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[object Object],[object Object]
Classification based on Matrices Composite materials Matrices Polymer Matrix Composites (PMC) Metal Matrix Composites MMC) Ceramic Matrix Composites (CMC) Thermoset Thermoplastic Rubber
[object Object],[object Object],[object Object],repeat unit repeat unit repeat unit Examples of polymers: ,[object Object],C C C C C C H H H H H H H H H H H H Polyethylene (PE) Cl Cl Cl C C C C C C H H H H H H H H H Polyvinyl chloride (PVC) H H H H H H Polypropylene (PP) C C C C C C CH 3 H H CH 3 CH 3 H
Polymer Matrix Composite (PMC)  is the material consisting of a polymer (resin) matrix combined with a fibrous reinforcing dispersed phase.  Polymer Matrix Composites are very popular due to their low cost and simple fabrication methods.
Discontinuous phase - Reinforcement Continuous phase  - Matrix Polymer(Matrix) Composite (Matrix + Reinforcement) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Classification of Polymers ,[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object]
 
[object Object],[object Object],[object Object],[object Object],Thermosetting resins are the most widely used polymers in PMCs. Epoxy and polyester are commonly mixed with fiber reinforcement.  The most widely used form is a laminar structure, made by stacking and bonding thin layers of fiber and polymer until the desired thickness is obtained. Fibers in PMCs
[object Object],[object Object],[object Object],[object Object],[object Object],Degree of polymerization = No of monomer units in a chain      10 3  to 10 5
Thermosets ,[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object]
 
Types of Thermosetting plastics
Epoxy: Epoxy is a polymer that contain an epoxide group in its chemical structure. Example: DGEBA (Diglcidyl Ether of Bisphenol A ) ‏ ,[object Object],[object Object],[object Object],[object Object]
Polyester: A condensation reaction between a glycol and an unsaturated dibasic acid results in polyster. This contains a double bond C=C between its carbon atoms. Example: poly ethylene terephthalate (PET).  ,[object Object],[object Object],[object Object],[object Object]
Thermosetting plastics - applications
Thermoplastics ,[object Object],[object Object]
[object Object],[object Object]
 
Reasons for the use of thermoplastic matrix composites ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
UNIQUE CHARACTERISTIC OF THERMOPLASTIC ,[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object]
Types of Thermoplastics
COMPARISON OF THE THREE POLYMER CATEGORIES
Thermoplastics Vs Thermosets
Functions of Matrix ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Desired Properties of a Matrix ,[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Effect of Temperature on Thermoplastics ,[object Object],[object Object],The effect of temperature on the modulus of elasticity for an amorphous thermoplastic.
Stress-strain behavior of different polymer matrices  Thermoplastic polymers Thermosetting polymers Notice to the range of ultimate strains of different polymers
Comparision of various polymers as matrix materials
Limitations  of PMC   ,[object Object],[object Object],[object Object],[object Object]
Polymer Processing  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Hand Layup ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Hand Layup ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Hand Layup ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Hand layup products:
Hand layup products:
SPRAYUP  In Sprayup process liquid resin matrix and chopped reinforcing fibers are sprayed by two separate sprays onto the mold surface.  The fibers are chopped into fibers of 1-2” (25-50 mm) length and then sprayed by an air jet simultaneously with a resin spray at a predetermined ratio between the reinforcing and matrix phase.  The Sprayup method permits rapid formation of uniform composite coating, however the mechanical properties of the material are moderate since the method is unable to use continuous reinforcing fibers.
SPRAYUP  A spray gun supplying resin in two converging streams into which roving is chopped. Automation with robots results in high rate of production. Labor costs are lower.
[object Object],[object Object],[object Object]
Hand and Spray Layup ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Advantages of Hand Layup and Sprayup ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Disadvantages of Hand Layup and Sprayup ,[object Object],[object Object],[object Object],[object Object],[object Object]
PREPREG  ,[object Object],[object Object],[object Object]
PREPREG PROCESS ,[object Object],[object Object],[object Object],[object Object]
PREPREG ,[object Object],[object Object],[object Object],[object Object]
PREPREG ,[object Object],[object Object],[object Object],[object Object],Easily obtained with epoxies .
Filament Winding ,[object Object],[object Object]
Filament Winding ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Filament Winding ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Copyright Joseph Greene 2001
Filament Winding
Filament winding - applications ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object]
Filament winding
Filament winding - winding patterns ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Filament winding patterns ,[object Object],[object Object],[object Object]
[object Object]
Filament wound pressure bottles for gas storage
Pultrusion ,[object Object],[object Object]
Pultrusion ,[object Object],[object Object]
Pultrusion ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pultrusion ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pultrusion ,[object Object],[object Object]
[object Object]
 
