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SDS Number : 133
Latest Revision : November 2017
SAFETY DATA SHEET
Page 1 / 6
1. PRODUCT IDENTIFICATION
Product name : SODEL 118
Description / identification : Coated electrode, Aluminum alloy
Recommended use : Use for arc welding, SMAW
Restriction on use : Not known. Read this SDS before using this product.
Manufacturer / Supplier : Sodel LTD. 823A McCaffrey
St-Laurent, Québec
H4T1N3
Telephone : 1-800-363-1821
Emergency telephone : 1-800-363-1821
2. HAZARDS IDENTIFICATION
Hazard classification These products are not normally considered hazardous as shipped. However, when
these products are used in a welding process, the most important hazards are heat,
radiation, electric shock and welding fumes
Symbols Hazards during welding process
Heat Spatter and melting metal can cause burn injuries and start fires.
Radiation Arc rays can severely damage eyes or skin.
Electricity Electric shock can kill
Welding fumes Welding fumes cannot be classified simply, the composition and quantity of both are
dependent on the alloy being welded, the filler metal, the process and welding
parameters.
Short term overexposure to welding fumes may result in symptoms like metal fume
fever, dizziness, nausea, dryness or irritation of the nose, throat or eyes.
Long term overexposure to welding fumes may affect pulmonary function, may induce
cancer or irreversible damage to the central nervous system, including the brain
SDS Number : 133
Latest Revision : November 2017
SAFETY DATA SHEET
Page 2 / 6
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical name CAS number Concentration in percentage
Aluminum 7429-90-5 60 - 100
Silicone 7440-21-3 3 - 7
Potassium fluoride 7789-23-3 5 - 10
Aluminum fluoride 7784-18-1 3 - 7
Lithium fluoride 7789-24-4 3 - 7
Magnesium fluoride 7783-40-6 3 - 7
4. FIRST AID MEASURES
Inhalation If breathing has stopped, perform artificial respiration and obtain medical assistance
immediately. If breathing is difficult, provide fresh air and call physician.
Eye contact Flush eyes with clear water for at least 15 minutes to remove dusts or fumes. If
irritation persists, obtain medical assistance. For burns eyes caused by arc flash,
consult a physician.
Skin contact For skin burns from arc radiation, promptly flush with cold water and get medical
attention. To remove dust or particles wash with mild soap and water.
Ingestion Rinse mouth thoroughly with water, do not induce vomiting and call a physician or the
local poison control center.
Most important symptoms
and effects
Short-term (acute) overexposure to welding fumes may result in discomfort such as the
irritation and corrosion of the skin, eyes and respiratory tract, coughing, fever, shivers,
headaches, vomiting, breathing difficulties and a chemical pneumonitis.
Long-term (chronic) overexposure to welding fumes may lead to the irritation of the
respiratory tract, sensitization of the pulmonary and cutaneous systems, tremors,
muscular weakness and problems to the central nervous system.
5. FIRE-FIGHTING MEASURES
Fire hazards As shipped, these products are non-flammable, non-explosive and essentially inert.
However, during welding process, electrical arc and sparks can ignite combustibles and
flammable products.
Suitable extinguishing
media
Use appropriate extinguishing agent according to the type of fire situation.
Unsuitable extinguishing
media
Using water jet as an extinguisher, may spread the fire
Special protective
equipment and precautions
for fire-fighters
Wear self-contained breathing apparatus and a full protective clothing.
SDS Number : 133
Latest Revision : November 2017
SAFETY DATA SHEET
Page 3 / 6
6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures
As shipped, these products presents a low risk in case of accidental release. Wear
proper protective clothing and a respiratory gear if required. Evacuate and secure the
spill area.
Methods and materials for
containment and cleaning
up
Ensure adequate ventilation, avoid dispersion of spilled material, avoid generating dust
and prevent the release of the product into the environment. Store the released product
and dust into an appropriated waste container. Refer to section 13 for proper disposal.
7. MANUTENTION ET STOKAGE
Precaution for safe
handling
Handle with care to avoid injury. Wear glove and individual protective equipment. Avoid
exposure to dust and do not ingest.
