2015 Broken Hill Resources Investment Symposium - Geological Survey of South Australia - Liz Jagodzinski

Symposium
SymposiumAdmim um Symposium
GEOCHRONOLOGY IN THE
CURNAMONA PROVINCE
Elizabeth A. Jagodzinski and Wolfgang V. Preiss
Geological Survey of South Australia
Broken Hill Resources Investment Symposium, 24-27 May, 2015
www.statedevelopment.sa.gov.au
2Department of State Development
Bulletin 56
3Department of State Development
Revision of Geochronology
•  Work was initially carried out at Geoscience Australia as part of the
Broken Hill Exploration Initiative by Rod Page.
•  The aim was to establish a time framework for the stratigraphy of
the Curnamona Province, to accompany the mapping program, in
both Broken Hill and Olary Domains.
 
	
  
4Department of State Development
STRATHEARN GROUP
Mount Howden Subgroup
SUNDOWN GROUPSALTBUSH
GROUP BROKEN HILL GROUP
Larry Macs Sgp: Plumbago, Bimba Ettlewood Calc-silicate Member
THACKARINGA GROUP
RANTYGA GROUP
CURNAMONA GROUP
Ethiudna Subgroup: Peryhumuck Fm v v v v v
Cathedral Rock Formation
Tommie Wattie Formation v v v v v v
Wiperaminga Subgroup v v v v v v v
15 m.y. hiatus
~1655-1640
~1685
~1705	
  
~1710	
  
~1715-
1720
~1720
Purnamoota Subgp: Hores Gneiss
PARAGON GROUP
?15 m.y. hiatus
Allendale Metasediments
OLARY DOMAIN BROKEN HILL DOMAIN Ma
~1695-1700
Walparuta Formation
Raven Hill Subgroup
5Department of State Development
Bulletin 56
Ameroo	
  
11 rectified maps showing the spatial
location and geological context of
the geochronology samples
Mulga	
  
6Department of State Development
Revision of Geochronology 1
•  SHRIMP data were collected between 1998 and 2006, using many
different versions and generations of software
•  Rod used earlier software (PRAWN) written by RSES, which allowed
user bias to creep in to the data processing
•  In the late 1990’s Ken Ludwig (Berkeley) developed a ‘black box’
processing package that removed this user bias by identifying outliers
on a statistical basis, called SQUID.
•  In order to compare all data on a level playing field, all the analyses
havebeen reprocessed with the same software package: SQUID 1.
•  Rod Page used the standard QGNG to monitor the 207Pb/206Pb ratio:
for each session, he compared the measured SHRIMP age of QGNG
to its TIMS-determined age of 1851.6 ± 0.6 Ma
•  Measured ages for QGNG ranged from 1844 to 1856 Ma
•  Rod Page normalised some of the sample data to the correct
reference age, but not all
•  A correction has now been applied to all samples, which normalises the
ages to the TIMS reference age of QGNG, so these session differences
are eliminated. This is called an IMF correction (instrumental mass
fractionation (Stern et al. 2007)
Revision of Geochronology 2
50 SHRIMP sessions of QGNG compared
•  All	
  4	
  instruments	
  means	
  lower	
  than	
  TIMS	
  	
  mean	
  	
  ~	
  1849.1	
  Ma	
  
•  instruments	
  1,3,4	
  show	
  excess	
  session-­‐session	
  dispersion,	
  with	
  a	
  range	
  	
  
up	
  to	
  .5%	
  between	
  highest	
  and	
  lowest	
  
•  Isoplot	
  2σ	
  external	
  error	
  required	
  for	
  all	
  sessions	
  =	
  	
  ±	
  4.1	
  Ma	
  (.22%)	
  	
  
84 SHRIMP sessions of OG1 on GA’s SHRIMP IIe compared
(Feb 2008-2010)
Rod’s QGNG standards for the BHEI project
Rod’s QGNG standards for the BHEI project
Tommie	
  Wa)e	
  Fm	
  quartz-­‐phyric	
  granofels	
  (volcanic)	
  
North	
  Walparuta	
  region	
  
original	
  processing normalised	
  data	
  sets
2092274 1719 4 1719 3
480533 1713 2 1717 2
12
Results: Saltbush Group
1.  Plumbago Formation - inferred volcaniclastic psammite
immediately overlying the Bimba Formation. Zircons
consistently yield 1697 Ma when normalised
1	
  
Plumbago Formation volcaniclastic psammite
(1693 Ma)
graphitic metasiltstone near
Mt Howden Co mine
Pb loss	
  
13
2.  Detrital zircons in sandy facies of the Bimba Formation
define a maximium depositional age of 1706 ± 4 Ma
Saltbush Group
2	
  
1706±4 Ma	
  
14
Saltbush Group
3	
  
3.  The Portia Formation has been proposed
for the mineralised section above the
Curnamona Group in the Mulyungarie
Domain. A thin tuff in two drillholes gives
ages ranging from 1697 to 1704 Ma but
within error, so contemporary with the
Bimba Formation
Cu-­‐Au	
  and	
  Pb-­‐Zn	
  mines	
  and	
  prospects	
  
e.g.	
  PorEa,	
  Kalkaroo,	
  Hunters	
  Dam,	
  McBrides,	
  Polygonum,	
  Thunderdome	
  
15Department of State Development
•  Ages on felsic volcanics range between 1712 and 1721 Ma.
	
