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Arsenic Contamination in Ground Water
            of Bihar ,India



    Arsenic Mitigation: The Way Forward
                    Dr.Ashok Ghosh
                 Professor -in-Charge
     Dept. of Environment and Water Management
                   A.N.College, Patna
            e mail: ghosh51@ancollege.org
                    ghosh51@ancollege org
Napoleon Bonaparte
                      p          p




                            A lock of Napoleon's Hair




www.ancollege.org
Origin of arsenic crisis  in Indian subcontinent 
 [switching from surface water to underground water]
    i hi f          f               d       d

                                                Underground
People used surface       Reduction of infant
                                                water became
  water until 1970s       and child mortality
                                                widely popular



                            Millions            Problems arose
   Poor quality
  due to pollution        of t be ells
                             tubewells           due to
                                                 d t arsenici
                                                 contamination
                            installed

                             Best option:
 High prevalence of                             Affects almost
                             underground
water-borne diseases                            whole country
                                water



                             Demand f
                             D      d for
  High infant and                                Poses severe
                          pathogen free safe
  child mortality                               health problems
      www.ancollege.org     drinking water
Arsenic  ‐ Gloabal Threat 




           Courtesy :Dr.Deepankar Chakrovorty,Jadavpur Univ.Kolkata
www.ancollege.org
Arsenic in India 
    GANGA‐              GMB Plains -Area 569 thousand sq km
                              Population >500 million
   MEGHNA‐
BRAMHAPUTRA
 RIVER BASINS
 RIVER BASINS
Arsenic  Hotbed



    www.ancollege.org
Arsenic in Bihar


• In2002 Mr Kuneshwar Ojha a school
  In2002 Mr.Kuneshwar Ojha,a school 
    teacher living close to river Ganga in 
    Ojhapatti ,Bhojpur, became very 
    concerned after his wife and 
    mother died of liver cancer and 
    other family members developed 
    other family members developed
    skin lesions.
•   He took water samples from family 
                        p              y
    tube well to SOES, Jadavpur
    University, Kolkata
•   Subsequently, high Arsenic
    S b          l hi h A      i
                                              Mr.Kuneshwar Ojha

    content was detected in 
    these samples
    these samples
        www.ancollege.org
NEPAL




BIHAR - Play Ground of
        Rivers



Arsenic in 
  Bihar ‐
  Highly 
  Arsenic 
 Infested


                               Ganga   Indian Craton

           www.ancollege.org
Arsenic  Map of Bihar ‐ 2002
               West Champaran
                        p




                                                  Sheohar
                                   East   Champaran
                                          Ch
                     Gopalganj
                                                       Sitamarhi
                                                                         Madhubani
                                                                                                      Supaul                Kishanganj
                                                                                                               Araria
                        Siwan                      Muzaffarpur
                                                                       Darbhanga                 M adhepura
                                                                                                                Purnia
                                           Saran      Vaishali Samastipur                   Saharsa


                          Bhojpur             Patna                    Begusarai            Khagaria                    Katihar
           Buxar
                                                      NalandaSheikhpura            Munger               Bhagalpur
            Rohtas                   Jehanabad
Kaimur                                                             Lakhisarai
                                                              Nawada                             Banka
                      Aurangabad                                                   Jamui
                                           Gaya




         1 Arsenic Affected District
           www.ancollege.org
Arsenic  Map of Bihar ‐2004
              West Champaran
                       p




                                 East Ch      Sheohar
                                      Champaran
                Gopalganj
                                                  Sitamarhi
                                                                    Madhubani
                                                                                                 Supaul                Kishanganj
                                                                                                          Araria
                      Siwan                   Muzaffarpur
                                                                  Darbhanga                 M adhepura
                                                                                                           Purnia
                                     Saran       Vaishali Samastipur                   Saharsa


                        Bhojpur          Patna                    Begusarai            Khagaria                    Katihar
          Buxar
                                                 Nalanda Sheikhpura           Munger               Bhagalpur
           Rohtas                 Jehanabad
Kaimur                                                        Lakhisarai
                                                        Nawada                              Banka
                    Aurangabad       Gaya                                     Jamui




         2 Arsenic Affected Districts
          www.ancollege.org
Arsenic Map  of Bihar ‐2005
               West Champaran
                        p




                                                 Sheohar
                                  East   Champaran
                                         Ch
                 Gopalganj
                                                     Sitamarhi
                                                                       Madhubani
                                                                                               Supaul               Kishanganj
                                                                                                        Araria
                       Siwan                      Muzaffarpur
                                                                     Darbhanga            Madhepura
                                                                                                         Purnia
                                          Saran    Vaishali Samastipur               Saharsa


                        Bhojpur              Patna                   Begusarai       Khagaria                    Katihar
           Buxar
                                                     NalandaSheikhpura Munger                   Bhagalpur
            Rohtas                  Jehanabad
Kaimur                                                           Lakhisarai
                                                           Nawada                         Banka
                     Aurangabad                                              Jamui
                                          Gaya




         4 Arsenic  Affected Districts
           www.ancollege.org
Arsenic Map of Bihar ‐2007
               West Champaran
                        p




