Nano batteries are batteries fabricated using nanotechnology. They have electrodes made of nanomaterials which allows lithium ions to move faster between electrodes during charging and discharging compared to conventional lithium-ion batteries. This enables nano batteries to charge and discharge more quickly. Additionally, the use of nanomaterials prevents the formation of a solid electrolyte interface barrier that conventional batteries experience at high temperatures. Nano batteries could potentially be used in applications like electronics, defense, aerospace, industrial, and healthcare due to their faster charging capabilities and ability to operate at higher temperatures than conventional lithium-ion batteries.
2. INTRODUCTION
Evolution of Nano batteries
DEFINITION
Batteries that are fabricated employing technology at
the nanoscale.
3. Lithium Ion Battery Basics
Electrochemical performance is determined by properties of the anode and cathode
materials.
Currently, carbon is used as the anode material.
Li Ion Discharge
Electrolyte Cathode
Charge battery (lithiation): large volume expansion 200-400% LiM
Discharge battery (delithiation): volume contraction
xLi+ + xe- + M ↔ charge Lix
+M-Anode
Li Ion
Charge
4. Fabrication and Measurement
Si NWs were synthesized using the VLS process on stainless steel
substrates using Au catalyst.
The electrochemical properties were evaluated under an argon
atmosphere by both cyclic voltammetry and galvanostatic cycling in
a three electrode configuration, with the Si NWs on the stainless
steel substrate as the working electrode and Li foil as both
reference and counter-electrodes.
8. Li-Ion Battery:
Drawback : The battery cannot be charged
at temperatures before 320 F.
Reason : Due to the formation of solid
electrolyte interface barrier.
9. Nano Battery:
Advantage : Electrode is made up of
nanomaterial.
Result : No formation of solid electrolyte
interface barrier.
10. Mechanism of Nano Battery
Anode
Li+ Li+
Li+ Li+
Li+ Li+
Cathode
Li+
Li+
Li+
Li+
Charger
Current
Separator
Electrolyte
(Polymer battery: gel polymer electrolyte)
11. Li-Ion Battery:
Drawback : These batteries are slow to
charge and discharge.
Reasons :
• Due to the long distance Li-ions have to travel
through the electrode material in the battery.
• Speed at which the Li-ions make their way
through the electrode material is also slow.
12. Nano Battery:
Advantage : Electrode particles are non-structured.
Result :
• Shortens the existing distance with in the
electrode material.
• Accelerates the recharging and discharging
rate.
13. Applications of Nano Battery
The Nanotechnological Batteries make every thing possible from a hybrid
vehicle capable of giving 150 miles/gallon to battery powered fabrics which
enables soldiers to plug electronic devices into their uniform.
The nanobatteries to be more specific has the potential to be used in the
following fields:
Electronics
Defense
Aerospace
Industrial
Health care sectors
14. Research and Development
At University of Tulsa
Under Dr Dale Teeters from the Dept of
Chemistry and Biochemistry.
15. Nano Battery:
Anode : Vanadium Oxide
Cathode : Graphite
Electrolyte : A wax solution of PEO and
lithium triflate.
16. Charging and Testing
Atomic force microscope
AC Impedance