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MATTER & ATOMS
Year 9
SLOS
 SLO 1: Show understanding of the particle nature of matter
 SLO 2: Explain the difference between the three states of matter
 SLO 3: Outline how matter changes from one state to another
 SLO 4: Show understanding of the concept of density and investigate
the densities of different substances
 SLO 5: Use the particle theory to explain the processes of diffusion,
expansion and contraction
 SLO 6: Explain and give examples of the processes of conduction and
convection
 SLO 7: Describe the present atomic model (including the number of
protons, neutrons and electrons) and relate some historical models of
the atom
 SLO 8: Show understanding of the definitions of atom, element,
compound, molecule and mixture and be able to distinguish between
them
 SLO 9: Understand what a chemical formula represents
 SLO 10: Recall names and symbols of some of the most common
elements
SLO
SLO 1: Show understanding of
the particle nature of matter
SLO 2: Explain the difference
between the three states of matter
PARTICLE NATURE OF MATTER
 Matter is everything that has mass and takes
up space (everything on earth)
 Everything is made up of particles called
atoms
 Gold is made of gold atoms
 Oxygen is made of oxygen atoms
 Water is made of hydrogen and oxygen atoms
PARTICLE THEORY
 Matter is made up of tiny particles (Atoms &
Molecules)
 Particles of Matter are always moving
 Particles of Matter are held together by very
strong electric forces
 Temperature affects the speed of the
particles. The higher the temperature, the
faster the speed of the particles.
PARTICLE THEORY
Particle theory is all about explaining the properties of solids,
liquids and gases by looking at what the particles do.
In a solid the particles ______
around a _____ position. There is
a ______ force of attraction
between each particle and they
are very _____ together
SOLIDS
Words – strong, close, vibrate, fixed
View animation
LIQUIDS
GASES
In a liquid the particles are _____
together but can move in any
direction. They won’t keep a
_____ shape like _____ do.
In a gas the particles are very far
apart and move _____ in all
directions. They often ______
with each other and because they
are far apart they can be easily
_______.
Words – fixed, collide, quickly, close, solids, compressed
CHANGE OF STATE
 A small piece of ice which lived in a test tube
fell in love with a Bunsen burner. "Bunsen!
my flame!
 I melt whenever I see you" said the ice.
 The Bunsen burner replied :"It's just a phase
you're going through".
SUCCESS CRITERIA
 Complete cut and paste on states of matter
 Complete page 50-51 in Scipad
 Describe two properties that are different between solids and
liquids
 Forces of attraction between particles are weaker in liquids than
solids
 Solids particles vibrate slowly while liquids roll over each other
 Describe two properties that are different between liquids and
gases
 Gas particles move faster than liquids
 Gases have a weaker force of attraction between particles than liquids
 What are the three states that matter can exist in?
 Liquids solids and gases
SLO
SLO 3: Outline how matter changes from one
state to another
CHANGING STATES
 When heat is added or taken away states of
matter change.
 Adding heat makes molecules move faster and
further apart, solids turn to liquids then gases as
heat is added
 Removing heat makes molecules move slower
and closer together, gases turn into liquids then
solids as heat is removed
 Pressure also effects states of matter
/solidification
CHANGING STATE
 Changing state requires energy
 Energy is used in changing state so
temperature stays the same
SUCCESS CRITERIA
 Complete Scipad pages 52-53 Making a Key and
Changing States
 Complete Investigation in State Changes on page 54-
55
 What happens to the particles in a liquid when it is
turned into a solid? (HINT: discuss speed,
closeness, energy level of particles)
 What happens to the particles in a liquid when it is
heated and turned into a gas? (HINT: discuss
speed, closeness, energy level of particles)
SLO
SLO 4: Show understanding of the concept of
density and investigate the densities of
different substances
DENSITY
 All objects are made out of particles
 Density is how tightly packed those particles
are.
 The more tightly packed the particles, the
more dense.
decreasing density
DENSITY
Which is heavier: 1kg of feathers or 1 kg of gold?
They have the same mass, but what is different about
them?
Density describes how heavy an object is for its size
eg: 1kg of feathers would take up a lot of room because
feathers are not very heavy for their size. They have a low
density.
