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PLASMA ARC
     AND
WASTE DISPOSAL
 CONVERSION

 Li HE1, Mahmoud SAYED AHMED2
  1Ph.D   Assistant Prof, 2M.Eng Student

                                           1
CONTENT
1.   Introduction
2.   PGP Process Diagram
3.   Plasma Gasification PGP, Plasma Arc
4.   Reactors
5.   Waste-to-Energy and Heat Value
6.   Vetrification
7.   Management and Applications
8.   Conclusion and SWOT Analysis
9.   Reference
                                           2
1. INTRODUCTION




                  3
1. INTRODUCTION
The increasing concern for environmental issues, regulations
  by Clean Air Act, the limitation for the landfill usage & Zero
  Disposal, need of energy, and the consumer price index
  (CPI) regarding the cost of disposal and energy is the
  main purpose for this study.




                                                                   4
2.1 PROCESS DIAGRAM




5




    www.plasma-wr.com/Process_diagram.html
2.2 Flow Chart
The system is mainly
  consists from four
  phases:-

•   Waste preparation and
    feeding system
•   Plasma thermal
    treatment system
•   Synthesis gas cleaning
    system
•   Energy recovery system




                             Pierre Carabin et al   6
3.1. PLASMA ARC
Qin Wang, et al




                                                                   HTT Canada
                  Torch uses various types of gases - Air, Argon
                   (Ar), Nitrogen (N2), Oxygen (O2), etc. and
                   electrodes from different metals such as
                   Copper (Cu), Hafnium (Hf), Tungsten (W), etc.

                                                                   7
3.2. PLASMA GASIFICATION



• Gasification is to produces fuel gas to
  produce steam and electricity.
• Partial Oxidation Process
             C + H2O => CO + H2
                C +½ O2 => CO
• Typical Range of Operation:
  10,000º - 40,000º F (5,600º - 22,400º C)
  near the arc operating pressure            8
4. REACTORS
• Plasma Cold Hearth Furnace (PCH)
• Plasma Rotating Hearth Furnace PRH
  (Electron Beam – EB)
• Plasma Arc Centrifugal Treatment (PACT)




  R. Burkhard et al     INEICHEN, Robert    9
4.2 The PACT System
The wastes are fed into
   a tub rotating at 10–
   40 rpm and melted
   by a plasma arc,
   forming a molten
   pool of metals and
   oxides. The slag
   cools to form a
   glass-like, leach-
   resistant slag, while
   organics are
   evaporated, treated,
   cleaned up, and
   released   .


                           R.K. Womack   10
4.3 Equation of State (EOS)
Any amount of substance contained in a
 system, the temperature1, volume2,
 pressure3, and (internal energy) 4 are not
 independent quantities; they are connected
 in a relationship.




                                              11
5. W-t-E AND HEAT VALUE
Heat Value is
  generated from
  burring of
  organic




                           David H.F. Liu et al
  materials




                           12
Where   HHV = higher heating value in Btu/Lb
                                                                           5.2 Estimating Combustion




Velzy and Hechlinger 1987
13




                                        David H.F. Liu et al
6.1. VETRIFICATION
Generates a durable, homogenous,
 vitrified waste with safe confinement of
 the hazardous feeds and high organic
 removal efficiency.




         J.P. Chu et al                     14
6.




     J.P. Chu et al   15
6.2    Phase Separation
Producing
• Glass
• Construction Materials




                           Qin Wang, et al
                           16
7. MANAGEMENT & APPLICATIONS




                                  Marie Lynn Miranda et al




A study done to calculate the estimated prices for
  landfill versus WTE for several countries based on a
  production for 578 kWh from 1 ton of waste in landfill
  or in WTE.
                                                             17
7.1 Electricity Generation & Environment




