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MATERIALS : METALS                  AND      NON-METALS


Y
      ou are familiar with a number of     similar change if we try to beat a
      materials like iron, aluminium,      wood log ?
      copper, etc. Some materials have        Let us find out.
been given in Table 4.1.
                                           Activity 4.1
         Table 4.1 : Appearance and
           Hardness of materials            Take a small iron nail, a coal piece,
                                            a piece of thick aluminium wire and
  Object       Appearance     Hardness      a pencil lead. Beat the iron nail with
 /Material     (Shiny/Dull) (Very hard/
                                            a hammer (Fig. 4.1). (But take care
                              Not very
                                hard)       that you don’t hurt yourself in the
                                            process). Try to hit hard. Hit hard
 Iron
 Coal
 Sulphur
 Aluminium
 Copper
 -----                                      Fig. 4.1 : Beating an iron nail with hammer
                                            also the aluminium wire. Then
   Can you name the materials which         repeat the same kind of treatment
are metals? The rest of the materials in    on the coal piece and pencil
Table 4.1 are non-metals. Metals can be     lead. Record your observations in
distinguished from non-metals on the        Table 4.2.
basis of their physical and chemical
properties. Recall that lustre and          Table 4.2 Malleability of Materials
hardness are physical properties.           Object/             Change in Shape
                                            Material            (Flattens/Breaks
4.1 Physical Properties of                                      into pieces)
    Metals and Non-metals                   Iron nail
Have you ever seen a blacksmith beating     Coal piece
an iron piece or an article made up of      Aluminium wire
iron, like a spade, a shovel, an axe? Do
you find a change in the shape of these     Pencil lead
articles on beating? Would you expect a
You saw that the shape of the iron nail
and the aluminium wire changed on               the activity with various objects in
beating. If they were beaten harder these       Class VI. Now, repeat the activity
could be changed into sheets. You might         with the materials mentioned in
be familiar with silver foil used for           Table 4.3. Observe and group these
decorating sweets. You must also be             materials into good conductors and
familiar with the aluminium foil used for       poor conductors.
wrapping food. The property of metals by               Table 4.3 : Electrical
which they can be beaten into thin sheets            conductivity of materials
is called malleability. This is a
characteristic property of metals. As you      S.No. Materials       Good Conductor /
                                                                     Poor
must have noticed, materials like coal and
                                                                     Conductor
pencil lead do not show this property. Can
we call these as metals?                        1.   Iron rod/nail
    Can you hold a hot metallic pan which       2.   Sulphur
is without a plastic or a wooden handle
and not get hurt? Perhaps not! Why? Try         3.   Coal piece
to list some other experiences in which a       4.   Copper wire
wooden or plastic handle protects you
from being hurt while handling hot                You observe that iron rod, nail and
things. On the basis of these experiences     copper wire are good conductors while
what can you say about the conduction         rolled sulphur piece and coal piece are
of heat by wood and plastic?                  poor conductors.
    You must have seen an electrician
using his screw driver. What kind of
handle does it have? Why?
    Let us find out.                                   Oh! The meaning of recalling
                                                       our experiences and then of
Activity 4.2                                          this activity was to show that
                                                      metals are good conductors of
  Recall how to make an electric                      heat and electricity. We learnt
  circuit to test whether electricity can                    this in Class VI.
  pass through an object or not
  (Fig. 4.2). You might have performed           Where do you find the use of
                                              aluminium and copper wires? Have you
                                              seen wires of coal? Definitely not!
                                                 The property of metal by which it can
                                              be drawn into wires is called ductility.
                                                 Have you ever noticed the difference
                                              in sound on dropping an iron sheet/
                                              plate, a metal coin, and a piece of coal
                                              on the floor? If not, you can try it now.
                                                 Do you note any difference in the sound
           Fig. 4.2 : Electric tester         produced?
MATERIALS : METALS AND NON-METALS                                                   45
Have you seen wooden bells in            which rust is formed. You had also
temples? Can you give reason?                performed in Class VII an activity of
    The things made of metals produce        burning a magnesium ribbon in air. You
ringing sound when struck hard.              had learnt that in both the processes
Suppose you have two boxes similar in        oxide formation takes place. Complete
appearance, one made of wood and the         the following reactions of iron and
other of metal. Can you tell which box       magnesium with oxygen.
is made of metal by striking both the        Iron (Fe) + Oxygen (O2) + Water (H2O) → ?
boxes?                                       Magnesium (Mg) + Oxygen (O2) → ?
    Since metals produce ringing
sounds, they are said to be sonorous.        Activity 4.3
The materials other than metals are not
sonorous.                                      Let us check the nature of rust
    After performing the above activities,     formed as a result of the reaction
we can say that some materials are hard,       between iron, oxygen and water.
lustrous, malleable, ductile, sonorous         Collect a spoonful of rust and
and good conductors of heat and                dissolve it in a very little amount of
electricity. The materials which               water. You will find that the rust
generally posses these properties are          remains suspended in water. Shake
called metals. The examples of metals          the suspension well. Test the
are iron, copper, aluminium, calcium,          solution with red and blue litmus
magnesium, etc. In contrast, materials         papers (Fig. 4.3). What do you
like coal and sulphur are soft and dull        observe? Is the solution acidic or
in appearance. They break down into            basic?
powdery mass on tapping with hammer.
They are not sonorous and are poor
conductors of heat and electricity. These                            Rust
materials are called non-metals. The                              suspension
examples of non-metals are sulphur,
carbon, oxygen, phosphorus, etc.
                                                                                 Red litmus
                                                                                   paper
  Metals like sodium and potassium are
  soft and can be cut with a knife.
  Mercury is the only metal which is
  found in liquid state at room
  temperature. These are exceptions.