1kg of gold metal does not take up much space as it has a
high density
CALCULATING DENSITY
The formula to calculate density is:
Density = mass ÷ volume
The unit used to measure density is gcm-3
(grams per cm cubed)
FLOATING AND SINKING
 Anything with a density of more than 1
gcm-3 will sink in water
 Anything with a density less than 1 gcm-3
will float
Substance Mass in g Volume in cm3 Density in
gcm-3 (m/V)
Float or sink in
water?
Aluminium 54 20
Glass 12.5 5
Cork 0.5 2.5
FLOATING AND SINKING
 Anything with a density of more than 1
gcm-3 will sink in water
 Anything with a density less than 1 gcm-3
will float
Substance Mass in g Volume in cm3 Density in
gcm-3 (m/V)
Float or sink in
water?
Aluminium 54 20 2.7 sink
Glass 12.5 5 2.5 Sink
Cork 0.5 2.5 0.2 float
SUCCESS CRITERIA
 Put the states of matter in to order of most
dense to least dense
 Why are gases less dense than solids?
More particles in a given area in solids than
gases making them heavier and therefore
more dense.
SLO
SLO 5: Use the particle theory to explain the
processes of diffusion, expansion and
contraction
DIFFUSION
 Mixing that is due to molecules moving and
colliding is called diffusion
 Diffusion is the net movement of molecules
from an area of high concentration to an
area of low concentration.
FACTORS AFFECTING RATE OF DIFFUSION
The rate of diffusion depends on:
 The size of the molecules – smaller move
_____
 The temperature – warmer moves ______
 The state of the matter diffusing – gases move
______ then liquids.
 The concentration of the chemicals – the
_______ the concentration gradient the _____
the diffusion rate
TASKS:
 Complete Sci pad pages 56-57 Diffusion,
including experiment
 Explain why you can smell bread baking in
an oven throughout the house
 Why does diffusion only occur in gases?
EXPANSION
 When matter is heated, the particles inside
them move faster, and take up more room
 As a result the matter expands
Effects of heat
Heat produces the
following effects on
matter:
Expansion: The increase in volume which occurs
when a system gains heat.
Expansion
Contraction
Effects of heat
Heat produces the
following effects on
matter:
Expansion
Contraction
Contraction: the decrease in
volume which occurs when a
system loses heat.
THERMOMETERS
SUCCESS CRITERIA
 Complete Sci pad pages 58-59 including
practicals
 Ball and ring practical
 Explain why power lines sag in the summer
When the metal in the power lines gets heated,
the particles move faster, take up more room and
so the line expands, with more length covering the
same distance the line sags
SLO
SLO 6: Explain and give examples of the
processes of conduction and convection
Conduction
The kinetic energy of
the particles increases.
particles of a solid
This is the transfer of
heat in most solids.
Heat is transferred
by direct contact.
http://tdflashzone.net23.net/index.php?p=2_73
CONDUCTION
Conduction is the movement of heat
through solids.
Heat energy travels from the hot end to the cold
end by particles vibrating and jostling less
energetic neighbors giving them extra energy
CONDUCTION EXPERIMENTS
Aim:
Which metal conducts heat the fastest?
Method:
1. Melt wax and attach drawing pins to ends of
metals
2. Hold over Bunsen
3. Record the order in which the pins fall off.
(metals: brass, copper, aluminium, mild steel and
stainless steel)
Conclusion:
Which metal conducts heat the fastest? Why?
Conductors and insulators
metal
Insulators do not
allow heat to move
through them easily. plastic Double-glazed window
air
air space
cork
Conductors allow
heat to move through
them easily.
Examples of good conductors are:
Copper (on the bottom of pots), Most metals , Water
Steel, tin-foil, solder
Insulation is the prevention of the transfer of heat.
Insulators do not allow the transfer of heat to occur
easily.
Examples of good insulators are:
Pink batts, Wool, Plastic, air, wood
SUCCESS CRITERIA
 Complete pages 60-61 including experiment in Scipad
 Explain what is happening to the particles in a steel rod as
heat moves down it?
Particles are in constant motion, as the molecules hit into each
other they pass the energy down the rod.
 Does conduction occur in solids, liquids or gases?
Solids
 Give a use of conduction.
Conduction – heating food
 When is conduction a problem?
CONVECTION
Convection is the movement of heat through liquids or
gases.
The flow of heat through water or air is called convection
current.
