1. PAPER-1
PART-A
Select the correct alternative. (Only one is correct) [99 × 3 = 297]
There is NEGATIVE marking. 1 mark will be deducted for eachwrong answer.
Q.34 20mlof0.05 M solutionof theconjugate acidof an -amino acid methionine(H2A+)is taken.Thepka
of –COOH group in methionine is 2.8 and pkb ofbasic group is 4.8. Pick out onlyincorrect statement
among thefollowing. [Uselog2= 0.3]
(A) pH oforiginal aminoacidsolutionwas ~ 2.05
(B) pH ofsolution was ~ 2.8 when 10 ml 0.05 M NaOH solution is added to original solution
(C) pH of solution is ~ 6when 20 ml 0.05 M NaOH solution is added to original solution
(D*) pH ofsolution is 3.8 when 20 ml 0.05 M NaOH solution is added to original solution
Q.35 Whichofthe followingcompound(s)will givebluecolourwhenit is converted intoLassaigne's extract
and FeSO4 is added followed byFeCl3.
(I) (II) (III) CH3–NMe2 (IV) NH2–NH2
(A*) III only (B) II & III (C) II, III & IV (D) I, II, III & IV
Q.36 ZnO shows yellow colour on Heatingdue to
(A)d–d transition (B) C–T spectra
(C)Higher polarisation causedbyZn2+ ion (D*) F– centres
Q.37 Thedecomposition of N2O5 inchloroform was followedbymeasuringthevolumeof O2 gas evolved :
2N2O5 (CCl4) 2N2O4 (CCl4) + O2(g). The maximum volume of O2 gas obtained was 100 cm3. In
500 minutes, 90 cm3 of O2 were evolved. The first order rate constant (in min–1) for the rate of
disappearance of N2O5 is
(A*)
500
303
.
2
(B)
500
303
.
2
log
90
100
(C)
500
303
.
2
log
100
90
(D)
500
10
100

Q.38 What will be the order of rotation barriers about C–N bond among these compounds ?
(I) CH3–CH2–NH2 (II) (III)
(A) I > II > III (B*) I < II < III (C) II > III > I (D) III > I > II
Q.39 Complex compound [Cr(NCS)(NH3)5] [ZnCl4] will be
(A)Colourless&diamagnetic
(B) Greencoloured& diamagnetic
(C*)Greencoloured& shows coordination isomerism
(D)Diamagnetic&showslinkageisomerism

2. Q.40 The vapour pressureofpure perflourocyclohexane (C6F12)aregiven bythefollowingequations:
Solid C6F12 : log10 p(mm Hg) = 8.68 –
T
1890
Liquid C6F12 : log10 p(mm Hg) = 7.60 –
T
1530
Themolarenthalpyoffusionofsolid C6F12 is approximately
(A*) 1658 cal (B) 360 cal (C) 3420 cal (D) 720 cal
Q.41 + HNO3 + H2SO4  Product.
Productis:
(A*) (B) (C) (D) Both B & C
Q.42 Whichofthefollowingis correct.
(A) F2 has higherdissociation energythan Cl2
(B)Fhas higherelectronaffinitythanCl
(C) HF is stronger acid than HCl
(D*)Boilingpoint increases downthegroupinhalogens
Q.43 3
H
N

– CH(R)– CO2H has its Ka1 = 10–7. The isoelectric point of the -amino acid occur at pH = 8.2
hence pKa2 of the conjugate acid of -amino acid is equal to
(A*) 9.4 (B) 1.2 (C) 7.6 (D) 2.4
Q.44 Theproduct ofI– with 
4
MnO inalkalinemedium is
(A) I2 (B*) 
3
IO (C) IO– (D) 
4
IO
Q.45 Whichofthe followingwill racemizeinpresenceofacidorbaseimpuritiesinaqueousmedium.
(A)
Cl
O
|
|
|
Ph
C
C
Me
|
CH3


