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ENVIRONMENTAL POLLUTION
Assoc. prof. Jānis Zaļoksnis
2
Environmental pollution and degradation can be caused by
chemical substances, physical factors or the development of
undesirable living organisms.
The past, present and potential global threat of environmental pollution and
degradation is one of the main factors that has an effect on the formation of
society’s environment.
Environmental degradation means that the environment becomes
unusable for its designed purposes or that the development of living
organisms and their communities in the environment is disturbed.
Pollutant is any substance released into the environment as a result of
human activity or natural processes that has an adverse impact on living
organisms.
PEOPLE – ENVIRONMENT - POLLUTION
3
Life on the Earth is fragile, and every living being can
continue to live only in the environmental conditions
optimal for its life.
Factors which can influence living
organisms and life itself:
Natural factors Anthropogenic factors
Rise
or fall of temperature above
or below the optimum
Intensive flow of
electromagnetic
radiation
Chemical
substances
Depletion of
needed
nutrients
Any chemical, biological or physical factor is
called toxic if it causes an adverse biological
reaction.
4
Different substances or factors have
different effects:
Chemicals Biological factors
Pollutants,
for example,
pesticides.
Physical factors
Rise
or fall of
temperature.
Ionising
radiation.
Development of
the undesirable
living forms.
In the case of environmental
degradation:
creation of the
unfavourable conditions for living
organisms
limits for development of the
organisms and their
communities
5
Environmental degradation as a soil erosion
due to over-grazing
ENVIRONMENTAL DEGRADATION
Pollution of the environment by chemical substances can be classified depending on the properties
and structure of these substances.
Environmental contamination with metals or their compounds (Cu, Pb, Co, Hg and others) and
toxic trace elements (F, B, As, Se and others) can be marked out first.
6
Oxidizing
agents
Irritant
(kairinošs)
Flammable
substances
Toxic
substances
Harmful for
environment
Corrosive
mordant
Explosives
DANGEROUS CHEMICAL SUBSTANCES
Dangerous Substances Directive 67/548/EEC
7
Produced by synthesis or as by-
products in the process of
production of other substances.
Toxic substances:
Naturally occurring Human-made (xenobiotic)
Plant’s toxins,
poisons
Toxic substances
All toxic substances are hazardous,
but not all hazardous substances are toxic.
8
Pollutants :
Metals and
their
compounds
Toxic micro-
elements
Organic
pollutants
Chemically inert compounds in a
state of fine particles can also
contaminate the environment
Cu, Pb,
Co, Hg
etc.
F, B, As,
Se etc.
pesticides,
industrial by-
products
etc.
dust and aerosols in the air
and suspensions in water
Environmental pollution
with POP’s :
by destruction of the
products, used in
households
by use pesticides and
other plant’s
protection chemicals
by industrial (chemical)
production
The environmental pollution threat increases if the organic substances that
have been released into the environment are persistent (Persistent Organic
Pollutants – POP), i.e., if they remain there for a long period of time
(even several decades in the soil).
9
POP’s are pesticide DDT, dioxins,
polychlorinated biphenyls and others.
Persistent Organic Pollutants
10
All kinds of chemical
compounds are increasingly
released into the
environment
approximately 10 million known chemical
substances, and a large part of them do
not exist in the natural environment
approximately 120 000 industrially produced
chemical compounds
widely used and 10 000 substances produced in the
amounts exceeding 500 kg per year
the number of types of industrially produced substances is
increasing from approximately one to three thousand new ones
every year
CHEMICAL COMPOUNDS IN THE ENVIRONMENT
11
Registration, Evaluation, Authorisation and Restriction of Chemicals
(EC) No 1907/2006
REACH
REACH is a EU Regulation of 18 December 2006. REACH addresses the production and use of chemical
substances, and their potential impacts on both human health and the environment.
Its 849 pages took seven years to pass, and it has been described as the most complex legislation in the Union's
history and the most important in 20 years.
It is the strictest law to date regulating chemical substances and will affect industries throughout the world.
European Chemicals Agency headquarters
in Annankatu, Helsinki.
The European Chemicals Agency has set three major deadlines for
registration of chemicals. In general these are determined by tonnage
manufactured or imported, with 1000 tonnes/a. being required to be
registered by 1 December 2010, 100 tonnes/a. by 1 June 2013 and 1
tonne/a. by 1 June 2018. In addition, chemicals of higher concern or
toxicity also have to meet the 2010 deadline.
REACH requirement is to communicate information on chemicals up and down the supply chain. This ensures that
manufacturers, importers and also their customers are aware of information relating to health and safety of the
products supplied. For many retailers (mazumtirgotājs) the obligation to provide information about substances in
their products within 45 days of receipt of a request from a consumer is particularly challenging. Having detailed
information on the substances present in their products will allow retailers to work with the manufacturing base to
substitute or remove potentially harmful substances from products. The list of harmful substances is continuously
growing and requires organizations to constantly monitor any announcements and additions to the REACH scope.
This can be done on the European Chemicals Agency 's website.
12
Chemistry is the science of chemical elements and compounds
Volatile Organic Compound (VOC)
Emission Sources:
Paints
Varnishes (lakas)
Moth balls (kožu tabletes)
Solvents
Gasoline
Newspaper
Cooking
Cleaning chemicals
Vinyl fluors
Carpets
Photocopying
Upholstery (polsteri) fabrics
Adhesives (līmvielas)
Sealing caulks (tepe)
Cosmetics
Airf fresheners
Fuel oil
Vehicle exhaust
Pressed wood furniture
Tobacco smoke
VOC by products:
Benzene
Toluene
Methylene chloride
Formaldehyde
Xylene
Ethylene glycol
Texanol 1,3-butadiene
13
Environment degradation
factors :
 electromagnetic radiation
 noise pollution
 thermal pollution
• infectious agents
• parasites
• living organisms whose
metabolism or decay products
are harmful to humans or other
living organisms
Physical factors Biological factors
The quality of the environment
Air is one of the essential factors making life on the Earth possible.
Depending on the body constitution, a human being consumes 6–13
cubic metres of air daily or even more in cases of heavy physical loads.
14
Consequently, trace amounts of harmful
substances in the air may have an
adverse effect on the human health.
Pollutants spread rapidly and to far distances in the atmosphere;
therefore, the problem of atmospheric pollution should be dealt with
on a global scale, and international cooperation is vital in this
regard.
Air cleanness in dwelling premises and working environment is a
special air pollution problem because today people become
increasingly exposed to hazardous and toxic substances at home or
work.
AIR POLLUTION
Industrial pollution mostly occurs in the industrially developed
regions of North America, Europe and Asia.