                                                 Sheohar
                                  East   Champaran
                                         Ch
                 Gopalganj
                                                      Sitamarhi
                                                                        Madhubani
                                                                                                  Supaul                 Kishanganj
                                                                                                            Araria
                       Siwan                      Muzaffarpur
                                                                      Darbhanga              Madhepura
                                                                                                             Purnia
                                          Saran      Vaishali Samastipur                Saharsa


                        Bhojpur              Patna                    Begusarai         Khagaria                     Katihar
           Buxar
                                                     Nalanda Sheikhpura        Munger               Bhagalpur
            Rohtas                  Jehanabad
Kaimur                                                            Lakhisarai
                                                            Nawada                           Banka
                     Aurangabad                                                Jamui
                                          Gaya




         12 Arsenic Affected Districts
           www.ancollege.org
Arsenic Map of Bihar ‐2009
               West Champaran
                        p




                                  East   Ch      Sheohar
                                         Champaran
                 Gopalganj
                                                     Sitamarhi         Madhubani
                                                                                               Supaul                Kishanganj
                                                                                                        Araria
                       Siwan                      Muzaffarpur
                                                                     Darbhanga            Madhepura
                                                                                                         Purnia
                                          Saran    Vaishali Samastipur               Saharsa


                        Bhojpur              Patna                   Begusarai       Khagaria                    Katihar
           Buxar
                                                     NalandaSheikhpura Munger                    Bhagalpur
            Rohtas                  Jehanabad
Kaimur                                                           Lakhisarai
                                                           Nawada                         Banka
                     Aurangabad           Gaya                               Jamui




         16 Arsenic Affected Districts
           www.ancollege.org
Sources of arsenic 
      So rces of arsenic
       affecting human 
       affecting human
            health


www.ancollege.org
Arsenic Ingestion Routes


•Drinking Water
•Drinking Water

•Irrigation Water ‐ Food 
Chain

•Burning Cowdung Cake
 Burning Cowdung




     www.ancollege.org
The  Hottest Arsenic Hand Pump of Bihar 
                1860 ppb ‐ Panday Tola,Bhojpur




 Panday Tola – 100 % hand
pumps with arsenic> 50 ppb




                             Arsenic Concentration of  1861 ppb 



     www.ancollege.org
 Krishna Kumar Panday
Maximum As. Conc. In Different 
                  Districts of Bihar  in mg/lt




www.ancollege.org
BIHAR FINDINGS (Ghosh et.al.‐2008)
                          GS (G os et a 008)
• 7,218 of 27,061  hand pumps tested 
   ,         ,          p p
    had arsenic contaminated water of>10 
    ppb.[26.67%]
•   Highest As. Value Recorded – 1861 ppb
•   A total of 16 Bihar districts ( 57 blocks)  
    are affected by high level of arsenic in 
    the groundwater
•   Trivalent arsenic 87 % in ground water 
      i l           i 8 %i            d
    of Bihar
•   Worst‐affected districts are Bhojpur, 
    Worst affected districts are Bhojpur
    Buxar, Vaishali, Bhagalpur, 
    Samastipur, Khagaria, Katihar, Chapra, 
    Samastipur, Khagaria, Katihar, Chapra,
    Munger and Darbhanga.
         www.ancollege.org
Maize:Total As -0.24 ug As g-1




                                 Arsenic in food 
                                 Arsenic in food
                                 chain of Bihar
     Rice - 0.36 ug As g-1
                                   Food Chain



                                 Irrigation Tube well =As 980 ppb
    www.ancollege.org
Arsenic in River Water – Jamunia,Bhagalpur
  se c        e ate Ja u a, aga pu




 As Content > 50 ppb

    www.ancollege.org
आसिनक का बढ़ता दायरा

 ितलका मांझी िव िवद्यालय भागलपर क वन पित
                                      ु े
  िवभाग की टीम नेे डा. सुनी कमार चौधरी और पटना
  ि          ी ी           ील ु           ौ ी औ
  ि थत अनग्रह नारायण कालेज क पयार्वरण और जल
              ु                  े
  प्रबंंधन िवभाग क डा. एक घोष क नेेत ृ व म एक सव
           ि        े     े ो       े
  िकया। इसम भागलपर होकर बहने वाली जमिनया नदी
                      ु
  की सतह पर भी आसिनक की मौजदगी पायी।
     ी            ी     ि      ी ौ ू ी        ी
  जमुिनया नदी गंगा से िलंक नदी है और इसी नदी क    े
  पानी का ट्रीटमट कर भागलपर क लोग को पानी
        ी       ी            ु     े ो      ो   ी
  आपूितर् की जाती है

Source:http://hindi.indiawaterportal.org/pollution_arsenic
          p                   p        gp

     www.ancollege.org
Consequences of 
                         q
                       Arsenicosis




www.ancollege.org
Consequences of arsenicosis (Health )
Health consequences
              Dermatological
                Respiratory
                   p      y
              Gastrointestinal
              Cardiovascular
                  Hepatic
               Neurological
              Haematological
                   Renal
               Mutagenesis
               Reproductive
                   Cancer
               Mental health
    www.ancollege.org
Consequences of arsenicosis
      (Social ) consequences
          Social
                          Social 
                    hazards/instability
                    Marriage related 
                      p
                      problems