 (B)
D
O
|
|
|
CH
C
CH
C
Me
|
H
3
2 



(C) (D*)
3
3
2
CH
O
|
|
|
CH
CH
C
C
Ph
|
H





3. Q.46 (X) + K2CO3 + Air 
 
Heat (Y)
(Y) + Cl2  (Z) Pink
Whichofthefollowingiscorrect?
(A) X = black, MnO2 , Y = Blue, K2CrO4, Z = KMnO4
(B) X = green, Cr2O3, Y = Yellow, K2CrO4 , Z = K2Cr2O7
(C*) X = black, MnO2 Y = green , K2MnO4, Z = KMnO4
(D) X = black, Bi2O3, Y= colourless KBiO2, Z = KBiO3
Q.47 Writecorrect order of stability
(A) I > II > III > IV (B*) III > II > I > IV (C) III > I > II > IV (D) III > II > IV > I
Q.48 The structure of diborane (B2H6)contains
(A) Four (2C–2e–) bonds and two (2C–3e–) bonds
(B) Two (2C–2e–) bonds and two (3C–2e–) bonds
(C) Four (2C–2e–) bonds and four (3C– 2e–) bonds
(D*) None
Q.49 This question consist of two statements each, printed as assertion and reason, while answering this
question youare required to chooseanyone of thefollowing responses.
(A) If both assertion and reason are true and the reason is a correct explanation of assertion.
(B) If both assertion and reason are true but reason is not a correct explanation of assertion.
(C) If assertionis true but thereason is false.
(D) If assertion is false but thereason is true.
Assertion : Me MgBr give CH4 with acetone.
Reason :  – H of carbonyl compounds are active (acidic). [Ans.D]
Q.50 Nitrogen dioxide cannot be obtained from
(A) Cu(NO3)2 (B) Hg(NO3)2 (C*) NaNO3 (D)AgNO3
Q.51 PhCHO&HCHOwillbehavedifferentlywithwhichofthefollowingreagents
(A)Tollen's Reagent (B*)FehlingSolution (C)Schiff'sreagent (D) NaBH4
Q.52 The oxide does not have coordinate bond is
(A) N2O (B*) NO (C) N2O5 (D) NO2

4. Q.53 & are:
(A*)chainisomers (B)positionalisomers (C)conformers (D)enantiomers
Q.54 FeSO4 is a verygood absorber for NO, the new compound formed by this process is found to contain
number ofunpairedelectrons
(A) 4 (B) 5 (C*) 3 (D) 6
Q.55 Most stableformofethyleneglycol is:
(A)anti (B*)gauche (C)fullyeclipsed (D)partiallyeclipsed
Q.56 Theformation of 
4
PH is difficultcompared to 
4
NH because
(A)lonepairofphosphorus isopticallyinert
(B) lone pairof phosphorus resides at almost pure p-orbital
(C) lone pair of phosphorus resides at sp3 orbital
(D*) lone pairof phosphorus resides atalmost pure s-orbital
Q.57 Whichofthe followingheptanols arechiral 1-heptanol, 2-heptanol, 3-heptanol, 4-heptanol.
(A)All arechiral (B*) 2-heptanol and 3-heptanol
(C) 2-heptanol, 3-heptanol & 4-heptanol (D) 3-heptanol and 4-heptanol
Q.58 What products areformedduring, the electrolysis of a concentrated aqueous solution of NaCl?
(I) Cl2 (g) (II) NaOH (aq) (III) H2 (g)
(A) Ionly (B) I & II only (C) I & III only (D*) I, II & III
Q.59 Predict themajorproductP infollowingreaction:
HCl
NaNO2


 
 P
(A*) (B)
(C) (D)

5. Q.60 The product Octalone is obtained byMichael addition followed byaldol condensation of reactants R
and S in presence of a base. S gives positiveiodoform test.
R + S 
 