15
The main sources of anthropogenic
pollution that also affect the quality of
air are :
transport
industrial
production
agriculture
energy
production,
heating
SOURCES OF ANTHROPOGENIC
POLLUTION OF AIR
16
THE MAIN AIR
POLLUTANTS
ARE:
sulphur compounds
nitrogen compounds
carbon compounds
halogenated organic substances
metals and their compounds
aerosols and dust
radioactive elements
Both industrial processes and heating contributes to air pollution.
Incineration of household waste pollutes air significantly.
Air pollution in the human living environment – living rooms and
workplaces – are affect the human health considerably.
17
Room ventilation also affects the air pollution level.
Ventilation should be balanced with the need to maintain the
optimum temperature in dwelling premises.
Main sources of the indoor air pollution
kitchens stoves furniture domestic
animals
painted
surfaces
polymers
Indoor air pollution
18
Piesārņojošā viela Vielas avots
Formaldehyde
NO2
CO
Polyaromatic hydrocarbons
SO2
Cl2
volatile organic compound
aerosols or dust
Microorganisms, virus
Radon
Plates of wooden chips, smoking, insulating materials,
natural gas heating systems
Stoves, exhaust gases from road transport
Burning of the timber, coal, petrol
Burning of the fuel
Burning of the timber, coal, petrol
Bleach (whitener), chlorinated water
Paints, households' chemistry, polymers
Burning of the fuel, food cooking, insulating materials,
carpets and mats, smoking
Mould (pelējuma sēnītes), domestic animals
Buildings, soil, water
Typical pollutants in living environment:
19
Water is considered to be polluted if certain substances or physical
factors affect the quality of water and functioning of ecosystems and, as
a result, the use of water for particular purposes is restricted.
Classification of the water
pollution sources:
point source
pollution
non-point source
pollution
WATER POLLUTION
20
pipes for draining treated or untreated urban
or factory wastewater into reservoirs, rivers,
lakes and seas
agricultural wastewater
oil and oil product pipelines
Point source pollution are:
Point source pollution
21
Non-point water pollution sources are dissipated, and it is much
more difficult to identify and assess them.
Typical non-point
pollution sources are:
fallout of substances with precipitation
surface runoff from building areas
runoff from abandoned and active mining sites and
quarries
runoff from agricultural fields
drainage from landfills
NON-POINT SOURCE POLLUTION
22
The main aquatic environment
pollutants are:
Inorganic substances Organic substances Physical factors
 Biogenic elements
 Inorganic salts
 Toxic
microelements
 Radionuclide's etc.
 Biologically degradable
substances
 Oil products
 Pesticides
 Surface active substances etc.
 Radiation etc.
Pollution of natural waters
23
Pollution of natural waters with crude oil, oil
products and other persistent substances is
particularly hazardous.
POP’s can be
divided:
plant protection products – pesticides (aldrin, DDT,
dieldrin, endrin, hexachlor benzene, hepta chlor,
chlordane, mirex, toxaphen)
by-products (polychlorinated dibenzo-p-dioxins,
poly-chlorinated dibenzofurans, polyaromatic
hydrocarbons) of production processes
chemical products for industrial use
(hexachlor benzene, polychlorinated biphenyls)
Persistent organic pollutants (POP’s) have a special place among these
hazardous substances.
24
Chemical substances at
different oxidation degree and
forms, taking into account their
exclusive role for guarantee of
the life processes in water bilges
The aquatic environment pollutants are
nutrients, inter alia, nitrogen and
phosphorus compounds:
Nitrogen
compounds
Inorganic (PO4
3-,
HPO4
2-, H2PO4
-,
poly-phosphate
ions) and organic
compounds
Inorganic ions
(NH4
+, NO2
+, NO3
-)
and organic
compounds
Phosphorus
compounds
Iron
compounds
Silicon
compounds
Nutrients to come into waters with atmospheric
precipitation, wastewater and surface run-off.
Overgrown part oo the river Lielupe between Bauska and
Mežotne
Larger or lesser amounts of nutrients enter surface waters all the time, and they
provide the necessary conditions for the formation of organic substances in aquatic
organisms using energy from sunlight.
These are photosynthesising plants and include different algae, higher aquatic plants –
such as reeds, rush, pondweed, duckweed and others – as well some bacteria.
25
If the inflow of substances
containing nutrients increases, their
concentration in water increases
too, in effect boosting the growth of
plants, mostly algae, thus
increasing the overall live mass of
aquatic organisms.
This process is called
eutrophication (from the Greek –
eu- ‘well’ + trophe –
‘nourishment’ = ‘well nourished’).
Eutrophication of the water
26
The main nutrients found in waters, considering their significance for the life
processes in water bodies, are the following: nitrogen compounds – inorganic ions
(NH4
+, NO2
-, NO3
-) and organic compounds; phosphorus compounds – inorganic
(PO4
3-, HPO4
2-, H2PO4
-, polyphosphate ions) and organic compounds; and iron and
silicon compounds in different forms and oxidation stages.
algae thrive, making the water cloudy, so that you
cannot see through it deeper than 0.5 m
Signs indicate that an intensive eutrophication
process is in taking place in water:
rocks and plants have periphyton and
filamentary algae on them
fish are choking even in summer and under ice
in winter
gas bubbles come to the surface from
rotting plants and animal remains
Visual signs Other signs
abundance of nutrients
concentration of oxygen in water
decreases oxygen can be absent
in deeper water layers
animal species adapted to living
in clean, nutrient-poor water – for
example, the salmon fish family –
die out
Eutrophication
27
Pollutants quite often penetrate soil, affecting the organisms that
live there.
However, the effect of the presence of pollutants in soil or the
lithosphere on both terrestrial animals and ecosystems is much
more considerable as these substances accumulate
in food chains.
The mobile component of the soil environment – water, or, more
exactly, the underground water – can disperse the pollutants quite
quickly.
The soil and lithosphere environmental pollution concentrates at its
outlets yet can quickly dissipate, and it intensively interacts with the
soil-forming rocks.
SOIL POLLUTION
28
Typical
pollutants of the EU cities and
soils of industrial use:
Organic compounds
• Polyaromatic hydrocarbons
• Halogenorganic substances
• Oil products
• Phenols
• Cyanides
Inorganic compounds
 Radioactive elements
 Heavy metals
 Toxic microelements
The soil environment and the food depends on the soil
composition. Consider, for example, such a trace element as
selenium – its shortage or excess in human food may cause
specific diseases.
SOIL POLLUTANTS
29
Soil contamination in Europe after the Chernobyl nuclear disaster
After the nuclear reactor accident, the fallout of radioactive isotopes (as seen in the 137Cs example)
occurred for the most part in the region of the accident site, whereas a significant part of radioactive
elements was carried away with air masses and reached even the Scandinavian countries.
Global environmental
pollution caused :
Depletion of the ozone
layer
Global warming
30
GLOBAL ENVIRONMENTAL POLLUTION PROBLEMS
Ozone (O3) is one of the oxygen molecule forms composed of
three interconnected oxygen atoms.
