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                             Topic 4
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                    LESSON
   Determining Molecule Polarity
DEMONSTRATION - POLAR MOLECULES
Evidence    place a liquid in a burette
            allow it to run out
            place a charged rod alongside the stream of liquid
            polar molecules are attracted by electrostatic attraction
            non-polar molecules will be unaffected




                                   NET DIPOLE - POLAR      NON-POLAR
Determining Molecular Polarity
We must know   if individual covalent bonds are polar
               and
               the shape of the molecule


Example 1 : nitrogen gas




                                                molecules
                                                containing only
                                                non-polar bonds
                                                ARE NOT POLAR
Determining Molecular Polarity
We must know   if individual covalent bonds are polar
               and
               the shape of the molecule


Example 2 : hydrofluoric acid HF

        bond dipole
Determining Molecular Polarity
We must know   if individual covalent bonds are polar
               and
               the shape of the molecule


Example 2 : hydrofluoric acid HF

        molecule dipole




                                              molecule is POLAR
Example 3 Methane

                    C-H bonds slightly polar

                    but molecule is symmetrical

                    bond dipoles cancel out
            C




                    molecule is NON-POLAR
Example 4 Ammonia
                    N-H bonds polar

                    molecule is asymmetrical

                    lone pair (negative)

                    hydrogen atoms (positive)




                    molecule is POLAR
Example 5 water
POLAR MOLECULES - SUMMARY
Concept s     molecules containing non-polar bonds are non-polar
              symmetrical polar bonds: the molecule isnโ€™t polar
              asymmetrical polar bonds: the molecule will be polar



   HYDROGEN CHLORIDE    TETRACHLOROMETHANE              WATER




NET DIPOLE - POLAR          NON-POLAR            NET DIPOLE - POLAR


 To determine molecular polarity, we must know molecular shape and
 bond polarity.

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2012 Molecule Polarity

  • 1. IB Chemistry Power Points Topic 4 Bonding www.pedagogics.ca LESSON Determining Molecule Polarity
  • 2. DEMONSTRATION - POLAR MOLECULES Evidence place a liquid in a burette allow it to run out place a charged rod alongside the stream of liquid polar molecules are attracted by electrostatic attraction non-polar molecules will be unaffected NET DIPOLE - POLAR NON-POLAR
  • 3. Determining Molecular Polarity We must know if individual covalent bonds are polar and the shape of the molecule Example 1 : nitrogen gas molecules containing only non-polar bonds ARE NOT POLAR
  • 4. Determining Molecular Polarity We must know if individual covalent bonds are polar and the shape of the molecule Example 2 : hydrofluoric acid HF bond dipole
  • 5. Determining Molecular Polarity We must know if individual covalent bonds are polar and the shape of the molecule Example 2 : hydrofluoric acid HF molecule dipole molecule is POLAR
  • 6. Example 3 Methane C-H bonds slightly polar but molecule is symmetrical bond dipoles cancel out C molecule is NON-POLAR
  • 7. Example 4 Ammonia N-H bonds polar molecule is asymmetrical lone pair (negative) hydrogen atoms (positive) molecule is POLAR
  • 9. POLAR MOLECULES - SUMMARY Concept s molecules containing non-polar bonds are non-polar symmetrical polar bonds: the molecule isnโ€™t polar asymmetrical polar bonds: the molecule will be polar HYDROGEN CHLORIDE TETRACHLOROMETHANE WATER NET DIPOLE - POLAR NON-POLAR NET DIPOLE - POLAR To determine molecular polarity, we must know molecular shape and bond polarity.