 Almost one ton of MSW gives 550 kilowatt of energy
   which is approximately, the same amount produced
   by 1 barrel of oil (138.8 kg / barrel of oil). Electricity
   consumption per capita was recorded to be 16,753
   KWh per Capita in Canada, 1,275 KWh per Capita in
   Egypt, and 2,179 KWh per Capita in China.
                                                                18
7.2 Prevalence of WTE




Source: P. Stehlik / Journal of Cleaner
   Production 17 (2009) 919–931

MSW management in EU is divided into
 distribution between Landfill, Recycling, and
 Incineration
                                                 19
8. CONCLUSION & SWOT

Strength      : controlled temperature
Weakness      : high operational cost
Opportunity   : treat all types of wastes
Threat        : competing technology




                                            20
REFERENCES
•   Startech Environmental Corp, http://www.youtube.com/watch?v=jhNqL-1VrcE
•   R.K. Womack, ” Using the Centrifugal Method for the Plasma-Arc Vitrification
    of Waste “,JOM, 51 (10) (1999), pp. 14–16.,
•   Burkhard, W. Hoffelner and R.C. Eschenbach, “Recycling of metals from
    waste with thermal Plasma”, Resources, Conservation and Recycling, 10 (
    1994 ) 11-16. Elsevier Science B.V
•   US Department of Energy, “Waste Vitrification Systems”, March 1999
•   Marie Lynn Miranda, Brack Hale, “Waste not, want not”, ELSEVIER, Energy
    Policy, Vol. 25, No. 6, pp. 587-600, 1997
•   Pierre Carabin, Gillian Holcraft, “Plasma Resource Recovery Technology”,
    NAWTEC13-3155, ASME, May 23-25, 2005, Orlando, Florida USA.
•   Petr Stehlik, “Contribution to advances in waste-to-energy technologies”,
    Journal of Cleaner Production, Journal of Cleaner Production 17 (2009)
    919–931
•   David H.F. Liu, “Environmental Engineer’s Handbook”, CRC Press LLC, 1999
•   Qin Wang, Jian-Hua Yan, Yong Chi, Xiao-Dong Li, Sheng-Yong Lu,
    “Application of thermal plasma to vitrify fly ash from municipal solid waste
    incinerators”, Elsevier, 2009
                                                                                   21
Cont.
•   J. P. Chua, I. J. Hwanga, C. C. Tzengb, Y. Y. Kuob and Y. J. Yub,
    “Characterization of vitrified slag from mixed medical waste surrogates
    treated by a thermal plasma system”, Journal of Hazardous Materials
    Volume 58, Issues 1-3, February 1998, Pages 179-194.
•   Jonathan S. Bilmes, Susan F. Hemenway, “Applying Lessons Learned
    from WtE Feasibility Study”,NAWTEC14-3183
•   Jeremy K. O’Brien, “Comparison of Air Emission from W-t-E Facilities
    to Fossil Fuel Power Plants”, NAWTEC14-3187
•   PWR, Website http://www.plasma-wr.com/PWR_web_fullscreen.html
•   P. Kavouras, Ph. Komninou*, K. Chrissafis, G. Kaimakamis, S. Kokkou,
    K. Paraskevopoulos, Th. Karakostas, “Microstructural changes of
    processed vitrified solid waste products”, Journal of the European
    Ceramic Society 23 (2003) 1305–1311
•   Enori Gemellia*, Nelson Heriberto Almeida Camargob, Janaína
    Brescansinc, “Evaluation of Paper Industry Wastes in Construction
    Material Applications”, ISSN 1516-1439, Mat. Res. vol.4 no.4 São
    Carlos Oct. 2001


                                                                              22
WE COVERED
 Plasma Arc and Waste Disposal Conversion
1.   Introduction
2.   PGP Process
3.   PGP & Plasma Arc
4.   Reactors
5.   W-t-E and HHR
6.   Vetrification
7.   Management
8.   Conclusion and SWOT
9.   Reference
                                            23
THANK YOU
  Plasma arc gasification facility is a
      recourse recovery process
Trash + Plasma = Electricity + Obsidian

             QUESTIONS?

