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Collision Theory
What is collision theory?
For molecules to react they
must first collide
In addition, they must be
the right orientation …
… and have
enough energy
cv cv
What affects reaction rate?
Temperature
Pressure
Concentration
Particle size
Catalyst
How fast a chemical reaction
goes is affected by many
factors.
List them …
What about enzymes?
Enzymes are biological
catalysts and for our purposes
will be considered the same
as chemical catalysts
How fast a chemical reaction
goes is affected by many
factors.
List them ...
Chemical reaction rates
Temperature
Why does sugar dissolve
in tea faster than water?
High Temp
Molecules have
more energy …
… fewer collisions
Low Temp
Molecules have
less energy …
… fewer collisions
As surface area
increases the rate
of reaction
generally increases
The particles
on the
surface can
react
When cut into
smaller pieces
the particles
on the inside
can react
Chemical reaction rates
Surface Area
Which one will dissolve first in
a cup of tea?
As the concentration of
reactants increases, so
does the likelihood that
reactant molecules will
collide …The fewer red particles
in a volume - the less
chance of a collision
The more red particles in
the same volume -
there is more chance of
a collision
Chemical reaction rates
Concentration
… the rate of
reaction increases
Chemical reaction rates
Pressure
What happens if you
increase the pressure in a
reaction?
Increase in Pressure
Molecules
are closer
together
Number of
collisions
increases
Rate of
reaction
increases
A substance that
increases the rate
of a reaction
without being
consumed in the
reaction
Chemical reaction rates
Catalysts
What is a catalyst?
Provide an alternative
pathway for reactions
… are biological catalysts (proteins)
that increase the rate of biochemical
reactions
Enzymes …
Chemical reaction rates
Look at the picture below …
A =
B =
reactants
products
Activation
energy
The energy
required for two
colliding
molecules to
react
Activation Energy
Our picture from before
can be redrawn …
Enthalpy
Extent of reaction
Activation energy (Ea)
enthalpy = energy
Activation Energy
Enthalpy
Extent of reaction
Ea
Energy of reactants
Energy of products
Because …
Energy of
reactants
Energy of
products
Exothermic
>
Energy
given out
Activation Energy
Enthalpy
Extent of reaction
Energy of reactants
Energy of productsEa
Because …
Energy of reactants Energy of products
Endothermic
>
Energy
taken in

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Kinetics Revision

  • 1.
  • 2. Collision Theory What is collision theory? For molecules to react they must first collide In addition, they must be the right orientation … … and have enough energy cv cv
  • 3. What affects reaction rate? Temperature Pressure Concentration Particle size Catalyst How fast a chemical reaction goes is affected by many factors. List them … What about enzymes? Enzymes are biological catalysts and for our purposes will be considered the same as chemical catalysts How fast a chemical reaction goes is affected by many factors. List them ...
  • 4. Chemical reaction rates Temperature Why does sugar dissolve in tea faster than water? High Temp Molecules have more energy … … fewer collisions Low Temp Molecules have less energy … … fewer collisions
  • 5. As surface area increases the rate of reaction generally increases The particles on the surface can react When cut into smaller pieces the particles on the inside can react Chemical reaction rates Surface Area Which one will dissolve first in a cup of tea?
  • 6. As the concentration of reactants increases, so does the likelihood that reactant molecules will collide …The fewer red particles in a volume - the less chance of a collision The more red particles in the same volume - there is more chance of a collision Chemical reaction rates Concentration … the rate of reaction increases
  • 7. Chemical reaction rates Pressure What happens if you increase the pressure in a reaction? Increase in Pressure Molecules are closer together Number of collisions increases Rate of reaction increases
  • 8. A substance that increases the rate of a reaction without being consumed in the reaction Chemical reaction rates Catalysts What is a catalyst? Provide an alternative pathway for reactions … are biological catalysts (proteins) that increase the rate of biochemical reactions Enzymes …
  • 9. Chemical reaction rates Look at the picture below … A = B = reactants products Activation energy The energy required for two colliding molecules to react
  • 10. Activation Energy Our picture from before can be redrawn … Enthalpy Extent of reaction Activation energy (Ea) enthalpy = energy
  • 11. Activation Energy Enthalpy Extent of reaction Ea Energy of reactants Energy of products Because … Energy of reactants Energy of products Exothermic > Energy given out
  • 12. Activation Energy Enthalpy Extent of reaction Energy of reactants Energy of productsEa Because … Energy of reactants Energy of products Endothermic > Energy taken in