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©Copyright AIB International
May not be reproduced without
written permission.
SHELF LIFE
EXTENSION
All Things Baking October 2011
Presented by Aaron Clanton, Baking Curriculum Manager
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
What determines the shelf-life of a
product?
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
SHELF LIFE
“The length of time during which the
product remains acceptable to the
consumer without a significant loss in
quality, or how long the consumer
perceives a product to be fresh”.
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Staling Most Identified by
Consumers
Visible mold growth = “spoilage”
Firmness or crumbliness of crumb
Dryness
Flavor loss and/or change
Loss of shine or migration of color
Shrinkage or breakdown of filling
Icings drying or cracking
“Sugar bloom” or “Fat Bloom”
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
What factors into Shelf life?
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
What factors into Shelf life?
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Control of Mold
 Minimize contamination
of product with mold
 Control factors that
enhance mold growth
 Establish clear expected
shelf life
 Usage of mold inhibitors
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Minimizing Mold Contamination
Cleaning and Sanitation
 Food contact surfaces must be properly
cleaned and sanitized.
 Organic debris should not be allowed to
accumulate.
Old product, stales, crumbs, waste dough,
etc.
 Cleaning in and around the plant.
Any mold growth will produce spores.
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Minimizing Mold Contamination
continued
Cleaning and Sanitation
continued
Air should be filtered to
reduce spores in the air.
 Most spores become airborne.
 Filtering of any air coming inside.
 Be sure to filter compressed air as
well.
 Maintain positive pressure to
prevent outside air from coming in.
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Factors Affecting Mold Growth
Condition for mold
growth (optimum)
Method of controlling
condition
Temperature ≈ 80 °F (27°C)
Air conditioning
Heat sterilization
Relative Humidity ≈ 80 % Air conditioning
Presence of oxygen, carbon,
hydrogen and nitrogen
Modified Atmospheric
Packaging, UV Lights,
Oxygen Scavengers
Water activity = 0.8 to 1.0 Formulation – if possible
pH = 6 to 7 (slightly acidic) Use of mold inhibitors***
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Factors that Enhance Mold Growth
continued
Moisture / Water Activity (Aw)
 For mold growth water activity is the
important measure.
 Water activity is a measurement of the
amount of “free” water in a system.
It measures the amount of water available
for chemical reactions (microbial growth).
 Water activity is NOT water
content.
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Moisture vs Water Activity
Flour
17% Moisture – which will mold first?
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
aw and the Baker
aw is a useful tool in understanding
baked food systems
Mold growth, sensory, icing breakdown,
color bleeding…
aw is a useful tool in protecting the
consumer
Food safety is a growing concern with
new technology
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Minimum Water Activity for Microbial Growth
Microorganism Minimum Aw
Bacteria 0.91
Wild yeasts 0.87
Penicillium molds 0.82
Aspergillus molds 0.78
Halophilic bacteria 0.75
Osmophilic yeast 0.60
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Water Activity of Bakery Products
Product Aw
Bread, rolls 0.96-0.98
Fruit pie fillings 0.95-0.98
Tortillas, muffins 0.91-0.95
Cheeses 0.91-0.95
Cakes, cake donuts 0.85-0.87
Crème-filled cakes 0.78-0.81
Soft cookies 0.50-0.78
Cookies, crackers 0.20-0.30
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
aw and Moisture Migration
Moisture migrates from
high aw to low aw
Interior to crust
Component to component
Product to atmosphere; atmosphere to
product
Impacts packaging choices
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Usage of Mold Inhibitors
Preservatives inhibit the growth of
microorganisms.
Artificial (chemical)
Natural
Effect of preservative is related to the level of
contamination
High number of spores, inhibitor less effective.
Low number of spores, inhibitor more effective.
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Preservatives
Do not stop
microorganism
growth ONLY inhibit.
Do NOT replace
good manufacturing
practices (sanitation
and cleaning).
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Preservatives types
 Propionates
 Benzoates
 Sorbates
 Acetates
 Parabens
 Vinegar
 Spices
 Raisin juice conc.
