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Blending Coals
Impacts on Slag
1
Rod Hatt
Ash Deposits
Slagging - Molten
Fouling - Sulfate Salts
Most Slag
Starts on
walls
Coal Blending
Chemical Data Blends
• Heating Value
• Sulfur
• Ash Chemistry
Coal Blending
Physical Test - Difficult
• Hardgrove (HGI)
• Ash Fusion Temps
• Combustion Properties
Measuring Coal Quality
Coal Lab Testing
only produces
average data
Power plants respond to
swings in quality
Does this coal meet spec?
5.7
6.1
Average
Plant Limit
Measuring Coal Quality
Coal Lab Testing
only produces
Bulk or Total Quality
PC power plants respond to
Individual Particle
SiO2 Fe2O3
Al2O3 CaO
TiO2 MgO
K2O
Na2O
Acid Oxides Basic Oxides
Glass Formers Fluxes
Ash Chemistry
Base/Acid =
Fe2O3+CaO+MgO+K2O+Na2O
SiO2+Al2O3+TiO2
Slag and Fouling Index
Bituminous
SI = %dry sulfur x B/A
FI % sodium X B/A
Sub-Bituminous
% Sodium (Na2O)
You are on your own?
Slag is a build up
of rate process
so,
the amount of
ash should matter.
17
Lets look at all boiler related
coal qualities on a heat
basis; lets put all
percentages on a per million
Kcal basis
LOADING LEVELS
Kg. of ash/MKcal
= %ash / (Kcal/10,000)
Kg. of element/MKcal
= %ash / (Kcal/10,000)
X (%Element/100)
Many slagging concerns
have been addressed using
Ash Loading and Elemental
loading levels; especially
Fe2O3, CaO, Na2O
Lessons Learned From Experience
1. Ash Fusion Temps do not
work
2. Increase in Moisture Causes
more Slag
3. Lowering Sodium by Dilution
Causes more Slag
B/A Ratio
Fusion
Fusion verse Base to Acid Ratio
Low Sulfur Bit
Mid/High Sulfur
Fe2O3
High Calcium
Sub Bit
0 0.5 1.0 1.5
Can Not Blend Fusions
(1200 + 1200) = 1100 ?
2
Amount of Ash
Matters
18 Month Study
1300 MW PC Boiler
Slag Observations
Coal Quality
Statistical Review
#1 – Did you have slag yesterday
#1 CQ - Moisture
Sub-Bit Impacted by OSD (Rock)
Bit Coal Combustion
30
Sub-Bit Coal Combustion
31
Coal Combustion
32
Coal Combustion
33
Coal Combustion
34
Sub-Bit Coal Combustion
35
Quartz and rocks stay big,
sticking in wet wall.
Splat Factor
Velocity is Important
Kinetic Energy =
Mass x (velocity)2
2
Large dense particles
Pyrite Quartz, rock
Coal pipe velocity
Low Btu, Hi Moist.
Hi PA Flow
SPLAT FACTOR
Coal Pipe Velocity increases
due to:
1. High PA flow (mill A/F)
2. Low CV coal
3. High moisture
SPLAT FACTOR
1. Calculate KE for Quartz and
Pyrite particles
2. Multiply KE times Q & P
loading levels
3. Multiply result by % on 50
mesh screen
(>300 microns)
SPLAT FACTOR
Low with low levels of large
particles
Low with low levels of ash and
sulfur
Lowers with less PA flow A/F
is important
Coal Combustion
43
Bituminous
1.Maintain 70%+ passing 200 mesh screen
2.High Calorific Value and low moisture
allow for low mill loading
3.Lower Primary Air due to lower coal flow
can allow for rejects
Coal Combustion
44
Sub - Bituminous
1.Maintain 70% passing 200 mesh screen to
Minimize Slag, (lower to increase ton rate)
2.Low Calorific Value and high moisture
make for high mill loading
3.High Primary Air for drying and high coal
flow sends reject material into the furnace
Advice – Set up plant
1.Pulverize to meet Un-reactive coal
2.Pulverize for slag control-not carbon
3.Maintain CV to take load off mill
or
1.Change Expectation – Load, Forced
Outage Rate (SLAG, TUBE LEAK)
Maintenance
www.asiansbcusers.com
46
Thank You

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2018 Coal Blending and Slag Formation.pdf