                     Stigmatization

                      Superstition

                         Poverty

www.ancollege.org
A few arsenic poisoning 
   symptoms in Bihar 
detected by my research 
         group 
 www.ancollege.org
Gift of home coming………Keratosis




     Keratosis




Ram Ashan Panday – Ex Army Man – Developed Symptoms after his 
       www.ancollege.org
          Return to native village ‐ Panday Tola,Bhojpur
Diffuse and Spotted Keratosis on Palm
                     p




www.ancollege.org
Gift of home coming……
             Gift of home coming

                      Kisan Panday
                      Ex army man 
                      Ex army man
                      developed  
                      symptoms after his 
                      symptoms after his
                      return to native 
                      village,PandayTola,
                       ill    P d T l
        Keratosis
                      Bhojpur six years 
                      ago.

www.ancollege.org
Low Blood Pressure and Anemic 
     Low Blood Pressure and Anemic


                    Wife of Munna Panday
                    [25 years old
                    with 4 children] –
                       h hl        ]
                    Arsenicosis with low 
                    Blood Pressure – Panday Tola,
                     l d                  d   l
                    Bhojpur,Bihar



www.ancollege.org
Arsenicosis with Low BP
      Arsenicosis with Low BP




 Aunty of Munna
 Aunty of Munna Panday [45 years] – Panday
                             [45 years] 
www.ancollege.org
                  Tola,Bhojpur,Bihar
              And Anaemia – Panday Tola ,Bihar
Hypertension  Depression 
              Hypertension – Depression


                      Anuj Panday of
                          j       y
                      Panday Tola with
                      early symptom of
                      early symptom of
                      arsenicosis has
                      very high BP and 
                      depression ‐ due 
                      depression due
                      to uncertain future??
www.ancollege.org
Arsenic Toxicity and Obstetric Outcome
                    Arsenic Toxicity and Obstetric Outcome

 Arsenic in drinking water = 630 μg/L

    Arsenic in urine = 900 μg/L


    Anita Devi  expired  in 2007 due to
            arsenic poisoning


Obstetric outcome of Anita Devi, Maner,Patna

First Pregnancy:  Preterm Stillbirth
         g    y
Second Pregnancy:  Abortion
Third Pregnancy:
Third Pregnancy:          y
                      Early neonatal death 

           www.ancollege.org
Arsenic  Induced Cytogenetic and Gene Mutation

Chromosomal anomalies
 Cytogenetic  Mutation
 Cytogenetic Mutation



     Arsenic – A
       human
     carcinogen


  Genotoxic events  
   Gene Mutation
              i



www.ancollege.org
Genotoxicity of Arsenic  in humans
             Genotoxicity of Arsenic in humans




Chromosomal Aberrations 




       Micronucei
    www.ancollege.org
                                    DNA Damage
So e add t o a
                  Some additional findings
                                     d gs
• Consistent dose‐response relationships were found 
                     p                p
  between As. exposure and risk of skin lesions.
• Thi
  Thinner/weaker persons are more likely to be 
          /    k                  lik l     b
  affected by As exposure. 
• Use of fertilizer and excessive sun exposure increase 
  the susceptibility to risk of skin lesions due to Arsenic 
  the susceptibility to risk of skin lesions due to Arsenic
  exposure. 
• Tobacco smoking and high level of Arsenic  exposure 
  synergistically increase the risk of skin lesions and 
  cancer. 
   www.ancollege.org
Other emerging health problems identified 
           by our research group 


    • Adverse relationship between 
      arsenic level and intelligence in 
      y
      young children?
           g
    • Adverse affect on foetus
    • Low birth weight
           b h        h
    • Obstructive airway diseases in 
                         y
      young adult and children

www.ancollege.org
Factors  which may  aggravate Arsenicosis


• Type of arsenic and level of exposure 
         f           dl l f
• Body immunity and genetic
   Body immunity and genetic 
  configuration plays significant role
• Nutritional status and food habit
•L h
  Low haemoglobin l l
                l bi level may enhance ill 
                                   h    ill
  effects of arsenic


 www.ancollege.org
Arsenic Management




www.ancollege.org
Management  of arsenicosis
              a age e t o a se cos s

• Arsenic free safe water
• Dietary Supplement and anti‐oxidant 
  fruits/vegetables/protein is important along with 
  application of ointment (5 – 20% Urea and salicylic)
• Complicated cases like skin cancer, ulcer, gangrene needs 
  spec a ed ed ca a d su g ca a age e
  specialized medical and surgical management
• Social, economic and physical rehabilitation.
• Mass community awareness and support to develop
  Mass community awareness and support to develop
 community based rehabilitation system.

      www.ancollege.org
Improvement by Drinking Arsenic Free 
      Water




www.ancollege.org
MAJOR PROBLEMS OF “ARSENICOSIS” 
          MANAGEMENT
• Lack of knowledge information and training for case
  Lack of knowledge information and training for case 
  detection and management by field workers
• Poor community motivation for safe water use
  Poor community motivation for safe water use 
  complicated by physical nature of arsenic in water 
  (tasteless, colorless and odorless)
  (tasteless colorless and odorless)
• Socio‐economic hazards due to ill‐conceived idea about 
  “Arsenicosis”
  “A     i i”
• Poor Resource allocation for rehabilitation and treatment
• Indiscriminate installation of Tube‐well both private and 
  public sector
     www.ancollege.org
Lack of Awareness




