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Norcem CO2 Capture Project
Status and Results
Liv Bjerge | Norcem CO2 Capture Project Manager
Workshop NRC - 18. March 2015
Background – Why CCS?
Mar 2015
Norcem CO2 capture project - Project Manager Liv Bjerge
Slide 2 -
850 °C
1450 °C
- Cement industry major emitter of CO2: 5 % (1,9 Gt/ y)
Two sources:
1) 2/3 Main raw material (limestone)
2) 1/3 Fuels  to keep the high temperature in cyclone tower and kiln
- HeidelbergCement: 100 cement plant  50 mill tons CO2/y
- Norcem Brevik: Approx. 800 000 t CO2/ y
Norcem CO2 capture project - Project Manager Liv Bjerge
The Project
 Small scale test centre at Norcem Brevik
 4 post-combustion CO2-capture technologies
 Small scale testing  full scale perspective
 Kicked off in May 2013 – scheduled for 3,5 years
 Partners:
• Norcem
• HeidelbergCement
• ECRA (European Cement Research Academy)
 Project on behalf of the cement industry in Europe!
 Total budget: 93 mill. NOK (11,7 M€)
 Gassnova / Climit-Program: 75% support
Mar 2015Slide 3 -
Mandate and Main Objectives
■ Study and compare various CO2-capture technologies on real
conditions
■ Qualification of technologies
– Determine how suitable these are for implementation at modern cement kiln
systems
■ Focus on CO2 Capture
– Transport and storage is not part of the study
■ Technology Performance due to:
– Capture rate
– Energy consumption
– Impact from flue gas impurities
– Costs (CAPEX/ OPEX)
■ Full Scale/ Commercial Scale Perspective
– Utilization of waste heat
– Full scale not necessarily 100 % capture
Mar 2015
Norcem CO2 capture project - Project Manager Liv Bjerge
Slide 4
Benchmark Study | Commercial Scale Perspective
Norcem CO2 capture project - Project Manager Liv Bjerge
Slide 5 Mar 2015
Benchmark Report – Project Milestone Delivery
Benchmark Study - 3 Commercial Cases
■ Case 1:
– Full-size (min 85%) cleaning, no waste heat
■ Case 2:
– Full-size (min 85%) cleaning, waste heat as per Norcem Brevik
■ Case 3:
– Reduced-size cleaning, based on cost-optimal utilization of waste heat
as per Norcem Brevik. In this case the technology provider will decide
which capture ratio is cost-optimal
Mar 2015
Norcem CO2 capture project - Project Manager Liv Bjerge
Slide 6 -
Aker Solution | Results from Long Term Testing
■ Amine technology: Solvent S26
■ 6 months test program completed (May – Oct 2014)
■ Long term testing: 2700 test hours/ 300 t CO2 captured
■ Promising test results
■ More than 90 % capture rate
■ Energy consumption (RBD) in the range of 2,7-2,8 MJ/ kg CO2
■ Low degradation and consumption of amine
■ Low emissions of amines and degradation products detected
Norcem CO2 capture project - Project Manager Liv Bjerge
Slide 7 Mar 2015
Aker Solution | Commercial scale capture at Norcem
■ Feasibility Study:
– Capture incl. CO2 handling for transport (pipeline 100 bar)
■ Benchmark Study: Input to all 3 cases
■ What is identified (first estimates)?