Convection currents follow two rules:
Heat rises (hot air or water rises)
Cold sinks (cold air or water sinks)
This is how the heat in the Earth’s mantle moves
FLYING AND CONVECTION CURRENTS
http://tdflashzone.net23.net/index.php?p=2_52
Convection
gas particles
liquid particles
convection currents
This is the transfer of heat
in liquids and gases.
Heat is transferred
by the movement
of currents.
CONVECTION SNAKES
 What causes the snakes to turn?
CONVECTION EXPERIMENTS
SUCCESS CRITERIA
 Complete Scipad pages 62-65 including
experiments
 How is convection helpful?
 Why doesn’t convection occur in solids?
SLO
SLO 7: Describe the present atomic model
(including the number of protons, neutrons and
electrons) and relate some historical models of
the atom
ATOMS
 All matter is made up of atoms
 Chemistry involves the rearrangement of
atoms or groups of atoms
ATOMS ARE MOSTLY EMPTY SPACE . . .
 Structure of atom
 How do we know?
ATOMS ARE MADE UP OF THE FOLLOWING
SUB ATOMIC PARTICLES:
 Electrons
 negative charge
 outside nucleus, in shells
 constant motion
 very very small (1/2000 of a
proton)
 Neutrons
 No charge, neutral
 Inside nucleus
 Same size as proton
 Protons
 Positively charged
 Inside nucleus
 Atoms have an overall neutral charge,
therefore:
Number of protons = Number of electrons
MAKING MODELS . . .
 You are going to make a model of the
lithium atom, Li.
 Li is Lithium, a metal.
 Li has 3 protons, 3 _________ + 4
neutrons.
(remember atoms are neutral so they must
have the same number of protons
(positive) and electrons (negative)
ATOM MODEL:
 Protons – 1 colour of pebble
 Electron – chocolate chip
 Neutron – different coloured pebble
 Nucleus - Marshmallow
 Electron orbit - cotton
SUCCESS CRITERIA
 Copy the title into your books,
and draw your model atom.
 Label your drawing, protons,
neutrons, electrons
 What colour pebble
represents the protons?
 What colour pebble
represents the neutrons?
 What particles make up the
nucleus?
 Complete Scipad page 10
Atoms
Atomic Number:
 Smaller number
 Number of protons
 Number of electrons
Atomic Mass or Mass Number:
 Bigger number of the two
 Total number of sub atomic particles
 Number of protons + neutrons.
ATOM INFORMATION
How do we work out the number of:
 Protons
= Atomic number
 Electrons
= Atomic number
 Neutrons
= Mass number – atomic number
big number – small number
ATOMIC INFORMATION
 Complete Sci pad pages11-13 Elements, Getting the know the Periodic
Table, Element Bingo
 How can you tell if a chemical change has occurred?
 Draw a labeled diagram of an atom, state the charge and size of each
particle
 What information does the atomic number tell us?
 What information does the mass number tell us?
 How many protons, neutrons and electrons does Lithium have?
SUCCESS CRITERIA
SLO
SLO 8: Show understanding of the definitions
of atom, element, compound, molecule and
mixture and be able to distinguish between
them
 Elements are made of one kind of atom
 Compounds are made of two or more elements
chemically combined
 Mixtures are made up of two or more elements
which are NOT chemically combined
ELEMENTS MIXTURES AND COMPOUNDS
Aim: Investigate compounds and mixtures
Method:
1. Separate a mixture of iron and sulphur using a
magnet
2. Heat a mixture of iron and sulphur to form iron
sulfide which is a compound
3. Now try to separate iron with a magnet
Results:
Mixtures can/cannot be physically separated
Compounds can/cannot be physically separated
COMPOUNDS AND MIXTURES
SUCCESS CRITERIA
SLO
SLO 9: Understand what a chemical formula
represents
 Elements contain only one capital letter
 Al, H, He
 Compounds contain more than one element
and therefore more than one capital letter
 H2O, CuSO4
 Each capital letter represents a different
atom
 H2O has Hydrogen and Oxygen atoms in it
ATOMS AND COMPOUNDS
 The numbers in a compound tell us how many atoms
there are:
 H2O = two hydrogen atoms for every one oxygen
atom
 CO2 = two oxygen atoms for every one carbon atom
 CuSO4 = 1 copper, 1 sulphur, 4 oxygen
Methane has four hydrogen atoms for every one carbon
atom, what is its formula? (Carbon goes first)
Complete Scipad page 18-19 Mixtures and Compounds
Matter

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Matter

  • 2.