Conditions for safe storage Store in closed original container in a dry place
Incompatible materials Keep away from chemical substance like acids and strong bases, which could cause
chemical reactions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters Chemical name Exposure limit values Source
Aluminum 5 mg /m3, TWA ACGIH
Silicone 2 mg /m3, TWA ACGIH
Potassium fluoride 2.5 mg /m3
, TWA as F ACGIH
Aluminum fluoride 2.5 mg /m3
, TWA as F ACGIH
Lithium fluoride 2.5 mg /m3
, TWA as F ACGIH
Magnesium fluoride 2.5 mg /m3
, TWA as F ACGIH
Welding fume 5 mg /m3
, TWA ACGIH
The Threshold Limit Values (TLV) are published by the American Conference of
Governmental Industrial Hygienists (ACGIH). The recommended general limit for
welding fumes (not otherwise classified) is 5 mg/m3. The ACGIH 2014 states that the
Threshold Limit Values (TLV) should be used as guides in the control of potential
health hazards and should not be used as fine lines between safe and dangerous
concentrations.
TWA : Time-weighted average = VEMP : Valeur d’exposition moyenne pondérée.
STEL : Short-term exposure limit = VECD : Valeur d’exposition courte durée.
CL : Ceiling limit = VP : Valeur plafond.
Appropriate engineering
controls
Use enough general ventilation and local exhaust at the work site to keep the fumes,
gases and dusts from the worker's breathing zone and the general area. Train the
worker to keep his head out of the fumes.
SDS Number : 133
Latest Revision : November 2017
SAFETY DATA SHEET
Page 4 / 6
Individual protection
measures
Eye/face protection:
Wear helmet or use face shield with filter lens. Provide protection screens and flash
goggles, if necessary, to shield others. As a rule, start with a shade that is too dark to
see the work zone. Then go to the next lighter shade which gives sufficient view of the
weld zone.
Skin protection:
Wear hand, head and body protection which help prevent injury from radiation, sparks
and flames. (See CSA W117.2.) At a minimum, this includes gloves and a protective
face shield, and may include arm protectors, aprons, hats, shoulder protection, as well
as dark substantial clothing. Train the worker not to touch live electrical parts and to
insulate himself from work and ground. Additional protection for fluxes and chemicals
aids may be required to prevent skin or eye contact.
Respiratory protection
Use a CSA approved respirator when working in confined space or where local exhaust
or ventilation does not keep exposure below the recommended exposure limit.
(Refer to CSA Z94.4 "Selection, Care and Use of Respirators").
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance, physical state Metal rod with extruded flux coating
Colour White
Odour No data available.
Odour threshold No data available.
pH No data available.
Melting point / Freezing point > 1000°
C
Initial boiling point / boiling range No data available.
Flash point No data available.
Evaporation rate No data available.
Flammability (solid, gas) No data available.
Lower flammable / explosive limit No data available.
Upper flammable / explosive limit No data available.
Vapour pressure No data available.
Vapour density No data available.
Relative density 4 – 6 g/cm3
Solubility No data available.
Partition coefficient – n-octanol/water No data available.
Auto-ignition temperature No data available.
Decomposition temperature No data available.
Viscosity No data available.
SDS Number : 133
Latest Revision : November 2017
SAFETY DATA SHEET
Page 5 / 6
10. STABILITY ET REACTIVITY
Reactivity These products are non-reactive under normal conditions of use, storage and transport
Chemical stability These products are stable under normal conditions of use, storage and transport
Possibility of hazardous
reactions
None under normal conditions
Conditions to avoid None under normal conditions.
Incompatible materials Contact with acids solutions may generate explosive gas like hydrogen
Hazardous decomposition
products
Under normal conditions of storage and use, any decomposition products may be
produce.
When these products are used in a welding process, hazardous fumes and gas may
generated by the volatilisation, the reaction or the oxidation of the ingredients listed at
the section 3, with those from the base metal, coating, shielding gas and contaminants.
During welding process, some hazardous gas may be produced, such as carbon
monoxide and carbon dioxide (CO and CO2). Use of argon (Ar) as shielding gas can
generate ozone (O3) and nitrogen oxides (NOx). The presence of residual degreasing
solvents (chlorinated hydrocarbon) on the welding surface may generate phosgene
(COCl2) and hydrogen chloride (HCl) which are highly toxic gases.
11. TOXICOLOGICAL INFORMATION
Routes of exposure The most likely risk of exposure during a welding process may affect respiratory route,
skin and eyes
Inhalation These products when use during a welding process, produce welding fumes and gas
which can be absorbed by respiratory route and may lead to major health problem.
