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Rivers of salt:
                    The Llobregat
 How salt mining has destroyed some rivers in
the Sallent area (Catalonia, NE Spain) and still
  is a threat for the Llobregat river ecosystem,
   the water supply of great Barcelona region
  and the health of more than 2 million people

                            Narcís Prat
  Maria Rieradevall, Pau Fortuño and the members of the F.E.M. research group

Many thanks to Jordi Badia (Montsalat platform) and to the students of the
master course : “Indicadors d’estat ecològic de les aigües continentals” of the
year 2012
Salt effects in the vicinity of the mines: Sites studied
  Vilafruns salt waste disposal                   L68 Balsareny Usptream of salt area
  (restored in 2011)                              (mesocosm’s site)


            Torrent Conangles
                                      1


                                                            Sallent village



                         Torrent Soldevila                       Llobregat (Botjosa)
                                              2                      5
                                                       Mine
                Water with salt percolates             facilities)
     Riu d’Or   though the calcareous rocks
                3
                                          Main salt waste
                                          disposal

                     4
Rivers of salt: The Llobregat
                 The Llobregat before the salt: Balsareny station
           In red: conductivity; in blue: biological quality (EQR values)


      L68 - Llobregat a Balsareny                                                               EQR IBMWP                          Conductivitat (µS/cm2)

    1.00                                                                                                                                                        2500

    0.80                                                                                                                                                        2000

    0.60                                                                                                                                                        1500

    0.40                                                                                                                                                        1000

    0.20                                                                                                                                                        500
            0.31

                   0.41

                          0.22

                                 0.15

                                        0.23

                                               0.15

                                                      0.24

                                                             0.30

                                                                    0.79

                                                                           0.85

                                                                                  0.46

                                                                                         0.40

                                                                                                0.55

                                                                                                       0.75

                                                                                                              0.24

                                                                                                                     0.44

                                                                                                                            0.72

                                                                                                                                    0.49

                                                                                                                                           0.78

                                                                                                                                                  0.53

                                                                                                                                                         1.13
    0.00                                                                                                                                                        0




Conductivity: 0,6 mS/cm; Number of taxa (families): 30;
Biological quality (IBMWP index based on macroinvertebrates): good.
Despite the river regulation and the many villages and sewage plants
upstream of the mining area the biological quality at this point is good
and has been improved in the recent years.
The salt waste: Montsalat




                            The salt mine
                            waste mountain:
                            Montsalat
Effects on the Llobregat river and tributaries
  Site 1. Riera de Conangles. Water coming from a salt mine waste recently restored
  (Vilafruns). Subterranean inflow in the stream has conductivities up to 50 mS/cm.




Conductivity: 4,5 mS/cm;
Number of taxa (families): 16;
Biological quality: poor.
Observe that the Phragmites living into the river are very small in size
compared with those in the background. No riparian vegetation.
Effects on the Llobregat river and tributaries
  Site 2: Torrent Soldevila, Salty water coming from the actual main salt
  waste deposit (active, increasing every year).




                                              Picture: Rubén Landrera

Conductivity: 132 mS/cm;
Number of taxa (families): 2;
Biological quality: Very poor
The fauna inhabiting the stream is reduced mostly to Ephydridae, a salt tolerant
dipteran taxon. Observe the dead vegetation.
Effects on the tributaries
 Site 2: Inlet to the Soldevila Torrent, water coming from the salt
 waste. Left: in normal conditions; Right: after a heavy rain.




Conductivity: Left 177 mS/cm;
              Right 4,5 mS/cm;
Effects on tributaries: Unaffected headstream

  Site 3: Riu d’Or, just before the entrance of salt coming from the
  Salt Waste. An agricultural area with many fields.




Picture: Rubén Landrera

Conductivity: 1,3mS/cm;
Number of taxa (families): 18;
Biological quality: Moderate
Small Mediterranean stream, pools and riffles with some eutrophication.
Observe the Phragmites and other semiaquatic vegetation growing without problems.
Effects on tributaries

  Between site 3 and 4: Salt incoming to the stream trough the
  calcareous rocks




Conductivity of the resurgent water up to 55 mS/cm
Conductivity in the stream is close to 10 mS/cm.
Observe the dead vegetation in the resurgence area.
Effects on tributaries

Site 4: Riu d’Or 2 km downstream of the
resurgence area




Conductivity: 10mS/cm;
Number of taxa (families): 7;
Biological quality: Very poor
Again the Phragmites are very small in the river bed area
Effects on the LLobregat river: Entrance of salt
  Site 5: Llobregat river at La Butjosa. In this area there is a large inflow
  of subterranean salt water in the middle of the river. In the bottom of
  the river conductivities of sediments are close to 20 mS/cm.