Ozone is a pale blue gas that has a higher density than air.
Ozone is formed when energy – for example, electromagnetic
radiation – splits the oxygen molecules. As a chemical
substance, ozone is a powerful oxidant.
31
The presence of ozone in the atmosphere, its formation and
disintegration reactions are vital for the absorption of the UV
radiation from the Sun.
EARTH’S OZONE LAYER AND THE CONSEQUENCES OF ITS DEPLETION
The ozone concentration near the Earth’s surface is ~0.001% by volume,
whereas in the stratosphere its concentration may be even more than 100
times higher.
The ozone layer is thickest at the height of 25–30 kilometres in
equatorial regions and 15 – 20 kilometres around the Earth’s poles.
32
The ozone layer (its thickness in the atmosphere under normal
conditions is approximately 2.5 mm if only the dispersed ozone
molecules were gathered together) protects the biosphere from the
ultraviolet part of the solar radiation spectrum.
season
Factors affecting the
concentration of ozone:
the movement of air
masses
natural and anthropogenic
processes
geographical
latitude
activity of the Sun
SIGNIFICANCE OF THE OZONE LAYER
UV radiation is absorbed during the ozone molecule formation process,
and the new ozone molecule also is capable of absorbing it.
At the same time, UV radiation that has a shorter wavelength (and higher
energy) splits the ozone molecules.
As a consequence, the concentration of ozone is decreasing in the upper
layers of the atmosphere.
33
In the first stage of ozone molecule synthesis, an oxygen
molecule is excited by absorbing the UV radiation energy. The
excited oxygen molecule splits into two oxygen atoms that are
free to react with another oxygen molecule to form an ozone
molecule.
Ozone molecule formation
34
Ozone molecule formation
OZONE CYCLE
Three forms of oxygen are involved in the ozone-oxygen cycle: oxygen atoms (O or atomic oxygen),
oxygen gas (or diatomic oxygen), and ozone gas (or tri-atomic oxygen). Ozone is formed in the
stratosphere when oxygen molecules photo-dissociate after absorbing an ultraviolet photon whose
wavelength is shorter than 240 nm.
This converts a single into two atomic oxygen ions. The atomic oxygen ions then combine with separate
molecules to create two molecules. These ozone molecules absorb UV light between 310 and
200 nm, following which ozone splits into a molecule of and an oxygen atom. The oxygen atom then
joins up with an oxygen molecule to regenerate ozone. This is a continuing process which terminates
when an oxygen atom "recombines" with an ozone molecule to make two molecules.
O + O3 → 2 O2
The overall amount of ozone in the stratosphere is determined by a balance between photochemical
production and recombination.
Ozone can be destroyed by a number of free radical catalysts, the most important of which are the
hydroxyl radical (OH·), the nitric oxide radical (NO·), the atomic chlorine ion (Cl-) and the atomic
bromine ion (Br -). All of these have both natural and man-made sources; at the present time, most
of the OH· and NO· in the stratosphere is of natural origin, but human activity has dramatically
increased the levels of chlorine and bromine.
These elements are found in certain stable organic compounds, especially chlorofluorocarbons (CFCs),
which may find their way to the stratosphere without being destroyed in the troposphere due to
their low reactivity. Once in the stratosphere, the Cl and Br atoms are liberated from the parent
compounds by the action of ultraviolet light, e.g.
CFCl3 + electromagnetic radiation → CFCl2+ Cl
The Cl and Br atoms can then destroy ozone molecules through a
variety of catalytic cycles. In the simplest example of such a
cycle, a chlorine atom reacts with an ozone molecule, taking an
oxygen atom with it (forming ClO) and leaving a normal oxygen
molecule. The chlorine monoxide (i.e., the ClO) can react with a
second molecule of ozone (i.e., ) to yield another chlorine atom
and two molecules of oxygen. The chemical shorthand for these
gas-phase reactions is:
Cl + O3 → ClO + O2
ClO + O3 → Cl + 2 O2
The overall effect is a decrease in the amount of ozone. More
complicated mechanisms have been discovered that lead to
ozone destruction in the lower stratosphere as well.
OZONE CYCLE
The atmospheric contamination with halogenated
hydrocarbons, produced in relatively large amounts, is
considered to be particularly hazardous to the
environment.
Halogenated hydrocarbon molecules are composed of carbon, hydrogen
and halogen (F, Cl, Br, I) atoms. Those halogenated hydrocarbons whose
molecules contain one or two carbon atoms and have their remaining
hydrogen atoms replaced by fluorine or chlorine atoms are called freons.
37
MAIN SUBSTANCES THAT AFFECT THE OZONE LAYER
The lifetime of freons in the atmosphere is from 29 to 500 years. After
entering the stratosphere, freons interact with UV radiation, releasing
chlorine or fluorine atoms that can subsequently become involved in
ozone degradation reactions.
FREONS
Considering the wide range of industrial use of freons,
their production in industrial quantities began in the
30s of the 20th century.
Initially freons were used as a replacement for such
hazardous and toxic gases as ammonia (NH3) and
sulphur dioxide (SO2) in refrigerators.
Since freons had low toxicity and were non-
combustible, they were found useful in a wide range
of other applications as well.
At the end of the 1980s, the total production amount
of freons reached 1.2 million tons per year.
39
Freons are emitted into the
environment as a result of:
after use of
products (e.g.,
aerosols)
technological
processes (e.g.,
microchip cleaning)
specific features of
technological processes
(e.g., refrigeration
systems)
SOURCES THAT AFFECT THE OZONE LAYER
Main freons that affect the ozone layer.
Principal CFCs
Systematic name
Common/trivial
name(s), code
Boiling
point
(°C)
Formula
Trichloro fluoromethane Freon-11, R-11, CFC-11 23 CCl3F
Dichlorofluoromethane Freon-12, R-12, CFC-12 −29.8 CCl2F2
Chlorotrifluoromethane Freon-13, R-13, CFC-13 −81 CClF3
Chlorodifluoromethane R-22, HCFC-22 −40.8 CHClF2
Dichlorofluoromethane R-21, HCFC-21 8.9 CHCl2F
Chlorofluoromethane Freon 31, R-31, HCFC-31 CH2ClF
Bromochlorodifluoromethane
BCF, Halon 1211, H-1211,
Freon 12B1
CBrClF2
40
Profile of the ozone hole over the Antarctic
(ozone concentration in Dobson units)
The reduction of the ozone
concentration (the ozone layer
depletion) was observed for the first
time over the Antarctic, where natural
processes initiate an especially
intensive breakdown of ozone
molecules.
At the beginning of the 1970s, the
size of the Antarctic ozone hole was
a few million square kilometres, while
now it exceeds 25 million square
kilometres.
