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Middlefield-Ellis-Whisman (MEW)
          Superfund Study Area


             EPA Update
      Groundwater Feasibility Study


Presentation for Community Advisory Board


               March 31, 2011

          Penny Reddy, EPA Region 9
2
MEW / NAS Moffett Field Site – Shallow TCE
Groundwater Plume

 Fairchild

 Intel

 Raytheon

 NEC/Renasas

 SMI

 Vishay/ SUMCO

 NASA

 Navy
Estimated Extent of Regional TCE Shallow Groundwater
Plume
Purpose of Site-wide Groundwater
Feasibility Study

• Evaluate alternative technologies to accelerate
 groundwater cleanup
 – Efficiency of system decreasing
 – Minimize need for vapor mitigation by reducing
   groundwater concentrations (Vapor Intrusion RAO).

• Feasibility Study Considerations:
  – Community Criteria and Suggested Strategy
  – Incorporating results of pilot tests
Scope of Groundwater
Cleanup

• Large disperse
 commingled plume with
 multiple source areas

• Range of concentrations
 within plume

• FS strategy treatment of
 source & high conc. areas;
 move to passive remedy

• Cleanup timeframes key
 component of FS
B1/A2 Aquifer   B2 Aquifer
EPA Screening of Technologies
In Situ Treatment Technologies:
  Enhanced Reductive Dechlorination (ERD), In Situ Chemical
  Oxidation (ISCO), and Abiotic Dechlorination using Zero
  Valent Iron (ZVI)

Extraction, Removal, Treatment and Disposal Technologies –
 – Physical Treatment with Air Sparging
 – Groundwater Extraction and Treatment
 – Multiphase Extraction
 – In Situ Thermal
 – Removal by Excavation
Barriers – Permeable reactive barriers, phytoremediation
Monitored Natural Attenuation
In Situ Treatment Technologies
• Evaluating ERD (Intel/GTE study), In Situ Chemical Oxidation
 (ISCO), and Abiotic Dechlorination using Zero valent iron

• Technologies rely on direct contact or create conditions to
 degrade contaminants.

• Typically used for hot spot treatment/limited area.

• Challenging to distribute material into heterogeneous
 subsurface. Multiple injections typically needed.

• Technologies piloted at the site with varying success.
Extraction, Removal, Treatment and
Disposal Technologies

  Air Sparging
  Air injected into saturated
  zone at high pressure; strips
  solvents, which are extracted.

  In Situ Thermal
  Uses electrodes or heaters
  attached to power supplies to
  heat subsurface and
  volatilize VOCs; vapor
  collection.

  Multiphase Extraction
  Uses a high vacuum system
  to extract soil vapor and
  groundwater simultaneously.
Barriers
                                   Continuous
Permeable Reactive Barriers        Wall

• Intercepts and treats
  contaminants as groundwater
  flows through reactive barrier

• Common reactive media ZVI;

• Construction – Depths
 generally less than 100 feet
                                                Funnel and
• Lifespan (15 to 25 years)                     Gate System
                                                (need to add
                                                photo)

• Issues – fouling/movement
 around wall
Monitored Natural Attenuation

 – Relies on natural processes to cleanup pollution in
  soil and groundwater.

 – Conditions monitored to ensure that contaminants are
  degrading and not migrating.

 – Criteria to demonstrate MNA:
   • Plume stability
   • Review of temporal trends in well
   • Geochemical and biological parameters indicate conditions
     supporting degradation


 – Component of alternative
Technologies Retained

1. Groundwater Extraction and Treatment
2. In Situ Redox Technologies (including Enhanced
   reductive dechlorination, In Situ Chemical Oxidation
   and Zero Valent Iron Injections) to treat high conc.
   areas
3. Permeable Reactive Barriers (PRB)
4. Monitored Natural Attenuation (as component of an
   alternative)
Projected VOC Plume – A Aquifer (0 to
45 feet bgs)


     1992           2009          2019
EPA Working Alternatives – Shallow A Aquifer
Alt. 1 (No Action)
Alt. 2A (P&T/Slurry Wall) -Existing Remedy
Alt. 2B (P&T/Slurry Wall) - Existing Remedy Optimized for mass removal