 
,
B
Octalone
R andS are respectively:
(A) + CH3–CH=O (B) +
O
|
|
H
C
CH
CH2 


(C*) +
O
|
|
CH
C
CH
CH 3
2 

 (D) +
O
|
|
CH
C
CH
CH 3
2
3 


Question No. 61 & 62 (2 questions)
Q.61 StepC(refining)involvedinpurificationofPbmetal
(A)Distillation (B)Bessemerization
(C)Cupelation (D*)Electrolyticrefining
Q.62 Whichofthefollowingmetalsareobtained byautoreduction method:
Pb, Mn, Cu, Cr, Fe,Al.
(A) Cu, Fe (B) Cu, Pb, Mn (C) Mn, Cr, Pb (D*) Pb, Cu
Q.63 Thiscompoundonozonolysisgiveswhich ofthefollowingcompounds
(I) (II)
O
O
|
|
|
|
CHO
C
CH
C
C
OHC
|
|
O
2 




(III)
CHO
|
CHO (IV)
O
|
|
O
CH
CH
C
C
OHC
|
|
O
2 




(A) I, II, III & IV (B) I, III, IV (C*) I, II, III (D) I, II, IV

6. Q.64 In the reaction;
OH
CH
ONa
CH
3
3


 
 ; the product is
(A) (B*) (C) (D)
Q.65 ThecorrectIUPAC name of thefollowing compound is:
O
C
H
OH
|
|
CHO
CH
CH
C
O 2






(A)3,3-diformyl propanoic acid (B*) 3-formyl-4-oxo-butanoic acid
(C) 3,3-dioxo propanoic acid (D) 3,3-dicarbaldehyde propanoic acid
Q.66 CH2=CH–CH2–CH2–CCH )
eq
1
(
HBr

 
 Product is
(A) BrCH2–CH2–CH2–CH2–CCH (B) CH2=CH–CH2–CH2–CH = CH–Br
(C)
Br
|
CH
C
CH
CH
CH
CH 2
2
2
2 



 (D*)
Br
|
CH
C
CH
CH
CH
CH 2
2
3 





7. PAPER-1
PART-A
Select the correct alternative. (Only one is correct) [99 × 3 = 297]
There is NEGATIVE marking. 1 mark will be deducted for eachwrong answer.
Q.34 20 ml of 0.05 M solution of theconjugateacid of an -amino acid methionine(H2A+)is taken.Thepka
of –COOH group in methionine is 2.8 and pkb ofbasic group is 4.8. Pick out onlyincorrect statement
among thefollowing. [Uselog2= 0.3]
(A) pH oforiginal aminoacidsolutionwas ~ 2.05
(B) pH ofsolution was ~ 2.8 when 10 ml 0.05 M NaOH solution is added to original solution
(C) pH of solution is ~ 6when 20 ml 0.05 M NaOH solution is added to original solution
(D*) pH ofsolution is 3.8 when 20 ml 0.05 M NaOH solution is added to original solution
Q.35 Whichofthe followingcompound(s)will givebluecolourwhenit is converted intoLassaigne's extract
and FeSO4 is added followed byFeCl3.
(I) (II) (III) CH3–NMe2 (IV) NH2–NH2
(A*) III only (B) II & III (C) II, III & IV (D) I, II, III & IV
Q.36 ZnO shows yellow colour on Heatingdue to
(A)d–d transition (B) C–T spectra
(C)Higher polarisation causedbyZn2+ ion (D*) F– centres
Q.37 Thedecomposition of N2O5 inchloroform was followedbymeasuringthevolumeof O2 gas evolved :
2N2O5 (CCl4) 2N2O4 (CCl4) + O2(g). The maximum volume of O2 gas obtained was 100 cm3. In
500 minutes, 90 cm3 of O2 were evolved. The first order rate constant (in min–1) for the rate of
disappearance of N2O5 is
(A*)
500
303
.
2
(B)
500
303
.
2
log
90
100
(C)
500
303
.
2
log
100
90
(D)
500
10
100