Skin contact Arc ray can injure skin and cause skin cancer
Eye contact Arc ray can injure eyes and lead to blindness
Acute toxicity Short term (Acute) overexposure to welding fumes (ACGIH 2014 TLV-TWA of 5 mg/m3
)
may lead to the irritation of the skin, eyes and respiratory tract, coughing, fever, shivers,
headaches, vomiting, breathing difficulties and a chemical pneumonitis.
Chronic toxicity Long term (Chronic) overexposure may lead to the irritation of the respiratory tract,
sensitization of the pulmonary and cutaneous systems, dermatitis, tremors, muscular
weakness, problems to the central nervous system and a pulmonary fibrosis.
Welding fumes and dust may contain oxides and/or fluorides of aluminum, lithium,
magnesium, potassium and silicone which may cause eye and skin burns, pulmonary
edema, abdominal pain, convulsions, loss of consciousness and death.
Numerical measures of
toxicity
Classification and quantification of welding fumes and dust generated during welding
process are difficult to determine because of varying base metal, coating and
contaminations.
SDS Number : 133
Latest Revision : November 2017
SAFETY DATA SHEET
Page 6 / 6
12. ECOLOGICAL INFORMATION
Écotoxicity No data available.
Persistence and
degradability
No data available.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Other adverse effects No data available.
13. DISPOSAL CONSIDERATIONS
Disposal instruction Dispose of non-recyclable products in full compliance with the local and governmental
regulations. Reduce waste production by recycling containers and packaging residues
in order to protect environment in accordance with the local and governmental
regulations.
Used filters form fumes extractor must be considered hazardous material and discarded
in full compliance with the local and governmental regulations.
14. TRANSPORT INFORMATION
UN number No UN number applicable, these products are not classified as dangerous goods for
transport.
UN proper shipping name No UN designation applicable, these products are not classified as dangerous goods
for transport.
Transport hazard class(es) Not regulated
Packing group Not regulated
Environmental hazards Not regulated
Special precautions Not regulated
15. REGULATION INFORMATION
Read and understand the manufacturer's instructions and the precautionary label on the product. (See CSA W117.2
"Code for Safety in Welding and Cutting" published by Canadian Standards Association).
16. AUTRES INFORMATIONS
Date de création Date de révision Numéro de révision
25 novembre 2017 0

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22711.pdf

  • 1. SDS Number : 133 Latest Revision : November 2017 SAFETY DATA SHEET Page 1 / 6 1. PRODUCT IDENTIFICATION Product name : SODEL 118 Description / identification : Coated electrode, Aluminum alloy Recommended use : Use for arc welding, SMAW Restriction on use : Not known. Read this SDS before using this product. Manufacturer / Supplier : Sodel LTD. 823A McCaffrey St-Laurent, Québec H4T1N3 Telephone : 1-800-363-1821 Emergency telephone : 1-800-363-1821 2. HAZARDS IDENTIFICATION Hazard classification These products are not normally considered hazardous as shipped. However, when these products are used in a welding process, the most important hazards are heat, radiation, electric shock and welding fumes Symbols Hazards during welding process Heat Spatter and melting metal can cause burn injuries and start fires. Radiation Arc rays can severely damage eyes or skin. Electricity Electric shock can kill Welding fumes Welding fumes cannot be classified simply, the composition and quantity of both are dependent on the alloy being welded, the filler metal, the process and welding parameters. Short term overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or irritation of the nose, throat or eyes. Long term overexposure to welding fumes may affect pulmonary function, may induce cancer or irreversible damage to the central nervous system, including the brain
  • 2. SDS Number : 133 Latest Revision : November 2017 SAFETY DATA SHEET Page 2 / 6 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical name CAS number Concentration in percentage Aluminum 7429-90-5 60 - 100 Silicone 7440-21-3 3 - 7 Potassium fluoride 7789-23-3 5 - 10 Aluminum fluoride 7784-18-1 3 - 7 Lithium fluoride 7789-24-4 3 - 7 Magnesium fluoride 7783-40-6 3 - 7 4. FIRST AID MEASURES Inhalation If breathing has stopped, perform artificial respiration and obtain medical assistance immediately. If breathing is difficult, provide fresh air and call physician. Eye contact Flush eyes with clear water for at least 15 minutes to remove dusts or fumes. If irritation persists, obtain medical assistance. For burns eyes caused by arc flash, consult a physician. Skin contact For skin burns from arc radiation, promptly flush with cold water and get medical attention. To remove dust or particles wash with mild soap and water. Ingestion Rinse mouth thoroughly with water, do not induce vomiting and call a physician or the local poison control center. Most important symptoms and effects Short-term (acute) overexposure to welding fumes may result in discomfort such as the irritation and corrosion of the skin, eyes and respiratory tract, coughing, fever, shivers, headaches, vomiting, breathing difficulties and a chemical pneumonitis. Long-term (chronic) overexposure to welding fumes may lead to the irritation of the respiratory tract, sensitization of the pulmonary and cutaneous systems, tremors, muscular weakness and problems to the central nervous system. 5. FIRE-FIGHTING MEASURES Fire hazards As shipped, these products are non-flammable, non-explosive and essentially inert. However, during welding process, electrical arc and sparks can ignite combustibles and flammable products. Suitable extinguishing media Use appropriate extinguishing agent according to the type of fire situation. Unsuitable extinguishing media Using water jet as an extinguisher, may spread the fire Special protective equipment and precautions for fire-fighters Wear self-contained breathing apparatus and a full protective clothing.
