- Radici Group is a global manufacturer of engineering plastics with 3,200 employees and annual sales of €392 million.
- Radici Plastics is the group's global player in polyamides and has a vertically integrated production process from polymerization to specialty compounds.
- Radici Plastics has a global manufacturing footprint and offers a wide range of polyamide grades for automotive, electrical/electronics, and consumer/industrial applications.
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Radici Plastics: innovation and wide range of materials in a global context
1. Radici Group Press Conference
Gandhinagar (India) - February 6th
“Radici Plastics: innovation and wide range of“Radici Plastics: innovation and wide range of
materials in a global context”
By Erico SPINI – Radici Plastics MKT&Application Development Director
2. Radici Plastics : the RadiciGroup’s Global Player
in Engineering Plastics Polyamides
KEY RADICIGROUP NUMBERS
Personnel: 3,200 employees
Sales Turnover (Millions of Euro)
392
248
516
5
0 100 200 300 400 500 600
Chemicals
Plastics
Fibres
Other
M€
5. Radici Plastics : Global Manufacturing
Footprint
AMERICASAMERICASAMERICASAMERICAS ASIAASIAASIAASIAEUROPEEUROPEEUROPEEUROPE
Radici Novacips SpARadici Novacips SpARadici Novacips SpARadici Novacips SpA Villa d’Ogna – ITALY
Investment in fast-growing regions. Application development support worldwide.
Radici Plastics USA IncRadici Plastics USA IncRadici Plastics USA IncRadici Plastics USA Inc.... USA Radici Plastics (Suzhou) Co.,Radici Plastics (Suzhou) Co.,Radici Plastics (Suzhou) Co.,Radici Plastics (Suzhou) Co., Ltd. CHINARadici Novacips SpARadici Novacips SpARadici Novacips SpARadici Novacips SpA Villa d Ogna – ITALY
Radici Novacips SpARadici Novacips SpARadici Novacips SpARadici Novacips SpA Chignolo d’Isola – ITALY
Radici Plastics GmbHRadici Plastics GmbHRadici Plastics GmbHRadici Plastics GmbH - GERMANY
Radici Plastics USA IncRadici Plastics USA IncRadici Plastics USA IncRadici Plastics USA Inc.... USA
Radici Plastics LtdaRadici Plastics LtdaRadici Plastics LtdaRadici Plastics Ltda BRAZIL
Radici Plastics (Suzhou) Co.,Radici Plastics (Suzhou) Co.,Radici Plastics (Suzhou) Co.,Radici Plastics (Suzhou) Co., Ltd. CHINA
Radici Plastics Modi Pvt., LtdRadici Plastics Modi Pvt., LtdRadici Plastics Modi Pvt., LtdRadici Plastics Modi Pvt., Ltd –––– INDIA*INDIA*INDIA*INDIA*
* Toll compounding* Toll compounding* Toll compounding* Toll compounding
6. Radici Plastics : Worldwide Polymer Brands
A line of PA6, PA6.6, High Temperature PA, PA6.12 and
64% renewably sourced PA6.10 polymers and copolymers used
for injection, extrusion and blow-moulding in industrial,
electrical/electronics and automotive applications.
A line of PA, PET and PBT flame-retardant grades used
for injection and extrusion in all applications where high fi re
resistance is required, especially in the electrical/electronics and
automotive sectors.
Polyamides +
complementary
materials
electrical/electronics and automotive applications.
A line of thermoplastic semi-crystalline PBT, PET and
glassfibre-reinforced PBT used for injection moulding in
industrial, electrical/electronics and automotive applications.
Eco-sustainable range of materials mainly coming from
RadiciGroup’s polymerization, fibres and compound plants
scraps used for injection and extrusion in industrial,
electrical/electronics and automotive applications.
automotive sectors.
A line of thermoplastic elastomers based on SEBS,
SBS and co-polyesters; used for injection and blow moulding in
industrial, electrical/electronics and automotive.
A line of long fibre polyamides for injection
moulding.This material family represents a major step forward
in metal replacement due to its exceptional impact, creep and
high temperature properties.
