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Objectives
 Be able to define an atom
 Distinguish between a molecule and a compound
Atoms
 Definition
   - the smallest particle that has the properties of
   an element, basic unit of matter
- surprising the number of atoms is small
- the number of combinations these atoms make
   are huge
       ex. color print: 3 colors can make
   numerous colors
- 119 distinct atoms as of 1999, form elements
Atoms Cont.
- hydrogen makes up more than 90% of the atoms in
   the universe
- 1st direct evidence was inadvertently discovered in
   1827, by Scottish botanist Robert Brown while he
   was studying pollen
- grains were in a constant state of agitation
- thought they were moving life forms, later
   discovered a perpetual jiggling of particles known as
   brownian motion; collisions between visible
   particles and invisible atoms
Atomic Symbols

- each element has its own name, accompanied by
  a symbol
- usually two/three letters (first is always
  capitalized)
      ex. Iron: Fe
      - Fe represents 1 atom of iron,
      - 2Fe represents 2 atoms of iron etc…
      - can also be written as Fe2
Molecules
 Definition
  - the smallest unit of a substance that exhibits all the
  properties characteristics of that substance
- two or more atoms
      ex. H8, O2
Compound
 Definition
  - a substance that is made from two or more simpler
  substances and can be broken down into those
  simpler substances
      ex. H2SO4
Objectives
 Describe ancient Greek models of of matter
 List the main points of Dalton’s atomic theory and
  describe his evidence for the existence of atoms
 Explain how Thomson and Rutherford used data
  from experiments to produce their atomic models
Democritus Theory
 Greek Philosopher in the 4th century B.C
  - believed that all matter consisted of extremely
  small particles
  - suggested these particles are made of invisible
  units called atoms
  - term atom is derived from a Greek word
  meaning “unable to divide”
  - believed there were different types of atoms,
  liquids: round,smooth solids: rough, prickly
  - unable to provide evidence that an atom existed,
  therefore many people were very skeptical
Dalton’s Atomic Theory
 John Dalton
   - interested in predicting the weather SO.. studied
  the behavior of gases in the air, concluded that a gas
  consists of individual particles
 Evidence
  - masses of elements as they combined to form
  compounds always produced the same ratio no
  matter what the size of the sample
       ex. carbon dioxide
             - 1 carbon 2 oxygen: 1:2 ratio
Dalton’s Atomic Theory
 Theory
  - used a Greek concept of the atom and the 3 laws to
  give the atomic theory a scientific basis
Dalton’s Atomic Theory Cont.
 5 Principles
      1. All matter is made of indivisible and
  indestructible atoms
      2. All atoms of a given element are identical in
      their physical and chemical properties
      3. Atoms of different elements differ in
  their physical and chemical properties
      4. Atoms of different elements combine in
  simple whole-numbers ratios to form
  compounds
Dalton’s Atomic Theory Cont.
5. Chemical reactions consist of the
  combination, separation, or rearrangement of
  atoms
  - theory explained most of the chemical data of
  the day and was readily accepted
  - evidence since has shown the first two
  principles are not valid; overlooked that most
  atoms will combined with other of their own
  kind
  - NOT discarded only modified
Objectives
 Explain JJ Thompson’s experiment in detail
 Understand Thompson’s observations and
  conclusions
 Draw a Thomson’s model of the atom
Thomson’s Experiment
 J.J Thomson
  1st experiment
       - pumped most the air out of a glass tube,
  placed a metal plate at each end
       - applied a voltage to two metal plates one
  became positively charged:anode
       other became negatively charged: cathode
Thomson’s Experiment Cont.

2nd experiment
     - placed a charged metal plate on either side
of the glass tube
Thomson’s Experiment Cont.
 Observations
  1st experiment
  - glowing ray emerged between the cathode and
  anode
  2nd experiment
  - charged plates caused the beam to deflect/bend
       - repelled from the negative
       - attracted to the positive
 Conclusion
  - beam of light (stream of charged particles)
  - negative
Thomson’s Experiment Cont.
Uses
  - TV screens
  - computer monitors
  - radar displays
*Later became known as cathode rays due to their
  origin now known as an electron beam
- 1st to provide evidence that atoms are made of
  smaller particles
- revised Dalton’s model
Thomson’s Model
* If there is a negative charge there must also be a
  positive charge
 Why?
       - believes the atom is neutral