  • 3. SDS Number : 133 Latest Revision : November 2017 SAFETY DATA SHEET Page 3 / 6 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures As shipped, these products presents a low risk in case of accidental release. Wear proper protective clothing and a respiratory gear if required. Evacuate and secure the spill area. Methods and materials for containment and cleaning up Ensure adequate ventilation, avoid dispersion of spilled material, avoid generating dust and prevent the release of the product into the environment. Store the released product and dust into an appropriated waste container. Refer to section 13 for proper disposal. 7. MANUTENTION ET STOKAGE Precaution for safe handling Handle with care to avoid injury. Wear glove and individual protective equipment. Avoid exposure to dust and do not ingest. Conditions for safe storage Store in closed original container in a dry place Incompatible materials Keep away from chemical substance like acids and strong bases, which could cause chemical reactions. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters Chemical name Exposure limit values Source Aluminum 5 mg /m3, TWA ACGIH Silicone 2 mg /m3, TWA ACGIH Potassium fluoride 2.5 mg /m3 , TWA as F ACGIH Aluminum fluoride 2.5 mg /m3 , TWA as F ACGIH Lithium fluoride 2.5 mg /m3 , TWA as F ACGIH Magnesium fluoride 2.5 mg /m3 , TWA as F ACGIH Welding fume 5 mg /m3 , TWA ACGIH The Threshold Limit Values (TLV) are published by the American Conference of Governmental Industrial Hygienists (ACGIH). The recommended general limit for welding fumes (not otherwise classified) is 5 mg/m3. The ACGIH 2014 states that the Threshold Limit Values (TLV) should be used as guides in the control of potential health hazards and should not be used as fine lines between safe and dangerous concentrations. TWA : Time-weighted average = VEMP : Valeur d’exposition moyenne pondérée. STEL : Short-term exposure limit = VECD : Valeur d’exposition courte durée. CL : Ceiling limit = VP : Valeur plafond. Appropriate engineering controls Use enough general ventilation and local exhaust at the work site to keep the fumes, gases and dusts from the worker's breathing zone and the general area. Train the worker to keep his head out of the fumes.
  • 4. SDS Number : 133 Latest Revision : November 2017 SAFETY DATA SHEET Page 4 / 6 Individual protection measures Eye/face protection: Wear helmet or use face shield with filter lens. Provide protection screens and flash goggles, if necessary, to shield others. As a rule, start with a shade that is too dark to see the work zone. Then go to the next lighter shade which gives sufficient view of the weld zone. Skin protection: Wear hand, head and body protection which help prevent injury from radiation, sparks and flames. (See CSA W117.2.) At a minimum, this includes gloves and a protective face shield, and may include arm protectors, aprons, hats, shoulder protection, as well as dark substantial clothing. Train the worker not to touch live electrical parts and to insulate himself from work and ground. Additional protection for fluxes and chemicals aids may be required to prevent skin or eye contact. Respiratory protection Use a CSA approved respirator when working in confined space or where local exhaust or ventilation does not keep exposure below the recommended exposure limit. (Refer to CSA Z94.4 "Selection, Care and Use of Respirators"). 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance, physical state Metal rod with extruded flux coating Colour White Odour No data available. Odour threshold No data available. pH No data available. Melting point / Freezing point > 1000° C Initial boiling point / boiling range No data available. Flash point No data available. Evaporation rate No data available. Flammability (solid, gas) No data available. Lower flammable / explosive limit No data available. Upper flammable / explosive limit No data available. Vapour pressure No data available. Vapour density No data available. Relative density 4 – 6 g/cm3 Solubility No data available. Partition coefficient – n-octanol/water No data available. Auto-ignition temperature No data available. Decomposition temperature No data available. Viscosity No data available.