                    •The unsafe sources (PAINTED
                    •The unsafe sources  (PAINTED  
                     RED) are still being used by
                     villagers due to lack of  awareness. 
                     villagers due to lack of awareness
                    •Intensive awareness campaign is
                     required in affected villages.
                     required in affected villages
www.ancollege.org
Arsenic Mitigation Options




www.ancollege.org
Arsenic mitigation strategies and sustainability
 Options
              Pond        Rainwater harvesting
                                             g     Dug well
                                                     g

Water source


              Surface            Rain            Sub-surface

Problems

           •Pollution         •Collection          •Bacterial
         •Accessibility      •Preservation       contamination
          •Acceptibilty
           A     tibilt   •Seasonal variabilty
                           S       l    i bilt   •Acceptability
                                                  A     t bilit




Feasibility

               Low                Low                Better


     www.ancollege.org
Arsenic mitigation strategies and
                                 and ……………
Options
           Deep well            Piped water        Arsenic removal filters

Water source

           Deep aquifers   Deep aquifers/treated   Arsenic contaminated
                              Surface water                water
Problems

           •Uncertain           •Expensive             •Effectiveness?
           •Expensive        •No infrastructure          •Expensive
                                                      •Environmentally
                                                         problematic


Feasibility

        Better but…….               Low                     Better



     www.ancollege.org
Most of mitigation
        strategies have failed in
                 Bihar



www.ancollege.org
Results of Arsenic  Mitigation Strategies 
                                      g            g




REDUNDENT RAINWATER                                       REDUNDENT RESTORED 
  HARVESTING UNIT                                             OPEN WELL


                           DEFUNCT OVERHEAD TANK TO TAP
       www.ancollege.org          SAFE AQUIFER 
Rs.53 Crore GoB initiative in Bhojpur

                                                      • Ganga Water to be supplied
                                                        after treatment
                                                      • Dependent on electric power ,
                                                        a scarce commodity in Bihar
                                                                            y
                                                      • Ganga is shifting from its
                                                        current location as per our
                                                        studies




              Ganga River Piped Water Scheme launched by GoB at Bhojpur

www.ancollege.org
Sustainable arsenic mitigation
technologies for rural population
    [possible alternatives]




 www.ancollege.org
Possible alternative I: Gravity 
                                             y
               driven filter
• G it D i Filt
  Gravity Driven Filter  not 
                           t
  dependent on electricity
• Easy to maintain
• Easy to operate
  Easy to operate
• Low cost
• Quick disposal of backwash 
  and sludge through 
  and sludge through
  bioremediation

       www.ancollege.org
Possible Alternative  II‐ TRADITIONAL DUGWELLS 
          PROPERLY SANITIZED [Project Well Initiative]
          PROPERLY SANITIZED [Project Well Initiati e]




    Courtesy :Project
www.ancollege.org       Well- Dr .Meera H. Smith, USA
                         Project Well_MMS_June 2009
Interior of the dugwell

                              The pvc pipe is 
                              shortened after 
                                 insertion


                            The delivery pipe is flexible for self 
                            The delivery pipe is flexible for self
                                  adjustable water level 




Courtesy :Project Well- Dr. Meera H. Smith,USA
The net and the tin cover 
                    are used for protection from 
                         external debris and 
                             tampering.



www.ancollege.org
There are 112  PROJECT  WELL DUGWELLS as of 
        2009 in  N24 PARGANAS, WEST BENGAL, INDIA
        2009 in N24 PARGANAS WEST BENGAL INDIA




               Courtesy
www.ancollege.org         :Project Well- Dr.Meera H. Smith
Possible alternative III: In Situ Arsenic Treatment
 [TiPOT technology of Queen's University Belfast, UK]




                                           Shower Head
                                           Sh     H d




 Rangapur, Nilgunj ( WB) Plant   Courtesy - Dr.Bhaskar Sengupta
  Supported by World Bank
   www.ancollege.org                   Univ. of Belfast, UK
In Situ Arsenic Treatment………..

• In the in‐situ treatment method, the aerated tube well 
  water is stored in feed water tanks and released back 
  into the aquifers. 
• The dissolved oxygen in aerated water oxidizes arsenite
  to less‐mobile arsenate, the ferrous iron to ferric iron 
                           ,
  and Manganese(II) to Manganese(III), followed by 
  adsorption of arsenate on Fe(III) and manganese(III) and 
         p                       ( )         g       ( )
  subsequent precipitation resulting in a reduction of the 
  arsenic content in tube well water.
• Oxidation is further enhanced biologically by bacteria 
  living in the subsurface 
  living in the subsurface ‐ bioremediation
      www.ancollege.org
In Situ Arsenic Treatment…….




                         Courtesy - Dr.Bhaskar Sengupta
                                y                  g
                               Univ. of Belfast,UK

     www.ancollege.org
In Situ Arsenic Treatment……………..