4.2 Chemical Properties of
    Metals and Non-metals
                                                                          Rust
A. Reaction with Oxygen
You are familiar with the phenomenon
                                                  Fig. 4.3 : Testing the nature of rust
of rusting of iron. Recall the reaction by
46                                                                                   SCIENCE
As soon as sulphur starts burning,
    Does copper also get
    rusted? I have seen
                                                introduce the spoon into a gas jar/
     a greenish deposit                         glass tumbler [Fig. 4.4 (a)]. Cover the
      on the surface of                         tumbler with a lid to ensure that
       copper vessels.                          the gas produced does not escape.
                                                Remove the spoon after some time.
                                                Add a small quantity of water into
  When a copper vessel is exposed to            the tumbler and quickly replace the
  moist air for long, it acquires a dull        lid. Shake the tumbler well. Check
  green coating. The green material is
                                                the solution with red and blue
  a mixture of copper hydroxide
  (Cu(OH) 2 ) and copper carbonate
                                                litmus papers [Fig. 4.4 (b)].
  (CuCO3). The following is the reaction
  2Cu+H2O+CO2+O2→Cu (OH)2 + CuCO3
         moist air
                                                                             Improvised
                                                                             deflagrating
    Now recall the activity of burning                                          spoon
magnesium ribbon. The ash obtained
on burning magnesium ribbon is
dissolved in water and tested for its
acidic / basic nature.
    Is the solution acidic or basic? How
do you ascertain this?
    You must have observed that the red
litmus turns blue. So, oxide of magnesium        Fig. 4.4 (a) : Burning of sulphur powder
is also basic in nature. In general, metallic
oxides are basic in nature.
    Let us now observe the reaction of
non-metals with oxygen.
Activity 4.4
  (To be demonstrated by the teacher
  in the class)
  Take a small amount of powdered
  sulphur in a deflagrating spoon and
  heat it. If deflagrating spoon is not
  available, you may take a metallic cap
  of any bottle and wrap a metallic wire
  around it and give it the shape
  shown in Fig. 4.4 (a).                        Fig. 4.4 (b) : Testing of solution with litmus
                                                                    papers

MATERIALS : METALS AND NON-METALS                                                           47
Table 4.4 : Metals and Non-metals in Acids and Bases

     S.No.   Name of the base         Metal       Name of the acid          Non-metal

      1.     Calcium hydroxide      Calcium        Sulphuric acid            Sulphur

      2.

      3.

      4.

      5.


   The name of the product formed in
the reaction of sulphur and oxygen is
                                              Activity 4.5
sulphur dioxide gas. When sulphur              To be demonstrated by the teacher.
dioxide is dissolved in water sulphurous       During demonstration special care
acid is formed. The reaction can be given      should be taken that the size of the
as follows:                                    sodium metal piece is roughly the
                                               size of a wheat grain. It should be
Sulphur dioxide (SO2) + Water (H2O) →          held with a pair of tongs.)
Sulphurous acid (H2SO3)                        Take a 250 mL beaker/glass tumbler.
    The sulphurous acid turns blue             Fill half of it with water. Now
litmus paper red. Generally, oxides of         carefully cut a small piece of sodium
                                               metal. Dry it using filter paper and
non-metals are acidic in nature.
                                               wrap it in a small piece of cotton.
    Recall the name of some of the             Put the sodium piece wrapped in
laboratory acids and bases you have read       cotton into the beaker. Observe
in Class VII. Note down their names in         carefully. During observation keep
Table 4.4. Identify the metal or non-          away from the beaker. When reaction
metal present in them which forms              stops touch the beaker. What do you
oxides with oxygen.                            feel? Has the beaker become hot?
                                               Test the solution with red and blue
B. Reaction with Water                         litmus papers. Is the solution acidic
Let us see how metals and non-metals           or basic?
react with water.

  Sodium metal is very reactive. It
  reacts vigorously with oxygen and
  water. A lot of heat is generated in
  the reaction. It is, therefore, stored
  in kerosene.                                  Fig. 4.5 : Reaction of sodium with water

48                                                                                 SCIENCE
You observed that sodium reacts                test tubes and label them as A, B,
vigorously with water. Some other metals           C, D, E, and F. With the help of a
do not do so. For example, iron reacts             dropper add 5 mL of dilute
with water slowly.                                 hydrochloric acid to each test tube
    Generally, non-metals do not react             one by one. Observe the reactions
with water though they may be very                 carefully. If no reaction occurs in a
reactive in air. Such non-metals are               cold solution, warm the test tube
stored in water. For example,                      gently. Bring a burning matchstick
phosphorus is a very reactive non-metal.           near the mouth of each test tube.
It catches fire if exposed to air. To prevent      Repeat the same activity using
the contact of phosphorus with                     dilute sulphuric acid instead of the
atmospheric oxygen, it is stored in water.         dilute hydrocholoric acid. Record
                                                   your observations in Table 4.5.
C. Reactions with Acids
Let us see how metals and non-metals                Is there a difference in the way metals
behave with acids.                               and non-metals react with acids? What
                                                 could the ‘pop’ sound in some cases be
Activity 4.6                                     due to when a burning match stick is
                                                 brought near the mouth of the test
  Warning : Keep the mouth of the
                                                 tubes?
  test tube away from your face. Use
                                                    You must have found that non-
  test tube holder to hold the test
                                                 metals generally do not react with acids
  tube.
                                                 but metals react with acids and produce
  Take samples of metals and non-
                                                 hydrogen gas that burns with a ‘pop’
  metals listed in Table 4.5 in separate
                                                 sound. You must have noticed that
             Table 4.5 : Reaction of metals and non-metals with acids