 
Pultrusion ,[object Object],[object Object],[object Object],[object Object],[object Object]
· Very low scrap. Up to 95% utilization of materials (75% for layup).  · Rollers are used to ensure proper resin impregnation of the fiber.  · Material forms can also be used at the inlet to the die when materials such as mats, weaves, or stitched material is used.  · For curing, tunnel ovens can be used. After the part is formed and gelled in the die, it emerges, enters a tunnel oven where curing is completed.  · Another method is, the process runs intermittently with sections emerging from the die, and the pull is stopped, split dies are brought up to the sections to cure it, they then retract, and the pull continues. (Typical lengths for curing are 6" to 24")
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Copyright Joseph Greene 2001
Pultrusion ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pultrusion -characteristics ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object]
Pultrusion -applications ,[object Object],[object Object],[object Object],[object Object],[object Object]
Pultrusion Applications ,[object Object],[object Object],[object Object],[object Object]
Resin Transfer Molding ,[object Object],[object Object],[object Object],[object Object]
[object Object],Close mold low pressure process. A dry preform is placed in a matched metal die. A vaccum pulls the Low – viscosity resin through a flow medium that helps impregnate the preform. Resin may also be forced by means of a pump.
Resin Transfer Moulding
RTM ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
RTM ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Advantages of RTM ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Disadvantages of RTM  ,[object Object],[object Object]
Resin Transfer Moulding ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
RTM Products:
Autoclave moulding ,[object Object],[object Object],[object Object],[object Object]
Autoclave moulding ,[object Object]
Autoclave ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Copyright Joseph Greene 2001
a) Autoclave process to make a laminated composite b) Prepregs of different orientations stacked to form a laminated composite a) b) Higher fiber volume fractions (60 – 65%) can be obtained
Autoclave process- Charcteristics ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Autoclave Mol u ding
Injection moulding  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Injection moulding  ,[object Object],[object Object],[object Object],[object Object],[object Object]
Injection moulding
Injection moulding machine ,[object Object],[object Object],[object Object],[object Object]
The Injection Mold ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Features of injection molding Direct path from molding compound to finished product Process can be fully automated High productivity & quality
Injection molding machine
 
Injection Molding Machine
INJECTION MOLDING Thermoplastics : Polystyrene,PE, PP, ABC, PC,PMMA etc
Injection Molding Cycle ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Thermosets  : Unsaturated polyester resin, Phenol formaldehyde etc
Reaction injection moulding ,[object Object]
Reinforced reaction injection molding ,[object Object],[object Object],[object Object]
Film stacking ,[object Object],[object Object]
DIAPHRAGM FORMING   ,[object Object],[object Object]
DIAPHRAGM FORMING   ,[object Object],[object Object]
DIAPHRAGM FORMING ,[object Object],[object Object],[object Object]
DIAPHRAGM FORMING  ,[object Object],[object Object],[object Object]
Thermoplastic tape laying  (Automated Layup) ,[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],Automated tape‑laying machines operate by dispensing a prepreg tape onto an open mold following a programmed path . Typical machine consists of overhead gantry to which the dispensing head is attached  The gantry permits x‑y‑z travel of the head, for positioning and following a defined continuous path.
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object]
Reinforcement-Matrix Interface ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],Interfacial bonding
Types of interfacial bonding at interface ,[object Object],[object Object],[object Object],Mechanical Bonding ,[object Object],[object Object],[object Object]
Physical Bonding ,[object Object],[object Object],[object Object],[object Object],[object Object]
Chemical bonding ,[object Object],[object Object]
[object Object],[object Object],[object Object]
Another Interphase Interphase consisting of a solution of primary and  secondary phases
APPLICATIONS OF PMCs ,[object Object],[object Object]

