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Microelectronics Biotechnology New Functional
Materials
Solid State Physics Biological
Science
Nanoscience and
Nanotechnology
1950 1975 2000 2025
IMPACT
TECHNOLOGY WAVES
A nanometre is one millionth of a millimetre
80,000 nanoparticles in a row
Football (22cm) Flea
(1mm)
Hair
(80ฮผm)
Red blood cell
(7ฮผm)
Virus
(150nm)
Buckyball
(0.8nm)
60nm 40nm 1nm20nm80nm100nm
1m 10-1m 10-2m 10-3m 10-4m 10-5m 10-6m 10-7m 10-8m 10-9m 10-10m
1mm1m 1ฮผm 1nm100nm
DNAstrand
(2nm)
Sunscreen TiO2
(35nm)
APPRECIATING SIZE
Cassein nanoparticles
USS John C Stennis & HMS Illustrious
1 m
Cube
Size
No. of cubes in
1 cubic metre
1
Total surface
area
6 m2
1 nm 1027 6,000,000,000 m2 = 6,000 km2
1 cm 1,000,000 600 m2
1 mm 1,000,000,000 6,000 m2
710 km2
1 cm3
1 nm3
PROPORTION OF SURFACE ATOMS
1 in 107
80% on surface
PROPERTIES OF NANOPARTICLES
Conditions: 25oC, pH7, in water
1 nm3
Time to dissolve:SAND
1 mm3
34 million years
1.1 seconds
Billions US$
3,000
2,500
2,000
1,500
1,000
500
0
2001 2003 2005 2007 2009 2011 2013 2015
PESIMISTIC
OPTIMISTIC
Sources: German Government, Evolution Capital, National Science Foundation, Sal. Oppenheim, DG Bank, DTI, US
Business Alliance, Cientifica, In Realis, MitsubishiResearch Institute, Deutsche Bank, Nomura Research Institute, BCC,
GEMZ Corp, Helmut Kaiser Consultancy, Lux Research.
52%
24%
24%
$5.8 billion
by 2012
2006
NANOTECHNOLOGY VALUE CHAIN
CUSTOMERSystemNano-enabled
product
Nano-
intermediate
e.g.
nanocomposite
Nanomaterial
component
e.g.
nanoparticles
738
209
124
105
82
59 44 30
0
100
200
300
400
500
600
700
800
COMMERCIAL PRODUCTS USING NANOTECHNOLOGY
NUMBEROFPRODUCTS
Nanotechnology types
DIMENSIONS EXAMPLES BENEFITS
Thin films
Barrier properties
Lighter weight
Reinforcement
Durable surfaces
Clays
Surface coatings
Graphene
Nanoparticles
SiO2
TiO2
ZnO
CeO2
fullerenes
etc.
Reinforcement
Scratch resistance
Antimicrobial
UV resistance
Flame retardancy
Carbon nanotubes
Nanofibres
Mechanical reinforcement
Weight saving
Nano tubes
NANOTECHNOLOGY
IN THE
FOOD SECTOR
LIGHTER WEIGHT
PACKAGING
NOVEL BARRIER
MATERIALS
TEXTURE, TASTE &
HEALTH IMPROVEMENT
TRACK & TRACE AND FOOD
SPOILAGE DETECTION
ANTI-MICROBIALS
FUNCTIONAL
COATINGS
LIGHTER WEIGHT
PACKAGING
1 micron
TEM of refined Montmorillonite
1 nanometre thick
DIMENSIONS OF A CLAY PLATLET
THE PROCESSING CHALLENGE
8ยต particle size > 1 million platelets
+ + + + +
+
+
+ + + + +
+
+
Dry clay mineral
+ + + + +
+
+
+ + + + +
+
+
Expansion due to
absorption of water
Clay Exfoliated Clay Exfoliated Nanocomposite
Good dispersion
is crucial
CHEVY AVALANCHE
FORD THUNDERBIRD
HUMMER
CHEVROLET IMPALA
TANGIBLE BENEFITS OF NANOCOMPOSITE THERMOPLASTIC POLYOLEFINS
Mass savings up to 25%
Improved appearance
Large processing window
Reduced paint delamination
Retains low temperature ductility
Improved recyclability
Lower flammability
38%
22%
7%
6%
2%
25%
Packaging
Construction
Transport
Electrical
Medical
All others
Source: European Plastics Converters
For every ยฃ50 spent on
food, ยฃ8 goes towards the
packaging costs.