  
Results: Curnamona Group
16
•  Ages on felsic volcanics range between 1712 and 1721 Ma.
•  Analysis of Variance test (or ANOVA) compares all pairs of dates for the
Curnamona Group
•  It indicates a significant difference in age between only a few of the dates
obtained for volcanics in the Peryhumuck Formation and the George Mine
Formation; these are coloured yellow in the table.
Results: Curnamona Group
Tukey-­‐Kramer	
  minimum	
  significant	
  difference	
  
Actual	
  difference	
  
('*'	
  if	
  significant)	
  
Conclusion
Whereas SHRIMP dating could
delineate broad stratigraphic
variations at the Group level,
stratigraphic differences of
< 10 m.y. can not be resolved.
Curnamona: where next?
•  Future research: key volcanic horizons will be selected for dating by
Thermal Ionisation Mass Spectroscopy (TIMS), which has a resolution
of < 1 m.y.
•  Hf isotopes on metasedimentary rocks of the Willyama Supergroup
	
  
19
TIMS dating
•  We have a collaborative research partnership with the University of Idaho to
provide TIMS dating for the GSSA. Successful projects so far:
1.  Early Cambrian stratigraphy, tectonics, biostratigraphy and Timescale study
2.  GRV/Hiltaba Suite
	
  1	
   2	
  
2020
Mount Howden Subgroup: 1657±7 Ma
Plumbago Formation: 1697±4 Ma
Bimba Formation: max dep age 1706± 4 Ma
tuff mean age 1701±6 Ma
SUMMARY	
  
Curnamona Group: ages on felsic
volcanics range between 1712 and
1721 Ma	
  
Denotes samples selected for TIMS dating 	
  
Where to find our publications
hUp://minerals.statedevelopment.sa.gov.au/geoscience/geological_survey/geoscienEfic_data/geochronology	
  
Where to find our publications
hUps://www.researchgate.net/profile/Elizabeth_Jagodzinski	
  
www.statedevelopment.sa.gov.au
Geological Survey of South Australia
Level 4, 101 Grenfell Street
Adelaide, South Australia 5000
GPO Box 320
Adelaide, South Australia 5001
T: +61 8 8463 3081
E: liz.jagodzinski@sa.gov.au
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2015 Broken Hill Resources Investment Symposium - Geological Survey of South Australia - Liz Jagodzinski

