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SLB-Private
VPS – Valves and Process
Seawater Injection
Schlumberger - Private
SLB-Private
Why Inject Seawater?
Primary production (10 - 25% oil in place (OIP))
Maintain reservoir pressure
Secondary (IOR) (+ 15 - 35% OIP)
Tertiary (EOR) (+5 -15% OIP)
Schlumberger - Private
SLB-Private
Flow Assurance Issues
▪ Reservoir pores blocked with solids
▪ Corrosion of downhole piping
▪ Biological contamination of reservoir
▪ Scaling of reservoir
▪ Souring of reservoir due to activity of sulfate reducing bacteria
Schlumberger - Private
SLB-Private
Treatment Methods
▪ Solids Removal
▪ Dissolved Oxygen Removal
▪ Bio-Growth Control
▪ Chemical Treatment
▪ Modification of Seawater
Schlumberger - Private
SLB-Private
Seawater Portfolio
APPLICATION PRODUCTS ENABLING TECHNOLOGY
Biofouling Control
BFCC Copper Chlorine Systems
Electrochlorination
METROL SEA-CELL
Particle Filtration
50 µm METROL SEA-SCREEN Strainer Filtration
2 µm Multi Media Filters Filtration
0.5 µm Cartridge Filters Filtration
0.01 µm Ultrafiltration (UF) Membrane
Ionic Filtration
0.001 µm Sulphate Removal
Membrane
0.0001 µm Reverse Osmosis
Deoxygenation
40 ppb VDX Vacuum Deaeration
Mass Transfer
< 10 ppb Membrane Deaeration
Chemical Injection** Custom Designed & Fabricated
** Supplied only with SW packages
Schlumberger - Private
SLB-Private
Water Injection System
Biofouling
control
Media Filtration
or Ultrafiltration
Membrane
System
De-oxygenation
Reject to
Overboard
From lift
pumps
Coarse
Strainer
Cartridge
filtration
To other users
Reject to
Overboard
Oxygen scavanger
Biocide
Antiscalant
To water
injection
manifold
Schlumberger - Private
SLB-Private
FILTRATION SPECTRUM
media filtration
media filtration
microfiltration
microfiltration
ultrafiltration
ultrafiltration
nanofiltration
nanofiltration
reverse
osmosis
reverse
osmosis
Filtration Process
Operating Pressures
(barg)
15 to 80 5 to 25 1 to 5 1 < 1
Particulate Range ions molecules macro molecules small particles sand particles
Size (microns) 0.001 0.01 0.1 1.0 10 100 1000
Applications soluble
soluble viruses
viruses bacteria
bacteria
metal ions
metal ions colloids
colloids algae & protozoa
algae & protozoa
pesticides
pesticides albumin
albumin oil emulsions
oil emulsions
sand
sand
Visibility electron optical human eye
microscope microscope
Schlumberger - Private
SLB-Private
BIOGROWTH CONTROL
Schlumberger - Private
SLB-Private
BIOGROWTH CONTROL – MACRO AND MICROFOULING
Schlumberger - Private
SLB-Private
BIOGROWTH CONTROL - PRODUCTS
Metrol Sea-Cell (electrochlorination)
1ppm chlorine = 1,000µg/l chlorine
BFCC (biofouling corrosion
control)
5µg/l copper, 50µg/l chlorine
Schlumberger - Private
SLB-Private
SOLIDS REMOVAL – METROL SEA-SCREEN
Schlumberger - Private
SLB-Private
SEA-SCREEN OVERVIEW
Flat strainer
surface.