Alt. 3 (P&T/Slurry Wall) - Existing Remedy Optimized for mass removal, Monitored
Natural Attenuation (MNA) (when demonstrated)
Alt. 4
Facility Specific Source Areas – In Situ Redox (see criteria)*

Regional Plume
In Situ Redox – High Conc. Areas (>1,000 ppb)
P&T and MNA (when Demonstrated)
Alt. 5A
Facility Specific Source Areas – In Situ Redox (see criteria)*
Regional Plume
In Situ Redox – High Conc. Areas (>1,000 ppb)
Permeable Reactive Barriers (PRBs)1, P&T and MNA (when Demonstrated)

Alt. 5B – Will be evaluating P&T Barrier Wells in lieu of PRBs
Conceptual Layout
In Situ Redox in A Aquifer   DRAFT FOR DISCUSSION ONLY
                                   Alternative 4:
                                    In Situ Redox (Facility Specific 
                                   Source Areas)
                                   In Situ Redox (High 
                                   Concentration Areas)
                                   P&T (Medium and Low 
                                   Concentration Areas)*

• In Situ Redox in high            MNA (when demonstrated)

                                            In Situ Redox
                                            Treatment Area 

 concentrations areas                       (gridded or transect 
                                            injections)




 >1,000 ppb (facility and
 regional plume)

• Groundwater pump and
 treat for remaining areas
 of plume until MNA
 demonstrated
Conceptual Layout           DRAFT FOR DISCUSSION ONLY



with PRBs in A Aquifer
                                  Alternative 5A:
                                  In Situ Redox (Facility Specific 
                                  Source Areas)
                                  PRBs (Range of Concentrations)
                                  P&T (Low Concentration Areas)*
                                  MNA (when demonstrated)




                                           In Situ Redox 

• PRBs downgradient of                     Treatment Area 
                                           (gridded or transect 
                                           injections)


 high concentration areas                  PRB




 to treat residual
 contamination

• Modeling to determine
 number of PRBs

• Type of PRBs to be
 determined
EPA Working Alternatives – Deeper Aquifers
Alt. 1 (No Action)
Alt. 2A (P&T/Slurry Wall) -Existing Remedy
Alt. 2B (P&T/Slurry Wall) - Optimized for mass removal
Alt. 3 (P&T/Slurry Wall) - MNA (when demonstrated)
Alt. 4
Facility Specific Source Areas – In Situ Redox (see criteria)*

Regional Plume - P&T and MNA (when Demonstrated)
Alt. 5A
Facility Specific Source Areas – In Situ Redox (see criteria)*

Regional Plume -PRBs, P&T and MNA (when Demonstrated)

Alt. 5B
Facility Specific Source Areas – In Situ Redox (see criteria)*

Regional Plume -P&T Barrier Wells and MNA (when Demonstrated)
Projected VOC Plume – B2/A1 Aquifer
(50 to 75 feet bgs)


       1992       2009        2019
Groundwater Feasibility Study Summary

• Focusing on high concentrations and source areas; moving to more
  passive remedy.

• Evaluating reasonable timeframes to complete cleanup.

• Scale of cleanup challenging.

• Difficult to implement in situ technologies in developed areas.

• Geology & matrix diffusion effects limit ability to accelerate cleanup.

• Potential recontamination of areas treated within different portions of
  the plume.
EPA Site-wide Groundwater Feasibility
Study - Tentative Schedule

• TBD – Agenda topics for next CAB Meeting  
• Summer 2011 – Draft Feasibility Study Report for review
• Fall 2011 – Remedy Review Board
• Winter 2012 – Final Feasibility Study Report, Proposed Plan for 
  public review
• Spring 2012  – Public Meeting and Public Comment Period
• Fall 2012 – Groundwater ROD Amendment

**Community involvement activities throughout the process 
  Updates and Meetings with Moffett Field RAB, MEW Community Advisory 
  Board, City, Property Owners, Developers, Community Members
Discussion/Questions
Contact Information

