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ORGANIC DYE LASERS
By: AMIRAH BINTI BASIR
SIF170004
MODERN OPTICS & LASER PHYSICS (SIF2020)
PROF DR. OOI CHONG HENG
1
OUTCOMES
- INTRODUCTION
- CONSTRUCTION
- MECHANISM
- ADVANTAGES & DISADVANTAGES
- APPLICATIONS
2
INTRODUCTION
USES ORGANIC DYE AS LASING MEDIUM, USUALLY LIQUID
FORM
DYE HAVE VERY BROAD EMISSION AND GAIN SPECTRUMS
SOME OF ORGANIC DYES : RHODAMINE 6G, FLUORESCENT
COUMARIN
IT IS TUNABLE – USE BIREFRINGENT GRATING TO PRODUCE
A SPECIFIC WAVELENGTH
3 MAIN TYPES : PULSED DYE LASER, CONTINUOUS WAVE
DYE LASER, MODE-LOCKED DYE LASER
3
WHY
ORGANIC
DYE
LASER???
AT EXCITATION WAVELENGTH, DYE HAVE STRONG ABSORPTION AND
AT LASING WAVELENGTH HAVE MINIMAL ABSORPTION. MINIMUM
OVERLAP BETWEEN ABSORPTION AND EMISSION SPECTRA
HIGH QUANTUM YIELD (0.5-1)
GOOD PHOTOCHEMICAL STABILITY
A SHORT FLUORESCEENCE LIFETIME (5-10ns)
LOW ABSORPTION IN THE FIRST EXCITED STATE AT THE PUMPING AND
LASING WAVELENGTH
LOW PROBABILITY OF INTERSYSTEM CROSSING TO THE TRIPLET STATE
4
DYE SPECTRAL EMISSION CHARACTERISTICS
5
CONSTRUCTION
MAJOR REQUIRED COMPONENTS
• ACTIVE/LASING MEDIUM
• PUMPING SOURCE
• RESONATOR
6
ACTIVE MEDIUM
> LIQUID MATERIAL
ORGANIC DYE
+
WATER, BENZENE,
ALCOHOL E.T.C
PUMPING
SOURCE
> NEED ENERGY TO
EXCITE THE DYE
> FLASH LAMPS AND
SEVERAL TYPES OF
LASER IS USED
> ACTUALLY A
SOURCE OF PHOTONS
RESONATOR
> MIRRORS
> FOR TUNING -
REPLACE ONE OF THE
MIRRORS WITH
BIREFRINGENT
DIFFRACTION GRATING
7
CONFIGURATION 1
- DYE IS PUMPED THROUGH
THE CAPILLARY TUBE FROM
STORAGE TANK
- FLASH LAMP OPTICALLY
EXCITE THE DYE WHILE IN
CAPILLARY TUBE
- THE OUTPUT OF THE LASER
PASSES THROUGH BREWSTER
WINDOW TO THE OUTPUT
COUPLER
8
CONFIGURATION 2
- DYE IS PUMPED THROUGH
NOZZLE AT HIGH SPEED TO
FORM BREWSTER ANGLE
JET STREAM
- THE EXCITATION
MECHANISM : SECOND
LASER (Eg: ARGON LASER)
- THE LASER BEAM
REFLECTED FROM TWO
HIGH REFLECTIVE MIRRORS
TO THE OUTPUT COUPLER
9
MECHANISM
PUMP LIGHT SOURCE EXCITES THE DYE MOLECULES TO EXCITED SINGLET
STATE
THE DYE MOLECULES EMIT LIGHT VIA FLUORESCENCE, AND BECOME
TRANSPARENT TO THE LASING WAVELENGTH
WITHIN MICROSECOND, MOLECULES CHANGE TO THEIR TRIPLET STATE –
PHOSPHORESCENCE LIGHT EMITTED
MOLECULES ABSORB THE LASING WAVELENGTH, DYE BECOME OPAQUE
10
3 MAIN TYPES
OF ORGANIC
DYE LASER
• PUMPED BY OTHER LASERS (EXCIMER, NITROGEN OR
FREQUENCY-MULTIPLIED Nd:YAG LASER)
• 2MW dye laser pumped by Nitrogen laser
PULSED DYE LASER
• PUMPED BY A CONTINUOUS WAVE LASER (EG: Ar
LASER)
• CW dye laser with 5W Ar ion laser
CONTINUOUS WAVE DYE LASER
• PRODUCE VERY SHORT PULSES WHEN USING
DIPERSIVE PRISM / GRATINGS IN CAVITY
MODE-LOCKED (SHORT PULSE) DYE LASER
11
• ADVANTAGES
• SMALL BEAM DIAMETER
• LESS BEAM DIVERGENCE
• HIGH OUTPUT POWER
• NOT SO COMPLEX
CONSTRUCTION
• GOOD EFFICIENCY
• DISADVANTAGES
• HIGH COST – NEED TO INSERT
GRATINGS
• NEED OTHER LASER BEAMS
12
APPLICATION
S
RESEARCH TOOL
• LASER-INDUCED
FLUORESCENCE (LIF)
• TUNABLE DYE LASER
OSCILLATOR-AMPLIFIER
MEDICINE
• OPTICAL FIBRE CATHERER
• PULSED DYE LASER
13
