To prove that the complement of a disconnected graph G is connected, the solution shows that for any two distinct vertices u and v in the complement graph G-1, there is always a path between them of length at most 2. This is because if u and v are in different components of G, they are adjacent in G-1, and if in the same component, there is a third vertex w in a different component such that u and v are both adjacent to w in G-1.