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PLASMA FINISHING OF
POLYESTER FABRICS FOR
IMPROVING
HYDROPHILICITY
VIVEK YADAV
9457631264
TEXTILE CHEMISTRY
NITRA TECHNICAL CAMPUS
vivekntcgzb@gmail.com
INTRODUCTION
 Plasma – defined as the “4th state of matter”
 Found in the universe as Solar coronas,
lightning bolts and nuclear fusion
CLASSIFICATION OF PLASMA
 Hot-temperature plasma ( about100 million °C)
 Low-temperature ( ≈ near 50 °C - used for textile
applications)
 Low pressure
 Atmospheric pressure
 Plasma find its application in semiconductor
microchip manufacturing, in automotive and
aerospace industries and so on.
 From the past decade, textile chemical processing
industry has become more interested in plasma
applications as a novel finishing technology .
WHY PLASMA ?
Advantages of Plasma
 Environmental friendly technique : because of the
low energy consumption, the fact it is a dry
technique (no additional drying step), no waste
disposal problem and disposal cost.
 Operator friendly technique : no chemical
products, gases, etc.
 No substrate damage or bulk property changes
APPLICATION OF PLASMA IN
TEXTILE
 Desizing
 Wettability enhancement
 Water/soil-repellency
 Printability
 Dyeability
 Shrink-resistance
 Adhesion enhancement
 Sterilization, etc.
PLASMA SYSTEMS FOR TEXTILES
 Low-pressure plasma systems
 Atmospheric Pressure Plasma Systems
1. Continuous plasma processing
2. Semi-continuous plasma processing
3. Roll - to - Roll Plasma processing
Atmospheric Pressure Plasma Systems
 Corona discharge
 Dielectric barrier discharge (DBD)
 Atmospheric plasma glow discharge
PLASMA –SUBSTRATE
INTERACTION
Cleaning
Activation
Deposition
Grafting
PRINCIPLE OF PLASMA
APPLICATION TO TEXTILE
HYDROPHILICITY
ENHANCEMENT OF POLYESTER
(PET) FABRICS
 Plasma treatment in oxygen containing gas.
 Introduces various functional groups (–CO-, -C=O,
-COOH, -C-O-O-, O-COO- ) on the surface.
 Water (H2O) and H2O2 plasmas introduces alcohol and
carboxylic acid groups inducing hydrophilicity.
 But “Ageing” is the problem associated with those kind
of plasma treatments
 Plasma graft polymerization - acrylic acid, nitro
compounds, 2-hydroxyethyl methacrylate, methyl
methacrylate, acrylamide and acrylonitrile.
MECHANISMS OF SURFACE
MODIFICATION
Etching and Re-deposition
SEM image of
treated PET
SEM image of
untreated PET
Chain Scission and Functionalization
 Ion bombardment into substrate surface during
exposure to atmospheric plasma introduces chain
scission of molecules on the substrate’s surface
EFFECT OF PLASMA TREATMENT
ON HYDROPHILICITY OF PET
Effect of treatment time and power on moisture
content of PET fabric (at 40 % RH) [Bhat et al.]
Contact Angle Measurement of Plasma Treated
PET Films [Jerome et al]
Weight Loss (%) of Plasma Treated PET Films with
Different Storage Conditions (He/O2: He flow rate =
12 lpm) [Jerome et al]
Water contact angle of a PET film as a function of treatment
time for different operating pressures and for different gas
flow rate between the electrodes [Morent et al]
PLASMA MACHINERY
MANUFACTURES
 Europlasma, Belgium
 Unitex S.P.A., Italy
 4thstate Inc., U.S.A.
 APJet Inc., U.S.A.
 Enercon Industries Corporation, U.S.A.
CONCLUSION
Plasma can be an interesting alternative or
solution with described advantages of being
environmental and operator friendly, dry and
complete controllable. Therefore, plasma knows a
growing market.
THANK YOU

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Plasma finishing of poyester fabrics for improving hydrophilicity

  • 1. PLASMA FINISHING OF POLYESTER FABRICS FOR IMPROVING HYDROPHILICITY VIVEK YADAV 9457631264 TEXTILE CHEMISTRY NITRA TECHNICAL CAMPUS vivekntcgzb@gmail.com
  • 2. INTRODUCTION  Plasma – defined as the “4th state of matter”  Found in the universe as Solar coronas, lightning bolts and nuclear fusion
  • 3. CLASSIFICATION OF PLASMA  Hot-temperature plasma ( about100 million °C)  Low-temperature ( ≈ near 50 °C - used for textile applications)  Low pressure  Atmospheric pressure
  • 4.
  • 5.  Plasma find its application in semiconductor microchip manufacturing, in automotive and aerospace industries and so on.  From the past decade, textile chemical processing industry has become more interested in plasma applications as a novel finishing technology .
  • 7. Advantages of Plasma  Environmental friendly technique : because of the low energy consumption, the fact it is a dry technique (no additional drying step), no waste disposal problem and disposal cost.  Operator friendly technique : no chemical products, gases, etc.  No substrate damage or bulk property changes
  • 8. APPLICATION OF PLASMA IN TEXTILE  Desizing  Wettability enhancement  Water/soil-repellency  Printability  Dyeability  Shrink-resistance  Adhesion enhancement  Sterilization, etc.
  • 9. PLASMA SYSTEMS FOR TEXTILES  Low-pressure plasma systems  Atmospheric Pressure Plasma Systems 1. Continuous plasma processing 2. Semi-continuous plasma processing 3. Roll - to - Roll Plasma processing
  • 10. Atmospheric Pressure Plasma Systems  Corona discharge  Dielectric barrier discharge (DBD)  Atmospheric plasma glow discharge
  • 13. HYDROPHILICITY ENHANCEMENT OF POLYESTER (PET) FABRICS  Plasma treatment in oxygen containing gas.  Introduces various functional groups (–CO-, -C=O, -COOH, -C-O-O-, O-COO- ) on the surface.  Water (H2O) and H2O2 plasmas introduces alcohol and carboxylic acid groups inducing hydrophilicity.  But “Ageing” is the problem associated with those kind of plasma treatments  Plasma graft polymerization - acrylic acid, nitro compounds, 2-hydroxyethyl methacrylate, methyl methacrylate, acrylamide and acrylonitrile.
  • 14. MECHANISMS OF SURFACE MODIFICATION Etching and Re-deposition SEM image of treated PET SEM image of untreated PET
  • 15. Chain Scission and Functionalization  Ion bombardment into substrate surface during exposure to atmospheric plasma introduces chain scission of molecules on the substrate’s surface
  • 16.
  • 17.
  • 18. EFFECT OF PLASMA TREATMENT ON HYDROPHILICITY OF PET Effect of treatment time and power on moisture content of PET fabric (at 40 % RH) [Bhat et al.]
  • 19. Contact Angle Measurement of Plasma Treated PET Films [Jerome et al]
  • 20. Weight Loss (%) of Plasma Treated PET Films with Different Storage Conditions (He/O2: He flow rate = 12 lpm) [Jerome et al]
  • 21. Water contact angle of a PET film as a function of treatment time for different operating pressures and for different gas flow rate between the electrodes [Morent et al]
  • 22. PLASMA MACHINERY MANUFACTURES  Europlasma, Belgium  Unitex S.P.A., Italy  4thstate Inc., U.S.A.  APJet Inc., U.S.A.  Enercon Industries Corporation, U.S.A.
  • 23. CONCLUSION Plasma can be an interesting alternative or solution with described advantages of being environmental and operator friendly, dry and complete controllable. Therefore, plasma knows a growing market.