APPLICATIONS IN RESEARCH TOOLS
14
LASER-INDUCED
FLUORESCENCE (LIF) :
COMBINATION OF DYE LASER
AND NITROGEN LASER
-> analytical tool used in
combustion research
laboratories for sensitive,
spatially resolved detection of
minor species
TUNABLE DYE LASER
OSCILLATOR-AMPLIFIER :
DYE LASER PUMPED BY
COPPER VAPOR LASER
–> applied in atomic vapour
laser isotope separation
(ALVIS)
APPLICATIONS IN MEDICINE
15
PULSED DYE LASER TREATMENT
–> bright light is used to
destroy the abnormal blood
vessels under the skin, number
of pulses in a treatment
depend on the size of the
birthmark / malignancies
OPTICAL FIBRE CATHERER :
Laser angioplasty with pulsed
dye laser and integral ball-tiped
optical fibres
-> shatter kidney stones or gall
stones
SUMMARY
• USES ORGANIC DYE AS ACTIVE MEDIUM
• PRODUCE WIDE WAVELENGTH OUTPUT LASER
(VISIBLE, ULTRAVIOLET AND NEAR INFRARED
SPECTRUM)
• ALSO KNOWN AS TUNABLE LASER
• HAVE MORE ADVANTAGES THAN DISADVANTAGES
• USEFUL IN MANY APPLICATIONS
16
REFERENCES
• https://en.wikipedia.org/wiki/Dye_laser#Construction
• https://www.ias.ac.in/article/fulltext/reso/015/09/0804-0818
• https://www.daenotes.com/electronics/microwave-radar/dye-
laser
• https://www.colby.edu/chemistry/PChem/lab/DyeLaser.pdf
• https://www.youtube.com/watch?v=TYHVWQNdod0
• https://www.slideshare.net/search/slideshow?searchfrom=he
ader&q=dye+laser
• Silfvast, W.T., Laser Fundamentals, 1996, Cambridge University
Press
17
Thank You
18

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Presentation Modern Optics and Laser Physics (Organic Dye Laser)

  • 1. ORGANIC DYE LASERS By: AMIRAH BINTI BASIR SIF170004 MODERN OPTICS & LASER PHYSICS (SIF2020) PROF DR. OOI CHONG HENG 1
  • 2. OUTCOMES - INTRODUCTION - CONSTRUCTION - MECHANISM - ADVANTAGES & DISADVANTAGES - APPLICATIONS 2
  • 3. INTRODUCTION USES ORGANIC DYE AS LASING MEDIUM, USUALLY LIQUID FORM DYE HAVE VERY BROAD EMISSION AND GAIN SPECTRUMS SOME OF ORGANIC DYES : RHODAMINE 6G, FLUORESCENT COUMARIN IT IS TUNABLE – USE BIREFRINGENT GRATING TO PRODUCE A SPECIFIC WAVELENGTH 3 MAIN TYPES : PULSED DYE LASER, CONTINUOUS WAVE DYE LASER, MODE-LOCKED DYE LASER 3
  • 4. WHY ORGANIC DYE LASER??? AT EXCITATION WAVELENGTH, DYE HAVE STRONG ABSORPTION AND AT LASING WAVELENGTH HAVE MINIMAL ABSORPTION. MINIMUM OVERLAP BETWEEN ABSORPTION AND EMISSION SPECTRA HIGH QUANTUM YIELD (0.5-1) GOOD PHOTOCHEMICAL STABILITY A SHORT FLUORESCEENCE LIFETIME (5-10ns) LOW ABSORPTION IN THE FIRST EXCITED STATE AT THE PUMPING AND LASING WAVELENGTH LOW PROBABILITY OF INTERSYSTEM CROSSING TO THE TRIPLET STATE 4
  • 5. DYE SPECTRAL EMISSION CHARACTERISTICS 5
  • 6. CONSTRUCTION MAJOR REQUIRED COMPONENTS • ACTIVE/LASING MEDIUM • PUMPING SOURCE • RESONATOR 6
  • 7. ACTIVE MEDIUM > LIQUID MATERIAL ORGANIC DYE + WATER, BENZENE, ALCOHOL E.T.C PUMPING SOURCE > NEED ENERGY TO EXCITE THE DYE > FLASH LAMPS AND SEVERAL TYPES OF LASER IS USED > ACTUALLY A SOURCE OF PHOTONS RESONATOR > MIRRORS > FOR TUNING - REPLACE ONE OF THE MIRRORS WITH BIREFRINGENT DIFFRACTION GRATING 7