POM acetal copolymers for injection moulding
applications, obtained through the random insertion of co-
monomer units in a poly-trioxane chain.
7. A complete material range for the automotive, E/E, consumer and industrial goods sectors.
AUTOMOTIVEAUTOMOTIVEAUTOMOTIVEAUTOMOTIVE E/EE/EE/EE/E
Radici Plastics Main Markets
Consumer&IndustrialConsumer&IndustrialConsumer&IndustrialConsumer&Industrial
RadiciGroup |RadiciGroup |RadiciGroup |RadiciGroup | Plastics
More than 300
grades are
commercial
8. Radici Plastics Innovation
Philosophy
Meet the new demands of the market even in challenging
projects
R&D investments policy
Be a leader in offering innovative solutions to its customers
Be flexible in designing taylor made materials for its customers
Be able to propose innovative global grades
Provide advanced material characterization (long term
properties like fatigue, creep, ageing in different media, high
speed loading, etc)
Provide state of the art and advanced design support (FEA)
9. Radici Plastics Innovation Approach
Market Requirements
Lightweighting, low CO₂ emission,
NVH vehicles comfort, productivity,
cost reduction
Smaller and more powerful auto
engines, insulation properties at
high temperature in the EE sector,
LFS technology
Radici’s Answer
Specialty PA designed for metal replacement :
-High performance PA66PA66--GFGF
-High performance and highhigh flowflow PA6PA6--GFGF
- LGF polyamides Radistrong®Radistrong®
High temperature range of polyamides :
--Radilon®Radilon® HHRHHR family
--Radilon®Radilon® XTremeXTreme family
RadiciGroup |RadiciGroup |RadiciGroup |RadiciGroup | Plastics
LFS technology
Better chemical resistance,
improved dimensional stability,
improved hydrolysis resistance
Safety, technical performances,
respect of environmental standard
and productivity for the
electrical/electronics apparatus
--Radilon®Radilon® XTremeXTreme family
Two families of long chain polyamides :
--Radilon®Radilon® DD range of PA610 compounds
--Radilon®Radilon® DTDT range of PA612 compounds
An outstanding range of flame retardant materials
including red ph and halogen free families :
- Radiflam®Radiflam®
10.
11. Metal replacement offer
Specialties based on PA66-GF : Radici
Current Offer
50% GF PA66 Radilon® A RV500RW bk 339
35% GF PA66 Radilon® A RV350RW bk 33935% GF PA66 Radilon® A RV350RW bk 339
New ! 60% GF PA66 Radistrong® A X7957
that offers (when compared to standard PA66-GF):
- Higher tensile stress at break
- Higher deformation at break
- Improved welding line resistance
- Higher impact resistance
14. Approved/Serial parts made of :
•Radilon® A RV500RW 339 BK
(Engine bracket, Engine
mounts)
Metal replacement offer
•Radilon® A RV350RW 339 BK
(Engine mounts)
15. High flow & high filler content PA6:
Radici Current Offer
50% GF PA6 Radilon® S URV500
60% GF PA6 Radilon® S URV600
Metal replacement offer
that offer when compared to standard GF PA6 :
•Easier flow
•Less fibers breakage ; consequently higher mechanical
properties retention
•Improved design freedom
•Lower screw abrasion
•Lower processing temperature with great advantages for
FR materials
•Lower press size
•Higher productivity
18. Enhanced impact properties
Improved tensile strength at break at high
Radistrong® LGF Structural Composites
Key Feature versus PA-Short Glass Fibres
Metal replacement offer
Improved tensile strength at break at high
temperature
Improved creep and fatigue resistance
Lower parts warpage
Better performance at high temperatures
21. 1,50
2,00
2,50
3,00
3,50
Deformation(%)
Creep Behavior (140 °C, 60 Mpa)
PA66-GF50
Radistrong® ALGF50W
Metal replacement offer
0,00
0,50
1,00
1 10 100 1000 10000
Deformation(%)
Time (hours)
Radistrong® ALGF50W
Creep behaviour (140 °C, 60 MPa) of Radistrong® compared to a short-
fibre reinforced PA66 : after 10000 h the creep deformation is close to
1/3 of short fibers PA !