– Process description, layout, equipment list, space requirement
– Energy consumption (incl. waste heat recovery)
– Utilities & consumables (Sea water, el-power, amine, caustic)
– Waste streams (DCC, reclaimer)
– CO2 avoided
– Life Cycle Costs; CAPEX, OPEX
■ Case 3
Mar 2015
Norcem CO2 capture project - Project Manager Liv Bjerge
Slide 8 -
RTI - Research Triangle Institute| Testing Phase I
Phase I (Apr – Jun 2014):
– Cyclic thermal-swing, absorption-
desorption process
– Sorbent material is based on a CO2-philic
poly-ethylene-imine, PEI
– Dual fluidized, moving-bed reactor design
– Bench-scale; flue gas capacity: 6-10 slpm
Results:
– 300 absorption/ regeneration cycles with
capture loading between 5-7 wt %
– Sorbent exhibited no critical failure in CO2
capture performance
– Presence of contaminants  reduce
performance  pre-treatment system
required
– First estimates of full-scale capture plants
(based on the 3 cases)
Mar 2015
Norcem CO2 capture project - Project Manager Liv Bjerge
Slide 9 -
RTI - Research Triangle Institute| Phase II
3-floor pilot:
– Flue Gas capacity: 500-1500 slpm
– Detail engineering on-going
Long term testing (2016):
– Investigating new sorbent materials
expected capture loading: 9-11 wt%
– Economic analysis of full scale capture
plant (3 cases) incl CO2 handling for
shipment (piping)
Mar 2015
Norcem CO2 capture project - Project Manager Liv Bjerge
Slide 10 -
DNV GL, NTNU & Yodfat Engineers | Membrane Technology
Phase I: May – Oct 2014:
– One stage membrane module
– Flat sheet polysulfon membranes with a
top layer of poly-vinyl-amine (PVAm)
– Feed flow: ~ 25 m3/h
Results:
– Pre-treatment system is required to
remove water and contaminants
– Good separation performance with
permeate purity of 70 % CO2
– First LCC estimates (Case 1 and 3)
available for commercial scale capture
using the membrane technology in Brevik
Project terminated after Phase I
– Design/ Concept Phase II module too
immature
Norcem CO2 capture project - Project Manager Liv Bjerge
Slide 11 Mar 2015
Alstom Power │Calcium-Looping
1 year study completed:
– Characterization of local materials
(limestones from Norway)
– Confirmation of sorbent performance
through pilot testing
Pilot testing at IFK (Stuttgart University)
– Sorbent reactivity, degradation over time
– Circulation pattern between reactors – close
material balance
Results:
– Limestone from Verdal highest reactivity
– Sorbent deactivated more quickly with
thermal cycles than expected
– Input from field testing used as input to
modelling of various full-scale integration
cases
Norcem CO2 capture project - Project Manager Liv Bjerge
Slide 12 Mar 2015
Status
Focus the coming months:
■ Evaluation of project results
– Based on field testing & input to benchmark study
■ Compare technologies and evaluation of commercial scale
perspective
■ Before summer 2015 Norcem will have much more knowledge
regarding the realism of industrial carbon capture; especially in
the cement industry
Mar 2015
Norcem CO2 capture project - Project Manager Liv Bjerge
Slide 13 -
Further contribution towards CCS realization
■ Further testing at site using the MTU
– Long term testing (will achieve 5000 testing hours)
– Part of the Solvit R&D-project
– Optimize technical aspects and investigate new solvents
■ Concept Study:
– Identify most optimal integration of a 400 000 t CO2 capture amine plant
including CO2 handling for shipment in Brevik
– Best waste heat recovery (Norcem Brevik, capture plant/ compression train)
– Identify necessary re-constructions/ replacement of equipment
– Cost-estimate (Capture and further handling)
– Identify possible showstoppers/ possible risk elements
Mar 2015
Norcem CO2 capture project - Project Manager Liv Bjerge
Slide 14 -
Summary Norcem CO2 Capture Project
■ Important project to understand the realism of deployment of
carbon capture in the cement industry.
■ We have tested several technologies on REAL condition and the
technologies manages to capture the CO2 at expected level.
■ Our view is that Aker Solutions amine technology can be defined
as available technology.
■ Further step is to identify optimal integration of a commercial scale
capture plant including CO2 handling, based on Aker Solutions
amine technology, at site in Brevik.
■ We need a system for transport and storage/ reuse of the CO2
Mar 2015
Norcem CO2 capture project - Project Manager Liv Bjerge
Slide 15 -
Thank you for your attention!