Adds ยฃ470 to the average
annual bill
NOVEL BARRIER
MATERIALS
1nm
1ฮผm
e.g. oxygen
clay platelets
increased shelf-life
Top 3: beer
meat
soft drinks
30%
27%
11%
9%
4%
4%
4% 10%
1%
Fresh Meat
Processed Meat
Dairy
Fruit & Veg
Bakery & Snack Foods
Convenience
Other Foods
Medical
Non-Foods
Source: Flexible & Plastic Packaging Innovation; vol.2, issue 2 (2008)
Total Market: 1.05 โ€“ 1.20 million tons
Total market for all barrier films (inc. Al foil) = 60 billion m2
GLOBAL MARKET FOR TRANSPARENT FLEXIBLE BARRIER PACKAGING
A hybrid plastic, comprising polyamide (PA) and layered silicate barriers
DURETHAN POLYAMIDE FILM FROM BAYER
MITSUBISHI AND NANOCOR PLASTIC BEER BOTTLES DEVELOPMENT
85
90
95
100
105
0 5 10 15 20 25
Storage time (weeks)
%Carbondioxideretention
PET
M9/PET
Nano-clay barrier
30
CA
PLA
PET
OPP
Starch
PE & PP
Oxygen Transmission Rate (cm3/m2/24hr @ 23oC & 50%RH)
MoistureVapourTransmissionRate
(g/m2/24hr@38oC&90%RH)
0.1 1.0 10 100 1000
1.0
10
100
1000
IMPROVING BARRIER PROPERTIES WITH NANOCOMPOSITE MATERIALS
4
3.5
3
2.5
2
1.5
1
0 10 20 30 40
Filler concentration (weight %)
Modulus
(GPa)
Nanoclay
Nanotubes
Milled glass
Talc
MODULUS vs FILLER TYPE AND CONCENTRATION
T D Formes & D R Paul, Polymer, Vol. 44, 2003, p 4993-5013
Smaller fillers are expected to
achieve the required stiffness at
lower filler concentration
CARBON NANOTUBES
50-100 x STRONGER THAN STEEL 1/6
th THE WEIGHT
300
200
100
0
Dry
Weight,
klb
Carbon fibre
reinforced polymer
-60%
Nanotubes in
polymer matrix
-68%
Nanotubes in
aluminium matrix
WEIGHT REDUCTION WITH CARBON NANOTUBES
BAYER CARBON NANOTUBES IN VELOZZI SOLO CAR
The SOLO crossover alternative energy vehicle from California-based Velozzi has carbon
nanotubes for body panels, and achieves 100 miles per gallon.
82% weight reduction compared to a brass pin.
One fifth the cost of the brass pin, and the finished 3-pin plug is 40% cheaper.
NEW CNTโ€“BASED FUEL PUMP FOR THE AUDI A4 AND A5
Emshield โ€“ nanotube-based sheet
material for protection against
electrostatic discharge
10-12 kg of CARBON NANOTUBES in one slice of TOAST
Andre
Geim
Konstantin
Novoselov
๏‚ฎ Rough and wrinkled surface texture
๏‚ฎ Surface area greater
๏‚ฎ Effective crack deflection
Highest thermal conductivity known today, five times that of copper
Electrical conductivity similar to copper
Low density - four times lower than copper
Many times stronger than steel
Surface area twice that of carbon nanotubes
Ultra-high Youngโ€™s modulus
High intrinsic strength
Outstanding resistance to gas permeation
FresherLonger containers are infused with silver nanoparticles
(24 hour growth of bacteria was reduced by over 98% inside FresherLonger
containers, compared with conventional ones)
FresherLongerโ„ข
Miracle Food Storage
SHARPER IMAGEยฎ (USA)
STORAGE AFTER 15 DAYS
FresherLongerโ„ข
Non-silver container
NANO-SILVER FOOD PACKAGING FILM
5 Days
PP film without nano-silver
5 Days
PP film with nano-silver
Sukoyaka baby milk
(nano-silver food storage containers)
(nano-silver rubber gloves)
(nano-silver bristles for baby bottle brushes)
NANO CARE TECHNOLOGY
HONG KONG
Nano-silver based coatings for
cutlery and handles
Koichi Wakata
Japanese astronaut
Boeing 787
Special air filters to maintain higher air quality
Silver nanofilters kill 99.7% of influenza viruses
FUNCTIONAL COATINGS
& COMPOSITES
DURABLE
โ€ข Anti-corrosion
โ€ข Anti-scratch
โ€ข Increased strength
โ€ข Anti-UV
โ€ข Heat repulsion/transfer
โ€ข Self healing
AESTHETIC
โ€ข Colour effects
โ€ข Anti-fingerprint
MISCELLANEOUS
โ€ข Anti-reflective
โ€ข Anti-static
โ€ข Insulating
โ€ข Super hydrophobic
โ€ข Barrier provision
CLEANER
โ€ข Anti-microbial
โ€ข Anti-pollution
โ€ข Self cleaning
NANOPARTICLES
in
SUN-SCREENS
scatter harmful UV light
but not visible light
Sales: โ‚ฌ19.5 billion
Countries: 130
International Brands: 23
Operating Profit: โ‚ฌ3.1 billion
Research & Innovation: โ‚ฌ665 million
Employees: 66,600
Research Employees: 3,420
Patents: 612
Stenocara beetle, Namib Desert
Glass cleaner with Nano-Protectยฎ
from Henkel KGaA
Nano-based lacquers are now on the market.