23. Radici CAE service:
Structural Advanced simulation
• Advanced approach for process-dependent material properties
• Anisotropy induced by fiber orientation and local material properties can
be taken into account in an integrated, non-linear analysis, which use
process simulation data do build up a macromechanic model with local
anisotropic material properties
24.
25. Engine downsizing
Lower limits on CO₂₂₂₂ emission
Longer vehicles life time
Reduced under bonnet space
High temperature PA offer
₂₂₂₂
Reduced under bonnet space
•Better properties retention after ageing
•Longer life time
•Easy processing, competitive price
26. • Radilon® A HHR
High Heat Resistance PA66 for
injection and blow molding (from 180
to 210 °C CUT in air)
180 180
°C
210
High temperature PA offer
• New ! Radilon XTreme-
HHR
High Temperature Polyamides (from
190 to 230 °C CUT in air)
210
°C
230
°C
27. High temperature PA offer
Temperature upper limit in contact with hot air : 210 °C
28. •Radilon® A RV350 HHR : high heat resistant, PA66-
GF35, for injection molding
•Radilon® A BMV150 HHR & Radilon® A BMV200 HHR :
High temperature PA offer
•Radilon® A BMV150 HHR & Radilon® A BMV200 HHR :
high heat resistant PA66-GF15 & PA66-GF20, for blow
molding
•Radilon® A RV150 HHR AF : high heat resistant PA66-
GF15, flame retardant,UL-V0, for injection molding
29. 80,0
100,0
120,0
140,0
160,0
180,0
200,0TensileStrengthatBreak(Mpa)
Heat Ageing in Air at 210 °C
Radilon A RV350 HHR 3800 Ner
PA66-GF35 HS
High temperature PA offer
0,0
20,0
40,0
60,0
80,0
0,0 1000,0 2000,0 3000,0 4000,0
TensileStrengthatBreak(Mpa)
Time (h)
•Radilon® A RV350 HHR 3800 Ner : 57% of initial value after 3000h
•PA66-GF35 Heat Stabilized : 0% of initial value just after 2000 h
30. 40
50
60
70
80
90
100
TensileStrengthatBreak(Mpa)
Heat ageing in air at 210 °C
High temperature PA offer
The performance of blow molding grade :
•Radilon® A BMV150 HHR : 90% of initial value
•Benchmark : 41% of initial value
0
10
20
30
40
0 500 1000 1500 2000
TensileStrengthatBreak(Mpa)
Time (h)
CompPA66-GF15
RadilonA BMV150 HHR
31. HHR technology was also successfully used on a
flame-retardant product.
Material : Radiflam® A RV150HHR AF, a 15%-glass-
fibre-filled PA66
Technical specifications :
High temperature PA offer
Technical specifications :
• Maximum 35% mechanical property degradation
after ageing at 170°C for 1,000 hours
• Retention of a UL94 V0 flame-class rating by a 0.8-
mm-thick specimen after ageing at 170°C for 3,000
hours
32. High temperature PA offer
Hot side turbo air duct
Radilon® A BMV150 HHR
Air resonator box
Radilon® A RV350HHR
Turbo duct resonator
Radilon® A RV350HHR
33. Electrical motor components
Radilon® A RV350 HHR
(H Class rating UL 1446
insulating systems – 180 °C)
High temperature PA offer
Enginer cover
Radilon® A RV150HHR AF (FR)
34. New !
High temperature PA offer
Temperature upper limit in contact with hot air : 230 °C
35. Using a novel and proprietary approach Radici
scientists, from both Plastics and Chemical
High temperature PA offer
scientists, from both Plastics and Chemical
divisions, have developed a new polyamide
that is stable at elevated temperatures (up to
230°). This technology is developed mainly in
response to newer automotive performance
demands for under the hood applications.
36. Property PA66 PA6 XTreme PPS PPA PPA-2 PA46 PA46-2
Melt
Temp.
