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The Microscopic Structure of Matter ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Between species from  same  parent species  Between species from  different  parent species
“ Bonding”: General Ideas and Types ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Principles of Bond Formation ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Rationale for Ionic “Bonding” ,[object Object],[object Object],[object Object],[object Object],[object Object]
Electron Dot Structures ,[object Object],[object Object],[object Object],[object Object],[object Object]
Formation of Ions Repeat but with electronic configurations Na + + Na +   Cl Cl - Cl -   Na + Cl Na e - (1s 2 2s 2 2p 6 3s 2 3p 5 ) (1s 2 2s 2 2p 6 ) (1s 2 2s 2 2p 6 3s 1 ) (1s 2 2s 2 2p 6 3s 2 3p 6 )
Formation of Ions – another example Ca + + Ca 2+ O O 2-   O 2-   Ca 2+ O Ca 2 e - (1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 ) (1s 2 2s 2 2p 6 ) (1s 2 2s 2 2p 4 ) (1s 2 2s 2 2p 6 3s 2 3p 6 )
Structures of Ionic Compounds ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Crystals of Cesium Halides    CsF CsCl   CsI      CsBr
Crystals of copper salts
Formulas of Binary Ionic Compounds ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],* Method for Making Compounds O 2- e - K K + 2 O 2 e - 2 2 = K 2 O
Properties of Ionic Compounds ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Rationale for Covalent Bonding ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
VSEPR not in your textbook ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
The Octet and Duet Rules ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Types of Covalent Bonds ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Lewis Structures ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Table 4.11 Preferred Number of Bonds
Arrangements of Groups vs Molecular Geometry ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
LINEAR TETRAHEDRAL PLANAR ARRANGEMENT Two double or one triple bond One double bond All single bonds
Example 1: Correlation between Lewis structure, arrangement and molecular geometry
Example 2: Correlation between Lewis structure, arrangement and molecular geometry
Example 3: Correlation between Lewis structure, arrangement and molecular geometry
Electronegativity The most important idea in chemistry ,[object Object],[object Object],[object Object],[object Object]
Figure 4.5
Bond Polarity ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Table 4.14
Table 4.15
Molecular Polarity ,[object Object],[object Object],[object Object],[object Object]
A “Formula” for Success for Structure, Geometry and Polarity ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Systematic approach to making Lewis structures & determining their characteristics  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Lewis Structures – Facts to start with ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Lewis Structures – Neutral Species
Lewis Structures – Charged species ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Making Lewis Structures ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],*
Determining Arrangements & Bond Angles  around central atom(s) – Step by Step ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],*
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Determining Geometries around central atom(s) – Step by Step *
Rules for Overall Polarity of Neutral Species ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],ALWAYS USE THE ARRANGEMENT  TO DETERMINE POLARITY *
LINEAR TETRAHEDRAL PLANAR ARRANGEMENT Two double or one triple bond One double bond All single bonds 180 120 109.5 BOND ANGLE SUBCLASS THE ULTIMATE USEFUL SUMMARY SLIDE One of the S-O bonds is double

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