metals. Atoms share valence electrons in the outer shell. They do not form large crystals like ionic compounds. http://www.visionlearning.com/library/m A single bond is the force between odule_viewer.php?mid=55 (animation) two atoms which are sharing two electrons, e.g. H-H. Double bonds are formed when two atoms share four electrons, such as O=O. Water is an example of a polar covalent bond. Oxygen has more protons and pulls the shared electrons more strongly. The electrons are not σ- shared equally. http://www.allthingsscience.com/video/849/Ionic- The oxygen side is slightly O and-covalent-bonding-animation negative and the hydrogens are slightly positive. H H σ+ σ+ σ = “slightly”
  • 62. Only covalently-bonded compounds can be accurately called ‘molecules’. Ionic compounds interact in crystals.
  • 63. Covalent Bonding Non-metals will share electrons when they bond. How many electrons does oxygen have in total? O How many of these are valence electrons? How about hydrogen? Draw them on. Draw a Lewis Dot structure for each. H
  • 64. Covalent Bonding Non-metals will share electrons when they bond. Oxygen: 8 electrons, 6 valence electrons. Hydrogen: 1 electron, 1 valence electron. O O H Oxygen follows the octet rule and needs eight valence electrons to be stable. H Hydrogen follows the duet rule and needs two. It has one already, so will share it with oxygen.
  • 65. Covalent Bonding Non-metals will share electrons when they bond. H O Oxygen follows the octet rule and needs eight valence electrons to be stable. H O Hydrogen follows the duet rule and needs two. It has one already, so will share it with oxygen. Now the hydrogen has a full valence shell… … but the oxygen is one short.
  • 66. Covalent Bonding Non-metals will share electrons when they bond. H H O H Another hydrogen atom can share the final electron needed to fill the valence shell of oxygen. H O This gives water – H2O!
  • 67. Polar Bonds Larger atoms exert a greater pull on shared electrons. Oxygen has more protons than hydrogen. This means there is a stronger attraction between the shared electrons and oxygen than there is with the nucleus of hydrogen. The result is a polar bond. Electrons are pulled slightly closer to the oxygen, making it slightly negatively charged overall. The hydrogen ends up σ+ slightly positively charged. σ = “slightly” This will happen in any covalently-bonded molecule where there is a big difference in atomic σ+ numbers. The bigger the difference, the stronger the effect. σ-
  • 68. Hydrogen Bonding This is really an inter-molecular force σ- between polar molecules. It is a dipole-dipole attraction O involving H-O, H-F or H-N bonds. Electrons in covalent bonds can be unevenly shared, Animation from Sumanas: H H http://goo.gl/rblz1 making the molecule polar. σ+ σ+ These slight charges will attract opposites, such as in water and DNA! hydrogen bond σ = “slightly” σ- http://dna.microbiologyguide.com/s/10002/pics/dnabases.gif
  • 69. Water molecules are attracted to each other with hydrogen bonds. σ- O H H σ+ σ+ hydrogen bond σ = “slightly” σ-
  • 70. The polar nature of water allows it to act as a solvent for ionic solids. Annotate this model of water dissolving NaCl.
  • 71. Carbon dioxide C C O O O O
  • 72. Carbon dioxide: double bonds O C O C Two double bonds are formed. These are shorter and stronger shared O than single bonds. electrons shared electrons O C O Bonds and electrons can also be By forming a double bond with each oxygen represented with these lines. atom, carbon has shared four more electrons Each line represents two electrons. in its valence shell and is stable.
  • 73. Carbon monoxide: triple bonds C O C One triple bond is formed. These are shorter and stronger than single and double bonds. The oxygen atom shares four electrons and the carbon shares two. This gives six shared electrons – a triple bond. O C Bonds and electrons can also be represented with these lines. Each line represents two electrons.
