31. Cyclic Ethers
Thermo Plastic Elastomer
3,3-bis(azidomethyl)oxetane (BAMO)
O
CH2
CH2 N3
N3
O CH2 C
CH2N3
CH2N3
CH2
3-azidomethyl-3-methyl oxetane (AMMO)
O
CH3
CH2 N3
O CH2 C
CH2N3
CH3
CH2
BAMO AMMO BAMO
32. Cationic Polymerization
of Cyclic Ethers
OF3C S
O
O
O S CF3
O
O
O
F3C S
O
O
O S CF3
O
O
Difunctional PTMO (initiated by triflic anhydride)
O CH2CH2CH2CH2OF3C S
O
O
S
O
O
CF3
33. Cyclic Amides
C
N O
H
n
CH2
CH2 CH2 N CCH2CH2 CH2
H
O n
CH2 CH2 CCH2CH2 CH2N
O
N
O
H
Na
CH2
CH2
C
N
H2C
H2C
H2C
O
H
CH2 CH2 CCH2CH2 CH2N
O
N
O
H
H
CH2
CH2
C
N
H2C
H2C
H2C
O
+
imide dimer: actural initiating species:
exo-carbonyl makes it more reactive!Na
CH2
CH2
C
N
H2C
H2C
H2C
O
H
CH2
CH2
C
N
H2C
H2C
H2C
O
H
CH2
CH2
C
N
H2C
H2C
H2C
O
NaH
Anionic Initiated Polymerization
34. Siloxanes may be cyclic, linear or cross linked
polymer
Cyclosiloxanes