260 220 280 280 308 300 282 295
Water
Abs.
8,5 9,0 7,0 0,1 7,0 7,0 13,0 13,0
High temperature PA offer
Radilon® XTreme (pure polymer) vs other polymers
• same melting temperature of PPS and PA46. Lower than PPA
• same water absorption of PPA, lower than PA46
• same TG of PPS, higher than PA46, lower than PPA
• lower density versus PPS and PA46
Abs.
Tg 70 60 90 90 110 120 70 70
Density 1,14 1,14 1,15 1,35 1,15 1,15 1,18 1,18
37. 100
150
200
250
TensileStrengthatBreak(ISO527-Mpa)
Heat Ageing in Air at 220 °C
RadilonXTremeRV350HHR
PA*-GF35
PA46-GF40
PPA-GF45
40
60
80
100
120
TensileStrengthatBreakretention(%)
Heat Ageing in Air at 220 °C
RadilonXTreme RV350HHR
PA*-GF35
PA46-GF40
PPA-GF45
50%
Retention
High temperature PA offer
0
50
0 500 1000 1500 2000 2500 3000 3500
TensileStrengthatBreak(ISO527
Time(h)
Radilon® XTreme RV350HHR
• Residual Tensile Strength at Break better than
benchmark after 3000 h at 220 °C
• Tensile Strength at Break retention > 50% after 3000 h at
220 °C (Better than benchmark)
0
20
0 500 1000 1500 2000 2500 3000 3500
TensileStrengthatBreakretention(%)
Time(h)
38. 20
40
60
80
100
120
TensileElongationatBreakretention(%)
Heat Ageing in Air at 220 °C
Radilon XTreme RV350HHR
PA*-GF35
PA46-GF40
PPA-GF45
50%
Retention
1
1,5
2
2,5
3
3,5
4
TensileElongationatBreak(ISO527,%)
Heat Ageing in Air at 220 °C
RadilonXTremeRV350HHR
PA*-GF35
PA46-GF40
PPA-GF45
High temperature PA offer
Radilon® XTreme RV350HHR
• Elongation at break retention better/equivalent
than benchmark
• Residual deformation at break after 3000 h at
220 °C higher than benchmark
0
20
0 1000 2000 3000 4000
TensileElongationatBreakretention(%)
Time (h)
0
0,5
0 500 1000 1500 2000 2500 3000 3500
TensileElongationatBreak(ISO527,%)
Time(h)
39. • Radilon® XTreme RV350HHR 3800 Ner
(PA-35%GF-Injection Molding)
Radilon® Xtreme actual offer
High temperature PA offer
• Radilon® XTreme RV400HHR 3800 Ner
(PA-40%GF-Injection Molding)
• Radilon® XTreme RV500HHR 3800 Ner
(PA-50%GF-Injection Molding)
40. High temperature PA offer
Radilon®Xtreme comparisonwith other polymersforhigh temperatureapplications.
(Glassfilledversion30 to 40 %)
* Poor
** Fair
*** Good
****Excellent
Polymer Ease of Surface Heat ageing Stiffness Tensile ImpactPolymer Ease of
processing
Surface
aspect
Heat ageing
properties retention
at230 °C
Stiffness Tensile
Strength
Impact
Resistance
PPA * * ** *** *** **
PPS * ** **** *** *** *
PA46 * * *** **** DAM
*Cond
*** DAM
*Cond
***
Rad®XTreme *** **** *** *** *** ***
41. Radilon® S RV … W, S BMV150 K
Radilon® A RV…W
Radilon® XTreme complete the Radici
Plastics material portfolio for high
temperature applications
Radilon® A RV…W
Radilon® XTreme RV HHR
Metal
Radilon® A RV HHR, A BMV HHR
CUT in contact with air
42.