The ozone concentration in the atmosphere is expressed in
gas concentration units of measure (mg/m3, μg/m3) or in a
special unit of measure called the Dobson unit (DU) in
honour of Gordon Miller Bourne Dobson, who was one of
the first scientists studying the atmospheric ozone.
One Dobson unit is a 0.01 mm thick ozone layer under
standard temperature and atmospheric pressure.
OZONE HOLE
Tierra del Fuego
41
The depletion of the ozone layer and increase in the intensity of UV radiation reaching the Earth’s
surface have far-reaching consequences.
Diminishing the negative effects of UV radiation has become one of the central objectives of
environmental protection policy.
Suntan has for a long time been regarded as a sign of a healthy lifestyle and good health in general.
However, today views about the healthfulness of sunbathing have radically changed. The production
and use of various sunscreen cosmetic products and sunglasses that protect the skin and the eyes
from UV radiation has been increasing.
Chlorine atoms and radicals take part in reactions with
nitrogen compounds producing active substances
(ClONO2, HCl, HClO), which bring to destruction of
ozone molecules and ozone layer.
In winter air masses in Antarctic are isolated, but temperature fall down to
-85 °C. At such conditions nitrogen oxides in atmosphere under reaction
with water vapour produce nitric acid, which molecules operate as vapour
condensation centres.
DEPLETION OF THE OZONE LAYER
The depletion of the ozone layer by 5% will substantially increase the
intensity of UV-B and UV-C radiation reaching the Earth’s surface.
42
UV radiation is divided into three
radiation ranges with different
wavelengths according to its
biological effect:
UV-C (wavelength <290 nm)
UV-A ( = 320-400 nm)
UV-B ( = 290-320 nm)
Thickness of the ozone layer might
affect :
mortality rate from malignant
skin diseases will increase by
20%.
the agricultural production
the immune system
reproduction of living
organisms in the
World Ocean -
plankton
Threats by ozone layer changes
To a considerable extent, the legislation restricting the ozone layer depletion
had laid the foundations for further development of an effective environmental
law system. The environmental legislative acts drafted for the purpose to
restrict the use of substances that destroy the ozone layer provide for various
activities carried out on an international level, such as the ozone layer study
and monitoring, phasing out the production of these substances,
compensations to developing countries for the losses incurred due to the high
costs of alternative technologies.
43
Several legislative acts have been adopted with the aim to reduce the
destructive effects of pollution on the ozone layer. The drafting of
legislation pertaining to the ozone layer protection began in 1985.
The most important international treaty in this regard is the Montreal
Protocol on Substances That Deplete the Ozone Layer (a protocol
to the Vienna Convention of 1985 for the Protection of the Ozone
Layer) designed to restrict the production of these substances.
Protection of the ozone layer
Ozone hole in Arctic
Ozone layer in Arctic reduced by 40 % in April 2011. It is almost as in Antarctic, where
depletion level is 50 – 60 %.
Concentration of ozone has been les as 250 Dobson units 27 days
and less as 230 Db – one weak.
45
Ozone-depleting gas trends
Climate is expressed in averaged long-term atmospheric physical parameter
values characteristic of the Earth as a whole (global climate) or of a specific
territory (a country or region).
Like many other issues relating to climate change, the extent and character of
human influence on climate are still studied and analysed, but there is no doubt
that human activities do influence climate.
46
Climate is the statistical summary of weather and meteorological
phenomena and occurrences over a long period of time, ranging from a
few years or decades to thousands of years.
Climate is dependent of :
sun radiation annually and
by seasons
circulation of the
atmosphere
Earth surface
Climate
Projected rainfall changes
Mean changes in (a) precipitation (mm day-1), (b) soil moisture content (%), (c) runoff (mm day-1) and (d)
evaporation (mm day-1). Changes are annual means for the A1B scenario for the period 2080 to 2099 relative to
1980 to 1999. Soil moisture and runoff changes are shown at land points with valid data from at least 10 models.
Oil refinery in Italy Sand storm in Sahara
Pollutants, which influence regional
environment substantially:
Sulphur
compounds
Nitrogen
compounds
Dust and
aerosols
48
REGIONAL ENVIRONMENTAL POLLUTION EFFECTS
Production of the mineral
fertilizers
Forest fires
Today the main source of sulphur compounds in the
atmosphere is human economic activity.
49
Main processes by which sulphur
compounds release in environment :
Ore’s
mining
Burning of the fossil fuel
(coal, oil, peat)
Sulphur dioxide is a colourless gas with a very strong, pungent odour. It is easily liquefiable
and soluble in water, making a medium-strong acid – sulphurous acid (H2SO3). Sulphur
dioxide oxidises easily in the atmosphere, reacts with atmospheric water vapour, and
sulphuric acid solution is the end-product of these transformations. The fallout of compounds
formed as a result of sulphur dioxide oxidation occurs in the forms of rain and snow (wet
deposition) as well as dust (dry deposition).
Natural
Evaporation from
water reservoirs
Volcanic activity
Anthropogenic
Pollution with sulphur compounds
Today the emission of nitrogen oxides as well as another
environmental pollutant – ammonia – has become, overall, one of
the most hazardous environmental pollution factors in Europe.
50
Several nitrogen oxides can be present in the atmosphere as air
pollutants:
nitrogen (I) oxide N2O,
nitrogen (II),
(IV) oxides NO, NO2,
nitric acid HNO3.
Nitrogen oxides are also formed in the combustion processes of motor
vehicle engines. Intensive release of nitrogen oxides during the process
of electrical welding, especially in confined premises, is unsafe from the
viewpoint of work safety. Emitted in the stratosphere, nitrogen oxides
can participate in the ozone breakdown cycle. Supersonic aircraft
exhaust is a significant source of nitrogen oxides in the stratosphere.
Pollution with nitrogen compounds
51
Burning of the solid waste
Main sources of aerosols and
dust:
Natural Anthropogenic
Sea salts Soil Volcanoe
Forest fires
Agriculture
Industry (cement, steel)
Burning of the fossil fuel (coal,
oil, peat, timber)
Atmospheric air contains particles of every sort, size and composition. Their
sizes may vary from micron to milimetric parts. The finer particles (size
< 10 μm) are called aerosols, whereas the coarser are called dust. Liquid micro-
droplets (haze) are also counted as aerosols.
Since the effects of aerosols on humans, animals, plants and buildings can be
detrimental, and aerosols and dust can be considered, by their mass, the largest
group of atmospheric pollutants, it is crucial to limit their emission in the main
sectors responsible for this kind of pollution, namely the production and energy
industry.
DUST AND AEROSOLS
THANK YOU FOR ATTENTION !