  • 3. SLOS  SLO 1: Show understanding of the particle nature of matter  SLO 2: Explain the difference between the three states of matter  SLO 3: Outline how matter changes from one state to another  SLO 4: Show understanding of the concept of density and investigate the densities of different substances  SLO 5: Use the particle theory to explain the processes of diffusion, expansion and contraction  SLO 6: Explain and give examples of the processes of conduction and convection  SLO 7: Describe the present atomic model (including the number of protons, neutrons and electrons) and relate some historical models of the atom  SLO 8: Show understanding of the definitions of atom, element, compound, molecule and mixture and be able to distinguish between them  SLO 9: Understand what a chemical formula represents  SLO 10: Recall names and symbols of some of the most common elements
  • 4. SLO SLO 1: Show understanding of the particle nature of matter SLO 2: Explain the difference between the three states of matter
  • 5. PARTICLE NATURE OF MATTER  Matter is everything that has mass and takes up space (everything on earth)  Everything is made up of particles called atoms  Gold is made of gold atoms  Oxygen is made of oxygen atoms  Water is made of hydrogen and oxygen atoms
  • 6. PARTICLE THEORY  Matter is made up of tiny particles (Atoms & Molecules)  Particles of Matter are always moving  Particles of Matter are held together by very strong electric forces  Temperature affects the speed of the particles. The higher the temperature, the faster the speed of the particles.
  • 7.
  • 8.
  • 9. PARTICLE THEORY Particle theory is all about explaining the properties of solids, liquids and gases by looking at what the particles do. In a solid the particles ______ around a _____ position. There is a ______ force of attraction between each particle and they are very _____ together SOLIDS Words – strong, close, vibrate, fixed View animation
  • 10. LIQUIDS GASES In a liquid the particles are _____ together but can move in any direction. They won’t keep a _____ shape like _____ do. In a gas the particles are very far apart and move _____ in all directions. They often ______ with each other and because they are far apart they can be easily _______. Words – fixed, collide, quickly, close, solids, compressed
  • 11.
  • 12. CHANGE OF STATE  A small piece of ice which lived in a test tube fell in love with a Bunsen burner. "Bunsen! my flame!  I melt whenever I see you" said the ice.  The Bunsen burner replied :"It's just a phase you're going through".
  • 13.
  • 14. SUCCESS CRITERIA  Complete cut and paste on states of matter  Complete page 50-51 in Scipad  Describe two properties that are different between solids and liquids  Forces of attraction between particles are weaker in liquids than solids  Solids particles vibrate slowly while liquids roll over each other  Describe two properties that are different between liquids and gases  Gas particles move faster than liquids  Gases have a weaker force of attraction between particles than liquids  What are the three states that matter can exist in?  Liquids solids and gases
  • 15. SLO SLO 3: Outline how matter changes from one state to another
  • 16. CHANGING STATES  When heat is added or taken away states of matter change.  Adding heat makes molecules move faster and further apart, solids turn to liquids then gases as heat is added  Removing heat makes molecules move slower and closer together, gases turn into liquids then solids as heat is removed  Pressure also effects states of matter
  • 18. CHANGING STATE  Changing state requires energy  Energy is used in changing state so temperature stays the same
  • 19.
  • 20. SUCCESS CRITERIA  Complete Scipad pages 52-53 Making a Key and Changing States  Complete Investigation in State Changes on page 54- 55  What happens to the particles in a liquid when it is turned into a solid? (HINT: discuss speed, closeness, energy level of particles)  What happens to the particles in a liquid when it is heated and turned into a gas? (HINT: discuss speed, closeness, energy level of particles)
  • 21. SLO SLO 4: Show understanding of the concept of density and investigate the densities of different substances
  • 22.
  • 23.
  • 24. DENSITY  All objects are made out of particles  Density is how tightly packed those particles are.  The more tightly packed the particles, the more dense. decreasing density
  • 25.
