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Dyneema®, the world’s
strongest fiber™        Visit Eurocord
                               7-1-2010
2
Dyneema®, the world s strongest fiber™

 The strongest fiber in the world
   ü  15 times stronger than steel
   ü  Lighter than water
   ü  Extremely durable


 So it can:
   ü  Stop bullets
   ü  Pull oil tankers
   ü  Help to sail around the world in 50 days



                                    3
Applications with Dyneema®




                    4
Applications with Dyneema®




                    5
6
The basics

Dyneema is a fiber made from Ultra High
Molecular Weight Polyethylene (UHMWPE)



Normal Polyethylene, low orientation, low
molecular weight, crystalinity < 60%



Dyneema®, very high molecular orientation
and weigth, crystalinity approximately 95%




                                   7
Dyneema® Gel Spinning process

      suspension
      UHMW-PE

           continuous extrusion


                                  metering pump

                     spinneret            oven




                            8
Some yarn basics
How is Dyneema yarn build up?
•  Yarn consists our of multiple filaments.
•  The amount and diameter of the filaments determine the diameter of the yarn.
•  The diameter of filaments of Dyneema® grades is between 9 and 30 µm.
What does dtex mean?
•  Dtex is a measure for fiber weight (thickness) and is defined as dtex = gram / 10.000m
•  The dtex of Dyneema® fibers range between
    –  55 dtex (=25x monofilaments of 2,2 dtex each)
    –  2640 dtex (=780x monofilaments of 2.2dtex each)

What is a yarn construction?
•  Multiple yarns can be combined into a construction - linear (like a rope) or 3D (like a
   shape).
•  Variables: grade, dtex, textile process (braiding, weaving, knitting, …), stitch density, …
•  Various pre- and post treatment options have been developed by DSM Dyneema
•  Every specific construction has specific mechanical characteristics => opportunity to tailor!
•  EuroFibers helps to translate your mechanical needs into specific constructions.

                                              9
Microscopic view of a braid made of 16 yarns,
each yarn consisting of about 100 filaments




                             10
Typical properties of Dyneema®
                                          High pliability   Hydrophobic
                           Soft as silk

          Extremely                                                 Low melting
          strong                                                    point (~150°C)

                                                                              High fatigue
 Cut and tear
                                                                              resistance
 resistance

                                                                            High chemical
Creeps under                                                                resistance
constant load

                                                                          High abrasion
  Low coefficient                                                         resistance
  of friction
                                                              Low density
                    Electrical
                    insulator
                                            Low
                                            elongation

                                             11
Conventional Fibers Vs. Performance Fibers

   PES
   •  Dacron®                         HMPE
                       LCP            •  Dyneema®
   •  Diolen®          •  Vectran®    •  Spectra®
   •  Trevira®
   •  No brand name

   PA                  Aramid
   •  Nylon®           •  Kevlar®     PBO
   •  Enkalon®         •  Twaron®     •  Zylon®
   •  Perlon®          •  Technora®
   •  No brand name    •  Nomex®

  Conventional         High performance fibers
  fibers
                      12
There is a big difference in tenacity of fibers…



  Free breaking length
                     Dyneema®      349 Km
                        Zylon®     346 Km

                       Vectran®    247 Km
                     Technora®     227 Km
                       Twaron®     200 Km




                                            * Tested according to
                                             ISO 2062
                         Diolen®   77 Km    ** Literature value

                          Steel*   25 Km


                           13
…as well as in the elongation of materials
                     Diolen® Technora® Zylon®    Steel**
                           Twaron® Vectran® Dyneema®




                                                              2,8%            3,0%
                           3,1%                      3,3%
                                         4,0%                             3,5%
             5X
                               Elongation at break
                               * Synthetic fibers tested according to ISO 2062
                               ** Literature value




                        12%
* Literature value


                          14
Dyneema® is the only floating fiber

                                                          Floats
                            1

                            2
                                                          Sinks
                            3
                                                           Steel
Specific gravity*




                            4                              Diolen (PES)
                                                                 ®
                    g/cm3




                                                           Twaron (Aramid)
                                                                  ®
                            5                              Technora® (Aramid)
                                                           Vectran (LCP)
                                                                  ®
                            6                              Zylon (PBO)
                                                                ®
                                                           Dyneema (HMPE)
                                                                    ®
                            7