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8.LECTURE-Environmental_pollution.ppt

  • 2. 2 Environmental pollution and degradation can be caused by chemical substances, physical factors or the development of undesirable living organisms. The past, present and potential global threat of environmental pollution and degradation is one of the main factors that has an effect on the formation of society’s environment. Environmental degradation means that the environment becomes unusable for its designed purposes or that the development of living organisms and their communities in the environment is disturbed. Pollutant is any substance released into the environment as a result of human activity or natural processes that has an adverse impact on living organisms. PEOPLE – ENVIRONMENT - POLLUTION
  • 3. 3 Life on the Earth is fragile, and every living being can continue to live only in the environmental conditions optimal for its life. Factors which can influence living organisms and life itself: Natural factors Anthropogenic factors Rise or fall of temperature above or below the optimum Intensive flow of electromagnetic radiation Chemical substances Depletion of needed nutrients
  • 4. Any chemical, biological or physical factor is called toxic if it causes an adverse biological reaction. 4 Different substances or factors have different effects: Chemicals Biological factors Pollutants, for example, pesticides. Physical factors Rise or fall of temperature. Ionising radiation. Development of the undesirable living forms.
  • 5. In the case of environmental degradation: creation of the unfavourable conditions for living organisms limits for development of the organisms and their communities 5 Environmental degradation as a soil erosion due to over-grazing ENVIRONMENTAL DEGRADATION
  • 6. Pollution of the environment by chemical substances can be classified depending on the properties and structure of these substances. Environmental contamination with metals or their compounds (Cu, Pb, Co, Hg and others) and toxic trace elements (F, B, As, Se and others) can be marked out first. 6 Oxidizing agents Irritant (kairinošs) Flammable substances Toxic substances Harmful for environment Corrosive mordant Explosives DANGEROUS CHEMICAL SUBSTANCES Dangerous Substances Directive 67/548/EEC
  • 7. 7 Produced by synthesis or as by- products in the process of production of other substances. Toxic substances: Naturally occurring Human-made (xenobiotic) Plant’s toxins, poisons Toxic substances All toxic substances are hazardous, but not all hazardous substances are toxic.
  • 8. 8 Pollutants : Metals and their compounds Toxic micro- elements Organic pollutants Chemically inert compounds in a state of fine particles can also contaminate the environment Cu, Pb, Co, Hg etc. F, B, As, Se etc. pesticides, industrial by- products etc. dust and aerosols in the air and suspensions in water
  • 9. Environmental pollution with POP’s : by destruction of the products, used in households by use pesticides and other plant’s protection chemicals by industrial (chemical) production The environmental pollution threat increases if the organic substances that have been released into the environment are persistent (Persistent Organic Pollutants – POP), i.e., if they remain there for a long period of time (even several decades in the soil). 9 POP’s are pesticide DDT, dioxins, polychlorinated biphenyls and others. Persistent Organic Pollutants
  • 10. 10 All kinds of chemical compounds are increasingly released into the environment approximately 10 million known chemical substances, and a large part of them do not exist in the natural environment approximately 120 000 industrially produced chemical compounds widely used and 10 000 substances produced in the amounts exceeding 500 kg per year the number of types of industrially produced substances is increasing from approximately one to three thousand new ones every year CHEMICAL COMPOUNDS IN THE ENVIRONMENT
  • 11. 11 Registration, Evaluation, Authorisation and Restriction of Chemicals (EC) No 1907/2006 REACH REACH is a EU Regulation of 18 December 2006. REACH addresses the production and use of chemical substances, and their potential impacts on both human health and the environment. Its 849 pages took seven years to pass, and it has been described as the most complex legislation in the Union's history and the most important in 20 years. It is the strictest law to date regulating chemical substances and will affect industries throughout the world. European Chemicals Agency headquarters in Annankatu, Helsinki. The European Chemicals Agency has set three major deadlines for registration of chemicals. In general these are determined by tonnage manufactured or imported, with 1000 tonnes/a. being required to be registered by 1 December 2010, 100 tonnes/a. by 1 June 2013 and 1 tonne/a. by 1 June 2018. In addition, chemicals of higher concern or toxicity also have to meet the 2010 deadline. REACH requirement is to communicate information on chemicals up and down the supply chain. This ensures that manufacturers, importers and also their customers are aware of information relating to health and safety of the products supplied. For many retailers (mazumtirgotājs) the obligation to provide information about substances in their products within 45 days of receipt of a request from a consumer is particularly challenging. Having detailed information on the substances present in their products will allow retailers to work with the manufacturing base to substitute or remove potentially harmful substances from products. The list of harmful substances is continuously growing and requires organizations to constantly monitor any announcements and additions to the REACH scope. This can be done on the European Chemicals Agency 's website.
  • 12. 12 Chemistry is the science of chemical elements and compounds Volatile Organic Compound (VOC) Emission Sources: Paints Varnishes (lakas) Moth balls (kožu tabletes) Solvents Gasoline Newspaper Cooking Cleaning chemicals Vinyl fluors Carpets Photocopying Upholstery (polsteri) fabrics Adhesives (līmvielas) Sealing caulks (tepe) Cosmetics Airf fresheners Fuel oil Vehicle exhaust Pressed wood furniture Tobacco smoke VOC by products: Benzene Toluene Methylene chloride Formaldehyde Xylene Ethylene glycol Texanol 1,3-butadiene
  • 13. 13 Environment degradation factors :  electromagnetic radiation  noise pollution  thermal pollution • infectious agents • parasites • living organisms whose metabolism or decay products are harmful to humans or other living organisms Physical factors Biological factors The quality of the environment
  • 14. Air is one of the essential factors making life on the Earth possible. Depending on the body constitution, a human being consumes 6–13 cubic metres of air daily or even more in cases of heavy physical loads. 14 Consequently, trace amounts of harmful substances in the air may have an adverse effect on the human health. Pollutants spread rapidly and to far distances in the atmosphere; therefore, the problem of atmospheric pollution should be dealt with on a global scale, and international cooperation is vital in this regard. Air cleanness in dwelling premises and working environment is a special air pollution problem because today people become increasingly exposed to hazardous and toxic substances at home or work. AIR POLLUTION
  • 15. Industrial pollution mostly occurs in the industrially developed regions of North America, Europe and Asia. 15 The main sources of anthropogenic pollution that also affect the quality of air are : transport industrial production agriculture energy production, heating SOURCES OF ANTHROPOGENIC POLLUTION OF AIR
  • 16. 16 THE MAIN AIR POLLUTANTS ARE: sulphur compounds nitrogen compounds carbon compounds halogenated organic substances metals and their compounds aerosols and dust radioactive elements Both industrial processes and heating contributes to air pollution. Incineration of household waste pollutes air significantly.