 Plum Pudding
   - negative particles are evenly scattered throughout
   an atom with a positively charged mass of matter
   - similar to that of chocolate chip ice cream
- later proved to be incorrect
Objectives
 Explain Rutherford’s experiment in detail
 Understand Rutherford’s observations and
  conclusions
 Draw Rutherford’s model of the atom
 Compare and contrast Thomson’s and Rutherford’s
  models
Rutherford’s Theory
 Ernest Rutherford
   - a former student of Thomson came up with a more
   accurate picture of the atom in 1909
   -oversaw the now famous gold foil experiment
 Gold Foil Experiment
     Hypothesis
   - alpha particles are thousands of times more
   massive, hence they would not be impeded as it
   passed through the “atomic pudding”
- beam of positively charged particles, alpha particles
   from a radioactive source was directed through a
   sheet of very thin gold foil
Gold Foil Experiment
Gold Foil Experiment Cont.
 Observations
- nearly all passed through undeflected and produced
   spots of light
- some were widely deflected, and a few bounced
   straight back
What massive object did they hit?
   atomic nucleus, an extremely dense positively
   charged center of the atom
Gold Foil Experiment Cont.

Why did the others pass through then?
Gold Foil Experiment Cont.
Conclusion
 - atom is mostly empty space
 - most of its mass concentrated in the central
 region, atomic nucleus
Gold Foil Experiment Cont.

- the nucleus and surrounding electrons occupy only a
   tiny fraction of the atomic volume
   - diameter of an atom is generally about 10,000
   times greater than the diameter of its nucleus

* If the nucleus were the size of the period at the end
  of this sentence, the outer edges of the atom would
  be located some 3.3 meters away *
Gold Foil Experiment Cont.
 Rutherford’s Model
  - all of the atoms positive charge is concentrated in
  the nucleus, which only takes up a very small
  amount of the atom




Can we then say we are mainly empty space?
Objectives
 Identify three subatomic particles
 Understand how subatomic particle was discovered
 Compare the properties of the subatomic particles
 Distinguish between atomic number and mass
  number
 Calculate the number of protons, electrons and
  neutrons in an atom
Subatomic Particles
 Subatomic particles
     - 3 important to chemistry
           - protons, neutrons, electrons
Protons
 Definition
  - a positively charge subatomic particle that is found
  in the nucleus of an atom
 About Protons
  - proton is nearly 2000 times more massive than the
  electron, but equal in charge and opposite in sign to
  the electron
  - number of protons in the nucleus is electrically
  balanced by an equal number of electrons
      ex. oxygen atom: contains 8 electrons
         and protons: neutral atom, no net charge
Electron
 Definition
  - a negatively charged subatomic particle that is
  found in the space outside the nucleus
  - name comes from the Greek word for amber
  - Amber: material discovered by early Greeks that
  was found to exhibit the effects of electrical
  charging
      ex. Ben Franklin: Key/Kite

  - lead others to experiment with electric currents
  through gases in sealed tubes
Neutrons
 Definition
  - is a neutral subatomic particle that is found in the
  nucleus of the atom
  - mass almost exactly equal to that of the proton
Comparing Subatomic Particles
Atomic Number
 Definition
   - number of protons in the atom
       ex. Oxygen 8p + 8n = 16
- elements are classified by this number
- continues up to 119
- unique to a given element
- all atoms are electrically neutral, meaning the
   number of electrons must equal the number of
   protons
- this arrangement of elements by their atomic
   numbers makes up the periodic table
- Usually located at the upper left hand corner
Mass Number
 Definition
  - the total number of protons and neutrons in the
  nucleus of an atom
  - mass number – atomic number = neutrons
      ex. N: mass number of 14
              atomic number of 7
                               7 neutrons
Mass Number Cont.
- usually found at the bottom of the atomic symbol,
  and sometimes found written at the bottom left of an
  atomic symbol
     ex. 16O
Mass Number
- although a given type of atom will usually contain a
   certain number of neutrons in the nucleus, a small
   percentage will not
       ex. most hydrogen atoms contain no neutrons
- a small percentage contain one neutron and a smaller
   percentage two neutrons
 What do we call atoms with a different number of
   neutrons?
       - isotopes
Isotopes
 Definition
  - the number of neutrons in the nucleus of a given
  element may vary, protons remain the same
      ex. H contains 1 protons (1H)
           H contains 1 protons and 1 neutrons
           (2H) deuterium
           H contains 1 protons and 2 neutrons
           (3H) tritium


     ex. 14C: Carbon-14
Atomic Mass
 Definition
  - mass of an atom in atomic mass units (amu)
  - atoms have very little mass
  - equal to 1/12th of the mass of carbon
  - often an average mass
      - weighted mass