  Test      Metal/                    Reaction with dilute     Reaction with dilute
  tube     Non-Metal                   Hydrochloric acid          Sulphuric acid
  Label                                room       warm          room      warm
                                    temperature              temperature
     A     Magnesium
           (ribbon)
     B     Aluminium (foil)
     C     Iron (filings)
     D     Copper (peeled
           flexible wire)
     E     Charcoal (powder)
     F     Sulphur (powder)

MATERIALS : METALS AND NON-METALS                                                      49
copper does not react with dilute                    What does the ‘pop’ sound indicate?
hydrochloric acid even on heating but             As before, the ‘pop’ sound indicates the
it reacts with sulphuric acid.                    presence of hydrogen gas.
                                                     Metals react with sodium hydroxide
D. Reactions with Bases                           to produce hydrogen gas.
                                                     Reactions of non-metals with bases
Activity 4.7                                      are complex.

 To be demonstrated by the teacher.               E. Displacement Reactions
 During the preparation of sodium                 Recall the activity of the reaction between
 hydroxide solution, care should be               copper sulphate and iron that you
 taken that pellets of sodium                     performed in Class VII. Let us observe
 hydroxide are handled with a                     some more reactions of that kind.
 plastic spatula.
 Prepare a fresh solution of sodium               Activity 4.8
 hydroxide in a test tube by                         Take five 100 mL beakers and label
 dissolving 3-4 pellets of it in 5 mL                them A, B, C, D and E. Take about
 of water. Drop a piece of aluminium                 50 mL of water in each beaker.
 foil into it. Bring a burning match                 Dissolve in each beaker a
 stick near the mouth of the test                    teaspoonful of each substance as
 tube. Observe carefully.                            indicated in Fig. 4.6 (a).




     A    B       C        D       E      Beaker A : Copper sulphate (CuSO4) + Zinc granule (Zn),


                 (a)                      Beaker B : Copper sulphate (CuSO4) + Iron nail (Fe)


ZnSO4    FeSO4                            Beaker C : Zinc sulphate (ZnSO4) + Copper turnings (Cu),


                                          Beaker D : Iron sulphate (FeSO4) + Copper turnings (Cu)


                                          Beaker E : Zinc sulphate (ZnSO4) + Iron nail (Fe)
     A    B       C        D       E

Cu       Cu
                       No Change
                 (b)

                          Fig. 4.6 (a) and (b) : Displacement reactions
50                                                                                            SCIENCE
replace copper in beaker ‘A’ why cannot
    Keep the beakers undisturbed for        copper replace zinc in beaker ‘C’?
    some time.                              Remember that science is not arbitrary.
    Record your observations in your        It follows definite rules based on facts.
    note book.                              And the rule here is that zinc is more
                                            reactive than copper and iron. A more
   What changes do you observe in the
                                            reactive metal can replace a less reactive
various beakers? You have read that one
                                            metal, but a less reactive one cannot
metal displaces another metal from its
                                            replace a more reactive metal. Now you
compound in aqueous solution. In            can understand why there are no
beaker ‘A’ zinc (Zn) replaces copper (Cu)   displacement reactions in beakers D
from copper sulphate (CuSO4). That is       and E also. Can you guess the
why the blue colour of copper sulphate      sequence of metals from more reactive
disappears and a powdery red mass of        to less reactive among zinc, iron and
copper is deposited at the bottom of the    copper?
beaker. The reaction can be represented
as follows:                                 4.3 Uses of Metals and Non-
Copper Sulphate (CuSO4) + Zinc (Zn)             metals
        (Blue)                              You should be able to guess why metals
→ Zinc Sulphate (ZnSO4) + Copper (Cu)       are used in making machinery,
    (Colourless)             (Red)          automobiles, aeroplanes, trains,
                                            satellites, industrial gadgets, cooking
   You can write down the reaction
                                            utensils, water boilers, etc. You are also
taking place in beaker ‘B’ in a similar
                                            familiar with the uses of some non-
manner.
                                            metals. Here are some interesting ones.
                                            We are sure that you will guess them
                                            right:
                                               Non-metal essential for our life which
        I have understood the reactions        all living beings inhale during
         taking place in beakers ‘A’ and
                                               breathing,
        ‘B’. But I am still confused why
         there is no change in beakers
                                               Non-metals used in fertilisers to
                  ‘C’, ‘D’ and ‘E’?            enhance the growth of plants,
                                               Non-metal used in water purification
   There could have been displacement          process,
of zinc by copper in beaker ‘C’ and by         Non-metal used in the purple
iron in beaker ‘E’. Similarly iron could       coloured solution which is applied
be displaced by copper in beaker ‘D’.          on wounds as an antiseptic,
   Since we do not see any change in           Non-metals used in crackers.
beaker C, we can infer that copper is          You may add some more uses of
not able to replace zinc from zinc          metals and non-metals from your
sulphate. But why? When zinc can            experiences.