  • 17. Air pollution in the human living environment – living rooms and workplaces – are affect the human health considerably. 17 Room ventilation also affects the air pollution level. Ventilation should be balanced with the need to maintain the optimum temperature in dwelling premises. Main sources of the indoor air pollution kitchens stoves furniture domestic animals painted surfaces polymers Indoor air pollution
  • 18. 18 Piesārņojošā viela Vielas avots Formaldehyde NO2 CO Polyaromatic hydrocarbons SO2 Cl2 volatile organic compound aerosols or dust Microorganisms, virus Radon Plates of wooden chips, smoking, insulating materials, natural gas heating systems Stoves, exhaust gases from road transport Burning of the timber, coal, petrol Burning of the fuel Burning of the timber, coal, petrol Bleach (whitener), chlorinated water Paints, households' chemistry, polymers Burning of the fuel, food cooking, insulating materials, carpets and mats, smoking Mould (pelējuma sēnītes), domestic animals Buildings, soil, water Typical pollutants in living environment:
  • 19. 19 Water is considered to be polluted if certain substances or physical factors affect the quality of water and functioning of ecosystems and, as a result, the use of water for particular purposes is restricted. Classification of the water pollution sources: point source pollution non-point source pollution WATER POLLUTION
  • 20. 20 pipes for draining treated or untreated urban or factory wastewater into reservoirs, rivers, lakes and seas agricultural wastewater oil and oil product pipelines Point source pollution are: Point source pollution
  • 21. 21 Non-point water pollution sources are dissipated, and it is much more difficult to identify and assess them. Typical non-point pollution sources are: fallout of substances with precipitation surface runoff from building areas runoff from abandoned and active mining sites and quarries runoff from agricultural fields drainage from landfills NON-POINT SOURCE POLLUTION
  • 22. 22 The main aquatic environment pollutants are: Inorganic substances Organic substances Physical factors  Biogenic elements  Inorganic salts  Toxic microelements  Radionuclide's etc.  Biologically degradable substances  Oil products  Pesticides  Surface active substances etc.  Radiation etc. Pollution of natural waters
  • 23. 23 Pollution of natural waters with crude oil, oil products and other persistent substances is particularly hazardous. POP’s can be divided: plant protection products – pesticides (aldrin, DDT, dieldrin, endrin, hexachlor benzene, hepta chlor, chlordane, mirex, toxaphen) by-products (polychlorinated dibenzo-p-dioxins, poly-chlorinated dibenzofurans, polyaromatic hydrocarbons) of production processes chemical products for industrial use (hexachlor benzene, polychlorinated biphenyls) Persistent organic pollutants (POP’s) have a special place among these hazardous substances.
  • 24. 24 Chemical substances at different oxidation degree and forms, taking into account their exclusive role for guarantee of the life processes in water bilges The aquatic environment pollutants are nutrients, inter alia, nitrogen and phosphorus compounds: Nitrogen compounds Inorganic (PO4 3-, HPO4 2-, H2PO4 -, poly-phosphate ions) and organic compounds Inorganic ions (NH4 +, NO2 +, NO3 -) and organic compounds Phosphorus compounds Iron compounds Silicon compounds Nutrients to come into waters with atmospheric precipitation, wastewater and surface run-off.
  • 25. Overgrown part oo the river Lielupe between Bauska and Mežotne Larger or lesser amounts of nutrients enter surface waters all the time, and they provide the necessary conditions for the formation of organic substances in aquatic organisms using energy from sunlight. These are photosynthesising plants and include different algae, higher aquatic plants – such as reeds, rush, pondweed, duckweed and others – as well some bacteria. 25 If the inflow of substances containing nutrients increases, their concentration in water increases too, in effect boosting the growth of plants, mostly algae, thus increasing the overall live mass of aquatic organisms. This process is called eutrophication (from the Greek – eu- ‘well’ + trophe – ‘nourishment’ = ‘well nourished’). Eutrophication of the water
  • 26. 26 The main nutrients found in waters, considering their significance for the life processes in water bodies, are the following: nitrogen compounds – inorganic ions (NH4 +, NO2 -, NO3 -) and organic compounds; phosphorus compounds – inorganic (PO4 3-, HPO4 2-, H2PO4 -, polyphosphate ions) and organic compounds; and iron and silicon compounds in different forms and oxidation stages. algae thrive, making the water cloudy, so that you cannot see through it deeper than 0.5 m Signs indicate that an intensive eutrophication process is in taking place in water: rocks and plants have periphyton and filamentary algae on them fish are choking even in summer and under ice in winter gas bubbles come to the surface from rotting plants and animal remains Visual signs Other signs abundance of nutrients concentration of oxygen in water decreases oxygen can be absent in deeper water layers animal species adapted to living in clean, nutrient-poor water – for example, the salmon fish family – die out Eutrophication
  • 27. 27 Pollutants quite often penetrate soil, affecting the organisms that live there. However, the effect of the presence of pollutants in soil or the lithosphere on both terrestrial animals and ecosystems is much more considerable as these substances accumulate in food chains. The mobile component of the soil environment – water, or, more exactly, the underground water – can disperse the pollutants quite quickly. The soil and lithosphere environmental pollution concentrates at its outlets yet can quickly dissipate, and it intensively interacts with the soil-forming rocks. SOIL POLLUTION
  • 28. 28 Typical pollutants of the EU cities and soils of industrial use: Organic compounds • Polyaromatic hydrocarbons • Halogenorganic substances • Oil products • Phenols • Cyanides Inorganic compounds  Radioactive elements  Heavy metals  Toxic microelements The soil environment and the food depends on the soil composition. Consider, for example, such a trace element as selenium – its shortage or excess in human food may cause specific diseases. SOIL POLLUTANTS
  • 29. 29 Soil contamination in Europe after the Chernobyl nuclear disaster After the nuclear reactor accident, the fallout of radioactive isotopes (as seen in the 137Cs example) occurred for the most part in the region of the accident site, whereas a significant part of radioactive elements was carried away with air masses and reached even the Scandinavian countries.