 AMU or the Dalton (Da)
  - equal to 1.6605402 x 10-27 kg
Atomic Mass Number Cont.
    ex. 99% of all carbon atoms are the isotope
containing 6 neutrons, the remaining 1% is the
heavier isotope containing 7 neutrons, which
raises the average mass of carbon from      12.000 to
12.011
Objectives
 Describe Bohr’s model of the atom and the evidence
  for energy levels
 Explain how the electron cloud model represents the
  behavior and locations of electrons in atoms
Bohr’s Model of the Atom
 Bohr’s Model
  - an early conceptual model of the atom
  - classic planetary model in which electrons whirl
  around the small but dense nucleus: like planets
  orbiting the Sun
  - developed by the Danish physicist Niels Bohr in
  1911
  - each electron has a certain energy that is
  determined by it’s path around the nucleus
  - explains how atoms (lose) emit or (gain) absorb
  energy
      resulting energy: energy level
Bohr’s Model: Energy Levels
 Definition
  - any of the possible energies an electron may have
  in an atom
 Evidence
  - measured amount of energy gained or lost
  - when energy is lost we often see it as a light
      ex. fireworks
  - 1925 this model no longer explained all
  observations being made by scientists and new
  models were created
      ex. Electron cloud model
Electron Cloud Model
- visual model of the most likely locations for
  electrons in an atom
 Orbitals
  - a region in an atom where there is a high
  probability of finding an electron
      ex. propeller on a helicopter (you know its there
      you see a blur, can’t pinpoint exact location)
  - 4 orbitals
      s – 2 houses 2 e-
      p – 3 houses 6 e-
      d – 5 houses 10 e-
Orbitals

- electrons occupy the lowest energy levels first
- electrons in the outermost energy levels of an atoms
are called valence electron
Electron Configurations
 Definition
  - arrangement of electrons in the orbitals of an atom
  (similar to seating assignments on an airplane)
  - when all electrons at their lowest energies this is
  called ground state

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giant presentation on model of an atom