Q.38 What will be the order of rotation barriers about C–N bond among these compounds ?
(I) CH3–CH2–NH2 (II) (III)
(A) I > II > III (B*) I < II < III (C) II > III > I (D) III > I > II
Q.39 Complex compound [Cr(NCS)(NH3)5] [ZnCl4] will be
(A)Colourless&diamagnetic
(B) Greencoloured& diamagnetic
(C*)Greencoloured& shows coordination isomerism
(D)Diamagnetic&showslinkageisomerism

8. Q.40 The vapour pressureofpure perflourocyclohexane (C6F12)aregiven bythefollowingequations:
Solid C6F12 : log10 p(mm Hg) = 8.68 –
T
1890
Liquid C6F12 : log10 p(mm Hg) = 7.60 –
T
1530
Themolarenthalpyoffusionofsolid C6F12 is approximately
(A*) 1658 cal (B) 360 cal (C) 3420 cal (D) 720 cal
Q.41 + HNO3 + H2SO4  Product.
Productis:
(A*) (B) (C) (D) Both B & C
Q.42 Whichofthefollowingis correct.
(A) F2 has higherdissociation energythan Cl2
(B)Fhas higherelectronaffinitythanCl
(C) HF is stronger acid than HCl
(D*)Boilingpoint increases downthegroupinhalogens
Q.43 3
H
N

– CH(R)– CO2H has its Ka1 = 10–7. The isoelectric point of the -amino acid occur at pH = 8.2
hence pKa2 of the conjugate acid of -amino acid is equal to
(A*) 9.4 (B) 1.2 (C) 7.6 (D) 2.4
Q.44 Theproduct ofI– with 
4
MnO inalkalinemedium is
(A) I2 (B*) 
3
IO (C) IO– (D) 
4
IO
Q.45 Whichofthe followingwill racemizeinpresenceofacidorbaseimpuritiesinaqueousmedium.
(A)
Cl
O
|
|
|
Ph
C
C
Me
|
CH3


 (B)
D
O
|
|
|
CH
C
CH
C
Me
|
H
3
2 



(C) (D*)
3
3
2
CH
O
|
|
|
CH
CH
C
C
Ph
|
H





9. Q.46 (X) + K2CO3 + Air 
 
Heat (Y)
(Y) + Cl2  (Z) Pink
Whichofthefollowingiscorrect?
(A) X = black, MnO2 , Y = Blue, K2CrO4, Z = KMnO4
(B) X = green, Cr2O3, Y = Yellow, K2CrO4 , Z = K2Cr2O7
(C*) X = black, MnO2 Y = green , K2MnO4, Z = KMnO4
(D) X = black, Bi2O3, Y= colourless KBiO2, Z = KBiO3
Q.47 Writecorrect order of stability
(A) I > II > III > IV (B*) III > II > I > IV (C) III > I > II > IV (D) III > II > IV > I
Q.48 The structure of diborane (B2H6)contains
(A) Four (2C–2e–) bonds and two (2C–3e–) bonds
(B) Two (2C–2e–) bonds and two (3C–2e–) bonds
(C) Four (2C–2e–) bonds and four (3C– 2e–) bonds
(D*) None
Q.49 This question consist of two statements each, printed as assertion and reason, while answering this
question youare required to chooseanyone of thefollowing responses.
(A) If both assertion and reason are true and the reason is a correct explanation of assertion.
(B) If both assertion and reason are true but reason is not a correct explanation of assertion.
(C) If assertionis true but thereason is false.
(D) If assertion is false but thereason is true.
Assertion : Me MgBr give CH4 with acetone.
Reason :  – H of carbonyl compounds are active (acidic). [Ans.D]
Q.50 Nitrogen dioxide cannot be obtained from
(A) Cu(NO3)2 (B) Hg(NO3)2 (C*) NaNO3 (D)AgNO3
Q.51 PhCHO&HCHOwillbehavedifferentlywithwhichofthefollowingreagents
(A)Tollen's Reagent (B*)FehlingSolution (C)Schiff'sreagent (D) NaBH4
Q.52 The oxide does not have coordinate bond is
(A) N2O (B*) NO (C) N2O5 (D) NO2