  • 26. DENSITY Which is heavier: 1kg of feathers or 1 kg of gold? They have the same mass, but what is different about them? Density describes how heavy an object is for its size eg: 1kg of feathers would take up a lot of room because feathers are not very heavy for their size. They have a low density. 1kg of gold metal does not take up much space as it has a high density
  • 27. CALCULATING DENSITY The formula to calculate density is: Density = mass ÷ volume The unit used to measure density is gcm-3 (grams per cm cubed)
  • 28. FLOATING AND SINKING  Anything with a density of more than 1 gcm-3 will sink in water  Anything with a density less than 1 gcm-3 will float Substance Mass in g Volume in cm3 Density in gcm-3 (m/V) Float or sink in water? Aluminium 54 20 Glass 12.5 5 Cork 0.5 2.5
  • 29. FLOATING AND SINKING  Anything with a density of more than 1 gcm-3 will sink in water  Anything with a density less than 1 gcm-3 will float Substance Mass in g Volume in cm3 Density in gcm-3 (m/V) Float or sink in water? Aluminium 54 20 2.7 sink Glass 12.5 5 2.5 Sink Cork 0.5 2.5 0.2 float
  • 30. SUCCESS CRITERIA  Put the states of matter in to order of most dense to least dense  Why are gases less dense than solids? More particles in a given area in solids than gases making them heavier and therefore more dense.
  • 31. SLO SLO 5: Use the particle theory to explain the processes of diffusion, expansion and contraction
  • 32.
  • 33. DIFFUSION  Mixing that is due to molecules moving and colliding is called diffusion  Diffusion is the net movement of molecules from an area of high concentration to an area of low concentration.
  • 34. FACTORS AFFECTING RATE OF DIFFUSION The rate of diffusion depends on:  The size of the molecules – smaller move _____  The temperature – warmer moves ______  The state of the matter diffusing – gases move ______ then liquids.  The concentration of the chemicals – the _______ the concentration gradient the _____ the diffusion rate
  • 35. TASKS:  Complete Sci pad pages 56-57 Diffusion, including experiment  Explain why you can smell bread baking in an oven throughout the house  Why does diffusion only occur in gases?
  • 36.
  • 37. EXPANSION  When matter is heated, the particles inside them move faster, and take up more room  As a result the matter expands
  • 38. Effects of heat Heat produces the following effects on matter: Expansion: The increase in volume which occurs when a system gains heat. Expansion Contraction
  • 39. Effects of heat Heat produces the following effects on matter: Expansion Contraction Contraction: the decrease in volume which occurs when a system loses heat.
  • 41. SUCCESS CRITERIA  Complete Sci pad pages 58-59 including practicals  Ball and ring practical  Explain why power lines sag in the summer When the metal in the power lines gets heated, the particles move faster, take up more room and so the line expands, with more length covering the same distance the line sags
  • 42. SLO SLO 6: Explain and give examples of the processes of conduction and convection
  • 43.
  • 44. Conduction The kinetic energy of the particles increases. particles of a solid This is the transfer of heat in most solids. Heat is transferred by direct contact.
  • 46. CONDUCTION Conduction is the movement of heat through solids. Heat energy travels from the hot end to the cold end by particles vibrating and jostling less energetic neighbors giving them extra energy
  • 47. CONDUCTION EXPERIMENTS Aim: Which metal conducts heat the fastest? Method: 1. Melt wax and attach drawing pins to ends of metals 2. Hold over Bunsen 3. Record the order in which the pins fall off. (metals: brass, copper, aluminium, mild steel and stainless steel) Conclusion: Which metal conducts heat the fastest? Why?
  • 48. Conductors and insulators metal Insulators do not allow heat to move through them easily. plastic Double-glazed window air air space cork Conductors allow heat to move through them easily.
  • 49. Examples of good conductors are: Copper (on the bottom of pots), Most metals , Water Steel, tin-foil, solder Insulation is the prevention of the transfer of heat. Insulators do not allow the transfer of heat to occur easily. Examples of good insulators are: Pink batts, Wool, Plastic, air, wood
  • 50. SUCCESS CRITERIA  Complete pages 60-61 including experiment in Scipad  Explain what is happening to the particles in a steel rod as heat moves down it? Particles are in constant motion, as the molecules hit into each other they pass the energy down the rod.  Does conduction occur in solids, liquids or gases? Solids  Give a use of conduction. Conduction – heating food  When is conduction a problem?