 Ethyl alcohol
 Fermented flour or
whey
Chemical Natural
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Preservatives and pH ranges
 Benzoates best below pH of 4.5
 Propionates best below pH of 5.5
 Sorbates best below pH of 6.5
 Parabens affective up to a pH of 8.0
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
What factors into Shelf life?
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
What changes occur over time?
Crust
• Toughens
• Loses friability
(crispness)
• Changes from glassy to
rubbery state
• Mainly migration of water
from crumb
• Water activity
differences
Crumb
• Becomes crumbly, harsh,
and dry
• Loses flavor
• Loses moisture
• Blamed on starch
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
What causes the changes?
Moisture migration
 Disproved 150 years ago
 Boussingault (1858) - staling occurs w/o
moisture loss and can be reversed by heat
So what is it?
 Starch?
 Protein?
 Something else?
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Staling research
 Initial focus was on Starch
 1928-1934: J.R. Katz x-ray diffraction studies
 Freshly gelatinized starch = fresh bread
 Bread starch retrogrades concurrent with
staling
 Schoch (1947) also studied starch
 Conclusion was Starch retrogradation
causes bread firming.
 But…..
+ H2O
& heat
Native Gelatinized
Cools
Retrograded
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Role of Proteins
Where is the protein in the picture?
 Doughs do not have cross-linked starch
and protein
 Bread appears to have starch-protein
crosslinks
 All flours do not produce bread that firms at
the same rate
Still many unanswered questions
1
2
3
4
7
14
60
0 10 20 30 40 50 60 70 80 90 100
before 1940
1940
1950
1975
1990
2000
2007
Shelf-life (days)
For the most part of bread history,
bread was always made and consumed fresh
Soy lecithin was used in bread making to improve both dough handling and
bread shelf-life
Monoglyceride were used to improve bread shelf-life
Bacterial amylase were used to improve bread shelf-life
Maltogenic amylase were used to improve bread shelf-life
Baking industry began to launch ESL bread
New enzyme combinations ?
Major Historic Events that Affect the Shelf-life of Bread
+
Used with permission.
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Maximize Shelf-life with Formulation
Moisture retention
Keep within legal limits!
Breads have a 38%
maximum in US
Rich dough
 Increase hygroscopic
ingredients
Sugars
Gums
Fibers
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Maximize Shelf-life with Formulation
Continued
Sugars
Flavor
Crust color
Delays starch gelatinization
Moisture retention / humectancy
Decreases aw
Monosaccharides generally more
effective than disaccharides
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Maximize Shelf-life with Formulation
Continued
Gums (hydrocolloids)
Usage levels very low
Less and 0.5% total weight
Moisture retention
Increased finished moisture with
proper absorption
Decreases bake loss
Used to stabilizes icings & toppings
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Maximize Shelf-life with Formulation
Continued
Slow firming
Use fats
And/or emulsifiers
And/or crumb softeners
And/or enzymes
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Maximize Shelf-life with Formulation
Continued
Fats
Slow rate of firming (softens)
Increased usage levels
Flavor retention is increased
Mouth feel / lubricity
Oil usage = ↑softness
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Maximize Shelf-life with Formulation
Continued
Emulsifiers
Softens by slowing crumb firming
Increased gas retention
Increase tenderness
Enhanced air, fat and water
incorporation
Stabilized environment
Synergy
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Effects of Enzymes
Inactivation temperatures
Cereal
α-amylase: 180-185°F (82-85°C)
β-amylase: 160-165°F (71-74°C)
Fungal: 131-140°F (55-60°C)
Bacterial: more than 212°F (100°C)
Temperature Profiles of Amylases
Figure by AIB International
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Maximize Shelf-life with Production
Control volume and density
Control relative amounts of
components
Use proper packaging
Constant temperature storage
Freeze
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Maximize Shelf Life with Packaging
MAP packaging
Oxygen scavengers
Barrier films
Surface washes - acids, alcohol
Radiation - Heat, UV, white light
©Copyright AIB International
May not be reproduced without written permission. www.aibonline.org/schoolofbaking
Why Extend Shelf Life?
Longer market exposure (less stales)
Better logistics (fewer deliveries)
Possible warehousing
Less changeovers
Improved work schedule
Consumer acceptance?