MATERIALS : METALS AND NON-METALS                                                 51
I heard that magnesium is                 Doctor reported iron
             found in plants. In what               deficiency in my body.
            form is it found in them?              Where is iron in my body?



In Class VII, you have learnt that in a chemical reaction, new substances are formed.
These substances are different from those which underwent the reaction. Now, if a
substance cannot be broken down further by chemical reactions, by cooling, heating,
or by electrolysis, it is called ‘element’. Sulphur is an element. So is iron. Carbon, too,
is an element. The smallest unit of an element is atom. A sample of an element
contains only one kind of atoms. The atom of an element remains unaffected by physical
changes in the element. For example, an atom of liquid sulphur would be exactly the
same as the atom of solid or vapour sulphur.
   Although we have an infinite variety of substances in the universe, the number of
elements forming these substances is limited. There are no more than 92 naturally
occurring elements. An important classification of elements is in terms of metals and
non-metals. Most of the elements are metals. Less than 20 are non-metals. A few are
metalloids which possess characters of both metals and non-metals.




52                                                                                 SCIENCE
KEYWORDS                                WHAT YOU HAVE LEARNT
    ATOM                                          Metals are lustrous whereas non-metals have
                                                  no lustre.
    CONDUCTOR
                                                  Generally, metals are malleable and ductile.
    DISPLACEMENT                                  Non-metals do not have these properties.
    REACTION                                      Generally, metals are good conductors of heat
                                                  and electricity but non-metals are poor
    DUCTILITY
                                                  conductors.
    ELEMENTS                                      On burning, metals react with oxygen to
                                                  produce metal oxides which are basic in
    HARDNESS
                                                  nature. Non-metals react with oxygen to
    MALLEABILITY                                  produce non- metallic oxides which are acidic
                                                  in nature.
    METALS
                                                  Some metals react with water to produce metal
    METALLOIDS                                    hydroxides and hydrogen gas. Generally, non-
                                                  metals do not react with water.
    NON-METALS
                                                  Metals react with acids and produce metal
    SONOROUS                                      salts and hydrogen gas. Generally, non-metals
                                                  do not react with acids.
                                                  Some metals react with bases to produce
                                                  hydrogen gas.
                                                  More reactive metals displace less reactive
                                                  metals from their compounds in aqueous
                                                  solutions.
                                                  Metals and non-metals are used widely in
                                                  every day life.



      Exercises

             1.   Which of the following can be beaten into thin sheets?

                  (a) Zinc     (b) Phosphorus         (c) Sulphur   (d) Oxygen
             2.   Which of the following statements is correct?
                  (a)   All metals are ductile.

                  (b)   All non-metals are ductile.
                  (c)   Generally, metals are ductile.
                  (d)   Some non-metals are ductile.
MATERIALS : METALS AND NON-METALS                                                                 53
3.   Fill in the blanks :

     EXERCISES        (a)        Phosphorus is very                   non-metal.
                      (b)        Metals are               conductors of heat and                    .
                      (c)     Iron is                  reactive than copper.
                      (d)        Metals react with acids to produce                  gas.

                 4.   Mark ‘T’ if the statement is true and ‘F’ if it is false.
                      (a)        Generally, non-metals react with acids.                    ( )
                      (b)        Sodium is a very reactive metal.                           ( )
                      (c)     Copper displaces zinc from zinc sulphate solution.            ( )
                      (d)        Coal can be drawn into wires.                              ( )
                 5.   Some properties are listed in the following Table. Distinguish between
                      metals and non-metals on the basis of these properties.

                            Properties                                Metals           Non-metals
                            1.     Appearance
                            2.     Hardness
                            3.     Malleability
                            4.     Ductility
                            5.     Heat Conduction
                            6.     Conduction of Electricity

                 6.   Give reasons for the following :
                      (a)     Aluminium foils are used to wrap food items.
                      (b)     Immersion rods for heating liquids are made up of metallic substances.
                      (c)     Copper cannot displace zinc from its salt solution.
                      (d)     Sodium and potassium are stored in kerosene.

                 7.   Can you store lemon pickle in an aluminium utensil? Explain.
                 8.   In the following Table some substances are given in Column I. In Column II
                      some uses are given. Match the items in column I with those in Column II.

                       Column I                                     Column II
                            (i) Gold                             (a) Thermometers
                        (ii) Iron                                (b) Electric wire
                       (iii) Aluminium                           (c) Wrapping food
                       (iv) Carbon                               (d) Jewellery
                        (v) Copper                               (e) Machinary
                       (vi) Mercury                              (f) Fuel

54                                                                                                      SCIENCE
9.    What happens when
       EXERCISES          (a) Dilute sulphuric acid is poured on a copper plate?
                          (b) Iron nails are placed in copper sulphate solution?
                               Write word equations of the reactions involved.
                    10. Saloni took a piece of burning charcoal and collected the gas evolved in a
                        test tube.
                          (a)    How will she find the nature of the gas ?
                          (b)    Write down word equations of all the reactions taking place in this
                                 process.
                    11. One day Reeta went to a jeweller’s shop with her mother. Her mother gave
                        old gold jewellery to the goldsmith to polish. Next day when they brought
                        the jewellery back, they found that there was a slight loss in its weight.
                        Can you suggest a reason for the loss in weight?



