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Release Coats
       by
  Jimmy Lampley




                  April, 08
Definition of Release Coat

 What is a “release coat?”…..A
 coat/coating that will relieve,
 liberate, release, or free (as from
 restraint) when desired/ required.
Release Coat Schematic

               Release Coat



                Substrate:    Treated(Corona/chemical/primer)



Roll of tape   Adhesive
Types of Adhesive
Hot melt
Natural Rubber
SIS, SBS
Acrylate
Others
Substrates

Films: PE, PP, PET, PVC, Acetate,
       Perforated PE, Nonwoven
       PET
Paper
Foil
Cloth: Plain, PE coated
Release Coats Types

Silicone
Non-silicone
Non-Silicone
WATER                   SOLVENT
 Polyurethane             PVODC
 Urethane-Acrylic         PVSC
 Fluoro-polymer           Polyethylenimine
 PET/acrylic             Octadecyl Carbamate
 Vinylacetate/Acrylic    (PEIODC)
 Polysaccharide
Types of Release Coat
Type         Acrylate       Carbamate      Silicone
Release      1.0-1.5N/c      0.1-0.7N/c   0.01-0.1N/c
Level

              9-21 oz/in    1-6.5 oz/in   0.1-1 oz/in
Chemical
           Fluorochemical    PVODC         Silicone
Name
Types of Application
   Engraved Cylinder (rotogravure)
   Meyer Rod
   Reverse Doctor Blade
   Flexo

Need treatment (corona/chemical/primer)
Curing/Drying
Must dry web of solvent or water
Reach a temperature to remove fully the
solvent or water
Most release coats must also reach a specific
temperature to set, or film form
Web temperature/not air temperature
Assure the drying oven is free of obstructions
Film Forming Temperatures
Release Coat           Temp., C       Temp., F
Polyurethane           100            212

Ure-Acrylic            Dry of water   Dry of water

PET/Acrylic            100            212

Vinylacetate/acrylic   145            300

Polysaccharid          Dry of water   Dry of water
Film Forming Temperatures
Release Coat            Temp., C       Temp., F
Fluorpolymer, RA-110W   138            280

Fluorpolymer, RA-120W   Dry of water   Dry of water

PVODC                   80-92          176-196

PVSC                    >80            >176

PEIODC                  Approx. 90     Approx. 190
General Properties of Release Coats

  Liquid vs Powder
  Water-blended vs Solvent-blended
  A specific level of release, i.e. N/cm or Oz/in
  Any FDA requirements
  Long shelf life
  Aging at elevated temperature & humidity
Chemistries

PVODC

PVSC

PEIODC
Carbamate Release Coat Chemistry

                                          OH
                             CH2–CH–CH2–CH     n

CH2–CH      + C18H35N=C=O        O –C–N–C18H35
     OH n                           O H
                                    H
Polyvinyl       Octadecyl
 Alcohol        Isocyanate        Polyvinyl
                             Octadecyl Carbamate
Carbamate Release Coat Chemistry

                                                        OH
                                      CH2–CH–CH2–CH          n
CH2–CH           C18H37N=C=O
            +                             O –C–N–C18/16H35
      OH n        C16H37N=C=O
                                             O H
                                             H
Polyvinyl    Octadecyl Isocyanate
 Alcohol        Hexadecylisocyanate         Polyvinyl
                                        Stearyl Carbamate
Carbamate Release Coat Chemistry

   [H2N-(CH2–CH2N)x            -(CH2CH2NH)y]

          CH2CH2NH2

                                            (CH2-CH2N)n
Poly-Ethylenimine
         + C18H37N=C=O                           (C19H37NOC2H5N)X
                                 Pyridine
                                                    Polyethylenimine
        Octadecyl Isocyanate
                                                  Octadecyl Carbamate
Film Forming Temp
Performance Differences


                                 Anchorage


                                 Melt Point


                                 Solubility   PEIODC
                                     PVODC
                          PVSC
Film Forming Temp
Performance Differences


                                 Anchorage


                                 Melt Point


                                 Solubility   PEIODC
                                     PVODC
                          PVSC
Temperature   Cloud Point vs. Solvent




                0.3         0.5         0.7          1         1.5
                         Release Coat Solution % Solids

                      100% Toluene   15% Toluene/85% Heptane
Release Coat Weight vs.% Maximum Release

                                       Proper Film Forming Temperature Reached

                    100%
% Maximum Release




                    80%

                    60%

                    40%

                    20%

                     0%
                           0.1   0.2     0.5      1      1.5    2       3
                                       % Solids Release Coat
Coat Weight vs. Maximum Release

                          Proper Film Forming Temperature NOT Reached
% Maximum Release




                    100
                    80
                    60
                    40
                    20
                     0
                            0.1    0.2    0.5    1     1.5     2        3

                                   % Solids Release Coat
Release Coat Use Questions
 Oven Drying Capabilites (What web temp.
 can be obtained?)
 Recirculation equipment
 Temperature requirements
 Printable or not (What kinds of inks or with
 pencil/pen?)
 Foaming issues (with water based)
Water-Based Release Coat

               Preferred Emulsion
               Polymer system
                      R
    R

        R                     R
    R
                  R
Water-Based Release Coat
                                                    Relative Release Values
                            A ll S ilic o n e        Vin yla c e t a t e / a c rylic           Ure t h a n e - A c rylic        A c rylic

                      700

                      600
Pull Strength Value




                      500

                      400

                      300

                      200

                      100

                        0
                                 1       2      3    4       5       6       7         8   9       10      11      12      13   14    15