                     Mahmoud S. AHMED
                     M76Ahmed@ryerson.ca
       www.linkedin.com/in/mahmouchaaban

                                           24

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PGP Plasma Arc Waste Disposal Conversion

  • 1. PLASMA ARC AND WASTE DISPOSAL CONVERSION Li HE1, Mahmoud SAYED AHMED2 1Ph.D Assistant Prof, 2M.Eng Student 1
  • 2. CONTENT 1. Introduction 2. PGP Process Diagram 3. Plasma Gasification PGP, Plasma Arc 4. Reactors 5. Waste-to-Energy and Heat Value 6. Vetrification 7. Management and Applications 8. Conclusion and SWOT Analysis 9. Reference 2
  • 4. 1. INTRODUCTION The increasing concern for environmental issues, regulations by Clean Air Act, the limitation for the landfill usage & Zero Disposal, need of energy, and the consumer price index (CPI) regarding the cost of disposal and energy is the main purpose for this study. 4
  • 5. 2.1 PROCESS DIAGRAM 5 www.plasma-wr.com/Process_diagram.html
  • 6. 2.2 Flow Chart The system is mainly consists from four phases:- • Waste preparation and feeding system • Plasma thermal treatment system • Synthesis gas cleaning system • Energy recovery system Pierre Carabin et al 6
  • 7. 3.1. PLASMA ARC Qin Wang, et al HTT Canada Torch uses various types of gases - Air, Argon (Ar), Nitrogen (N2), Oxygen (O2), etc. and electrodes from different metals such as Copper (Cu), Hafnium (Hf), Tungsten (W), etc. 7
  • 8. 3.2. PLASMA GASIFICATION • Gasification is to produces fuel gas to produce steam and electricity. • Partial Oxidation Process C + H2O => CO + H2 C +½ O2 => CO • Typical Range of Operation: 10,000º - 40,000º F (5,600º - 22,400º C) near the arc operating pressure 8
  • 9. 4. REACTORS • Plasma Cold Hearth Furnace (PCH) • Plasma Rotating Hearth Furnace PRH (Electron Beam – EB) • Plasma Arc Centrifugal Treatment (PACT) R. Burkhard et al INEICHEN, Robert 9
  • 10. 4.2 The PACT System The wastes are fed into a tub rotating at 10– 40 rpm and melted by a plasma arc, forming a molten pool of metals and oxides. The slag cools to form a glass-like, leach- resistant slag, while organics are evaporated, treated, cleaned up, and released . R.K. Womack 10
  • 11. 4.3 Equation of State (EOS) Any amount of substance contained in a system, the temperature1, volume2, pressure3, and (internal energy) 4 are not independent quantities; they are connected in a relationship. 11
  • 12. 5. W-t-E AND HEAT VALUE Heat Value is generated from burring of organic David H.F. Liu et al materials 12
  • 13. Where HHV = higher heating value in Btu/Lb 5.2 Estimating Combustion Velzy and Hechlinger 1987 13 David H.F. Liu et al
  • 14. 6.1. VETRIFICATION Generates a durable, homogenous, vitrified waste with safe confinement of the hazardous feeds and high organic removal efficiency. J.P. Chu et al 14
  • 15. 6. J.P. Chu et al 15
  • 16. 6.2 Phase Separation Producing • Glass • Construction Materials Qin Wang, et al 16
  • 17. 7. MANAGEMENT & APPLICATIONS Marie Lynn Miranda et al A study done to calculate the estimated prices for landfill versus WTE for several countries based on a production for 578 kWh from 1 ton of waste in landfill or in WTE. 17