Mar 2015
Norcem CO2 capture project - Project Manager Liv Bjerge
Slide 16 -

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Status and Results from the Norcem CO2 Capture Project, Liv Bjerge (Norcem) UK/Norway/Canada Meeting 18/19 March 2015

  • 1. Norcem CO2 Capture Project Status and Results Liv Bjerge | Norcem CO2 Capture Project Manager Workshop NRC - 18. March 2015
  • 2. Background – Why CCS? Mar 2015 Norcem CO2 capture project - Project Manager Liv Bjerge Slide 2 - 850 °C 1450 °C - Cement industry major emitter of CO2: 5 % (1,9 Gt/ y) Two sources: 1) 2/3 Main raw material (limestone) 2) 1/3 Fuels  to keep the high temperature in cyclone tower and kiln - HeidelbergCement: 100 cement plant  50 mill tons CO2/y - Norcem Brevik: Approx. 800 000 t CO2/ y
  • 3. Norcem CO2 capture project - Project Manager Liv Bjerge The Project  Small scale test centre at Norcem Brevik  4 post-combustion CO2-capture technologies  Small scale testing  full scale perspective  Kicked off in May 2013 – scheduled for 3,5 years  Partners: • Norcem • HeidelbergCement • ECRA (European Cement Research Academy)  Project on behalf of the cement industry in Europe!  Total budget: 93 mill. NOK (11,7 M€)  Gassnova / Climit-Program: 75% support Mar 2015Slide 3 -
  • 4. Mandate and Main Objectives ■ Study and compare various CO2-capture technologies on real conditions ■ Qualification of technologies – Determine how suitable these are for implementation at modern cement kiln systems ■ Focus on CO2 Capture – Transport and storage is not part of the study ■ Technology Performance due to: – Capture rate – Energy consumption – Impact from flue gas impurities – Costs (CAPEX/ OPEX) ■ Full Scale/ Commercial Scale Perspective – Utilization of waste heat – Full scale not necessarily 100 % capture Mar 2015 Norcem CO2 capture project - Project Manager Liv Bjerge Slide 4
  • 5. Benchmark Study | Commercial Scale Perspective Norcem CO2 capture project - Project Manager Liv Bjerge Slide 5 Mar 2015 Benchmark Report – Project Milestone Delivery
  • 6. Benchmark Study - 3 Commercial Cases ■ Case 1: – Full-size (min 85%) cleaning, no waste heat ■ Case 2: – Full-size (min 85%) cleaning, waste heat as per Norcem Brevik ■ Case 3: – Reduced-size cleaning, based on cost-optimal utilization of waste heat as per Norcem Brevik. In this case the technology provider will decide which capture ratio is cost-optimal Mar 2015 Norcem CO2 capture project - Project Manager Liv Bjerge Slide 6 -
  • 7. Aker Solution | Results from Long Term Testing ■ Amine technology: Solvent S26 ■ 6 months test program completed (May – Oct 2014) ■ Long term testing: 2700 test hours/ 300 t CO2 captured ■ Promising test results ■ More than 90 % capture rate ■ Energy consumption (RBD) in the range of 2,7-2,8 MJ/ kg CO2 ■ Low degradation and consumption of amine ■ Low emissions of amines and degradation products detected Norcem CO2 capture project - Project Manager Liv Bjerge Slide 7 Mar 2015
  • 8. Aker Solution | Commercial scale capture at Norcem ■ Feasibility Study: – Capture incl. CO2 handling for transport (pipeline 100 bar) ■ Benchmark Study: Input to all 3 cases ■ What is identified (first estimates)? – Process description, layout, equipment list, space requirement – Energy consumption (incl. waste heat recovery) – Utilities & consumables (Sea water, el-power, amine, caustic) – Waste streams (DCC, reclaimer) – CO2 avoided – Life Cycle Costs; CAPEX, OPEX ■ Case 3 Mar 2015 Norcem CO2 capture project - Project Manager Liv Bjerge Slide 8 -
  • 9. RTI - Research Triangle Institute| Testing Phase I Phase I (Apr – Jun 2014): – Cyclic thermal-swing, absorption- desorption process – Sorbent material is based on a CO2-philic poly-ethylene-imine, PEI – Dual fluidized, moving-bed reactor design – Bench-scale; flue gas capacity: 6-10 slpm Results: – 300 absorption/ regeneration cycles with capture loading between 5-7 wt % – Sorbent exhibited no critical failure in CO2 capture performance – Presence of contaminants  reduce performance  pre-treatment system required – First estimates of full-scale capture plants (based on the 3 cases) Mar 2015 Norcem CO2 capture project - Project Manager Liv Bjerge Slide 9 -