  • 1. GEOCHRONOLOGY IN THE CURNAMONA PROVINCE Elizabeth A. Jagodzinski and Wolfgang V. Preiss Geological Survey of South Australia Broken Hill Resources Investment Symposium, 24-27 May, 2015 www.statedevelopment.sa.gov.au
  • 2. 2Department of State Development Bulletin 56
  • 3. 3Department of State Development Revision of Geochronology •  Work was initially carried out at Geoscience Australia as part of the Broken Hill Exploration Initiative by Rod Page. •  The aim was to establish a time framework for the stratigraphy of the Curnamona Province, to accompany the mapping program, in both Broken Hill and Olary Domains.
  • 4.     4Department of State Development STRATHEARN GROUP Mount Howden Subgroup SUNDOWN GROUPSALTBUSH GROUP BROKEN HILL GROUP Larry Macs Sgp: Plumbago, Bimba Ettlewood Calc-silicate Member THACKARINGA GROUP RANTYGA GROUP CURNAMONA GROUP Ethiudna Subgroup: Peryhumuck Fm v v v v v Cathedral Rock Formation Tommie Wattie Formation v v v v v v Wiperaminga Subgroup v v v v v v v 15 m.y. hiatus ~1655-1640 ~1685 ~1705   ~1710   ~1715- 1720 ~1720 Purnamoota Subgp: Hores Gneiss PARAGON GROUP ?15 m.y. hiatus Allendale Metasediments OLARY DOMAIN BROKEN HILL DOMAIN Ma ~1695-1700 Walparuta Formation Raven Hill Subgroup
  • 5. 5Department of State Development Bulletin 56 Ameroo   11 rectified maps showing the spatial location and geological context of the geochronology samples Mulga  
  • 6. 6Department of State Development Revision of Geochronology 1 •  SHRIMP data were collected between 1998 and 2006, using many different versions and generations of software •  Rod used earlier software (PRAWN) written by RSES, which allowed user bias to creep in to the data processing •  In the late 1990’s Ken Ludwig (Berkeley) developed a ‘black box’ processing package that removed this user bias by identifying outliers on a statistical basis, called SQUID. •  In order to compare all data on a level playing field, all the analyses havebeen reprocessed with the same software package: SQUID 1.
  • 7. •  Rod Page used the standard QGNG to monitor the 207Pb/206Pb ratio: for each session, he compared the measured SHRIMP age of QGNG to its TIMS-determined age of 1851.6 ± 0.6 Ma •  Measured ages for QGNG ranged from 1844 to 1856 Ma •  Rod Page normalised some of the sample data to the correct reference age, but not all •  A correction has now been applied to all samples, which normalises the ages to the TIMS reference age of QGNG, so these session differences are eliminated. This is called an IMF correction (instrumental mass fractionation (Stern et al. 2007) Revision of Geochronology 2
  • 8. 50 SHRIMP sessions of QGNG compared •  All  4  instruments  means  lower  than  TIMS    mean    ~  1849.1  Ma   •  instruments  1,3,4  show  excess  session-­‐session  dispersion,  with  a  range     up  to  .5%  between  highest  and  lowest   •  Isoplot  2σ  external  error  required  for  all  sessions  =    ±  4.1  Ma  (.22%)    
  • 9. 84 SHRIMP sessions of OG1 on GA’s SHRIMP IIe compared (Feb 2008-2010)
  • 10. Rod’s QGNG standards for the BHEI project
  • 11. Rod’s QGNG standards for the BHEI project Tommie  Wa)e  Fm  quartz-­‐phyric  granofels  (volcanic)   North  Walparuta  region   original  processing normalised  data  sets 2092274 1719 4 1719 3 480533 1713 2 1717 2
  • 12. 12 Results: Saltbush Group 1.  Plumbago Formation - inferred volcaniclastic psammite immediately overlying the Bimba Formation. Zircons consistently yield 1697 Ma when normalised 1   Plumbago Formation volcaniclastic psammite (1693 Ma) graphitic metasiltstone near Mt Howden Co mine Pb loss  
  • 13. 13 2.  Detrital zircons in sandy facies of the Bimba Formation define a maximium depositional age of 1706 ± 4 Ma Saltbush Group 2   1706±4 Ma  
  • 14. 14 Saltbush Group 3   3.  The Portia Formation has been proposed for the mineralised section above the Curnamona Group in the Mulyungarie Domain. A thin tuff in two drillholes gives ages ranging from 1697 to 1704 Ma but within error, so contemporary with the Bimba Formation Cu-­‐Au  and  Pb-­‐Zn  mines  and  prospects   e.g.  PorEa,  Kalkaroo,  Hunters  Dam,  McBrides,  Polygonum,  Thunderdome  
  • 15. 15Department of State Development •  Ages on felsic volcanics range between 1712 and 1721 Ma.   Results: Curnamona Group
  • 16. 16 •  Ages on felsic volcanics range between 1712 and 1721 Ma. •  Analysis of Variance test (or ANOVA) compares all pairs of dates for the Curnamona Group •  It indicates a significant difference in age between only a few of the dates obtained for volcanics in the Peryhumuck Formation and the George Mine Formation; these are coloured yellow in the table. Results: Curnamona Group Tukey-­‐Kramer  minimum  significant  difference   Actual  difference   ('*'  if  significant)  
  • 17. Conclusion Whereas SHRIMP dating could delineate broad stratigraphic variations at the Group level, stratigraphic differences of < 10 m.y. can not be resolved.
  • 18. Curnamona: where next? •  Future research: key volcanic horizons will be selected for dating by Thermal Ionisation Mass Spectroscopy (TIMS), which has a resolution of < 1 m.y. •  Hf isotopes on metasedimentary rocks of the Willyama Supergroup  
  • 19. 19 TIMS dating •  We have a collaborative research partnership with the University of Idaho to provide TIMS dating for the GSSA. Successful projects so far: 1.  Early Cambrian stratigraphy, tectonics, biostratigraphy and Timescale study 2.  GRV/Hiltaba Suite  1   2  
  • 20. 2020 Mount Howden Subgroup: 1657±7 Ma Plumbago Formation: 1697±4 Ma Bimba Formation: max dep age 1706± 4 Ma tuff mean age 1701±6 Ma SUMMARY   Curnamona Group: ages on felsic volcanics range between 1712 and 1721 Ma   Denotes samples selected for TIMS dating  
  • 21. Where to find our publications
  • 24. www.statedevelopment.sa.gov.au Geological Survey of South Australia Level 4, 101 Grenfell Street Adelaide, South Australia 5000 GPO Box 320 Adelaide, South Australia 5001 T: +61 8 8463 3081 E: liz.jagodzinski@sa.gov.au