  • 5. SDS Number : 133 Latest Revision : November 2017 SAFETY DATA SHEET Page 5 / 6 10. STABILITY ET REACTIVITY Reactivity These products are non-reactive under normal conditions of use, storage and transport Chemical stability These products are stable under normal conditions of use, storage and transport Possibility of hazardous reactions None under normal conditions Conditions to avoid None under normal conditions. Incompatible materials Contact with acids solutions may generate explosive gas like hydrogen Hazardous decomposition products Under normal conditions of storage and use, any decomposition products may be produce. When these products are used in a welding process, hazardous fumes and gas may generated by the volatilisation, the reaction or the oxidation of the ingredients listed at the section 3, with those from the base metal, coating, shielding gas and contaminants. During welding process, some hazardous gas may be produced, such as carbon monoxide and carbon dioxide (CO and CO2). Use of argon (Ar) as shielding gas can generate ozone (O3) and nitrogen oxides (NOx). The presence of residual degreasing solvents (chlorinated hydrocarbon) on the welding surface may generate phosgene (COCl2) and hydrogen chloride (HCl) which are highly toxic gases. 11. TOXICOLOGICAL INFORMATION Routes of exposure The most likely risk of exposure during a welding process may affect respiratory route, skin and eyes Inhalation These products when use during a welding process, produce welding fumes and gas which can be absorbed by respiratory route and may lead to major health problem. Skin contact Arc ray can injure skin and cause skin cancer Eye contact Arc ray can injure eyes and lead to blindness Acute toxicity Short term (Acute) overexposure to welding fumes (ACGIH 2014 TLV-TWA of 5 mg/m3 ) may lead to the irritation of the skin, eyes and respiratory tract, coughing, fever, shivers, headaches, vomiting, breathing difficulties and a chemical pneumonitis. Chronic toxicity Long term (Chronic) overexposure may lead to the irritation of the respiratory tract, sensitization of the pulmonary and cutaneous systems, dermatitis, tremors, muscular weakness, problems to the central nervous system and a pulmonary fibrosis. Welding fumes and dust may contain oxides and/or fluorides of aluminum, lithium, magnesium, potassium and silicone which may cause eye and skin burns, pulmonary edema, abdominal pain, convulsions, loss of consciousness and death. Numerical measures of toxicity Classification and quantification of welding fumes and dust generated during welding process are difficult to determine because of varying base metal, coating and contaminations.
  • 6. SDS Number : 133 Latest Revision : November 2017 SAFETY DATA SHEET Page 6 / 6 12. ECOLOGICAL INFORMATION Écotoxicity No data available. Persistence and degradability No data available. Bioaccumulative potential No data available. Mobility in soil No data available. Other adverse effects No data available. 13. DISPOSAL CONSIDERATIONS Disposal instruction Dispose of non-recyclable products in full compliance with the local and governmental regulations. Reduce waste production by recycling containers and packaging residues in order to protect environment in accordance with the local and governmental regulations. Used filters form fumes extractor must be considered hazardous material and discarded in full compliance with the local and governmental regulations. 14. TRANSPORT INFORMATION UN number No UN number applicable, these products are not classified as dangerous goods for transport. UN proper shipping name No UN designation applicable, these products are not classified as dangerous goods for transport. Transport hazard class(es) Not regulated Packing group Not regulated Environmental hazards Not regulated Special precautions Not regulated 15. REGULATION INFORMATION Read and understand the manufacturer's instructions and the precautionary label on the product. (See CSA W117.2 "Code for Safety in Welding and Cutting" published by Canadian Standards Association). 16. AUTRES INFORMATIONS Date de création Date de révision Numéro de révision 25 novembre 2017 0