  • 30. Global environmental pollution caused : Depletion of the ozone layer Global warming 30 GLOBAL ENVIRONMENTAL POLLUTION PROBLEMS
  • 31. Ozone (O3) is one of the oxygen molecule forms composed of three interconnected oxygen atoms. Ozone is a pale blue gas that has a higher density than air. Ozone is formed when energy – for example, electromagnetic radiation – splits the oxygen molecules. As a chemical substance, ozone is a powerful oxidant. 31 The presence of ozone in the atmosphere, its formation and disintegration reactions are vital for the absorption of the UV radiation from the Sun. EARTH’S OZONE LAYER AND THE CONSEQUENCES OF ITS DEPLETION
  • 32. The ozone concentration near the Earth’s surface is ~0.001% by volume, whereas in the stratosphere its concentration may be even more than 100 times higher. The ozone layer is thickest at the height of 25–30 kilometres in equatorial regions and 15 – 20 kilometres around the Earth’s poles. 32 The ozone layer (its thickness in the atmosphere under normal conditions is approximately 2.5 mm if only the dispersed ozone molecules were gathered together) protects the biosphere from the ultraviolet part of the solar radiation spectrum. season Factors affecting the concentration of ozone: the movement of air masses natural and anthropogenic processes geographical latitude activity of the Sun SIGNIFICANCE OF THE OZONE LAYER
  • 33. UV radiation is absorbed during the ozone molecule formation process, and the new ozone molecule also is capable of absorbing it. At the same time, UV radiation that has a shorter wavelength (and higher energy) splits the ozone molecules. As a consequence, the concentration of ozone is decreasing in the upper layers of the atmosphere. 33 In the first stage of ozone molecule synthesis, an oxygen molecule is excited by absorbing the UV radiation energy. The excited oxygen molecule splits into two oxygen atoms that are free to react with another oxygen molecule to form an ozone molecule. Ozone molecule formation
  • 35. OZONE CYCLE Three forms of oxygen are involved in the ozone-oxygen cycle: oxygen atoms (O or atomic oxygen), oxygen gas (or diatomic oxygen), and ozone gas (or tri-atomic oxygen). Ozone is formed in the stratosphere when oxygen molecules photo-dissociate after absorbing an ultraviolet photon whose wavelength is shorter than 240 nm. This converts a single into two atomic oxygen ions. The atomic oxygen ions then combine with separate molecules to create two molecules. These ozone molecules absorb UV light between 310 and 200 nm, following which ozone splits into a molecule of and an oxygen atom. The oxygen atom then joins up with an oxygen molecule to regenerate ozone. This is a continuing process which terminates when an oxygen atom "recombines" with an ozone molecule to make two molecules. O + O3 → 2 O2 The overall amount of ozone in the stratosphere is determined by a balance between photochemical production and recombination. Ozone can be destroyed by a number of free radical catalysts, the most important of which are the hydroxyl radical (OH·), the nitric oxide radical (NO·), the atomic chlorine ion (Cl-) and the atomic bromine ion (Br -). All of these have both natural and man-made sources; at the present time, most of the OH· and NO· in the stratosphere is of natural origin, but human activity has dramatically increased the levels of chlorine and bromine. These elements are found in certain stable organic compounds, especially chlorofluorocarbons (CFCs), which may find their way to the stratosphere without being destroyed in the troposphere due to their low reactivity. Once in the stratosphere, the Cl and Br atoms are liberated from the parent compounds by the action of ultraviolet light, e.g. CFCl3 + electromagnetic radiation → CFCl2+ Cl
  • 36. The Cl and Br atoms can then destroy ozone molecules through a variety of catalytic cycles. In the simplest example of such a cycle, a chlorine atom reacts with an ozone molecule, taking an oxygen atom with it (forming ClO) and leaving a normal oxygen molecule. The chlorine monoxide (i.e., the ClO) can react with a second molecule of ozone (i.e., ) to yield another chlorine atom and two molecules of oxygen. The chemical shorthand for these gas-phase reactions is: Cl + O3 → ClO + O2 ClO + O3 → Cl + 2 O2 The overall effect is a decrease in the amount of ozone. More complicated mechanisms have been discovered that lead to ozone destruction in the lower stratosphere as well. OZONE CYCLE
  • 37. The atmospheric contamination with halogenated hydrocarbons, produced in relatively large amounts, is considered to be particularly hazardous to the environment. Halogenated hydrocarbon molecules are composed of carbon, hydrogen and halogen (F, Cl, Br, I) atoms. Those halogenated hydrocarbons whose molecules contain one or two carbon atoms and have their remaining hydrogen atoms replaced by fluorine or chlorine atoms are called freons. 37 MAIN SUBSTANCES THAT AFFECT THE OZONE LAYER The lifetime of freons in the atmosphere is from 29 to 500 years. After entering the stratosphere, freons interact with UV radiation, releasing chlorine or fluorine atoms that can subsequently become involved in ozone degradation reactions.
  • 38. FREONS Considering the wide range of industrial use of freons, their production in industrial quantities began in the 30s of the 20th century. Initially freons were used as a replacement for such hazardous and toxic gases as ammonia (NH3) and sulphur dioxide (SO2) in refrigerators. Since freons had low toxicity and were non- combustible, they were found useful in a wide range of other applications as well. At the end of the 1980s, the total production amount of freons reached 1.2 million tons per year.
  • 39. 39 Freons are emitted into the environment as a result of: after use of products (e.g., aerosols) technological processes (e.g., microchip cleaning) specific features of technological processes (e.g., refrigeration systems) SOURCES THAT AFFECT THE OZONE LAYER Main freons that affect the ozone layer. Principal CFCs Systematic name Common/trivial name(s), code Boiling point (°C) Formula Trichloro fluoromethane Freon-11, R-11, CFC-11 23 CCl3F Dichlorofluoromethane Freon-12, R-12, CFC-12 −29.8 CCl2F2 Chlorotrifluoromethane Freon-13, R-13, CFC-13 −81 CClF3 Chlorodifluoromethane R-22, HCFC-22 −40.8 CHClF2 Dichlorofluoromethane R-21, HCFC-21 8.9 CHCl2F Chlorofluoromethane Freon 31, R-31, HCFC-31 CH2ClF Bromochlorodifluoromethane BCF, Halon 1211, H-1211, Freon 12B1 CBrClF2
  • 40. 40 Profile of the ozone hole over the Antarctic (ozone concentration in Dobson units) The reduction of the ozone concentration (the ozone layer depletion) was observed for the first time over the Antarctic, where natural processes initiate an especially intensive breakdown of ozone molecules. At the beginning of the 1970s, the size of the Antarctic ozone hole was a few million square kilometres, while now it exceeds 25 million square kilometres. The ozone concentration in the atmosphere is expressed in gas concentration units of measure (mg/m3, μg/m3) or in a special unit of measure called the Dobson unit (DU) in honour of Gordon Miller Bourne Dobson, who was one of the first scientists studying the atmospheric ozone. One Dobson unit is a 0.01 mm thick ozone layer under standard temperature and atmospheric pressure. OZONE HOLE Tierra del Fuego
  • 41. 41 The depletion of the ozone layer and increase in the intensity of UV radiation reaching the Earth’s surface have far-reaching consequences. Diminishing the negative effects of UV radiation has become one of the central objectives of environmental protection policy. Suntan has for a long time been regarded as a sign of a healthy lifestyle and good health in general. However, today views about the healthfulness of sunbathing have radically changed. The production and use of various sunscreen cosmetic products and sunglasses that protect the skin and the eyes from UV radiation has been increasing. Chlorine atoms and radicals take part in reactions with nitrogen compounds producing active substances (ClONO2, HCl, HClO), which bring to destruction of ozone molecules and ozone layer. In winter air masses in Antarctic are isolated, but temperature fall down to -85 °C. At such conditions nitrogen oxides in atmosphere under reaction with water vapour produce nitric acid, which molecules operate as vapour condensation centres. DEPLETION OF THE OZONE LAYER
  • 42. The depletion of the ozone layer by 5% will substantially increase the intensity of UV-B and UV-C radiation reaching the Earth’s surface. 42 UV radiation is divided into three radiation ranges with different wavelengths according to its biological effect: UV-C (wavelength <290 nm) UV-A ( = 320-400 nm) UV-B ( = 290-320 nm) Thickness of the ozone layer might affect : mortality rate from malignant skin diseases will increase by 20%. the agricultural production the immune system reproduction of living organisms in the World Ocean - plankton Threats by ozone layer changes
  • 43. To a considerable extent, the legislation restricting the ozone layer depletion had laid the foundations for further development of an effective environmental law system. The environmental legislative acts drafted for the purpose to restrict the use of substances that destroy the ozone layer provide for various activities carried out on an international level, such as the ozone layer study and monitoring, phasing out the production of these substances, compensations to developing countries for the losses incurred due to the high costs of alternative technologies. 43 Several legislative acts have been adopted with the aim to reduce the destructive effects of pollution on the ozone layer. The drafting of legislation pertaining to the ozone layer protection began in 1985. The most important international treaty in this regard is the Montreal Protocol on Substances That Deplete the Ozone Layer (a protocol to the Vienna Convention of 1985 for the Protection of the Ozone Layer) designed to restrict the production of these substances. Protection of the ozone layer
  • 44. Ozone hole in Arctic Ozone layer in Arctic reduced by 40 % in April 2011. It is almost as in Antarctic, where depletion level is 50 – 60 %. Concentration of ozone has been les as 250 Dobson units 27 days and less as 230 Db – one weak.