  • 1.
  • 2. Objectives  Be able to define an atom  Distinguish between a molecule and a compound
  • 3. Atoms  Definition - the smallest particle that has the properties of an element, basic unit of matter - surprising the number of atoms is small - the number of combinations these atoms make are huge ex. color print: 3 colors can make numerous colors - 119 distinct atoms as of 1999, form elements
  • 4. Atoms Cont. - hydrogen makes up more than 90% of the atoms in the universe - 1st direct evidence was inadvertently discovered in 1827, by Scottish botanist Robert Brown while he was studying pollen - grains were in a constant state of agitation - thought they were moving life forms, later discovered a perpetual jiggling of particles known as brownian motion; collisions between visible particles and invisible atoms
  • 5. Atomic Symbols - each element has its own name, accompanied by a symbol - usually two/three letters (first is always capitalized) ex. Iron: Fe - Fe represents 1 atom of iron, - 2Fe represents 2 atoms of iron etc… - can also be written as Fe2
  • 6. Molecules  Definition - the smallest unit of a substance that exhibits all the properties characteristics of that substance - two or more atoms ex. H8, O2
  • 7. Compound  Definition - a substance that is made from two or more simpler substances and can be broken down into those simpler substances ex. H2SO4
  • 8. Objectives  Describe ancient Greek models of of matter  List the main points of Dalton’s atomic theory and describe his evidence for the existence of atoms  Explain how Thomson and Rutherford used data from experiments to produce their atomic models
  • 9. Democritus Theory  Greek Philosopher in the 4th century B.C - believed that all matter consisted of extremely small particles - suggested these particles are made of invisible units called atoms - term atom is derived from a Greek word meaning “unable to divide” - believed there were different types of atoms, liquids: round,smooth solids: rough, prickly - unable to provide evidence that an atom existed, therefore many people were very skeptical
  • 10. Dalton’s Atomic Theory  John Dalton - interested in predicting the weather SO.. studied the behavior of gases in the air, concluded that a gas consists of individual particles  Evidence - masses of elements as they combined to form compounds always produced the same ratio no matter what the size of the sample ex. carbon dioxide - 1 carbon 2 oxygen: 1:2 ratio
  • 11. Dalton’s Atomic Theory  Theory - used a Greek concept of the atom and the 3 laws to give the atomic theory a scientific basis
  • 12. Dalton’s Atomic Theory Cont.  5 Principles 1. All matter is made of indivisible and indestructible atoms 2. All atoms of a given element are identical in their physical and chemical properties 3. Atoms of different elements differ in their physical and chemical properties 4. Atoms of different elements combine in simple whole-numbers ratios to form compounds
  • 13. Dalton’s Atomic Theory Cont. 5. Chemical reactions consist of the combination, separation, or rearrangement of atoms - theory explained most of the chemical data of the day and was readily accepted - evidence since has shown the first two principles are not valid; overlooked that most atoms will combined with other of their own kind - NOT discarded only modified
  • 14. Objectives  Explain JJ Thompson’s experiment in detail  Understand Thompson’s observations and conclusions  Draw a Thomson’s model of the atom
  • 15. Thomson’s Experiment  J.J Thomson 1st experiment - pumped most the air out of a glass tube, placed a metal plate at each end - applied a voltage to two metal plates one became positively charged:anode other became negatively charged: cathode
  • 16. Thomson’s Experiment Cont. 2nd experiment - placed a charged metal plate on either side of the glass tube
  • 17. Thomson’s Experiment Cont.  Observations 1st experiment - glowing ray emerged between the cathode and anode 2nd experiment - charged plates caused the beam to deflect/bend - repelled from the negative - attracted to the positive  Conclusion - beam of light (stream of charged particles) - negative
  • 18. Thomson’s Experiment Cont. Uses - TV screens - computer monitors - radar displays *Later became known as cathode rays due to their origin now known as an electron beam - 1st to provide evidence that atoms are made of smaller particles - revised Dalton’s model
  • 19. Thomson’s Model * If there is a negative charge there must also be a positive charge  Why? - believes the atom is neutral  Plum Pudding - negative particles are evenly scattered throughout an atom with a positively charged mass of matter - similar to that of chocolate chip ice cream - later proved to be incorrect
  • 20. Objectives  Explain Rutherford’s experiment in detail  Understand Rutherford’s observations and conclusions  Draw Rutherford’s model of the atom  Compare and contrast Thomson’s and Rutherford’s models
  • 21. Rutherford’s Theory  Ernest Rutherford - a former student of Thomson came up with a more accurate picture of the atom in 1909 -oversaw the now famous gold foil experiment  Gold Foil Experiment  Hypothesis - alpha particles are thousands of times more massive, hence they would not be impeded as it passed through the “atomic pudding” - beam of positively charged particles, alpha particles from a radioactive source was directed through a sheet of very thin gold foil
  • 23. Gold Foil Experiment Cont.  Observations - nearly all passed through undeflected and produced spots of light - some were widely deflected, and a few bounced straight back What massive object did they hit? atomic nucleus, an extremely dense positively charged center of the atom