10. Q.53 & are:
(A*)chainisomers (B)positionalisomers (C)conformers (D)enantiomers
Q.54 FeSO4 is a verygood absorber for NO, the new compound formed by this process is found to contain
number ofunpairedelectrons
(A) 4 (B) 5 (C*) 3 (D) 6
Q.55 Most stableformofethyleneglycol is:
(A)anti (B*)gauche (C)fullyeclipsed (D)partiallyeclipsed
Q.56 Theformation of 
4
PH is difficultcompared to 
4
NH because
(A)lonepairofphosphorus isopticallyinert
(B) lone pairof phosphorus resides at almost pure p-orbital
(C) lone pair of phosphorus resides at sp3 orbital
(D*) lone pairof phosphorus resides atalmost pure s-orbital
Q.57 Whichofthe followingheptanols arechiral 1-heptanol, 2-heptanol, 3-heptanol, 4-heptanol.
(A)All arechiral (B*) 2-heptanol and 3-heptanol
(C) 2-heptanol, 3-heptanol & 4-heptanol (D) 3-heptanol and 4-heptanol
Q.58 What products areformedduring, the electrolysis of a concentrated aqueous solution of NaCl?
(I) Cl2 (g) (II) NaOH (aq) (III) H2 (g)
(A) Ionly (B) I & II only (C) I & III only (D*) I, II & III
Q.59 Predict themajorproductP infollowingreaction:
HCl
NaNO2


 
 P
(A*) (B)
(C) (D)

11. Q.60 The product Octalone is obtained byMichael addition followed byaldol condensation of reactants R
and S in presence of a base. S gives positiveiodoform test.
R + S 
 
 
,
B
Octalone
R andS are respectively:
(A) + CH3–CH=O (B) +
O
|
|
H
C
CH
CH2 


(C*) +
O
|
|
CH
C
CH
CH 3
2 

 (D) +
O
|
|
CH
C
CH
CH 3
2
3 


Question No. 61 & 62 (2 questions)
Q.61 StepC(refining)involvedinpurificationofPbmetal
(A)Distillation (B)Bessemerization
(C)Cupelation (D*)Electrolyticrefining
Q.62 Whichofthefollowingmetalsareobtained byautoreduction method:
Pb, Mn, Cu, Cr, Fe,Al.
(A) Cu, Fe (B) Cu, Pb, Mn (C) Mn, Cr, Pb (D*) Pb, Cu
Q.63 Thiscompoundonozonolysisgiveswhich ofthefollowingcompounds
(I) (II)
O
O
|
|
|
|
CHO
C
CH
C
C
OHC
|
|
O
2 




(III)
CHO
|
CHO (IV)
O
|
|
O
CH
CH
C
C
OHC
|
|
O
2 




(A) I, II, III & IV (B) I, III, IV (C*) I, II, III (D) I, II, IV

12. Q.64 In the reaction;
OH
CH
ONa
CH
3
3


 
 ; the product is
(A) (B*) (C) (D)
Q.65 ThecorrectIUPAC name of thefollowing compound is:
O
C
H
OH
|
|
CHO
CH
CH
C
O 2






(A)3,3-diformyl propanoic acid (B*) 3-formyl-4-oxo-butanoic acid
(C) 3,3-dioxo propanoic acid (D) 3,3-dicarbaldehyde propanoic acid
Q.66 CH2=CH–CH2–CH2–CCH )
eq
1
(
HBr

 
 Product is
(A) BrCH2–CH2–CH2–CH2–CCH (B) CH2=CH–CH2–CH2–CH = CH–Br
(C)
Br
|
CH
C
CH
CH
CH
CH 2
2
2
2 



 (D*)
Br
|
CH
C
CH
CH
CH
CH 2
2
3 