  • 18. 7.1 Electricity Generation & Environment Almost one ton of MSW gives 550 kilowatt of energy which is approximately, the same amount produced by 1 barrel of oil (138.8 kg / barrel of oil). Electricity consumption per capita was recorded to be 16,753 KWh per Capita in Canada, 1,275 KWh per Capita in Egypt, and 2,179 KWh per Capita in China. 18
  • 19. 7.2 Prevalence of WTE Source: P. Stehlik / Journal of Cleaner Production 17 (2009) 919–931 MSW management in EU is divided into distribution between Landfill, Recycling, and Incineration 19
  • 20. 8. CONCLUSION & SWOT Strength : controlled temperature Weakness : high operational cost Opportunity : treat all types of wastes Threat : competing technology 20
  • 21. REFERENCES • Startech Environmental Corp, http://www.youtube.com/watch?v=jhNqL-1VrcE • R.K. Womack, ” Using the Centrifugal Method for the Plasma-Arc Vitrification of Waste “,JOM, 51 (10) (1999), pp. 14–16., • Burkhard, W. Hoffelner and R.C. Eschenbach, “Recycling of metals from waste with thermal Plasma”, Resources, Conservation and Recycling, 10 ( 1994 ) 11-16. Elsevier Science B.V • US Department of Energy, “Waste Vitrification Systems”, March 1999 • Marie Lynn Miranda, Brack Hale, “Waste not, want not”, ELSEVIER, Energy Policy, Vol. 25, No. 6, pp. 587-600, 1997 • Pierre Carabin, Gillian Holcraft, “Plasma Resource Recovery Technology”, NAWTEC13-3155, ASME, May 23-25, 2005, Orlando, Florida USA. • Petr Stehlik, “Contribution to advances in waste-to-energy technologies”, Journal of Cleaner Production, Journal of Cleaner Production 17 (2009) 919–931 • David H.F. Liu, “Environmental Engineer’s Handbook”, CRC Press LLC, 1999 • Qin Wang, Jian-Hua Yan, Yong Chi, Xiao-Dong Li, Sheng-Yong Lu, “Application of thermal plasma to vitrify fly ash from municipal solid waste incinerators”, Elsevier, 2009 21
  • 22. Cont. • J. P. Chua, I. J. Hwanga, C. C. Tzengb, Y. Y. Kuob and Y. J. Yub, “Characterization of vitrified slag from mixed medical waste surrogates treated by a thermal plasma system”, Journal of Hazardous Materials Volume 58, Issues 1-3, February 1998, Pages 179-194. • Jonathan S. Bilmes, Susan F. Hemenway, “Applying Lessons Learned from WtE Feasibility Study”,NAWTEC14-3183 • Jeremy K. O’Brien, “Comparison of Air Emission from W-t-E Facilities to Fossil Fuel Power Plants”, NAWTEC14-3187 • PWR, Website http://www.plasma-wr.com/PWR_web_fullscreen.html • P. Kavouras, Ph. Komninou*, K. Chrissafis, G. Kaimakamis, S. Kokkou, K. Paraskevopoulos, Th. Karakostas, “Microstructural changes of processed vitrified solid waste products”, Journal of the European Ceramic Society 23 (2003) 1305–1311 • Enori Gemellia*, Nelson Heriberto Almeida Camargob, Janaína Brescansinc, “Evaluation of Paper Industry Wastes in Construction Material Applications”, ISSN 1516-1439, Mat. Res. vol.4 no.4 São Carlos Oct. 2001 22
  • 23. WE COVERED Plasma Arc and Waste Disposal Conversion 1. Introduction 2. PGP Process 3. PGP & Plasma Arc 4. Reactors 5. W-t-E and HHR 6. Vetrification 7. Management 8. Conclusion and SWOT 9. Reference 23
  • 24. THANK YOU Plasma arc gasification facility is a recourse recovery process Trash + Plasma = Electricity + Obsidian QUESTIONS? Mahmoud S. AHMED M76Ahmed@ryerson.ca www.linkedin.com/in/mahmouchaaban 24