Vertical support wire
Gap determines
micron rating
Direction of flow
Schlumberger - Private
SLB-Private
SOLIDS REMOVAL – MEDIA FILTERS
Schlumberger - Private
SLB-Private
MULTI-MEDIA FILTRATION
• 98% > 2µm
• Filtrate suitable for downstream membrane processes
• High efficiency, deep bed filtration
• Design flux criteria
• Filtrate SDI around 3
• Proprietary Distribution/ Collection Systems
• Backwashing
• Low Operating Costs
Schlumberger - Private
SLB-Private
CARTRIDGE FILTRATION
• Particle removal efficiency e.g. 99% > 5µm
• Vertical or horizontal vessels
• Quick opening and counterbalanced lid designs
• Rating (absolute versus nominal)
Schlumberger - Private
SLB-Private
SOLIDS REMOVAL – ULTRAFILTRATION
Schlumberger - Private
SLB-Private
ULTRAFILTRATION
• Dead-end filtration
• Consistent high quality filtrate
• Back-washable system
• Total removal of suspended particles and bacteria – 99+% > 0.01
µm
• Reduction in quantity of downstream NF or RO membrane
• Energy savings compared to media + cartridge filtration
• Increased productivity
• Lower operating costs (cartridge filter replacements, NF cleaning,
NF element replacement)
Schlumberger - Private
SLB-Private
COMPARISON WITH MEDIA FILTRATION SYSTEM
Capacity
Operating
weight
Plot area
bpd te m2
Media & Cartridge Filtration 200000 480 220
Ultrafiltration 200000 170 160
Schlumberger - Private
SLB-Private
DISSOLVED OXYGEN REMOVAL
Schlumberger - Private
SLB-Private
TOWER DE-AERATION (VDX AND GDX)
• Capped downcomers and seal pots
• Pressurized first stage inlet distribution
• Allowance for loss in performance in floating environment:
– Random packing
– Interstage seals
– Liquid distributors
• Pumps achieve 1st stage vacuum
• Atm. air ejector assists creation of 2nd stage vacuum
• Gas strip when suitable natural gas available
Schlumberger - Private
SLB-Private
MEMBRANE DEAERATION
• Membrane Deaeration Technology brings the
gas and liquid phases in contact with each
other across a hydrophobic membrane
• In a typical design, the water flows in one side
(outside) while gas flows in the opposite side
(inside)
• Gas permeable skinned hollow fiber membrane
does not allow water to pass through the
membrane but freely allows gas to pass
through
• Lower gas concentrations and pressure on the
gas side create a driving force to remove
dissolved gases, such as O2, from water
• High surface area in small volume - modular,
small footprint, scalable and predictable
21
Schlumberger - Private
SLB-Private
MEMBRANE SEPARATION – SULFATE REMOVAL
Schlumberger - Private
SLB-Private
THE PROBLEM - SCALING
Seawater:
SO4
2-
Formation
Water:
Ba2+
and/or
Sr2+
Scaling:
BaSO4
and/or
SrSO4
=
+
Schlumberger - Private
SLB-Private
RESERVOIR SOURING
Application to sweet reservoirs initially absent of sulfur materials
Lower sulfate limits the source of sulfur that can be converted to hydrogen sulfide
SO4
2- H2S
nitrogen, phosphorus and fatty
acid compounds
thermophilic sulfate
reducing bacteria (SRB)
Schlumberger - Private
SLB-Private
TERMINOLOGY: 1PASS – 2 STAGE SYSTEM
Schlumberger - Private
SLB-Private
SUMMARY – BENEFITS OF LOW SULFATE WATER
Very High Quality Injection /Dilution Water
Reduction of Scaling in Piping and Equipment
Elimination of Squeeze Treatments
Avoid Well Workovers
Reduction in Health and Safety Hazards
Avoid Potential Well Souring
Reduction in Need for Biocides
Increased Productivity
Lower Operating Costs
Schlumberger - Private
SLB-Private
Membrane Separation System References
27
End user Project Installation year
Capacity (bpd)
Country
SR RO UF
OSX OSX 2 150000 3770 Brazil
OSX OSX 1 60000 Brazil
BP ETAP 1998 20000 UK
Maersk Janice 1999 70000 UK
Statoil Heidrun 2003 200000 Norway
ExxonMobil Kizomba A 2004 350000 Angola
ExxonMobil Kizomba B 2005 350000 Angola
Total Dalia 2007 9812 Angola
Hess Elon 2007 130000 Equatorial Guinea
Shell Ursa 2008 180000 USA
Talisman Tweedsmuir 2008 55000 UK