                   Extended Learning — Activities and Projects
                         1.     Prepare Index Cards for any four metals and four non-metals. The
                                card should have information like name of metal/non-metal; its
                                physical properties, chemical properties and its uses.
                         2.     Visit a blacksmith and observe how metals are moulded.

                         3.     Suggest an experiment to compare the conductivity of electricity by
                                iron, copper, aluminium and zinc. Perform the experiment and
                                prepare a short report on the results.

                         4.     Find out the locations of the deposits of iron, aluminium and zinc
                                in India. Mark these in an outline map of India. In which form are
                                the deposits found? Discuss in the class.

                         5.     Discuss with your parents/neighbours/goldsmiths why gold is
                                preferred for making jewellery.
                         6.     Visit the following websites and enjoy the quiz on metals and non-
                                metals:
                                   chemistry.about.com/library/weekly/bl050303a.htm
                                   chemistry.about.com/od/testsquizzes/Chemistry_Tests_
                                   Quizzes.htm
                                   www.syvum.com/cgi/online/mult.cgi/squizzes/science/
                                   metals.tdf?0
                                   www.gcsescience.com/q/qusemet.html
                                   www.corrosionsource.com/handbook/periodic/metals.htm



MATERIALS : METALS AND NON-METALS                                                                      55

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MATERIALS METALS NON-METALS

  • 1. MATERIALS : METALS AND NON-METALS Y ou are familiar with a number of similar change if we try to beat a materials like iron, aluminium, wood log ? copper, etc. Some materials have Let us find out. been given in Table 4.1. Activity 4.1 Table 4.1 : Appearance and Hardness of materials Take a small iron nail, a coal piece, a piece of thick aluminium wire and Object Appearance Hardness a pencil lead. Beat the iron nail with /Material (Shiny/Dull) (Very hard/ a hammer (Fig. 4.1). (But take care Not very hard) that you don’t hurt yourself in the process). Try to hit hard. Hit hard Iron Coal Sulphur Aluminium Copper ----- Fig. 4.1 : Beating an iron nail with hammer also the aluminium wire. Then Can you name the materials which repeat the same kind of treatment are metals? The rest of the materials in on the coal piece and pencil Table 4.1 are non-metals. Metals can be lead. Record your observations in distinguished from non-metals on the Table 4.2. basis of their physical and chemical properties. Recall that lustre and Table 4.2 Malleability of Materials hardness are physical properties. Object/ Change in Shape Material (Flattens/Breaks 4.1 Physical Properties of into pieces) Metals and Non-metals Iron nail Have you ever seen a blacksmith beating Coal piece an iron piece or an article made up of Aluminium wire iron, like a spade, a shovel, an axe? Do you find a change in the shape of these Pencil lead articles on beating? Would you expect a
  • 2. You saw that the shape of the iron nail and the aluminium wire changed on the activity with various objects in beating. If they were beaten harder these Class VI. Now, repeat the activity could be changed into sheets. You might with the materials mentioned in be familiar with silver foil used for Table 4.3. Observe and group these decorating sweets. You must also be materials into good conductors and familiar with the aluminium foil used for poor conductors. wrapping food. The property of metals by Table 4.3 : Electrical which they can be beaten into thin sheets conductivity of materials is called malleability. This is a characteristic property of metals. As you S.No. Materials Good Conductor / Poor must have noticed, materials like coal and Conductor pencil lead do not show this property. Can we call these as metals? 1. Iron rod/nail Can you hold a hot metallic pan which 2. Sulphur is without a plastic or a wooden handle and not get hurt? Perhaps not! Why? Try 3. Coal piece to list some other experiences in which a 4. Copper wire wooden or plastic handle protects you from being hurt while handling hot You observe that iron rod, nail and things. On the basis of these experiences copper wire are good conductors while what can you say about the conduction rolled sulphur piece and coal piece are of heat by wood and plastic? poor conductors. You must have seen an electrician using his screw driver. What kind of handle does it have? Why? Let us find out. Oh! The meaning of recalling our experiences and then of Activity 4.2 this activity was to show that metals are good conductors of Recall how to make an electric heat and electricity. We learnt circuit to test whether electricity can this in Class VI. pass through an object or not (Fig. 4.2). You might have performed Where do you find the use of aluminium and copper wires? Have you seen wires of coal? Definitely not! The property of metal by which it can be drawn into wires is called ductility. Have you ever noticed the difference in sound on dropping an iron sheet/ plate, a metal coin, and a piece of coal on the floor? If not, you can try it now. Do you note any difference in the sound Fig. 4.2 : Electric tester produced? MATERIALS : METALS AND NON-METALS 45