  • 24. Gold Foil Experiment Cont. Why did the others pass through then?
  • 25. Gold Foil Experiment Cont. Conclusion - atom is mostly empty space - most of its mass concentrated in the central region, atomic nucleus
  • 26. Gold Foil Experiment Cont. - the nucleus and surrounding electrons occupy only a tiny fraction of the atomic volume - diameter of an atom is generally about 10,000 times greater than the diameter of its nucleus * If the nucleus were the size of the period at the end of this sentence, the outer edges of the atom would be located some 3.3 meters away *
  • 27. Gold Foil Experiment Cont.  Rutherford’s Model - all of the atoms positive charge is concentrated in the nucleus, which only takes up a very small amount of the atom Can we then say we are mainly empty space?
  • 28. Objectives  Identify three subatomic particles  Understand how subatomic particle was discovered  Compare the properties of the subatomic particles  Distinguish between atomic number and mass number  Calculate the number of protons, electrons and neutrons in an atom
  • 29. Subatomic Particles  Subatomic particles - 3 important to chemistry - protons, neutrons, electrons
  • 30. Protons  Definition - a positively charge subatomic particle that is found in the nucleus of an atom  About Protons - proton is nearly 2000 times more massive than the electron, but equal in charge and opposite in sign to the electron - number of protons in the nucleus is electrically balanced by an equal number of electrons ex. oxygen atom: contains 8 electrons and protons: neutral atom, no net charge
  • 31. Electron  Definition - a negatively charged subatomic particle that is found in the space outside the nucleus - name comes from the Greek word for amber - Amber: material discovered by early Greeks that was found to exhibit the effects of electrical charging ex. Ben Franklin: Key/Kite - lead others to experiment with electric currents through gases in sealed tubes
  • 32. Neutrons  Definition - is a neutral subatomic particle that is found in the nucleus of the atom - mass almost exactly equal to that of the proton
  • 34. Atomic Number  Definition - number of protons in the atom ex. Oxygen 8p + 8n = 16 - elements are classified by this number - continues up to 119 - unique to a given element - all atoms are electrically neutral, meaning the number of electrons must equal the number of protons - this arrangement of elements by their atomic numbers makes up the periodic table - Usually located at the upper left hand corner
  • 35. Mass Number  Definition - the total number of protons and neutrons in the nucleus of an atom - mass number – atomic number = neutrons ex. N: mass number of 14 atomic number of 7 7 neutrons
  • 36. Mass Number Cont. - usually found at the bottom of the atomic symbol, and sometimes found written at the bottom left of an atomic symbol ex. 16O
  • 37. Mass Number - although a given type of atom will usually contain a certain number of neutrons in the nucleus, a small percentage will not ex. most hydrogen atoms contain no neutrons - a small percentage contain one neutron and a smaller percentage two neutrons  What do we call atoms with a different number of neutrons? - isotopes
  • 38. Isotopes  Definition - the number of neutrons in the nucleus of a given element may vary, protons remain the same ex. H contains 1 protons (1H) H contains 1 protons and 1 neutrons (2H) deuterium H contains 1 protons and 2 neutrons (3H) tritium ex. 14C: Carbon-14
  • 39. Atomic Mass  Definition - mass of an atom in atomic mass units (amu) - atoms have very little mass - equal to 1/12th of the mass of carbon - often an average mass - weighted mass  AMU or the Dalton (Da) - equal to 1.6605402 x 10-27 kg
  • 40. Atomic Mass Number Cont. ex. 99% of all carbon atoms are the isotope containing 6 neutrons, the remaining 1% is the heavier isotope containing 7 neutrons, which raises the average mass of carbon from 12.000 to 12.011
  • 41. Objectives  Describe Bohr’s model of the atom and the evidence for energy levels  Explain how the electron cloud model represents the behavior and locations of electrons in atoms
  • 42. Bohr’s Model of the Atom  Bohr’s Model - an early conceptual model of the atom - classic planetary model in which electrons whirl around the small but dense nucleus: like planets orbiting the Sun - developed by the Danish physicist Niels Bohr in 1911 - each electron has a certain energy that is determined by it’s path around the nucleus - explains how atoms (lose) emit or (gain) absorb energy resulting energy: energy level
  • 43. Bohr’s Model: Energy Levels  Definition - any of the possible energies an electron may have in an atom  Evidence - measured amount of energy gained or lost - when energy is lost we often see it as a light ex. fireworks - 1925 this model no longer explained all observations being made by scientists and new models were created ex. Electron cloud model
  • 44. Electron Cloud Model - visual model of the most likely locations for electrons in an atom  Orbitals - a region in an atom where there is a high probability of finding an electron ex. propeller on a helicopter (you know its there you see a blur, can’t pinpoint exact location) - 4 orbitals s – 2 houses 2 e- p – 3 houses 6 e- d – 5 houses 10 e-
  • 45. Orbitals - electrons occupy the lowest energy levels first - electrons in the outermost energy levels of an atoms are called valence electron
  • 46. Electron Configurations  Definition - arrangement of electrons in the orbitals of an atom (similar to seating assignments on an airplane) - when all electrons at their lowest energies this is called ground state