(How to Program) Paul Deitel, Harvey Deitel-Java How to Program, Early Object...
Moffett Superfund Site 26 Update to the Moffett Restoration Advisory Board
1. Former NAS Moffett Field
Site 26 Eastside Aquifer Treatment System
Neil Hey, PG
Shaw Environmental, Inc.
Valerie Harris, PE
Harris
Navy BRAC PMO West
September 8, 2011
S t b 8
RAB Meeting
1
4. Treatability Study Purpose
Evaluate the applicability and effectiveness of
EHC®, an in situ abiotic/biotic treatment
technology,
technology to reduce the chemicals of concern
(COC; PCE, TCE, DCE, & VC) concentrations in
g
groundwater to levels below the ROD cleanup p
standards at IR Site 26
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5. EHC® Treatment Technology
• A product of Adventus Americas, Inc.
• Patented combination of zero-valent iron (ZVI)
zero valent
particles & plant-based carbon
• Combination of chemical (abiotic) and biological
(biotic) reductive dechlorination processes
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6. Project Description
• Installed 5
observation wells
• Injected EHC® at
16 locations
• Performed 10
post-injection
groundwater
monitoring events
g
6
7. EHC® Injection
Site Location
Total CEs ~80
µg/L
50 ft x 50 ft area
40 to 8 feet bgs
~6,600 gallons
6,600
hydrant water
~23,000
~23 000 pounds
EHC® Groundwater
Flow
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10. TS Conclusions
• EHC® easy to prepare but difficult to inject
• EHC® not di t ib t d uniformly due to h t
t distributed if l d t heterogeneous
nature of subsurface
• Complete reductive dechlorination observed in all
treatment area wells
• 98% reduction in total COCs concentration in treatment
area
• PCE, TCE, & DCE concentrations in treatment area
reduced below ROD cleanup standards in < 1 year
• Vinyl hl id
Vi l chloride concentration in treatment area remains
i i i
slightly above ROD cleanup standard but decreasing
• EHC® continues to treat on-flow of COCs 2 years after
y
treatment
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12. Site 26 Background
• Chlorinated solvents identified in groundwater near
Hangar 3 in 1983
• Record of decision (ROD) signed in 1996. Selected
remedy was groundwater extraction and treatment
to restore groundwater to cleanup standards.
• Cleanup standards – drinking water
– Tetrachloroethene (PCE) = 5 g/L
– Trichloroethene (TCE) = 5 g/L
–CCis-1,2-dichloroethene = 6 g/L
2 d hl h /
– Vinyl chloride = 0.5 g/L
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13. Site 26 Background (continued)
• Eastside Aquifer Treatment System (EATS) began
q y ( ) g
operating in 1999.
– extracted 67 million gallons of water
– removed 23.7 pounds of chlorinated volatile organic
compounds (VOCs)
• Shut down in 2003 to evaluate:
– Evaluate plume stability
– Chemical rebound
– Natural attenuation
– HRC in plume hot spots
– Treatability study (almost completed)
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14. 2010 Groundwater Plume
Combined CVOC concentrations
• 85.9 g/L (maximum)
located near current treatability
study
• Max combined CVOC
concentration in other areas
about 25 g/L
b t /
TREATABILITY STUDY AREA
Groundwater
Flow
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15. Focused Feasibility Study
Purpose – to evaluate several technologies along with
the selected remedy
• Identify remedial action objectives and applicable
regulations
• Identify and screen treatment technologies
– Monitored Natural Attenuation
– Abiotic/Biotic Treatment (EHC®)
– In Situ Biostimulation/Bioaugmentation
• Develop and evaluate remedial alternatives against
seven of the nine NCP criteria
• Compare the remedial alternatives against each other
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16. Preliminary Remedial Alternatives
• Alternative 1 – No Action
• Alternative 2 – Monitored Natural Attenuation
(MNA)
• Alternative 3 – Optimized Pump and Treat
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17. Preliminary Remedial Alternatives
• Alternative 4 – Abiotic/biotic Treatment and
MNA
• Alternative 5 – In Situ Biostimulation
/Bioaugmentation and MNA
/Bi t ti d
Biotic PCE
TCE
Cis 1,2‐DCE Trans 1,2‐DCE
VC
Ethene
Ethane
α‐elimination 17
β‐elimination
18. Conceptual Treatment Areas
•Trend analysis
performed for
each well
•Identify areas
th t could b
that ld benefit
fit
from treatment
Natural
processes =
60 years Natural
processes >
60 years
(increasing
trend/no
trend)
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19. Sustainability
• An evaluation of sustainability will be included
in the feasibility study (FS)
• FS will use SiteWiseTM
– Streamlined life cycle analysis tool
life-cycle
– Developed by Navy, Army Corps and Battelle
– Available at http://www.ert2.org/t2gsrportal
• Sustainability metrics considered are:
– Energy and resource consumption
gy p
– Greenhouse gas and criteria pollutant emissions
– Water and ecological impacts
– Worker and community safety
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20. Schedule
• November 30, 2011- Draft FS Report
p
• December 1, 2011 to January 29,
2011 – Agency/RAB Review of draft
g y/
• April 30, 2012 - Final FS Report
Next Steps
– Proposed plan
– ROD amendment
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