  • 3. Have you seen wooden bells in which rust is formed. You had also temples? Can you give reason? performed in Class VII an activity of The things made of metals produce burning a magnesium ribbon in air. You ringing sound when struck hard. had learnt that in both the processes Suppose you have two boxes similar in oxide formation takes place. Complete appearance, one made of wood and the the following reactions of iron and other of metal. Can you tell which box magnesium with oxygen. is made of metal by striking both the Iron (Fe) + Oxygen (O2) + Water (H2O) → ? boxes? Magnesium (Mg) + Oxygen (O2) → ? Since metals produce ringing sounds, they are said to be sonorous. Activity 4.3 The materials other than metals are not sonorous. Let us check the nature of rust After performing the above activities, formed as a result of the reaction we can say that some materials are hard, between iron, oxygen and water. lustrous, malleable, ductile, sonorous Collect a spoonful of rust and and good conductors of heat and dissolve it in a very little amount of electricity. The materials which water. You will find that the rust generally posses these properties are remains suspended in water. Shake called metals. The examples of metals the suspension well. Test the are iron, copper, aluminium, calcium, solution with red and blue litmus magnesium, etc. In contrast, materials papers (Fig. 4.3). What do you like coal and sulphur are soft and dull observe? Is the solution acidic or in appearance. They break down into basic? powdery mass on tapping with hammer. They are not sonorous and are poor conductors of heat and electricity. These Rust materials are called non-metals. The suspension examples of non-metals are sulphur, carbon, oxygen, phosphorus, etc. Red litmus paper Metals like sodium and potassium are soft and can be cut with a knife. Mercury is the only metal which is found in liquid state at room temperature. These are exceptions. 4.2 Chemical Properties of Metals and Non-metals Rust A. Reaction with Oxygen You are familiar with the phenomenon Fig. 4.3 : Testing the nature of rust of rusting of iron. Recall the reaction by 46 SCIENCE
  • 4. As soon as sulphur starts burning, Does copper also get rusted? I have seen introduce the spoon into a gas jar/ a greenish deposit glass tumbler [Fig. 4.4 (a)]. Cover the on the surface of tumbler with a lid to ensure that copper vessels. the gas produced does not escape. Remove the spoon after some time. Add a small quantity of water into When a copper vessel is exposed to the tumbler and quickly replace the moist air for long, it acquires a dull lid. Shake the tumbler well. Check green coating. The green material is the solution with red and blue a mixture of copper hydroxide (Cu(OH) 2 ) and copper carbonate litmus papers [Fig. 4.4 (b)]. (CuCO3). The following is the reaction 2Cu+H2O+CO2+O2→Cu (OH)2 + CuCO3 moist air Improvised deflagrating Now recall the activity of burning spoon magnesium ribbon. The ash obtained on burning magnesium ribbon is dissolved in water and tested for its acidic / basic nature. Is the solution acidic or basic? How do you ascertain this? You must have observed that the red litmus turns blue. So, oxide of magnesium Fig. 4.4 (a) : Burning of sulphur powder is also basic in nature. In general, metallic oxides are basic in nature. Let us now observe the reaction of non-metals with oxygen. Activity 4.4 (To be demonstrated by the teacher in the class) Take a small amount of powdered sulphur in a deflagrating spoon and heat it. If deflagrating spoon is not available, you may take a metallic cap of any bottle and wrap a metallic wire around it and give it the shape shown in Fig. 4.4 (a). Fig. 4.4 (b) : Testing of solution with litmus papers MATERIALS : METALS AND NON-METALS 47
  • 5. Table 4.4 : Metals and Non-metals in Acids and Bases S.No. Name of the base Metal Name of the acid Non-metal 1. Calcium hydroxide Calcium Sulphuric acid Sulphur 2. 3. 4. 5. The name of the product formed in the reaction of sulphur and oxygen is Activity 4.5 sulphur dioxide gas. When sulphur To be demonstrated by the teacher. dioxide is dissolved in water sulphurous During demonstration special care acid is formed. The reaction can be given should be taken that the size of the as follows: sodium metal piece is roughly the size of a wheat grain. It should be Sulphur dioxide (SO2) + Water (H2O) → held with a pair of tongs.) Sulphurous acid (H2SO3) Take a 250 mL beaker/glass tumbler. The sulphurous acid turns blue Fill half of it with water. Now litmus paper red. Generally, oxides of carefully cut a small piece of sodium metal. Dry it using filter paper and non-metals are acidic in nature. wrap it in a small piece of cotton. Recall the name of some of the Put the sodium piece wrapped in laboratory acids and bases you have read cotton into the beaker. Observe in Class VII. Note down their names in carefully. During observation keep Table 4.4. Identify the metal or non- away from the beaker. When reaction metal present in them which forms stops touch the beaker. What do you oxides with oxygen. feel? Has the beaker become hot? Test the solution with red and blue B. Reaction with Water litmus papers. Is the solution acidic Let us see how metals and non-metals or basic? react with water. Sodium metal is very reactive. It reacts vigorously with oxygen and water. A lot of heat is generated in the reaction. It is, therefore, stored in kerosene. Fig. 4.5 : Reaction of sodium with water 48 SCIENCE