BHP Billiton Shenzi 2012 125000 167000 USA
Statoil Peregrino 2013 32000 Brazil
Petrobras Lula NE pilot - Cidade De Paraty 2013 154000 Brazil
Pemex Akal J 2014 25000 50000 Mexico
Total Ofon 2 2014 250000 Nigeria
Hess Stampede 2017 100000 133333 USA
Shell Appomattox 2018 277500 USA
ExxonMobil Liza 2020 200000 Guyana
ZADCO West Island 2020 240000 320000 Abu Dhabi
ENI Amoca 2022 136586 8000 Mexico
Chevron Jack St. Malo 2022 70000 111112 USA
Petrobras Mero 2 2022 250000 Brazil
ADOC Hail Terminal, Mubarraz Island 2022 32000 Abu Dhabi

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VPS Seawater Intro.pdf

  • 1. SLB-Private VPS – Valves and Process Seawater Injection
  • 2. Schlumberger - Private SLB-Private Why Inject Seawater? Primary production (10 - 25% oil in place (OIP)) Maintain reservoir pressure Secondary (IOR) (+ 15 - 35% OIP) Tertiary (EOR) (+5 -15% OIP)
  • 3. Schlumberger - Private SLB-Private Flow Assurance Issues ▪ Reservoir pores blocked with solids ▪ Corrosion of downhole piping ▪ Biological contamination of reservoir ▪ Scaling of reservoir ▪ Souring of reservoir due to activity of sulfate reducing bacteria
  • 4. Schlumberger - Private SLB-Private Treatment Methods ▪ Solids Removal ▪ Dissolved Oxygen Removal ▪ Bio-Growth Control ▪ Chemical Treatment ▪ Modification of Seawater
  • 5. Schlumberger - Private SLB-Private Seawater Portfolio APPLICATION PRODUCTS ENABLING TECHNOLOGY Biofouling Control BFCC Copper Chlorine Systems Electrochlorination METROL SEA-CELL Particle Filtration 50 µm METROL SEA-SCREEN Strainer Filtration 2 µm Multi Media Filters Filtration 0.5 µm Cartridge Filters Filtration 0.01 µm Ultrafiltration (UF) Membrane Ionic Filtration 0.001 µm Sulphate Removal Membrane 0.0001 µm Reverse Osmosis Deoxygenation 40 ppb VDX Vacuum Deaeration Mass Transfer < 10 ppb Membrane Deaeration Chemical Injection** Custom Designed & Fabricated ** Supplied only with SW packages
  • 6. Schlumberger - Private SLB-Private Water Injection System Biofouling control Media Filtration or Ultrafiltration Membrane System De-oxygenation Reject to Overboard From lift pumps Coarse Strainer Cartridge filtration To other users Reject to Overboard Oxygen scavanger Biocide Antiscalant To water injection manifold
  • 7. Schlumberger - Private SLB-Private FILTRATION SPECTRUM media filtration media filtration microfiltration microfiltration ultrafiltration ultrafiltration nanofiltration nanofiltration reverse osmosis reverse osmosis Filtration Process Operating Pressures (barg) 15 to 80 5 to 25 1 to 5 1 < 1 Particulate Range ions molecules macro molecules small particles sand particles Size (microns) 0.001 0.01 0.1 1.0 10 100 1000 Applications soluble soluble viruses viruses bacteria bacteria metal ions metal ions colloids colloids algae & protozoa algae & protozoa pesticides pesticides albumin albumin oil emulsions oil emulsions sand sand Visibility electron optical human eye microscope microscope
  • 9. Schlumberger - Private SLB-Private BIOGROWTH CONTROL – MACRO AND MICROFOULING
  • 10. Schlumberger - Private SLB-Private BIOGROWTH CONTROL - PRODUCTS Metrol Sea-Cell (electrochlorination) 1ppm chlorine = 1,000µg/l chlorine BFCC (biofouling corrosion control) 5µg/l copper, 50µg/l chlorine
  • 11. Schlumberger - Private SLB-Private SOLIDS REMOVAL – METROL SEA-SCREEN
  • 12. Schlumberger - Private SLB-Private SEA-SCREEN OVERVIEW Flat strainer surface. Vertical support wire Gap determines micron rating Direction of flow
  • 13. Schlumberger - Private SLB-Private SOLIDS REMOVAL – MEDIA FILTERS
  • 14. Schlumberger - Private SLB-Private MULTI-MEDIA FILTRATION • 98% > 2µm • Filtrate suitable for downstream membrane processes • High efficiency, deep bed filtration • Design flux criteria • Filtrate SDI around 3 • Proprietary Distribution/ Collection Systems • Backwashing • Low Operating Costs