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59a1 polymer matrix composites

  • 1.
  • 2. Classification based on Matrices Composite materials Matrices Polymer Matrix Composites (PMC) Metal Matrix Composites MMC) Ceramic Matrix Composites (CMC) Thermoset Thermoplastic Rubber
  • 3.
  • 4. Polymer Matrix Composite (PMC) is the material consisting of a polymer (resin) matrix combined with a fibrous reinforcing dispersed phase. Polymer Matrix Composites are very popular due to their low cost and simple fabrication methods.
  • 5.
  • 6.
  • 7.
  • 8.  
  • 9.
  • 10.
  • 11.
  • 12.
  • 13.  
  • 15.
  • 16.
  • 17. Thermosetting plastics - applications
  • 18.
  • 19.
  • 20.  
  • 21.
  • 22.
  • 23.
  • 25. COMPARISON OF THE THREE POLYMER CATEGORIES
  • 27.
  • 28.
  • 29.
  • 30.
  • 31. Stress-strain behavior of different polymer matrices Thermoplastic polymers Thermosetting polymers Notice to the range of ultimate strains of different polymers
  • 32. Comparision of various polymers as matrix materials
  • 33.
  • 34.
  • 35.
  • 36.
  • 37.
  • 40. SPRAYUP In Sprayup process liquid resin matrix and chopped reinforcing fibers are sprayed by two separate sprays onto the mold surface. The fibers are chopped into fibers of 1-2” (25-50 mm) length and then sprayed by an air jet simultaneously with a resin spray at a predetermined ratio between the reinforcing and matrix phase. The Sprayup method permits rapid formation of uniform composite coating, however the mechanical properties of the material are moderate since the method is unable to use continuous reinforcing fibers.
  • 41. SPRAYUP A spray gun supplying resin in two converging streams into which roving is chopped. Automation with robots results in high rate of production. Labor costs are lower.
  • 42.
  • 43.
  • 44.
  • 45.
  • 46.
  • 47.
  • 48.
  • 49.
  • 50.
  • 51.
  • 52.
  • 54.
  • 55.
  • 57.
  • 58.
  • 59.
  • 60. Filament wound pressure bottles for gas storage
  • 61.
  • 62.
  • 63.
  • 64.
  • 65.
  • 66.
  • 67.  
  • 68.  
  • 69.
  • 70. · Very low scrap. Up to 95% utilization of materials (75% for layup). · Rollers are used to ensure proper resin impregnation of the fiber. · Material forms can also be used at the inlet to the die when materials such as mats, weaves, or stitched material is used. · For curing, tunnel ovens can be used. After the part is formed and gelled in the die, it emerges, enters a tunnel oven where curing is completed. · Another method is, the process runs intermittently with sections emerging from the die, and the pull is stopped, split dies are brought up to the sections to cure it, they then retract, and the pull continues. (Typical lengths for curing are 6" to 24")
  • 71.
  • 72.
  • 73.
  • 74.
  • 75.
  • 76.
  • 77.
  • 78.
  • 80.
  • 81.
  • 82.
  • 83.
  • 84.
  • 86.
  • 87.
  • 88.
  • 89. a) Autoclave process to make a laminated composite b) Prepregs of different orientations stacked to form a laminated composite a) b) Higher fiber volume fractions (60 – 65%) can be obtained
  • 90.
  • 92.
  • 93.
  • 95.
  • 96.
  • 98.  
  • 100. INJECTION MOLDING Thermoplastics : Polystyrene,PE, PP, ABC, PC,PMMA etc
  • 101.
  • 102. Thermosets : Unsaturated polyester resin, Phenol formaldehyde etc
  • 103.
  • 104.
  • 105.
  • 106.
  • 107.
  • 108.
  • 109.
  • 110.
  • 111.
  • 112.
  • 113.
  • 114.
  • 115.
  • 116.
  • 117.
  • 118.
  • 119.
  • 120. Another Interphase Interphase consisting of a solution of primary and secondary phases
  • 121.