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Shelflifeextensionslides

  • 1. ©Copyright AIB International May not be reproduced without written permission. SHELF LIFE EXTENSION All Things Baking October 2011 Presented by Aaron Clanton, Baking Curriculum Manager
  • 2. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking What determines the shelf-life of a product?
  • 3. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking SHELF LIFE “The length of time during which the product remains acceptable to the consumer without a significant loss in quality, or how long the consumer perceives a product to be fresh”.
  • 4. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Staling Most Identified by Consumers Visible mold growth = “spoilage” Firmness or crumbliness of crumb Dryness Flavor loss and/or change Loss of shine or migration of color Shrinkage or breakdown of filling Icings drying or cracking “Sugar bloom” or “Fat Bloom”
  • 5. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking What factors into Shelf life?
  • 6. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking What factors into Shelf life?
  • 7. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Control of Mold  Minimize contamination of product with mold  Control factors that enhance mold growth  Establish clear expected shelf life  Usage of mold inhibitors
  • 8. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Minimizing Mold Contamination Cleaning and Sanitation  Food contact surfaces must be properly cleaned and sanitized.  Organic debris should not be allowed to accumulate. Old product, stales, crumbs, waste dough, etc.  Cleaning in and around the plant. Any mold growth will produce spores.
  • 9. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Minimizing Mold Contamination continued Cleaning and Sanitation continued Air should be filtered to reduce spores in the air.  Most spores become airborne.  Filtering of any air coming inside.  Be sure to filter compressed air as well.  Maintain positive pressure to prevent outside air from coming in.
  • 10. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Factors Affecting Mold Growth Condition for mold growth (optimum) Method of controlling condition Temperature ≈ 80 °F (27°C) Air conditioning Heat sterilization Relative Humidity ≈ 80 % Air conditioning Presence of oxygen, carbon, hydrogen and nitrogen Modified Atmospheric Packaging, UV Lights, Oxygen Scavengers Water activity = 0.8 to 1.0 Formulation – if possible pH = 6 to 7 (slightly acidic) Use of mold inhibitors***
  • 11. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Factors that Enhance Mold Growth continued Moisture / Water Activity (Aw)  For mold growth water activity is the important measure.  Water activity is a measurement of the amount of “free” water in a system. It measures the amount of water available for chemical reactions (microbial growth).  Water activity is NOT water content.
  • 12. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Moisture vs Water Activity Flour 17% Moisture – which will mold first?
  • 13. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking aw and the Baker aw is a useful tool in understanding baked food systems Mold growth, sensory, icing breakdown, color bleeding… aw is a useful tool in protecting the consumer Food safety is a growing concern with new technology
  • 14. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Minimum Water Activity for Microbial Growth Microorganism Minimum Aw Bacteria 0.91 Wild yeasts 0.87 Penicillium molds 0.82 Aspergillus molds 0.78 Halophilic bacteria 0.75 Osmophilic yeast 0.60
  • 15. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Water Activity of Bakery Products Product Aw Bread, rolls 0.96-0.98 Fruit pie fillings 0.95-0.98 Tortillas, muffins 0.91-0.95 Cheeses 0.91-0.95 Cakes, cake donuts 0.85-0.87 Crème-filled cakes 0.78-0.81 Soft cookies 0.50-0.78 Cookies, crackers 0.20-0.30
  • 16. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking aw and Moisture Migration Moisture migrates from high aw to low aw Interior to crust Component to component Product to atmosphere; atmosphere to product Impacts packaging choices
  • 17. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Usage of Mold Inhibitors Preservatives inhibit the growth of microorganisms. Artificial (chemical) Natural Effect of preservative is related to the level of contamination High number of spores, inhibitor less effective. Low number of spores, inhibitor more effective.
  • 18. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Preservatives Do not stop microorganism growth ONLY inhibit. Do NOT replace good manufacturing practices (sanitation and cleaning).