  • 6. You observed that sodium reacts test tubes and label them as A, B, vigorously with water. Some other metals C, D, E, and F. With the help of a do not do so. For example, iron reacts dropper add 5 mL of dilute with water slowly. hydrochloric acid to each test tube Generally, non-metals do not react one by one. Observe the reactions with water though they may be very carefully. If no reaction occurs in a reactive in air. Such non-metals are cold solution, warm the test tube stored in water. For example, gently. Bring a burning matchstick phosphorus is a very reactive non-metal. near the mouth of each test tube. It catches fire if exposed to air. To prevent Repeat the same activity using the contact of phosphorus with dilute sulphuric acid instead of the atmospheric oxygen, it is stored in water. dilute hydrocholoric acid. Record your observations in Table 4.5. C. Reactions with Acids Let us see how metals and non-metals Is there a difference in the way metals behave with acids. and non-metals react with acids? What could the ‘pop’ sound in some cases be Activity 4.6 due to when a burning match stick is brought near the mouth of the test Warning : Keep the mouth of the tubes? test tube away from your face. Use You must have found that non- test tube holder to hold the test metals generally do not react with acids tube. but metals react with acids and produce Take samples of metals and non- hydrogen gas that burns with a ‘pop’ metals listed in Table 4.5 in separate sound. You must have noticed that Table 4.5 : Reaction of metals and non-metals with acids Test Metal/ Reaction with dilute Reaction with dilute tube Non-Metal Hydrochloric acid Sulphuric acid Label room warm room warm temperature temperature A Magnesium (ribbon) B Aluminium (foil) C Iron (filings) D Copper (peeled flexible wire) E Charcoal (powder) F Sulphur (powder) MATERIALS : METALS AND NON-METALS 49
  • 7. copper does not react with dilute What does the ‘pop’ sound indicate? hydrochloric acid even on heating but As before, the ‘pop’ sound indicates the it reacts with sulphuric acid. presence of hydrogen gas. Metals react with sodium hydroxide D. Reactions with Bases to produce hydrogen gas. Reactions of non-metals with bases Activity 4.7 are complex. To be demonstrated by the teacher. E. Displacement Reactions During the preparation of sodium Recall the activity of the reaction between hydroxide solution, care should be copper sulphate and iron that you taken that pellets of sodium performed in Class VII. Let us observe hydroxide are handled with a some more reactions of that kind. plastic spatula. Prepare a fresh solution of sodium Activity 4.8 hydroxide in a test tube by Take five 100 mL beakers and label dissolving 3-4 pellets of it in 5 mL them A, B, C, D and E. Take about of water. Drop a piece of aluminium 50 mL of water in each beaker. foil into it. Bring a burning match Dissolve in each beaker a stick near the mouth of the test teaspoonful of each substance as tube. Observe carefully. indicated in Fig. 4.6 (a). A B C D E Beaker A : Copper sulphate (CuSO4) + Zinc granule (Zn), (a) Beaker B : Copper sulphate (CuSO4) + Iron nail (Fe) ZnSO4 FeSO4 Beaker C : Zinc sulphate (ZnSO4) + Copper turnings (Cu), Beaker D : Iron sulphate (FeSO4) + Copper turnings (Cu) Beaker E : Zinc sulphate (ZnSO4) + Iron nail (Fe) A B C D E Cu Cu No Change (b) Fig. 4.6 (a) and (b) : Displacement reactions 50 SCIENCE
  • 8. replace copper in beaker ‘A’ why cannot Keep the beakers undisturbed for copper replace zinc in beaker ‘C’? some time. Remember that science is not arbitrary. Record your observations in your It follows definite rules based on facts. note book. And the rule here is that zinc is more reactive than copper and iron. A more What changes do you observe in the reactive metal can replace a less reactive various beakers? You have read that one metal, but a less reactive one cannot metal displaces another metal from its replace a more reactive metal. Now you compound in aqueous solution. In can understand why there are no beaker ‘A’ zinc (Zn) replaces copper (Cu) displacement reactions in beakers D from copper sulphate (CuSO4). That is and E also. Can you guess the why the blue colour of copper sulphate sequence of metals from more reactive disappears and a powdery red mass of to less reactive among zinc, iron and copper is deposited at the bottom of the copper? beaker. The reaction can be represented as follows: 4.3 Uses of Metals and Non- Copper Sulphate (CuSO4) + Zinc (Zn) metals (Blue) You should be able to guess why metals → Zinc Sulphate (ZnSO4) + Copper (Cu) are used in making machinery, (Colourless) (Red) automobiles, aeroplanes, trains, satellites, industrial gadgets, cooking You can write down the reaction utensils, water boilers, etc. You are also taking place in beaker ‘B’ in a similar familiar with the uses of some non- manner. metals. Here are some interesting ones. We are sure that you will guess them right: Non-metal essential for our life which I have understood the reactions all living beings inhale during taking place in beakers ‘A’ and breathing, ‘B’. But I am still confused why there is no change in beakers Non-metals used in fertilisers to ‘C’, ‘D’ and ‘E’? enhance the growth of plants, Non-metal used in water purification There could have been displacement process, of zinc by copper in beaker ‘C’ and by Non-metal used in the purple iron in beaker ‘E’. Similarly iron could coloured solution which is applied be displaced by copper in beaker ‘D’. on wounds as an antiseptic, Since we do not see any change in Non-metals used in crackers. beaker C, we can infer that copper is You may add some more uses of not able to replace zinc from zinc metals and non-metals from your sulphate. But why? When zinc can experiences. MATERIALS : METALS AND NON-METALS 51