                                   Courtesy - Dr.Bhaskar Sengupta
       www.ancollege.org                 Univ. of Belfast,UK
Possible alternative IV ‐RO /nano membrane 
      system attached with solar power 




www.ancollege.org
UNRESOLVED ISSUES RELATING TO ARSENIC 
          CONTAMINATED DRINKING WATER SOURCES

• Research into Arsenic speciation, mobilization largely 
  fragmented and repetitive
• Almost entire investigation into the hydro‐geological
  Almost entire investigation into the hydro geological 
  aspects of arsenic contaminated aquifers have been 
  confined to Bengal basin, the geological variations along 
  the entire river basins warranting immediate attention.
  the entire river basins warranting immediate attention
• Lack of knowledge and  medical infrastructure relating to  
  diagnosis and treatment of arsenicosis.
• Lack of comprehensive database on arsenic contaminated 
  aquifers and its implications
• Lack of maintenance and monitoring of mitigation
  Lack of maintenance and monitoring of mitigation 
  structures
• Lack of Community Participation

 www.ancollege.org
Vision of the Action Group
                                          p
           Solution  Exchange –Water Community


Establishing a multi‐disciplinary, holistic 
Centre of Excellence for Arsenic Studies
Centre of Excellence for Arsenic Studies
in the sub‐continent, that will bypass 
political boundaries, and work for 
comprehensive solution to the scourge
comprehensive solution to the scourge
of arsenic.
  www.ancollege.org
Centre of Excellence for Arsenic
                                 Studies
                  AIMS  & OBJECTIVES
                  AIMS & OBJECTIVES
• To preserve and conserve the quality of ground 
  water reserves in terms of Arsenic contamination.
  water reserves in terms of Arsenic contamination.
• To prepare and maintain a comprehensive database 
  on all issues related to arsenic contaminated 
  ground water.
• To provide low‐cost, local resource–based, 
  sustainable mitigation strategies to the rural poor
     t i bl      iti ti     t t i t th         l
• To provide consultancy and linkage to communities,  
  research organizations, NGOs &   funding agencies 
  research organizations NGOs & funding agencies
  in water sector .

 www.ancollege.org
We strive for
                    Community based
                    C      it b d
YES                   Knowledge !
                      K       g


                    THANKS


www.ancollege.org

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Arsenic In Ground Water Of Bihar