For More Information

www.epa.gov/region9/mew
www.epa.gov/region9/moffettfield

Penny Reddy
Groundwater Project Manager
EPA Region 9 Superfund Division
415.972.3108
Reddy.Penny@epa.gov

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EPA Groundwater Cleanup Feasibility, MEW CAB

  • 1. Middlefield-Ellis-Whisman (MEW) Superfund Study Area EPA Update Groundwater Feasibility Study Presentation for Community Advisory Board March 31, 2011 Penny Reddy, EPA Region 9
  • 2. 2
  • 3. MEW / NAS Moffett Field Site – Shallow TCE Groundwater Plume Fairchild Intel Raytheon NEC/Renasas SMI Vishay/ SUMCO NASA Navy
  • 4. Estimated Extent of Regional TCE Shallow Groundwater Plume
  • 5. Purpose of Site-wide Groundwater Feasibility Study • Evaluate alternative technologies to accelerate groundwater cleanup – Efficiency of system decreasing – Minimize need for vapor mitigation by reducing groundwater concentrations (Vapor Intrusion RAO). • Feasibility Study Considerations: – Community Criteria and Suggested Strategy – Incorporating results of pilot tests
  • 6. Scope of Groundwater Cleanup • Large disperse commingled plume with multiple source areas • Range of concentrations within plume • FS strategy treatment of source & high conc. areas; move to passive remedy • Cleanup timeframes key component of FS
  • 7. B1/A2 Aquifer B2 Aquifer
  • 8. EPA Screening of Technologies In Situ Treatment Technologies: Enhanced Reductive Dechlorination (ERD), In Situ Chemical Oxidation (ISCO), and Abiotic Dechlorination using Zero Valent Iron (ZVI) Extraction, Removal, Treatment and Disposal Technologies – – Physical Treatment with Air Sparging – Groundwater Extraction and Treatment – Multiphase Extraction – In Situ Thermal – Removal by Excavation Barriers – Permeable reactive barriers, phytoremediation Monitored Natural Attenuation
  • 9. In Situ Treatment Technologies • Evaluating ERD (Intel/GTE study), In Situ Chemical Oxidation (ISCO), and Abiotic Dechlorination using Zero valent iron • Technologies rely on direct contact or create conditions to degrade contaminants. • Typically used for hot spot treatment/limited area. • Challenging to distribute material into heterogeneous subsurface. Multiple injections typically needed. • Technologies piloted at the site with varying success.
  • 10. Extraction, Removal, Treatment and Disposal Technologies Air Sparging Air injected into saturated zone at high pressure; strips solvents, which are extracted. In Situ Thermal Uses electrodes or heaters attached to power supplies to heat subsurface and volatilize VOCs; vapor collection. Multiphase Extraction Uses a high vacuum system to extract soil vapor and groundwater simultaneously.
  • 11. Barriers Continuous Permeable Reactive Barriers Wall • Intercepts and treats contaminants as groundwater flows through reactive barrier • Common reactive media ZVI; • Construction – Depths generally less than 100 feet Funnel and • Lifespan (15 to 25 years) Gate System (need to add photo) • Issues – fouling/movement around wall
  • 12. Monitored Natural Attenuation – Relies on natural processes to cleanup pollution in soil and groundwater. – Conditions monitored to ensure that contaminants are degrading and not migrating. – Criteria to demonstrate MNA: • Plume stability • Review of temporal trends in well • Geochemical and biological parameters indicate conditions supporting degradation – Component of alternative
  • 13. Technologies Retained 1. Groundwater Extraction and Treatment 2. In Situ Redox Technologies (including Enhanced reductive dechlorination, In Situ Chemical Oxidation and Zero Valent Iron Injections) to treat high conc. areas 3. Permeable Reactive Barriers (PRB) 4. Monitored Natural Attenuation (as component of an alternative)