  • 8. CONFIGURATION 1 - DYE IS PUMPED THROUGH THE CAPILLARY TUBE FROM STORAGE TANK - FLASH LAMP OPTICALLY EXCITE THE DYE WHILE IN CAPILLARY TUBE - THE OUTPUT OF THE LASER PASSES THROUGH BREWSTER WINDOW TO THE OUTPUT COUPLER 8
  • 9. CONFIGURATION 2 - DYE IS PUMPED THROUGH NOZZLE AT HIGH SPEED TO FORM BREWSTER ANGLE JET STREAM - THE EXCITATION MECHANISM : SECOND LASER (Eg: ARGON LASER) - THE LASER BEAM REFLECTED FROM TWO HIGH REFLECTIVE MIRRORS TO THE OUTPUT COUPLER 9
  • 10. MECHANISM PUMP LIGHT SOURCE EXCITES THE DYE MOLECULES TO EXCITED SINGLET STATE THE DYE MOLECULES EMIT LIGHT VIA FLUORESCENCE, AND BECOME TRANSPARENT TO THE LASING WAVELENGTH WITHIN MICROSECOND, MOLECULES CHANGE TO THEIR TRIPLET STATE – PHOSPHORESCENCE LIGHT EMITTED MOLECULES ABSORB THE LASING WAVELENGTH, DYE BECOME OPAQUE 10
  • 11. 3 MAIN TYPES OF ORGANIC DYE LASER • PUMPED BY OTHER LASERS (EXCIMER, NITROGEN OR FREQUENCY-MULTIPLIED Nd:YAG LASER) • 2MW dye laser pumped by Nitrogen laser PULSED DYE LASER • PUMPED BY A CONTINUOUS WAVE LASER (EG: Ar LASER) • CW dye laser with 5W Ar ion laser CONTINUOUS WAVE DYE LASER • PRODUCE VERY SHORT PULSES WHEN USING DIPERSIVE PRISM / GRATINGS IN CAVITY MODE-LOCKED (SHORT PULSE) DYE LASER 11
  • 12. • ADVANTAGES • SMALL BEAM DIAMETER • LESS BEAM DIVERGENCE • HIGH OUTPUT POWER • NOT SO COMPLEX CONSTRUCTION • GOOD EFFICIENCY • DISADVANTAGES • HIGH COST – NEED TO INSERT GRATINGS • NEED OTHER LASER BEAMS 12
  • 13. APPLICATION S RESEARCH TOOL • LASER-INDUCED FLUORESCENCE (LIF) • TUNABLE DYE LASER OSCILLATOR-AMPLIFIER MEDICINE • OPTICAL FIBRE CATHERER • PULSED DYE LASER 13
  • 14. APPLICATIONS IN RESEARCH TOOLS 14 LASER-INDUCED FLUORESCENCE (LIF) : COMBINATION OF DYE LASER AND NITROGEN LASER -> analytical tool used in combustion research laboratories for sensitive, spatially resolved detection of minor species TUNABLE DYE LASER OSCILLATOR-AMPLIFIER : DYE LASER PUMPED BY COPPER VAPOR LASER –> applied in atomic vapour laser isotope separation (ALVIS)
  • 15. APPLICATIONS IN MEDICINE 15 PULSED DYE LASER TREATMENT –> bright light is used to destroy the abnormal blood vessels under the skin, number of pulses in a treatment depend on the size of the birthmark / malignancies OPTICAL FIBRE CATHERER : Laser angioplasty with pulsed dye laser and integral ball-tiped optical fibres -> shatter kidney stones or gall stones
  • 16. SUMMARY • USES ORGANIC DYE AS ACTIVE MEDIUM • PRODUCE WIDE WAVELENGTH OUTPUT LASER (VISIBLE, ULTRAVIOLET AND NEAR INFRARED SPECTRUM) • ALSO KNOWN AS TUNABLE LASER • HAVE MORE ADVANTAGES THAN DISADVANTAGES • USEFUL IN MANY APPLICATIONS 16
  • 17. REFERENCES • https://en.wikipedia.org/wiki/Dye_laser#Construction • https://www.ias.ac.in/article/fulltext/reso/015/09/0804-0818 • https://www.daenotes.com/electronics/microwave-radar/dye- laser • https://www.colby.edu/chemistry/PChem/lab/DyeLaser.pdf • https://www.youtube.com/watch?v=TYHVWQNdod0 • https://www.slideshare.net/search/slideshow?searchfrom=he ader&q=dye+laser • Silfvast, W.T., Laser Fundamentals, 1996, Cambridge University Press 17