  • 1. Arsenic Contamination in Ground Water of Bihar ,India Arsenic Mitigation: The Way Forward Dr.Ashok Ghosh Professor -in-Charge Dept. of Environment and Water Management A.N.College, Patna e mail: ghosh51@ancollege.org ghosh51@ancollege org
  • 2. Napoleon Bonaparte p p A lock of Napoleon's Hair www.ancollege.org
  • 3. Origin of arsenic crisis  in Indian subcontinent  [switching from surface water to underground water] i hi f f d d Underground People used surface Reduction of infant water became water until 1970s and child mortality widely popular Millions Problems arose Poor quality due to pollution of t be ells tubewells due to d t arsenici contamination installed Best option: High prevalence of Affects almost underground water-borne diseases whole country water Demand f D d for High infant and Poses severe pathogen free safe child mortality health problems www.ancollege.org drinking water
  • 4. Arsenic  ‐ Gloabal Threat  Courtesy :Dr.Deepankar Chakrovorty,Jadavpur Univ.Kolkata www.ancollege.org
  • 5. Arsenic in India  GANGA‐ GMB Plains -Area 569 thousand sq km Population >500 million MEGHNA‐ BRAMHAPUTRA RIVER BASINS RIVER BASINS Arsenic  Hotbed www.ancollege.org
  • 6. Arsenic in Bihar • In2002 Mr Kuneshwar Ojha a school In2002 Mr.Kuneshwar Ojha,a school  teacher living close to river Ganga in  Ojhapatti ,Bhojpur, became very  concerned after his wife and  mother died of liver cancer and  other family members developed  other family members developed skin lesions. • He took water samples from family  p y tube well to SOES, Jadavpur University, Kolkata • Subsequently, high Arsenic S b l hi h A i Mr.Kuneshwar Ojha content was detected in  these samples these samples www.ancollege.org
  • 7. NEPAL BIHAR - Play Ground of Rivers Arsenic in  Bihar ‐ Highly  Arsenic  Infested Ganga Indian Craton www.ancollege.org
  • 8. Arsenic  Map of Bihar ‐ 2002 West Champaran p Sheohar East Champaran Ch Gopalganj Sitamarhi Madhubani Supaul Kishanganj Araria Siwan Muzaffarpur Darbhanga M adhepura Purnia Saran Vaishali Samastipur Saharsa Bhojpur Patna Begusarai Khagaria Katihar Buxar NalandaSheikhpura Munger Bhagalpur Rohtas Jehanabad Kaimur Lakhisarai Nawada Banka Aurangabad Jamui Gaya 1 Arsenic Affected District www.ancollege.org
  • 9. Arsenic  Map of Bihar ‐2004 West Champaran p East Ch Sheohar Champaran Gopalganj Sitamarhi Madhubani Supaul Kishanganj Araria Siwan Muzaffarpur Darbhanga M adhepura Purnia Saran Vaishali Samastipur Saharsa Bhojpur Patna Begusarai Khagaria Katihar Buxar Nalanda Sheikhpura Munger Bhagalpur Rohtas Jehanabad Kaimur Lakhisarai Nawada Banka Aurangabad Gaya Jamui 2 Arsenic Affected Districts www.ancollege.org
  • 10. Arsenic Map  of Bihar ‐2005 West Champaran p Sheohar East Champaran Ch Gopalganj Sitamarhi Madhubani Supaul Kishanganj Araria Siwan Muzaffarpur Darbhanga Madhepura Purnia Saran Vaishali Samastipur Saharsa Bhojpur Patna Begusarai Khagaria Katihar Buxar NalandaSheikhpura Munger Bhagalpur Rohtas Jehanabad Kaimur Lakhisarai Nawada Banka Aurangabad Jamui Gaya 4 Arsenic  Affected Districts www.ancollege.org
  • 11. Arsenic Map of Bihar ‐2007 West Champaran p Sheohar East Champaran Ch Gopalganj Sitamarhi Madhubani Supaul Kishanganj Araria Siwan Muzaffarpur Darbhanga Madhepura Purnia Saran Vaishali Samastipur Saharsa Bhojpur Patna Begusarai Khagaria Katihar Buxar Nalanda Sheikhpura Munger Bhagalpur Rohtas Jehanabad Kaimur Lakhisarai Nawada Banka Aurangabad Jamui Gaya 12 Arsenic Affected Districts www.ancollege.org
  • 12. Arsenic Map of Bihar ‐2009 West Champaran p East Ch Sheohar Champaran Gopalganj Sitamarhi Madhubani Supaul Kishanganj Araria Siwan Muzaffarpur Darbhanga Madhepura Purnia Saran Vaishali Samastipur Saharsa Bhojpur Patna Begusarai Khagaria Katihar Buxar NalandaSheikhpura Munger Bhagalpur Rohtas Jehanabad Kaimur Lakhisarai Nawada Banka Aurangabad Gaya Jamui 16 Arsenic Affected Districts www.ancollege.org
  • 13. Sources of arsenic  So rces of arsenic affecting human  affecting human health www.ancollege.org
  • 14. Arsenic Ingestion Routes •Drinking Water •Drinking Water •Irrigation Water ‐ Food  Chain •Burning Cowdung Cake Burning Cowdung www.ancollege.org
  • 15. The  Hottest Arsenic Hand Pump of Bihar  1860 ppb ‐ Panday Tola,Bhojpur Panday Tola – 100 % hand pumps with arsenic> 50 ppb Arsenic Concentration of  1861 ppb  www.ancollege.org Krishna Kumar Panday
  • 16. Maximum As. Conc. In Different  Districts of Bihar  in mg/lt www.ancollege.org
  • 17. BIHAR FINDINGS (Ghosh et.al.‐2008) GS (G os et a 008) • 7,218 of 27,061  hand pumps tested  , , p p had arsenic contaminated water of>10  ppb.[26.67%] • Highest As. Value Recorded – 1861 ppb • A total of 16 Bihar districts ( 57 blocks)   are affected by high level of arsenic in  the groundwater • Trivalent arsenic 87 % in ground water  i l i 8 %i d of Bihar • Worst‐affected districts are Bhojpur,  Worst affected districts are Bhojpur Buxar, Vaishali, Bhagalpur,  Samastipur, Khagaria, Katihar, Chapra,  Samastipur, Khagaria, Katihar, Chapra, Munger and Darbhanga. www.ancollege.org
  • 18. Maize:Total As -0.24 ug As g-1 Arsenic in food  Arsenic in food chain of Bihar Rice - 0.36 ug As g-1 Food Chain Irrigation Tube well =As 980 ppb www.ancollege.org
  • 19. Arsenic in River Water – Jamunia,Bhagalpur se c e ate Ja u a, aga pu As Content > 50 ppb www.ancollege.org