Conductivity: 2,5 mS/cm;
Number of taxa (families): 18;
Water quality: Moderate
Most of the river water (up to 1 m3/s) is diverted into a channel to produce electricity, only
part of the river water (close to 100 l/s) circulates by the stream channel in this reach.
Salinity downstream of the mine area

Effects downstream (15 Km away form the mine area):
Conductivity and biological quality downstream of the salt mines

      L102 - Llobregat al Pont de Vilomara                                               EQR IBMWP                         Conductivitat (µS/cm2)
    1.00                                                                                                                                                2500
    0.80                                                                                                                                                2000
    0.60                                                                                                                                                1500
    0.40                                                                                                                                                1000
    0.20                                                                                                                                                500
           0.26

                  0.15

                         0.08

                                0.18

                                       0.14

                                              0.04

                                                     0.08

                                                            0.13

                                                                   0.33

                                                                          0.48

                                                                                 0.42

                                                                                        0.25

                                                                                               0.24

                                                                                                      0.37

                                                                                                             0.26

                                                                                                                    0.18

                                                                                                                            0.34

                                                                                                                                   0.23

                                                                                                                                          0.15

                                                                                                                                                 0.24
    0.00                                                                                                                                                0




The river is affected by the salt inputs and by other anthropogenic
stressors (sewage plants inputs), in addition the river is extremely
regulated by weirs.
Conductivity values are always higher than 1 mS/cm.
Biological quality is always poor, moderate in some spring of wet years.
Historical data
Historical data since 1979, sampled twice every year since 1994
(macroinvertebrates)

  http://www.ub.edu/fem/
  http://ecobill.diba.cat/        Guardiola


 Salt mines are the
 breaking point for the           Salt Mines

 biological quality of                  L68
 water (Index
                                        L102
 IBMWP).
 Changes from green
 (good) to yellow
 (moderate) or                                           Area of the next slide
 orange (poor) colors                                St Boi Potabilization plant

                                     Molins de Rei
Effects on water supply of the great Barcelona region
  Molins de Rei (Red color, very
  poor, in the previous slide)
 1.00                                   4000
                                                       Water supply intake
 0.80                                   3000
 0.60                                   2000
 0.40
 0.20                                   1000
 0.00                                   0




                             Llobregat river
                                                                     Water supply plant




 This plant supplies water for up to 2 million people and due to its salt content many
 secondary products are produced during the potabilization process (as trihalometanes
 and bromides). Recently a RO process has been added to the potabilization process to
 guarantee the accomplishment of the levels of such secondary products in the water
 supplied.