43. RadiciRadiciRadiciRadici PlasticsPlasticsPlasticsPlastics LongLongLongLong ChainChainChainChain
PolyamidePolyamidePolyamidePolyamide OfferOfferOfferOffer
Long Chain Polyamides
• Radilon®Radilon®Radilon®Radilon® D PA6.10D PA6.10D PA6.10D PA6.10
• Radilon®Radilon®Radilon®Radilon® DT PA6.12DT PA6.12DT PA6.12DT PA6.12 New !New !New !New !
46. Long Chain Polyamides
GWP comparison plot for PA6,10 and other polymers (data from literature).
The graph shows that PA6,10 has the lowest GWP of all the polymers included
in the plot. The discriminating factor can be traced back to the component of
biological origin with a low environmental impact, which makes up about 64%
of the polymer by weight.
48. Long Chain Polyamides
PA6,10 exhibits much lower hygroscopicity than PA6 and PA66, and its
water uptake at saturation is not too far from PA12.
49. Long Chain Polyamides
The melting point and HDT of PA6,10 are close to PA6, but clearly higher than
for PA11 and PA12.
These characteristics could be valuable indicators in determining the usability
of PA6,10 as a valid alternative to PA11 and PA12 for all those applications,
such as diesel fuel lines, in which operating temperatures reach values that
PA12 and PA11 cannot withstand
66. Typical Applications
Power Distribution Connectivity
Halogen- and phosphorous free (FR)
Market
Segment
Power
Distribution
Part Name Mini Circuit Breaker
Material Radilon®
S UCW 250 FR2
Main
Technical
Requirements
•GWFI 960 °C
•Colour RAL 7035
•High Flow
•Laser Markability
Market
Segment
Connectors
Part Name •Terminal Block
•Connectors
Material Radiflam® A FR
Main
Technical
Requirements
•UL94-V0 at 0,4 mm
•Colourability
•Regrind addition
•Elongation at break
(snap fitting)
67. Typical Applications
Industrial Control Power Distribution
Halogen- and phosphorous free (HF)
Market
Segment
Industrial Control
Part Name Contactor Housing
Material Radiflam®
A RV250 HF
Main
Technical
Requirements
•High Mechanical
Properties
•UL94-V0
•Different Colours
Market
Segment
Power Distribution
Part Name MCCB Housing
Material Radiflam®
A RV250 HF
Main Technical
Requirements
•GWFI 960 °C at 1 mm
•UL94-V0 at 0,8 mm
•CTI > 400 V
•RoHs & WEEE
Compliance
68. Typical Applications
Appliance Insulation systems
Red phosphorous technology (AF)
Market
Segment
Household
Appliances
Part Name Connector for
cooking surfaces
Material Radiflam®
A RV250K AF
Main
Technical
Requirements
•High Mechanical
Properties
•GWIT > 775 at 1 mm
•IEC 60335-1
Compliance
• UL-V0
Market
Segment
Electrical
Insulation Systems
Part Name Coil Bobbin
Material Radiflam®
A RV300K AF
Main Technical
Requirements
•High Mechanical
Properties
• UL-V0 at 0,8 mm
• High tensile strength
at break
69. Typical Applications
Appliance Appliance
Halogen based technology (AE)
Market
Segment
Household
Appliances
Part Name Stator Housing
Material Radilon®
S V2 181C Nat
Main
Technical
Requirements
•IEC 60335-1
compliance
•High Flow
•Sb2O3 free
•IMQ & VDE
approved
Market
Segment
Household
Appliances
Part Name Washing Machine Timer
Components
Material Radiflam®
A RV300K AE 181 C Nat
Main
Technical
Requirements
•IEC 60335-1 compliance
•Good Mechanical
Properties
70. Radici Plastics Facts & Vision
Facts
•Upstream integration of PA6, PA66, PA6.10, PA6.12, High
temperature PA and copolymers.
•Worldwide industrial and sales network.
•Complete range of materials available in all countries.•Complete range of materials available in all countries.
•Competent global application development support.
Vision
•Growth through innovation, with a focus on specialty
polyamide grades.
•Sustainability commitment along the entire production
chain to minimize the environmental impact.
71. Radici Group Press Conference
Gandhinagar (India) - February 6th
Thank YouThank You
for Your Attention