                            8




                                * Literaturevalues




                                                     15
Aging of pure fibers differs quite a bit
         % original strength retained after aging 336 hrs*




                                                                         Dyneema® (HMPE)
                                                                         Diolen (PES)
                                                                               ®
                                                                         Twaron® (Aramid)
                                                                         Technora (Aramid)
                                                                                 ®
                                                                         Zylon (PBO)
                                                                              ®
                                                                         Vectran® (LCP)




                                                                   *Aged according to ASTM G–155
                                                                   *Tested according to ISO 2062




    0%   10%    20%    30%    40%    50%    60%    70%       80%




                                       16
Cut resistance
Dyneema® filament stretched over the edge of a razorblade (SEM)




   Polyethylene cables flatten when placed under tension.
   This property makes the fiber highly cut resistant.
                                      17
Abrasion resistance
                         80000

                                 Test on emery paper @ 25 C*
                                                        °
                         70000



                         60000
nr. of cycles to break




                         50000



                         40000                                        Diolen (PES)
                                                                            ®
                                                                      Twaron (Aramid)
                                                                             ®
                         30000                                        Technora® (Aramid)
                                                                      Vectran (LCP)
                                                                             ®
                         20000
                                                                      Zylon (PBO)
                                                                           ®
                                                                      Dyneema (HMPE)
                                                                               ®
                         10000
                                                               *Tested at Staatliches Pruefamt fuer
                                                               das Textilgewerbe Mü nchberg
                            0




                                                       18
Bending of an LCP filament




                     19
Bending of an aramid filament




                     20
Bending of a PBO filament




                     21
Bending of a Dyneema® filament




                    22
Comparison of fiber properties
               Diolen® Twaron ®            Technora ® Vectran ® Zylon®              Dyneema®
Properties         (PES)       (Aramid)        (Aramid)      (LCP)        (PBO)         (HMPE)

Tenacity            7,6          19,6            22,3        24,2         33,9          34,2
(cN/dTex)

Elongation         12,3           3,1                4,0      3,3          2,8          3,4
(%)



Specific gravity
      3
(Kg/dm )            1,38          1,39           1,39          1,41        1,56         0,97

Aging
                    Good            Poor             Poor     Very poor     Very poor    Very good


Abrasion           Very good       Very poor     Very poor      Poor         Poor        Very good




                                                23
Overview of titers and grades




                     24
Contact



EuroFibers BV
P.O.Box 599
6200 AN Maastricht
The Netherlands

info@eurofibers.com
www.eurofibers.com
+31 43 30 40 014




                      25

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Dyneema, the world's strongest fiber