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Salt power

  • 1. Rivers of salt: The Llobregat How salt mining has destroyed some rivers in the Sallent area (Catalonia, NE Spain) and still is a threat for the Llobregat river ecosystem, the water supply of great Barcelona region and the health of more than 2 million people Narcís Prat Maria Rieradevall, Pau Fortuño and the members of the F.E.M. research group Many thanks to Jordi Badia (Montsalat platform) and to the students of the master course : “Indicadors d’estat ecològic de les aigües continentals” of the year 2012
  • 2. Salt effects in the vicinity of the mines: Sites studied Vilafruns salt waste disposal L68 Balsareny Usptream of salt area (restored in 2011) (mesocosm’s site) Torrent Conangles 1 Sallent village Torrent Soldevila Llobregat (Botjosa) 2 5 Mine Water with salt percolates facilities) Riu d’Or though the calcareous rocks 3 Main salt waste disposal 4
  • 3. Rivers of salt: The Llobregat The Llobregat before the salt: Balsareny station In red: conductivity; in blue: biological quality (EQR values) L68 - Llobregat a Balsareny EQR IBMWP Conductivitat (µS/cm2) 1.00 2500 0.80 2000 0.60 1500 0.40 1000 0.20 500 0.31 0.41 0.22 0.15 0.23 0.15 0.24 0.30 0.79 0.85 0.46 0.40 0.55 0.75 0.24 0.44 0.72 0.49 0.78 0.53 1.13 0.00 0 Conductivity: 0,6 mS/cm; Number of taxa (families): 30; Biological quality (IBMWP index based on macroinvertebrates): good. Despite the river regulation and the many villages and sewage plants upstream of the mining area the biological quality at this point is good and has been improved in the recent years.
  • 4. The salt waste: Montsalat The salt mine waste mountain: Montsalat
  • 5. Effects on the Llobregat river and tributaries Site 1. Riera de Conangles. Water coming from a salt mine waste recently restored (Vilafruns). Subterranean inflow in the stream has conductivities up to 50 mS/cm. Conductivity: 4,5 mS/cm; Number of taxa (families): 16; Biological quality: poor. Observe that the Phragmites living into the river are very small in size compared with those in the background. No riparian vegetation.
  • 6. Effects on the Llobregat river and tributaries Site 2: Torrent Soldevila, Salty water coming from the actual main salt waste deposit (active, increasing every year). Picture: Rubén Landrera Conductivity: 132 mS/cm; Number of taxa (families): 2; Biological quality: Very poor The fauna inhabiting the stream is reduced mostly to Ephydridae, a salt tolerant dipteran taxon. Observe the dead vegetation.
  • 7. Effects on the tributaries Site 2: Inlet to the Soldevila Torrent, water coming from the salt waste. Left: in normal conditions; Right: after a heavy rain. Conductivity: Left 177 mS/cm; Right 4,5 mS/cm;
  • 8. Effects on tributaries: Unaffected headstream Site 3: Riu d’Or, just before the entrance of salt coming from the Salt Waste. An agricultural area with many fields. Picture: Rubén Landrera Conductivity: 1,3mS/cm; Number of taxa (families): 18; Biological quality: Moderate Small Mediterranean stream, pools and riffles with some eutrophication. Observe the Phragmites and other semiaquatic vegetation growing without problems.
  • 9. Effects on tributaries Between site 3 and 4: Salt incoming to the stream trough the calcareous rocks Conductivity of the resurgent water up to 55 mS/cm Conductivity in the stream is close to 10 mS/cm. Observe the dead vegetation in the resurgence area.
  • 10. Effects on tributaries Site 4: Riu d’Or 2 km downstream of the resurgence area Conductivity: 10mS/cm; Number of taxa (families): 7; Biological quality: Very poor Again the Phragmites are very small in the river bed area
  • 11. Effects on the LLobregat river: Entrance of salt Site 5: Llobregat river at La Butjosa. In this area there is a large inflow of subterranean salt water in the middle of the river. In the bottom of the river conductivities of sediments are close to 20 mS/cm. Conductivity: 2,5 mS/cm; Number of taxa (families): 18; Water quality: Moderate Most of the river water (up to 1 m3/s) is diverted into a channel to produce electricity, only part of the river water (close to 100 l/s) circulates by the stream channel in this reach.
  • 12. Salinity downstream of the mine area Effects downstream (15 Km away form the mine area): Conductivity and biological quality downstream of the salt mines L102 - Llobregat al Pont de Vilomara EQR IBMWP Conductivitat (µS/cm2) 1.00 2500 0.80 2000 0.60 1500 0.40 1000 0.20 500 0.26 0.15 0.08 0.18 0.14 0.04 0.08 0.13 0.33 0.48 0.42 0.25 0.24 0.37 0.26 0.18 0.34 0.23 0.15 0.24 0.00 0 The river is affected by the salt inputs and by other anthropogenic stressors (sewage plants inputs), in addition the river is extremely regulated by weirs. Conductivity values are always higher than 1 mS/cm. Biological quality is always poor, moderate in some spring of wet years.
  • 13. Historical data Historical data since 1979, sampled twice every year since 1994 (macroinvertebrates) http://www.ub.edu/fem/ http://ecobill.diba.cat/ Guardiola Salt mines are the breaking point for the Salt Mines biological quality of L68 water (Index L102 IBMWP). Changes from green (good) to yellow (moderate) or Area of the next slide orange (poor) colors St Boi Potabilization plant Molins de Rei
  • 14. Effects on water supply of the great Barcelona region Molins de Rei (Red color, very poor, in the previous slide) 1.00 4000 Water supply intake 0.80 3000 0.60 2000 0.40 0.20 1000 0.00 0 Llobregat river Water supply plant This plant supplies water for up to 2 million people and due to its salt content many secondary products are produced during the potabilization process (as trihalometanes and bromides). Recently a RO process has been added to the potabilization process to guarantee the accomplishment of the levels of such secondary products in the water supplied.