  • 20. आसिनक का बढ़ता दायरा ितलका मांझी िव िवद्यालय भागलपर क वन पित ु े िवभाग की टीम नेे डा. सुनी कमार चौधरी और पटना ि ी ी ील ु ौ ी औ ि थत अनग्रह नारायण कालेज क पयार्वरण और जल ु े प्रबंंधन िवभाग क डा. एक घोष क नेेत ृ व म एक सव ि े े ो े िकया। इसम भागलपर होकर बहने वाली जमिनया नदी ु की सतह पर भी आसिनक की मौजदगी पायी। ी ी ि ी ौ ू ी ी जमुिनया नदी गंगा से िलंक नदी है और इसी नदी क े पानी का ट्रीटमट कर भागलपर क लोग को पानी ी ी ु े ो ो ी आपूितर् की जाती है Source:http://hindi.indiawaterportal.org/pollution_arsenic p p gp www.ancollege.org
  • 21. Consequences of  q Arsenicosis www.ancollege.org
  • 22. Consequences of arsenicosis (Health ) Health consequences Dermatological Respiratory p y Gastrointestinal Cardiovascular Hepatic Neurological Haematological Renal Mutagenesis Reproductive Cancer Mental health www.ancollege.org
  • 23. Consequences of arsenicosis (Social ) consequences Social Social  hazards/instability Marriage related  p problems Stigmatization Superstition Poverty www.ancollege.org
  • 24. A few arsenic poisoning  symptoms in Bihar  detected by my research  group  www.ancollege.org
  • 25. Gift of home coming………Keratosis Keratosis Ram Ashan Panday – Ex Army Man – Developed Symptoms after his  www.ancollege.org Return to native village ‐ Panday Tola,Bhojpur
  • 27. Gift of home coming…… Gift of home coming Kisan Panday Ex army man  Ex army man developed   symptoms after his  symptoms after his return to native  village,PandayTola, ill P d T l Keratosis Bhojpur six years  ago. www.ancollege.org
  • 28. Low Blood Pressure and Anemic  Low Blood Pressure and Anemic Wife of Munna Panday [25 years old with 4 children] – h hl ] Arsenicosis with low  Blood Pressure – Panday Tola, l d d l Bhojpur,Bihar www.ancollege.org
  • 29. Arsenicosis with Low BP Arsenicosis with Low BP Aunty of Munna Aunty of Munna Panday [45 years] – Panday [45 years]  www.ancollege.org Tola,Bhojpur,Bihar And Anaemia – Panday Tola ,Bihar
  • 30. Hypertension  Depression  Hypertension – Depression Anuj Panday of j y Panday Tola with early symptom of early symptom of arsenicosis has very high BP and  depression ‐ due  depression due to uncertain future?? www.ancollege.org
  • 31. Arsenic Toxicity and Obstetric Outcome Arsenic Toxicity and Obstetric Outcome Arsenic in drinking water = 630 μg/L Arsenic in urine = 900 μg/L Anita Devi  expired  in 2007 due to arsenic poisoning Obstetric outcome of Anita Devi, Maner,Patna First Pregnancy:  Preterm Stillbirth g y Second Pregnancy:  Abortion Third Pregnancy: Third Pregnancy: y Early neonatal death  www.ancollege.org
  • 32. Arsenic  Induced Cytogenetic and Gene Mutation Chromosomal anomalies Cytogenetic  Mutation Cytogenetic Mutation Arsenic – A human carcinogen Genotoxic events   Gene Mutation i www.ancollege.org
  • 33. Genotoxicity of Arsenic  in humans Genotoxicity of Arsenic in humans Chromosomal Aberrations  Micronucei www.ancollege.org DNA Damage
  • 34. So e add t o a Some additional findings d gs • Consistent dose‐response relationships were found  p p between As. exposure and risk of skin lesions. • Thi Thinner/weaker persons are more likely to be  / k lik l b affected by As exposure.  • Use of fertilizer and excessive sun exposure increase  the susceptibility to risk of skin lesions due to Arsenic  the susceptibility to risk of skin lesions due to Arsenic exposure.  • Tobacco smoking and high level of Arsenic  exposure  synergistically increase the risk of skin lesions and  cancer.  www.ancollege.org
  • 35. Other emerging health problems identified  by our research group  • Adverse relationship between  arsenic level and intelligence in  y young children? g • Adverse affect on foetus • Low birth weight b h h • Obstructive airway diseases in  y young adult and children www.ancollege.org
  • 36. Factors  which may  aggravate Arsenicosis • Type of arsenic and level of exposure  f dl l f • Body immunity and genetic Body immunity and genetic  configuration plays significant role • Nutritional status and food habit •L h Low haemoglobin l l l bi level may enhance ill  h ill effects of arsenic www.ancollege.org
  • 38. Management  of arsenicosis a age e t o a se cos s • Arsenic free safe water • Dietary Supplement and anti‐oxidant  fruits/vegetables/protein is important along with  application of ointment (5 – 20% Urea and salicylic) • Complicated cases like skin cancer, ulcer, gangrene needs  spec a ed ed ca a d su g ca a age e specialized medical and surgical management • Social, economic and physical rehabilitation. • Mass community awareness and support to develop Mass community awareness and support to develop community based rehabilitation system. www.ancollege.org
  • 40. MAJOR PROBLEMS OF “ARSENICOSIS”  MANAGEMENT • Lack of knowledge information and training for case Lack of knowledge information and training for case  detection and management by field workers • Poor community motivation for safe water use Poor community motivation for safe water use  complicated by physical nature of arsenic in water  (tasteless, colorless and odorless) (tasteless colorless and odorless) • Socio‐economic hazards due to ill‐conceived idea about  “Arsenicosis” “A i i” • Poor Resource allocation for rehabilitation and treatment • Indiscriminate installation of Tube‐well both private and  public sector www.ancollege.org
  • 41. Lack of Awareness •The unsafe sources (PAINTED •The unsafe sources  (PAINTED   RED) are still being used by villagers due to lack of  awareness.  villagers due to lack of awareness •Intensive awareness campaign is required in affected villages. required in affected villages www.ancollege.org