  • 10. RTI - Research Triangle Institute| Phase II 3-floor pilot: – Flue Gas capacity: 500-1500 slpm – Detail engineering on-going Long term testing (2016): – Investigating new sorbent materials expected capture loading: 9-11 wt% – Economic analysis of full scale capture plant (3 cases) incl CO2 handling for shipment (piping) Mar 2015 Norcem CO2 capture project - Project Manager Liv Bjerge Slide 10 -
  • 11. DNV GL, NTNU & Yodfat Engineers | Membrane Technology Phase I: May – Oct 2014: – One stage membrane module – Flat sheet polysulfon membranes with a top layer of poly-vinyl-amine (PVAm) – Feed flow: ~ 25 m3/h Results: – Pre-treatment system is required to remove water and contaminants – Good separation performance with permeate purity of 70 % CO2 – First LCC estimates (Case 1 and 3) available for commercial scale capture using the membrane technology in Brevik Project terminated after Phase I – Design/ Concept Phase II module too immature Norcem CO2 capture project - Project Manager Liv Bjerge Slide 11 Mar 2015
  • 12. Alstom Power │Calcium-Looping 1 year study completed: – Characterization of local materials (limestones from Norway) – Confirmation of sorbent performance through pilot testing Pilot testing at IFK (Stuttgart University) – Sorbent reactivity, degradation over time – Circulation pattern between reactors – close material balance Results: – Limestone from Verdal highest reactivity – Sorbent deactivated more quickly with thermal cycles than expected – Input from field testing used as input to modelling of various full-scale integration cases Norcem CO2 capture project - Project Manager Liv Bjerge Slide 12 Mar 2015
  • 13. Status Focus the coming months: ■ Evaluation of project results – Based on field testing & input to benchmark study ■ Compare technologies and evaluation of commercial scale perspective ■ Before summer 2015 Norcem will have much more knowledge regarding the realism of industrial carbon capture; especially in the cement industry Mar 2015 Norcem CO2 capture project - Project Manager Liv Bjerge Slide 13 -
  • 14. Further contribution towards CCS realization ■ Further testing at site using the MTU – Long term testing (will achieve 5000 testing hours) – Part of the Solvit R&D-project – Optimize technical aspects and investigate new solvents ■ Concept Study: – Identify most optimal integration of a 400 000 t CO2 capture amine plant including CO2 handling for shipment in Brevik – Best waste heat recovery (Norcem Brevik, capture plant/ compression train) – Identify necessary re-constructions/ replacement of equipment – Cost-estimate (Capture and further handling) – Identify possible showstoppers/ possible risk elements Mar 2015 Norcem CO2 capture project - Project Manager Liv Bjerge Slide 14 -
  • 15. Summary Norcem CO2 Capture Project ■ Important project to understand the realism of deployment of carbon capture in the cement industry. ■ We have tested several technologies on REAL condition and the technologies manages to capture the CO2 at expected level. ■ Our view is that Aker Solutions amine technology can be defined as available technology. ■ Further step is to identify optimal integration of a commercial scale capture plant including CO2 handling, based on Aker Solutions amine technology, at site in Brevik. ■ We need a system for transport and storage/ reuse of the CO2 Mar 2015 Norcem CO2 capture project - Project Manager Liv Bjerge Slide 15 -
  • 16. Thank you for your attention! Mar 2015 Norcem CO2 capture project - Project Manager Liv Bjerge Slide 16 -