  • 15. Schlumberger - Private SLB-Private CARTRIDGE FILTRATION • Particle removal efficiency e.g. 99% > 5µm • Vertical or horizontal vessels • Quick opening and counterbalanced lid designs • Rating (absolute versus nominal)
  • 16. Schlumberger - Private SLB-Private SOLIDS REMOVAL – ULTRAFILTRATION
  • 17. Schlumberger - Private SLB-Private ULTRAFILTRATION • Dead-end filtration • Consistent high quality filtrate • Back-washable system • Total removal of suspended particles and bacteria – 99+% > 0.01 µm • Reduction in quantity of downstream NF or RO membrane • Energy savings compared to media + cartridge filtration • Increased productivity • Lower operating costs (cartridge filter replacements, NF cleaning, NF element replacement)
  • 18. Schlumberger - Private SLB-Private COMPARISON WITH MEDIA FILTRATION SYSTEM Capacity Operating weight Plot area bpd te m2 Media & Cartridge Filtration 200000 480 220 Ultrafiltration 200000 170 160
  • 20. Schlumberger - Private SLB-Private TOWER DE-AERATION (VDX AND GDX) • Capped downcomers and seal pots • Pressurized first stage inlet distribution • Allowance for loss in performance in floating environment: – Random packing – Interstage seals – Liquid distributors • Pumps achieve 1st stage vacuum • Atm. air ejector assists creation of 2nd stage vacuum • Gas strip when suitable natural gas available
  • 21. Schlumberger - Private SLB-Private MEMBRANE DEAERATION • Membrane Deaeration Technology brings the gas and liquid phases in contact with each other across a hydrophobic membrane • In a typical design, the water flows in one side (outside) while gas flows in the opposite side (inside) • Gas permeable skinned hollow fiber membrane does not allow water to pass through the membrane but freely allows gas to pass through • Lower gas concentrations and pressure on the gas side create a driving force to remove dissolved gases, such as O2, from water • High surface area in small volume - modular, small footprint, scalable and predictable 21
  • 22. Schlumberger - Private SLB-Private MEMBRANE SEPARATION – SULFATE REMOVAL
  • 23. Schlumberger - Private SLB-Private THE PROBLEM - SCALING Seawater: SO4 2- Formation Water: Ba2+ and/or Sr2+ Scaling: BaSO4 and/or SrSO4 = +
  • 24. Schlumberger - Private SLB-Private RESERVOIR SOURING Application to sweet reservoirs initially absent of sulfur materials Lower sulfate limits the source of sulfur that can be converted to hydrogen sulfide SO4 2- H2S nitrogen, phosphorus and fatty acid compounds thermophilic sulfate reducing bacteria (SRB)
  • 26. Schlumberger - Private SLB-Private SUMMARY – BENEFITS OF LOW SULFATE WATER Very High Quality Injection /Dilution Water Reduction of Scaling in Piping and Equipment Elimination of Squeeze Treatments Avoid Well Workovers Reduction in Health and Safety Hazards Avoid Potential Well Souring Reduction in Need for Biocides Increased Productivity Lower Operating Costs
  • 27. Schlumberger - Private SLB-Private Membrane Separation System References 27 End user Project Installation year Capacity (bpd) Country SR RO UF OSX OSX 2 150000 3770 Brazil OSX OSX 1 60000 Brazil BP ETAP 1998 20000 UK Maersk Janice 1999 70000 UK Statoil Heidrun 2003 200000 Norway ExxonMobil Kizomba A 2004 350000 Angola ExxonMobil Kizomba B 2005 350000 Angola Total Dalia 2007 9812 Angola Hess Elon 2007 130000 Equatorial Guinea Shell Ursa 2008 180000 USA Talisman Tweedsmuir 2008 55000 UK BHP Billiton Shenzi 2012 125000 167000 USA Statoil Peregrino 2013 32000 Brazil Petrobras Lula NE pilot - Cidade De Paraty 2013 154000 Brazil Pemex Akal J 2014 25000 50000 Mexico Total Ofon 2 2014 250000 Nigeria Hess Stampede 2017 100000 133333 USA Shell Appomattox 2018 277500 USA ExxonMobil Liza 2020 200000 Guyana ZADCO West Island 2020 240000 320000 Abu Dhabi ENI Amoca 2022 136586 8000 Mexico Chevron Jack St. Malo 2022 70000 111112 USA Petrobras Mero 2 2022 250000 Brazil ADOC Hail Terminal, Mubarraz Island 2022 32000 Abu Dhabi