  • 19. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Preservatives types  Propionates  Benzoates  Sorbates  Acetates  Parabens  Vinegar  Spices  Raisin juice conc.  Ethyl alcohol  Fermented flour or whey Chemical Natural
  • 20. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Preservatives and pH ranges  Benzoates best below pH of 4.5  Propionates best below pH of 5.5  Sorbates best below pH of 6.5  Parabens affective up to a pH of 8.0
  • 21. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking What factors into Shelf life?
  • 22. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking What changes occur over time? Crust • Toughens • Loses friability (crispness) • Changes from glassy to rubbery state • Mainly migration of water from crumb • Water activity differences Crumb • Becomes crumbly, harsh, and dry • Loses flavor • Loses moisture • Blamed on starch
  • 23. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking What causes the changes? Moisture migration  Disproved 150 years ago  Boussingault (1858) - staling occurs w/o moisture loss and can be reversed by heat So what is it?  Starch?  Protein?  Something else?
  • 24. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Staling research  Initial focus was on Starch  1928-1934: J.R. Katz x-ray diffraction studies  Freshly gelatinized starch = fresh bread  Bread starch retrogrades concurrent with staling  Schoch (1947) also studied starch  Conclusion was Starch retrogradation causes bread firming.  But…..
  • 25. + H2O & heat Native Gelatinized Cools Retrograded
  • 26. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Role of Proteins Where is the protein in the picture?  Doughs do not have cross-linked starch and protein  Bread appears to have starch-protein crosslinks  All flours do not produce bread that firms at the same rate Still many unanswered questions
  • 27. 1 2 3 4 7 14 60 0 10 20 30 40 50 60 70 80 90 100 before 1940 1940 1950 1975 1990 2000 2007 Shelf-life (days) For the most part of bread history, bread was always made and consumed fresh Soy lecithin was used in bread making to improve both dough handling and bread shelf-life Monoglyceride were used to improve bread shelf-life Bacterial amylase were used to improve bread shelf-life Maltogenic amylase were used to improve bread shelf-life Baking industry began to launch ESL bread New enzyme combinations ? Major Historic Events that Affect the Shelf-life of Bread + Used with permission.
  • 28. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Maximize Shelf-life with Formulation Moisture retention Keep within legal limits! Breads have a 38% maximum in US Rich dough  Increase hygroscopic ingredients Sugars Gums Fibers
  • 29. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Maximize Shelf-life with Formulation Continued Sugars Flavor Crust color Delays starch gelatinization Moisture retention / humectancy Decreases aw Monosaccharides generally more effective than disaccharides
  • 30. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Maximize Shelf-life with Formulation Continued Gums (hydrocolloids) Usage levels very low Less and 0.5% total weight Moisture retention Increased finished moisture with proper absorption Decreases bake loss Used to stabilizes icings & toppings
  • 31. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Maximize Shelf-life with Formulation Continued Slow firming Use fats And/or emulsifiers And/or crumb softeners And/or enzymes
  • 32. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Maximize Shelf-life with Formulation Continued Fats Slow rate of firming (softens) Increased usage levels Flavor retention is increased Mouth feel / lubricity Oil usage = ↑softness
  • 33. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Maximize Shelf-life with Formulation Continued Emulsifiers Softens by slowing crumb firming Increased gas retention Increase tenderness Enhanced air, fat and water incorporation Stabilized environment Synergy
  • 34. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Effects of Enzymes Inactivation temperatures Cereal α-amylase: 180-185°F (82-85°C) β-amylase: 160-165°F (71-74°C) Fungal: 131-140°F (55-60°C) Bacterial: more than 212°F (100°C)
  • 35. Temperature Profiles of Amylases Figure by AIB International
  • 36. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Maximize Shelf-life with Production Control volume and density Control relative amounts of components Use proper packaging Constant temperature storage Freeze
  • 37. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Maximize Shelf Life with Packaging MAP packaging Oxygen scavengers Barrier films Surface washes - acids, alcohol Radiation - Heat, UV, white light
  • 38. ©Copyright AIB International May not be reproduced without written permission. www.aibonline.org/schoolofbaking Why Extend Shelf Life? Longer market exposure (less stales) Better logistics (fewer deliveries) Possible warehousing Less changeovers Improved work schedule Consumer acceptance?