  • 43. Arsenic mitigation strategies and sustainability Options Pond Rainwater harvesting g Dug well g Water source Surface Rain Sub-surface Problems •Pollution •Collection •Bacterial •Accessibility •Preservation contamination •Acceptibilty A tibilt •Seasonal variabilty S l i bilt •Acceptability A t bilit Feasibility Low Low Better www.ancollege.org
  • 44. Arsenic mitigation strategies and and …………… Options Deep well Piped water Arsenic removal filters Water source Deep aquifers Deep aquifers/treated Arsenic contaminated Surface water water Problems •Uncertain •Expensive •Effectiveness? •Expensive •No infrastructure •Expensive •Environmentally problematic Feasibility Better but……. Low Better www.ancollege.org
  • 45. Most of mitigation strategies have failed in Bihar www.ancollege.org
  • 46. Results of Arsenic  Mitigation Strategies  g g REDUNDENT RAINWATER REDUNDENT RESTORED  HARVESTING UNIT  OPEN WELL DEFUNCT OVERHEAD TANK TO TAP www.ancollege.org SAFE AQUIFER 
  • 47. Rs.53 Crore GoB initiative in Bhojpur • Ganga Water to be supplied after treatment • Dependent on electric power , a scarce commodity in Bihar y • Ganga is shifting from its current location as per our studies Ganga River Piped Water Scheme launched by GoB at Bhojpur www.ancollege.org
  • 48. Sustainable arsenic mitigation technologies for rural population [possible alternatives] www.ancollege.org
  • 49. Possible alternative I: Gravity  y driven filter • G it D i Filt Gravity Driven Filter  not  t dependent on electricity • Easy to maintain • Easy to operate Easy to operate • Low cost • Quick disposal of backwash  and sludge through  and sludge through bioremediation www.ancollege.org
  • 50. Possible Alternative  II‐ TRADITIONAL DUGWELLS  PROPERLY SANITIZED [Project Well Initiative] PROPERLY SANITIZED [Project Well Initiati e] Courtesy :Project www.ancollege.org Well- Dr .Meera H. Smith, USA Project Well_MMS_June 2009
  • 51. Interior of the dugwell The pvc pipe is  shortened after  insertion The delivery pipe is flexible for self  The delivery pipe is flexible for self adjustable water level  Courtesy :Project Well- Dr. Meera H. Smith,USA
  • 52. The net and the tin cover  are used for protection from  external debris and  tampering. www.ancollege.org
  • 53. There are 112  PROJECT  WELL DUGWELLS as of  2009 in  N24 PARGANAS, WEST BENGAL, INDIA 2009 in N24 PARGANAS WEST BENGAL INDIA Courtesy www.ancollege.org :Project Well- Dr.Meera H. Smith
  • 54. Possible alternative III: In Situ Arsenic Treatment [TiPOT technology of Queen's University Belfast, UK] Shower Head Sh H d Rangapur, Nilgunj ( WB) Plant Courtesy - Dr.Bhaskar Sengupta Supported by World Bank www.ancollege.org Univ. of Belfast, UK
  • 55. In Situ Arsenic Treatment……….. • In the in‐situ treatment method, the aerated tube well  water is stored in feed water tanks and released back  into the aquifers.  • The dissolved oxygen in aerated water oxidizes arsenite to less‐mobile arsenate, the ferrous iron to ferric iron  , and Manganese(II) to Manganese(III), followed by  adsorption of arsenate on Fe(III) and manganese(III) and  p ( ) g ( ) subsequent precipitation resulting in a reduction of the  arsenic content in tube well water. • Oxidation is further enhanced biologically by bacteria  living in the subsurface  living in the subsurface ‐ bioremediation www.ancollege.org
  • 56. In Situ Arsenic Treatment……. Courtesy - Dr.Bhaskar Sengupta y g Univ. of Belfast,UK www.ancollege.org
  • 57. In Situ Arsenic Treatment…………….. Courtesy - Dr.Bhaskar Sengupta www.ancollege.org Univ. of Belfast,UK
  • 58. Possible alternative IV ‐RO /nano membrane  system attached with solar power  www.ancollege.org
  • 59. UNRESOLVED ISSUES RELATING TO ARSENIC  CONTAMINATED DRINKING WATER SOURCES • Research into Arsenic speciation, mobilization largely  fragmented and repetitive • Almost entire investigation into the hydro‐geological Almost entire investigation into the hydro geological  aspects of arsenic contaminated aquifers have been  confined to Bengal basin, the geological variations along  the entire river basins warranting immediate attention. the entire river basins warranting immediate attention • Lack of knowledge and  medical infrastructure relating to   diagnosis and treatment of arsenicosis. • Lack of comprehensive database on arsenic contaminated  aquifers and its implications • Lack of maintenance and monitoring of mitigation Lack of maintenance and monitoring of mitigation  structures • Lack of Community Participation www.ancollege.org
  • 60. Vision of the Action Group p Solution  Exchange –Water Community Establishing a multi‐disciplinary, holistic  Centre of Excellence for Arsenic Studies Centre of Excellence for Arsenic Studies in the sub‐continent, that will bypass  political boundaries, and work for  comprehensive solution to the scourge comprehensive solution to the scourge of arsenic. www.ancollege.org
  • 61. Centre of Excellence for Arsenic Studies AIMS  & OBJECTIVES AIMS & OBJECTIVES • To preserve and conserve the quality of ground  water reserves in terms of Arsenic contamination. water reserves in terms of Arsenic contamination. • To prepare and maintain a comprehensive database  on all issues related to arsenic contaminated  ground water. • To provide low‐cost, local resource–based,  sustainable mitigation strategies to the rural poor t i bl iti ti t t i t th l • To provide consultancy and linkage to communities,   research organizations, NGOs &   funding agencies  research organizations NGOs & funding agencies in water sector . www.ancollege.org
  • 62. We strive for Community based C it b d YES Knowledge ! K g THANKS www.ancollege.org