  • 14. Projected VOC Plume – A Aquifer (0 to 45 feet bgs) 1992 2009 2019
  • 15. EPA Working Alternatives – Shallow A Aquifer Alt. 1 (No Action) Alt. 2A (P&T/Slurry Wall) -Existing Remedy Alt. 2B (P&T/Slurry Wall) - Existing Remedy Optimized for mass removal Alt. 3 (P&T/Slurry Wall) - Existing Remedy Optimized for mass removal, Monitored Natural Attenuation (MNA) (when demonstrated) Alt. 4 Facility Specific Source Areas – In Situ Redox (see criteria)* Regional Plume In Situ Redox – High Conc. Areas (>1,000 ppb) P&T and MNA (when Demonstrated) Alt. 5A Facility Specific Source Areas – In Situ Redox (see criteria)* Regional Plume In Situ Redox – High Conc. Areas (>1,000 ppb) Permeable Reactive Barriers (PRBs)1, P&T and MNA (when Demonstrated) Alt. 5B – Will be evaluating P&T Barrier Wells in lieu of PRBs
  • 16. Conceptual Layout In Situ Redox in A Aquifer DRAFT FOR DISCUSSION ONLY Alternative 4: In Situ Redox (Facility Specific  Source Areas) In Situ Redox (High  Concentration Areas) P&T (Medium and Low  Concentration Areas)* • In Situ Redox in high MNA (when demonstrated) In Situ Redox Treatment Area  concentrations areas (gridded or transect  injections) >1,000 ppb (facility and regional plume) • Groundwater pump and treat for remaining areas of plume until MNA demonstrated
  • 17. Conceptual Layout DRAFT FOR DISCUSSION ONLY with PRBs in A Aquifer Alternative 5A: In Situ Redox (Facility Specific  Source Areas) PRBs (Range of Concentrations) P&T (Low Concentration Areas)* MNA (when demonstrated) In Situ Redox  • PRBs downgradient of Treatment Area  (gridded or transect  injections) high concentration areas PRB to treat residual contamination • Modeling to determine number of PRBs • Type of PRBs to be determined
  • 18. EPA Working Alternatives – Deeper Aquifers Alt. 1 (No Action) Alt. 2A (P&T/Slurry Wall) -Existing Remedy Alt. 2B (P&T/Slurry Wall) - Optimized for mass removal Alt. 3 (P&T/Slurry Wall) - MNA (when demonstrated) Alt. 4 Facility Specific Source Areas – In Situ Redox (see criteria)* Regional Plume - P&T and MNA (when Demonstrated) Alt. 5A Facility Specific Source Areas – In Situ Redox (see criteria)* Regional Plume -PRBs, P&T and MNA (when Demonstrated) Alt. 5B Facility Specific Source Areas – In Situ Redox (see criteria)* Regional Plume -P&T Barrier Wells and MNA (when Demonstrated)
  • 19. Projected VOC Plume – B2/A1 Aquifer (50 to 75 feet bgs) 1992 2009 2019
  • 20. Groundwater Feasibility Study Summary • Focusing on high concentrations and source areas; moving to more passive remedy. • Evaluating reasonable timeframes to complete cleanup. • Scale of cleanup challenging. • Difficult to implement in situ technologies in developed areas. • Geology & matrix diffusion effects limit ability to accelerate cleanup. • Potential recontamination of areas treated within different portions of the plume.
  • 21. EPA Site-wide Groundwater Feasibility Study - Tentative Schedule • TBD – Agenda topics for next CAB Meeting   • Summer 2011 – Draft Feasibility Study Report for review • Fall 2011 – Remedy Review Board • Winter 2012 – Final Feasibility Study Report, Proposed Plan for  public review • Spring 2012  – Public Meeting and Public Comment Period • Fall 2012 – Groundwater ROD Amendment **Community involvement activities throughout the process  Updates and Meetings with Moffett Field RAB, MEW Community Advisory  Board, City, Property Owners, Developers, Community Members
  • 23. Contact Information For More Information www.epa.gov/region9/mew www.epa.gov/region9/moffettfield Penny Reddy Groundwater Project Manager EPA Region 9 Superfund Division 415.972.3108 Reddy.Penny@epa.gov