  • 46. Climate is expressed in averaged long-term atmospheric physical parameter values characteristic of the Earth as a whole (global climate) or of a specific territory (a country or region). Like many other issues relating to climate change, the extent and character of human influence on climate are still studied and analysed, but there is no doubt that human activities do influence climate. 46 Climate is the statistical summary of weather and meteorological phenomena and occurrences over a long period of time, ranging from a few years or decades to thousands of years. Climate is dependent of : sun radiation annually and by seasons circulation of the atmosphere Earth surface Climate
  • 47. Projected rainfall changes Mean changes in (a) precipitation (mm day-1), (b) soil moisture content (%), (c) runoff (mm day-1) and (d) evaporation (mm day-1). Changes are annual means for the A1B scenario for the period 2080 to 2099 relative to 1980 to 1999. Soil moisture and runoff changes are shown at land points with valid data from at least 10 models.
  • 48. Oil refinery in Italy Sand storm in Sahara Pollutants, which influence regional environment substantially: Sulphur compounds Nitrogen compounds Dust and aerosols 48 REGIONAL ENVIRONMENTAL POLLUTION EFFECTS
  • 49. Production of the mineral fertilizers Forest fires Today the main source of sulphur compounds in the atmosphere is human economic activity. 49 Main processes by which sulphur compounds release in environment : Ore’s mining Burning of the fossil fuel (coal, oil, peat) Sulphur dioxide is a colourless gas with a very strong, pungent odour. It is easily liquefiable and soluble in water, making a medium-strong acid – sulphurous acid (H2SO3). Sulphur dioxide oxidises easily in the atmosphere, reacts with atmospheric water vapour, and sulphuric acid solution is the end-product of these transformations. The fallout of compounds formed as a result of sulphur dioxide oxidation occurs in the forms of rain and snow (wet deposition) as well as dust (dry deposition). Natural Evaporation from water reservoirs Volcanic activity Anthropogenic Pollution with sulphur compounds
  • 50. Today the emission of nitrogen oxides as well as another environmental pollutant – ammonia – has become, overall, one of the most hazardous environmental pollution factors in Europe. 50 Several nitrogen oxides can be present in the atmosphere as air pollutants: nitrogen (I) oxide N2O, nitrogen (II), (IV) oxides NO, NO2, nitric acid HNO3. Nitrogen oxides are also formed in the combustion processes of motor vehicle engines. Intensive release of nitrogen oxides during the process of electrical welding, especially in confined premises, is unsafe from the viewpoint of work safety. Emitted in the stratosphere, nitrogen oxides can participate in the ozone breakdown cycle. Supersonic aircraft exhaust is a significant source of nitrogen oxides in the stratosphere. Pollution with nitrogen compounds
  • 51. 51 Burning of the solid waste Main sources of aerosols and dust: Natural Anthropogenic Sea salts Soil Volcanoe Forest fires Agriculture Industry (cement, steel) Burning of the fossil fuel (coal, oil, peat, timber) Atmospheric air contains particles of every sort, size and composition. Their sizes may vary from micron to milimetric parts. The finer particles (size < 10 μm) are called aerosols, whereas the coarser are called dust. Liquid micro- droplets (haze) are also counted as aerosols. Since the effects of aerosols on humans, animals, plants and buildings can be detrimental, and aerosols and dust can be considered, by their mass, the largest group of atmospheric pollutants, it is crucial to limit their emission in the main sectors responsible for this kind of pollution, namely the production and energy industry. DUST AND AEROSOLS
  • 52. THANK YOU FOR ATTENTION !

Hinweis der Redaktion

  1. http://www.nasa.gov/images/content/115334main_image_feature_329_ys_full.jpg (Creative Commons) http://www.flickr.com/photos/dnorman/251646154/sizes/l/ (Creative Commons)
  2. http://www.flickr.com/photos/plant-trees/2175300153/sizes/o/ (Creative Commons)
  3. Attēli no teksta
  4. http://www.flickr.com/photos/ifdcphotography/4626396719/sizes/o/in/photostream (Creative Commons) http://www.flickr.com/photos/the_justified_sinner/4222602559/sizes/l/ (Creative Commons)
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  7. Attēla autors I.Druvietis
  8. Attēls sagatavots, izmantojot Atlas of Caesium Deposition on Europe after the Chernobyl Accident&quot;, EUR report nr. 16733, EC, Office for Official Publications of the European Communities, Luxembourg
  9. http://www.flickr.com/photos/bestrated1/205117457/sizes/o/ (Creative Commons)
  10. www.esa.int/esaCP/GGG11ITZ0GC_FeatureWeek_0.html
  11. Attēla autors © Valeria73 - Fotolia.com, http://www.fotolia.com/id/10548534 http://www.flickr.com/photos/western_sahara_project/2958913405/sizes/o/
  12. http://thumbs.dreamstime.com/thumb_457/125990154575jHS4.jpg