  • 51. CONVECTION Convection is the movement of heat through liquids or gases. The flow of heat through water or air is called convection current. Convection currents follow two rules: Heat rises (hot air or water rises) Cold sinks (cold air or water sinks) This is how the heat in the Earth’s mantle moves
  • 52.
  • 55. Convection gas particles liquid particles convection currents This is the transfer of heat in liquids and gases. Heat is transferred by the movement of currents.
  • 56. CONVECTION SNAKES  What causes the snakes to turn?
  • 58. SUCCESS CRITERIA  Complete Scipad pages 62-65 including experiments  How is convection helpful?  Why doesn’t convection occur in solids?
  • 59. SLO SLO 7: Describe the present atomic model (including the number of protons, neutrons and electrons) and relate some historical models of the atom
  • 60. ATOMS  All matter is made up of atoms  Chemistry involves the rearrangement of atoms or groups of atoms
  • 61. ATOMS ARE MOSTLY EMPTY SPACE . . .  Structure of atom  How do we know?
  • 62. ATOMS ARE MADE UP OF THE FOLLOWING SUB ATOMIC PARTICLES:  Electrons  negative charge  outside nucleus, in shells  constant motion  very very small (1/2000 of a proton)  Neutrons  No charge, neutral  Inside nucleus  Same size as proton  Protons  Positively charged  Inside nucleus
  • 63.  Atoms have an overall neutral charge, therefore: Number of protons = Number of electrons
  • 64. MAKING MODELS . . .  You are going to make a model of the lithium atom, Li.  Li is Lithium, a metal.  Li has 3 protons, 3 _________ + 4 neutrons. (remember atoms are neutral so they must have the same number of protons (positive) and electrons (negative)
  • 65. ATOM MODEL:  Protons – 1 colour of pebble  Electron – chocolate chip  Neutron – different coloured pebble  Nucleus - Marshmallow  Electron orbit - cotton
  • 66. SUCCESS CRITERIA  Copy the title into your books, and draw your model atom.  Label your drawing, protons, neutrons, electrons  What colour pebble represents the protons?  What colour pebble represents the neutrons?  What particles make up the nucleus?  Complete Scipad page 10 Atoms
  • 67. Atomic Number:  Smaller number  Number of protons  Number of electrons Atomic Mass or Mass Number:  Bigger number of the two  Total number of sub atomic particles  Number of protons + neutrons. ATOM INFORMATION
  • 68. How do we work out the number of:  Protons = Atomic number  Electrons = Atomic number  Neutrons = Mass number – atomic number big number – small number ATOMIC INFORMATION
  • 69.  Complete Sci pad pages11-13 Elements, Getting the know the Periodic Table, Element Bingo  How can you tell if a chemical change has occurred?  Draw a labeled diagram of an atom, state the charge and size of each particle  What information does the atomic number tell us?  What information does the mass number tell us?  How many protons, neutrons and electrons does Lithium have? SUCCESS CRITERIA
  • 70. SLO SLO 8: Show understanding of the definitions of atom, element, compound, molecule and mixture and be able to distinguish between them
  • 71.  Elements are made of one kind of atom  Compounds are made of two or more elements chemically combined  Mixtures are made up of two or more elements which are NOT chemically combined ELEMENTS MIXTURES AND COMPOUNDS
  • 72. Aim: Investigate compounds and mixtures Method: 1. Separate a mixture of iron and sulphur using a magnet 2. Heat a mixture of iron and sulphur to form iron sulfide which is a compound 3. Now try to separate iron with a magnet Results: Mixtures can/cannot be physically separated Compounds can/cannot be physically separated COMPOUNDS AND MIXTURES
  • 74. SLO SLO 9: Understand what a chemical formula represents
  • 75.  Elements contain only one capital letter  Al, H, He  Compounds contain more than one element and therefore more than one capital letter  H2O, CuSO4  Each capital letter represents a different atom  H2O has Hydrogen and Oxygen atoms in it ATOMS AND COMPOUNDS
  • 76.  The numbers in a compound tell us how many atoms there are:  H2O = two hydrogen atoms for every one oxygen atom  CO2 = two oxygen atoms for every one carbon atom  CuSO4 = 1 copper, 1 sulphur, 4 oxygen Methane has four hydrogen atoms for every one carbon atom, what is its formula? (Carbon goes first) Complete Scipad page 18-19 Mixtures and Compounds