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Anthropogenic Mercury Mobilization and Emissions in US and Florida, 1930-2000 ,[object Object],[object Object],[object Object],Supported by Florida Department of Environmental Protection Tetra-Tech, Inc
Health and Environmental Concerns ,[object Object],[object Object],[object Object],The importance of mercury (Hg) as an environmental contaminant stems from its omnipresent nature, due largely to the magnitude of sources, its volatility, mobility, and persistence.
Mercury Sources  Mercury is a building block of planet Earth (trace element).  Mercury metal is liquid and evaporates, depending on temperature and barometric pressure. Natural systems, wind, rain, volcanic disturbances shift mercury location. MAN-MADE  sources add to the environmental burden by taking mercury from its geological deposits and redistributing mercury to AIR , LAND and WATER. Mercury in environment is either in elemental form or reactive gaseous mercury (RGM). Atmospheric residence time   Hg o  order of 90 days Hg 2+  (RGM) order of days.
Biomagnifications of Hg ,[object Object],[object Object]
Approach for Assessment of Anthropogenic Mercury ,[object Object],[object Object],[object Object],[object Object]
Mercury mobilized in coal ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Mercury Mobilized in Petroleum Unlike for coal, the Hg content of crude oil is highly variable and the data are sparse.  Measured crude oil Hg concentration ranges between 10 and 30,000 ppb.  “ Other”  still gas, naphtas, unfinished oils, petroleum coke (consumed at refineries and electric utilities),   etc   Fate of Hg in Crude Oil Assuming 10 ppb in crude oil
US Mercury Mobilization Trend ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Data: Bureau of Mines (BOM), USGS, and DOE
Mercury Mobilized in Goods: Electrical Sector ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Mercury in Paint ,[object Object],[object Object],[object Object]
Mercury Flow in Goods ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Data: Bureau of Mines (BOM), USGS, and DOE Mobilized in 70 years ~112,000 Mg
Mercury Mobilization -> Atmospheric Emissions ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],50-75% Air 100% 66% Air 100% AIR Land Air+Land
Mercury Emissions: USA ,[object Object],[object Object],[object Object]
Mercury Flow: US -> Mercury Flow: Florida  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Acreage use prorated Population prorated Florida specific Mercury Flow: US Mercury Flow: Florida
Mercury in Coal and Petroleum: Florida ,[object Object],[object Object],E Kentucky Source of Coal Hg ,[object Object],[object Object],[object Object]
Mercury Flow in Florida Mercury flow in Florida has been steadily increasing until the 1980s The electrical sector (batteries) was dominant throughout the period The electrical sector contributed 50% of the cumulative Hg flow (1930-2000).  Cumulative Hg Flow: ~2000 Mg/70 yrs
Waste Combustion Fraction and Rate ,[object Object],[object Object],[object Object],[object Object],[object Object]
Mercury Emissions: US and Florida ,[object Object],[object Object],[object Object],[object Object]
Mercury Emissions:  Comparison of Florida DEP – Material Flow Method ,[object Object],[object Object],[object Object],[object Object]
Broward County mercury flow and emissions Paint and electrical goods contribution was the largest in the Broward County.
Summary ,[object Object],[object Object],[object Object],[object Object],[object Object]
Waste Combustion Fraction and Rate ,[object Object],[object Object],[object Object],[object Object]
Mercury in Agriculture: Florida ,[object Object]
Comparison of RMB and flow method ,[object Object]
Mercury Flow Methodology ,[object Object],[object Object],[object Object]

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  • 3. Mercury Sources Mercury is a building block of planet Earth (trace element). Mercury metal is liquid and evaporates, depending on temperature and barometric pressure. Natural systems, wind, rain, volcanic disturbances shift mercury location. MAN-MADE sources add to the environmental burden by taking mercury from its geological deposits and redistributing mercury to AIR , LAND and WATER. Mercury in environment is either in elemental form or reactive gaseous mercury (RGM). Atmospheric residence time Hg o order of 90 days Hg 2+ (RGM) order of days.
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  • 7. Mercury Mobilized in Petroleum Unlike for coal, the Hg content of crude oil is highly variable and the data are sparse. Measured crude oil Hg concentration ranges between 10 and 30,000 ppb. “ Other” still gas, naphtas, unfinished oils, petroleum coke (consumed at refineries and electric utilities), etc Fate of Hg in Crude Oil Assuming 10 ppb in crude oil
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  • 16. Mercury Flow in Florida Mercury flow in Florida has been steadily increasing until the 1980s The electrical sector (batteries) was dominant throughout the period The electrical sector contributed 50% of the cumulative Hg flow (1930-2000). Cumulative Hg Flow: ~2000 Mg/70 yrs
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  • 20. Broward County mercury flow and emissions Paint and electrical goods contribution was the largest in the Broward County.
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