                                                         Relative Amount of Release
Water-Based Release Coat
                                              Relative Release Values
                                          Vin yla c e t a t e / a c rylic             Ure th a n e - A c rylic
                      700
Pull Strength Value




                      600
                                    RA-130W
                      500
                      400
                                                     Escoat WFX 120
                      300
                                                                                Escoat WPM80
                      200
                      100
                       0
                            1   2     3        4       5        6       7   8     9     10 11           12 13 14 15
                                                         Relative Amount of Release

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Release coats presentation-pstc

  • 1. Release Coats by Jimmy Lampley April, 08
  • 2. Definition of Release Coat What is a “release coat?”…..A coat/coating that will relieve, liberate, release, or free (as from restraint) when desired/ required.
  • 3. Release Coat Schematic Release Coat Substrate: Treated(Corona/chemical/primer) Roll of tape Adhesive
  • 4. Types of Adhesive Hot melt Natural Rubber SIS, SBS Acrylate Others
  • 5. Substrates Films: PE, PP, PET, PVC, Acetate, Perforated PE, Nonwoven PET Paper Foil Cloth: Plain, PE coated
  • 7. Non-Silicone WATER SOLVENT Polyurethane PVODC Urethane-Acrylic PVSC Fluoro-polymer Polyethylenimine PET/acrylic Octadecyl Carbamate Vinylacetate/Acrylic (PEIODC) Polysaccharide
  • 8. Types of Release Coat Type Acrylate Carbamate Silicone Release 1.0-1.5N/c 0.1-0.7N/c 0.01-0.1N/c Level 9-21 oz/in 1-6.5 oz/in 0.1-1 oz/in Chemical Fluorochemical PVODC Silicone Name
  • 9. Types of Application Engraved Cylinder (rotogravure) Meyer Rod Reverse Doctor Blade Flexo Need treatment (corona/chemical/primer)
  • 10. Curing/Drying Must dry web of solvent or water Reach a temperature to remove fully the solvent or water Most release coats must also reach a specific temperature to set, or film form Web temperature/not air temperature Assure the drying oven is free of obstructions
  • 11. Film Forming Temperatures Release Coat Temp., C Temp., F Polyurethane 100 212 Ure-Acrylic Dry of water Dry of water PET/Acrylic 100 212 Vinylacetate/acrylic 145 300 Polysaccharid Dry of water Dry of water
  • 12. Film Forming Temperatures Release Coat Temp., C Temp., F Fluorpolymer, RA-110W 138 280 Fluorpolymer, RA-120W Dry of water Dry of water PVODC 80-92 176-196 PVSC >80 >176 PEIODC Approx. 90 Approx. 190
  • 13. General Properties of Release Coats Liquid vs Powder Water-blended vs Solvent-blended A specific level of release, i.e. N/cm or Oz/in Any FDA requirements Long shelf life Aging at elevated temperature & humidity
  • 15. Carbamate Release Coat Chemistry OH CH2–CH–CH2–CH n CH2–CH + C18H35N=C=O O –C–N–C18H35 OH n O H H Polyvinyl Octadecyl Alcohol Isocyanate Polyvinyl Octadecyl Carbamate
  • 16. Carbamate Release Coat Chemistry OH CH2–CH–CH2–CH n CH2–CH C18H37N=C=O + O –C–N–C18/16H35 OH n C16H37N=C=O O H H Polyvinyl Octadecyl Isocyanate Alcohol Hexadecylisocyanate Polyvinyl Stearyl Carbamate
  • 17. Carbamate Release Coat Chemistry [H2N-(CH2–CH2N)x -(CH2CH2NH)y] CH2CH2NH2 (CH2-CH2N)n Poly-Ethylenimine + C18H37N=C=O (C19H37NOC2H5N)X Pyridine Polyethylenimine Octadecyl Isocyanate Octadecyl Carbamate
  • 18. Film Forming Temp Performance Differences Anchorage Melt Point Solubility PEIODC PVODC PVSC
  • 19. Film Forming Temp Performance Differences Anchorage Melt Point Solubility PEIODC PVODC PVSC
  • 20. Temperature Cloud Point vs. Solvent 0.3 0.5 0.7 1 1.5 Release Coat Solution % Solids 100% Toluene 15% Toluene/85% Heptane
  • 21. Release Coat Weight vs.% Maximum Release Proper Film Forming Temperature Reached 100% % Maximum Release 80% 60% 40% 20% 0% 0.1 0.2 0.5 1 1.5 2 3 % Solids Release Coat
  • 22. Coat Weight vs. Maximum Release Proper Film Forming Temperature NOT Reached % Maximum Release 100 80 60 40 20 0 0.1 0.2 0.5 1 1.5 2 3 % Solids Release Coat
  • 23. Release Coat Use Questions Oven Drying Capabilites (What web temp. can be obtained?) Recirculation equipment Temperature requirements Printable or not (What kinds of inks or with pencil/pen?) Foaming issues (with water based)
  • 24. Water-Based Release Coat Preferred Emulsion Polymer system R R R R R R
  • 25. Water-Based Release Coat Relative Release Values A ll S ilic o n e Vin yla c e t a t e / a c rylic Ure t h a n e - A c rylic A c rylic 700 600 Pull Strength Value 500 400 300 200 100 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Relative Amount of Release
  • 26. Water-Based Release Coat Relative Release Values Vin yla c e t a t e / a c rylic Ure th a n e - A c rylic 700 Pull Strength Value 600 RA-130W 500 400 Escoat WFX 120 300 Escoat WPM80 200 100 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Relative Amount of Release