Firth of Forth Railway Bridge
GreenPanโ„ข Thermalon
Ceramic Nano-coating
NANO-COATED
BOWLING BALLS
DIRT
COATING
GLASS
UV
RAIN
Jubilee Church, Rome
(Dio Padre Misericordioso)
Yokohama Landmark Tower
Decomposes allergens, odours, germs, gases, fumes and more
(Nano TiO2 as oxidant)
THE NANOBREEZE ROOM AIR PURIFIER
NanoBreeze Room Air Purifier
TRACK & TRACE ANDTRACK & TRACE AND
FOOD SPOILAGE
DETECTION
Total market for
MOLECULAR DIAGNOSTICS
$5.5 billion
in 2004
$12 billion
in 2010
Sensors alert retailer and consumerSensors alert retailer and consumer
AgroMicron Nano Bioluminescence Detection SprayAgroMicron Nano Bioluminescence Detection Spray
Green fluorescent protein conjugated to pathogen-specific antibodies
When applied to a food or beverage, it reacts with the pathogen and produces
a visual glow
Glow intensity correlates to number of bacteria detected
Low cost and portable
Feasible for a broad range of pathogens
Colour Without Dyes
ROMAN, 400 AD
40 ppm Gold + 300 ppm Silver
70 nm nanoparticles
TEXTURE, TASTE
& HEALTH
IMPROVEMENT
EMULSIONS
PARTICLES
CAPSULES
CARRIERS
DELIVERY SYSTEMS
AT THE
NANO SCALE
Water droplets in oil
(5,000 nm)
Margarine
EMULSIONS
likes to be in oil
likes to be in water
emulsifier
water
oil
EMULSIONS
emulsifier
water
oil
EMULSIONS
emulsifier
water
water
oil
EMULSIONS
Saturday 31st January 2009
CAPSULES
The Miller โ€“ from an engraving of the sixteenth century by J Amman
Nano Micro
PARTICLE SIZE DISTRIBUTION
Macro
Amount
Size
ShenZhen jingyeNano-Tech Company Ltd
Nano Tea
Korea
Flavourings with RBC NanoCluster delivery systems
Combination of 8 powerful anti-oxidants
Products have been created that:
โ€ข Scavenge more free radicals
โ€ข Increase hydration
โ€ข Reduce the surface tension of foods and supplements to increase
wetness and absorption of nutrients
NANOTECHNOLOGY โ€“ THE SCIENCE OF BETTER SUPPLEMENTS
Royal Body Care
0
10
20
30
40
50
60
70
80
2007 2013
Supplements
Foods
Beverages
$117.3 billion
$ billion
CAGR 6.9%
CAGR 10.8%
GROWTH IN NUTRACEUTICALS
$176.6 billion
BCC Research
MISCELLANEOUS
APPLICATIONS
NANOPARTICLES IN INKJET PRINTING
Nanotechnology
Hype
Science
Fiction
Lack of
Awareness
Prof. Gunter Oberdรถrster argued that most studies
are of limited value to a risk assessment as they have
been performed at unrealistic exposure doses.
http://www.nanotech.com.hk/en/first.html
TATA NANO
TATA NANO
HEX BUG Nano
Daily Telegraph December 2007
Nanomaterials intentionally produced to have specific properties or specific
composition, a size range typically between 1 nm and 100 nm and material
which is either a nano-object (i.e. that is confined in one, two, or three
dimensions at the nanoscale) or is nanostructured (i.e. having an internal or
surface structure at the nanoscale).
Forest
50,000 per cm3
Urban street
100,000 per cm3
Normal room
15,000 per cm3
LIVING WITH NANOPARTICLES
10-12
pico
10-9
nano
10-15
femto
10-18
atto
10-21
zepto
10-24
yocto
10-6
micro
10-3
milli
103
kilo
106
Mega
109
Giga
1012
Tera
1015
Peta
1018
Exa
1021
Zetta
1024
Yotta
AFRIS. AsianFoodRegulationInformationService.
We have the largest database of Asian food regulations in the world and itโ€™s
FREE to use.
We publish a range of communication services, list a very large number of
food events and online educational webinars and continue to grow our Digital
Library.
We look forward to hearing from you soon!
www.asianfoodreg.com
adrienna@asianfoodreg.com

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