  • 74. Van der Waal’s Forces When non-polar molecules come in very close contact with each other, an attractive force called Van der Waal’s force can be created. This is because an induced dipole is created. It is is a very weak inter-molecular force, but the cumulative total of Van der Waal’s forces can be quite strong. Gecko feet are thought to use VdW’s forces. They have thousands of tiny hairs called spatulae, which maximise the surface area for forces to act. 1μm Read about how geckoes use Van der Waal’s forces here: http://news.bbc.co.uk/2/hi/science/nature/781611.stm
  • 75. Assessment: Knowledge and Understanding MrT will give you two elements and the conclusion of a fictitious student. Using all of your knowledge from Atoms and Bonding, explain how they will bond. Analyse and evaluate the student’s conclusion. Work through these steps: • Draw atomic structure diagrams of each • Identify the number of valence electrons • Draw Lewis dot structures • State whether they will bond ionically or covalently and why. • If they bond ionically, explain which will form an anion and which will forma cation and why. • Draw diagrams to show how they will bond • Show the final Lewsis Dot structures and state whether the bonds are single, double or triple and why. • If they bond covalently, try to determine if they will form a polar bond and identify which part will be positive and which negative, and why. Submit this on a separate piece of paper, along with this worksheet. It will be assessed for criterion C: Knowledge and Understanding.
  • 76. A H B C O O H H O H O D H H E F G + H 2- H H H O
  • 77. σ- O H H σ+ σ+ hydrogen bond σ = “slightly” σ-
  • 78.
  • 79. One World Issues: Group Poster Task Explain the problem and outline how the use of Explain how the A-bomb worked the bomb was thought to be a solution. and was used. Identify the stakeholders. Evaluate and discuss the Who are all the people or groups who were implications of the bomb. affected in some way by the use of the bomb? Discuss the use of the bomb, from multiple perspectives, for each of these One World issues: social moral ethical political environmental economic cultural This will help you write your own personal essay on One World in Chemistry…
  • 80. How do we use these radioisotopes? Quick research and presentation: - What is it and how is it an isotope? - What is it used for? - HOW is it used for this purpose? Uranium-235 Cesium-137 Cobalt-60
  • 81. Criterion A: One World “The role of radioisotopes in Science.” Level Level descriptor 0 The student does not reach a standard described by any of the descriptors below. 1–2 The student states how science is applied and how it may be used to address a specific problem or issue in a local or global context. The student states the effectiveness of science and its application in solving the problem or issue. 3–4 The student describes how science is applied and how it may be used to address a specific problem or issue in a local or global context. The student describes the effectiveness of science and its application in solving the problem or issue. The student describes the implications of the use and application of science interacting with at least one of the following factors: moral, ethical, social, economic, political, cultural and environmental. 5–6 The student explains how science is applied and how it may be used to address a specific problem or issue in a local or global context. The student discusses the effectiveness of science and its application in solving the problem or issue. The student discusses and evaluates the implications of the use and application of science interacting with at least two of the following factors: moral, ethical, social, economic, political, cultural and environmental. Criterion B: Communication in Science Level Level descriptor 0 The student does not reach a standard described by any of the descriptors below. 1–2 The student uses a limited range of scientific language correctly. The student communicates scientific information with limited effectiveness. When appropriate to the task, the student makes little attempt to document sources of information. 3–4 The student uses some scientific language correctly. The student communicates scientific information with some effectiveness. When appropriate to the task, the student partially documents sources of information. 5–6 The student uses sufficient scientific language correctly. The student communicates scientific information effectively. When appropriate to the task, the student fully documents sources of information correctly.
  • 82. Ions have unbalanced protons and electrons Common ions: Cations Anions +1 +2 +3 -3 -2 -1 + 2+ 3+ 3- 2- - H Mg Al N O Cl Li+ Ca2+ Fe3+ P3- S2- Br- + 2+ 3- 2- - Na Fe PO4 CO3 I + 2+ 2- - K Cu SO4 NO3 + 2+ - NH4 Zn HCO3 2+ - Pb OH Positively charged ions are cations. Negatively charged ions are anions. (Think: cats make old ladies happy) (Think: A Negative ION) What’s the difference between the ions in purple and those in black? Compare the elemental ions to the periodic table. Can you describe a trend? Can you explain why the elements above form these specific ions?
  • 83. What do you think? Ideas based on Concept Cartoons: http://www.conceptcartoons.com Clipart people from: http://www.clker.com/search/krug/1
  • 84. South-West A South-West B South-East A South-East B North-East A North-East B North-West A North-West B MrT’s Chemistry Shop
  • 85. @IBiologyStephen Please consider a donation to charity via Biology4Good. Click here for more information about Biology4Good charity donations. This is a Creative Commons presentation. It may be linked and embedded but not sold or re-hosted.