  • 9. I heard that magnesium is Doctor reported iron found in plants. In what deficiency in my body. form is it found in them? Where is iron in my body? In Class VII, you have learnt that in a chemical reaction, new substances are formed. These substances are different from those which underwent the reaction. Now, if a substance cannot be broken down further by chemical reactions, by cooling, heating, or by electrolysis, it is called ‘element’. Sulphur is an element. So is iron. Carbon, too, is an element. The smallest unit of an element is atom. A sample of an element contains only one kind of atoms. The atom of an element remains unaffected by physical changes in the element. For example, an atom of liquid sulphur would be exactly the same as the atom of solid or vapour sulphur. Although we have an infinite variety of substances in the universe, the number of elements forming these substances is limited. There are no more than 92 naturally occurring elements. An important classification of elements is in terms of metals and non-metals. Most of the elements are metals. Less than 20 are non-metals. A few are metalloids which possess characters of both metals and non-metals. 52 SCIENCE
  • 10. KEYWORDS WHAT YOU HAVE LEARNT ATOM Metals are lustrous whereas non-metals have no lustre. CONDUCTOR Generally, metals are malleable and ductile. DISPLACEMENT Non-metals do not have these properties. REACTION Generally, metals are good conductors of heat and electricity but non-metals are poor DUCTILITY conductors. ELEMENTS On burning, metals react with oxygen to produce metal oxides which are basic in HARDNESS nature. Non-metals react with oxygen to MALLEABILITY produce non- metallic oxides which are acidic in nature. METALS Some metals react with water to produce metal METALLOIDS hydroxides and hydrogen gas. Generally, non- metals do not react with water. NON-METALS Metals react with acids and produce metal SONOROUS salts and hydrogen gas. Generally, non-metals do not react with acids. Some metals react with bases to produce hydrogen gas. More reactive metals displace less reactive metals from their compounds in aqueous solutions. Metals and non-metals are used widely in every day life. Exercises 1. Which of the following can be beaten into thin sheets? (a) Zinc (b) Phosphorus (c) Sulphur (d) Oxygen 2. Which of the following statements is correct? (a) All metals are ductile. (b) All non-metals are ductile. (c) Generally, metals are ductile. (d) Some non-metals are ductile. MATERIALS : METALS AND NON-METALS 53
  • 11. 3. Fill in the blanks : EXERCISES (a) Phosphorus is very non-metal. (b) Metals are conductors of heat and . (c) Iron is reactive than copper. (d) Metals react with acids to produce gas. 4. Mark ‘T’ if the statement is true and ‘F’ if it is false. (a) Generally, non-metals react with acids. ( ) (b) Sodium is a very reactive metal. ( ) (c) Copper displaces zinc from zinc sulphate solution. ( ) (d) Coal can be drawn into wires. ( ) 5. Some properties are listed in the following Table. Distinguish between metals and non-metals on the basis of these properties. Properties Metals Non-metals 1. Appearance 2. Hardness 3. Malleability 4. Ductility 5. Heat Conduction 6. Conduction of Electricity 6. Give reasons for the following : (a) Aluminium foils are used to wrap food items. (b) Immersion rods for heating liquids are made up of metallic substances. (c) Copper cannot displace zinc from its salt solution. (d) Sodium and potassium are stored in kerosene. 7. Can you store lemon pickle in an aluminium utensil? Explain. 8. In the following Table some substances are given in Column I. In Column II some uses are given. Match the items in column I with those in Column II. Column I Column II (i) Gold (a) Thermometers (ii) Iron (b) Electric wire (iii) Aluminium (c) Wrapping food (iv) Carbon (d) Jewellery (v) Copper (e) Machinary (vi) Mercury (f) Fuel 54 SCIENCE
  • 12. 9. What happens when EXERCISES (a) Dilute sulphuric acid is poured on a copper plate? (b) Iron nails are placed in copper sulphate solution? Write word equations of the reactions involved. 10. Saloni took a piece of burning charcoal and collected the gas evolved in a test tube. (a) How will she find the nature of the gas ? (b) Write down word equations of all the reactions taking place in this process. 11. One day Reeta went to a jeweller’s shop with her mother. Her mother gave old gold jewellery to the goldsmith to polish. Next day when they brought the jewellery back, they found that there was a slight loss in its weight. Can you suggest a reason for the loss in weight? Extended Learning — Activities and Projects 1. Prepare Index Cards for any four metals and four non-metals. The card should have information like name of metal/non-metal; its physical properties, chemical properties and its uses. 2. Visit a blacksmith and observe how metals are moulded. 3. Suggest an experiment to compare the conductivity of electricity by iron, copper, aluminium and zinc. Perform the experiment and prepare a short report on the results. 4. Find out the locations of the deposits of iron, aluminium and zinc in India. Mark these in an outline map of India. In which form are the deposits found? Discuss in the class. 5. Discuss with your parents/neighbours/goldsmiths why gold is preferred for making jewellery. 6. Visit the following websites and enjoy the quiz on metals and non- metals: chemistry.about.com/library/weekly/bl050303a.htm chemistry.about.com/od/testsquizzes/Chemistry_Tests_ Quizzes.htm www.syvum.com/cgi/online/mult.cgi/squizzes/science/ metals.tdf?0 www.gcsescience.com/q/qusemet.html www.corrosionsource.com/handbook/periodic/metals.htm MATERIALS : METALS AND NON-METALS 55