  • 1. Dyneema®, the world’s strongest fiber™ Visit Eurocord 7-1-2010
  • 2. 2
  • 3. Dyneema®, the world s strongest fiber™ The strongest fiber in the world ü  15 times stronger than steel ü  Lighter than water ü  Extremely durable So it can: ü  Stop bullets ü  Pull oil tankers ü  Help to sail around the world in 50 days 3
  • 6. 6
  • 7. The basics Dyneema is a fiber made from Ultra High Molecular Weight Polyethylene (UHMWPE) Normal Polyethylene, low orientation, low molecular weight, crystalinity < 60% Dyneema®, very high molecular orientation and weigth, crystalinity approximately 95% 7
  • 8. Dyneema® Gel Spinning process suspension UHMW-PE continuous extrusion metering pump spinneret oven 8
  • 9. Some yarn basics How is Dyneema yarn build up? •  Yarn consists our of multiple filaments. •  The amount and diameter of the filaments determine the diameter of the yarn. •  The diameter of filaments of Dyneema® grades is between 9 and 30 µm. What does dtex mean? •  Dtex is a measure for fiber weight (thickness) and is defined as dtex = gram / 10.000m •  The dtex of Dyneema® fibers range between –  55 dtex (=25x monofilaments of 2,2 dtex each) –  2640 dtex (=780x monofilaments of 2.2dtex each) What is a yarn construction? •  Multiple yarns can be combined into a construction - linear (like a rope) or 3D (like a shape). •  Variables: grade, dtex, textile process (braiding, weaving, knitting, …), stitch density, … •  Various pre- and post treatment options have been developed by DSM Dyneema •  Every specific construction has specific mechanical characteristics => opportunity to tailor! •  EuroFibers helps to translate your mechanical needs into specific constructions. 9
  • 10. Microscopic view of a braid made of 16 yarns, each yarn consisting of about 100 filaments 10
  • 11. Typical properties of Dyneema® High pliability Hydrophobic Soft as silk Extremely Low melting strong point (~150°C) High fatigue Cut and tear resistance resistance High chemical Creeps under resistance constant load High abrasion Low coefficient resistance of friction Low density Electrical insulator Low elongation 11
  • 12. Conventional Fibers Vs. Performance Fibers PES •  Dacron® HMPE LCP •  Dyneema® •  Diolen® •  Vectran® •  Spectra® •  Trevira® •  No brand name PA Aramid •  Nylon® •  Kevlar® PBO •  Enkalon® •  Twaron® •  Zylon® •  Perlon® •  Technora® •  No brand name •  Nomex® Conventional High performance fibers fibers 12
  • 13. There is a big difference in tenacity of fibers… Free breaking length Dyneema® 349 Km Zylon® 346 Km Vectran® 247 Km Technora® 227 Km Twaron® 200 Km * Tested according to ISO 2062 Diolen® 77 Km ** Literature value Steel* 25 Km 13
  • 14. …as well as in the elongation of materials Diolen® Technora® Zylon® Steel** Twaron® Vectran® Dyneema® 2,8% 3,0% 3,1% 3,3% 4,0% 3,5% 5X Elongation at break * Synthetic fibers tested according to ISO 2062 ** Literature value 12% * Literature value 14
  • 15. Dyneema® is the only floating fiber Floats 1 2 Sinks 3 Steel Specific gravity* 4 Diolen (PES) ® g/cm3 Twaron (Aramid) ® 5 Technora® (Aramid) Vectran (LCP) ® 6 Zylon (PBO) ® Dyneema (HMPE) ® 7 8 * Literaturevalues 15
  • 16. Aging of pure fibers differs quite a bit % original strength retained after aging 336 hrs* Dyneema® (HMPE) Diolen (PES) ® Twaron® (Aramid) Technora (Aramid) ® Zylon (PBO) ® Vectran® (LCP) *Aged according to ASTM G–155 *Tested according to ISO 2062 0% 10% 20% 30% 40% 50% 60% 70% 80% 16
  • 17. Cut resistance Dyneema® filament stretched over the edge of a razorblade (SEM) Polyethylene cables flatten when placed under tension. This property makes the fiber highly cut resistant. 17
  • 18. Abrasion resistance 80000 Test on emery paper @ 25 C* ° 70000 60000 nr. of cycles to break 50000 40000 Diolen (PES) ® Twaron (Aramid) ® 30000 Technora® (Aramid) Vectran (LCP) ® 20000 Zylon (PBO) ® Dyneema (HMPE) ® 10000 *Tested at Staatliches Pruefamt fuer das Textilgewerbe Mü nchberg 0 18
  • 19. Bending of an LCP filament 19
  • 20. Bending of an aramid filament 20
  • 21. Bending of a PBO filament 21
  • 22. Bending of a Dyneema® filament 22
  • 23. Comparison of fiber properties Diolen® Twaron ® Technora ® Vectran ® Zylon® Dyneema® Properties (PES) (Aramid) (Aramid) (LCP) (PBO) (HMPE) Tenacity 7,6 19,6 22,3 24,2 33,9 34,2 (cN/dTex) Elongation 12,3 3,1 4,0 3,3 2,8 3,4 (%) Specific gravity 3 (Kg/dm ) 1,38 1,39 1,39 1,41 1,56 0,97 Aging Good Poor Poor Very poor Very poor Very good Abrasion Very good Very poor Very poor Poor Poor Very good 23
  • 24. Overview of titers and grades 24
  • 25. Contact EuroFibers BV P.O.Box 599 6200 AN Maastricht The Netherlands info@eurofibers.com www.eurofibers.com +31 43 30 40 014 25