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An overview on biodegradation:
   standards and certifications

Fernanda Farachi and Francesco Degli Innocenti
            NOVAMONT S.p.A.




                                                 1
What is biodegradation?

Why is biodegradation ‘‘important’’ today?

      Which materials/products are
           ‘‘biodegradable’’?




                                         2
everything is ““biodegradable””!

•• the organic carbon of any substance, after a
   series of degradation processes, more or less
   extreme and more or less prolonged, can be
   oxidized into carbon dioxide through
   microbial respiration.




                                               3
The term ““biodegradable”” can be
              misleading
In spite of its very large use (and abuse), the term
  biodegradable is not helpful because it is not
  informative. The term does not convey any
  information about the specific environment
  where the biodegradation is supposed to happen,
  the rate which will regulate the process (fast,
  slow, geological), and the extent of
  biodegradation (partial or total conversion into
  CO2).
                                                   4
Why is biodegradation important?

•• The impact of polymers on our current society, having a
   degradation time of decades and decades is different from
   the impact of polymers degrading with a rate compatible
   with the input rate in the environment.
•• The key factor, in waste management, is the rate of waste
   production which, nowadays, is very high.
•• The vast diffusion of plastics in the society can only be
   solved by a ““removal rate”” which is similar to the
   ““production rate””.


                                                           5
The solution!

•• Biodegradation can be a solution to the problem
   of waste production and management……..

•• ……on condition that ‘‘biodegradation’’ is defined
   and verified in a ‘‘standard way’’, suitable to the
   current needs in the environmental area!



                                                         6
Need for standardisation
•• Biodegradable materials and products have been
   on the market since 15-20years.
•• During this period there has been a great effort for
   the development of :
    –– Testing procedures able to generate reliable,
       reproducible and quantitative experimental
       results.
    –– Accepted evaluation criteria: standards

  in order to allow the transparency of the
  evaluation process and to avoid claims based on
  qualitative elements.
                                                      7
Available standards




                      8
The European norm
•• EN13432 Requirements for packaging recoverable
   through composting and biodegradation- Test
   scheme and evaluation criteria for the final
   acceptance of packaging.

•• EN14995 Plastics - Evaluation of compostability -
   Test scheme and specifications




                                                   9
Starting point

•• Directive 94/62/EC of 20 December 1994
   on packaging and packaging waste

•• (Official Journal L 365 , 31/12/1994 p. 0010 –– 0023)
••   http://europa.eu.int/eur-lex/en/lif/dat/1994/en_394L0062.html




                                                                     10
Final point

•• EN 13432:2000

•• Mentioned by the Official Journal of the
   European Communities L 190 12/07/2001
   P.0021-0023 (Harmonised norm)



                                         11
Technical content of EN 13432:

the key point is that ‘‘biodegradation’’ is
     considered in the context of a
  real organic waste treatment called
             ‘‘composting’’




                                              12
Compostability is a set of properties




                                        13
Biodegradability
••   Organic carbon         CO2 + water
••   Test method: EN 14046 (ISO 14855)
••   Matrix: mature compost
••   Temperature: 58°C
                            100
                            90
                            80
                            70
         biodegradation %




                            60
                            50
                            40
                            30
                            20
                            10
                             0
                                  0   1      2   3           4   5   6   7
                                                 Time (months)
                                                                             14
Disintegrability (EN 14045)

   Item under test




compost




                                    15
Heavy metals and other elements
     subject to restriction
  •• Limits to be checked (mg/kg) or ppm



  Zn 150                 Cr     50
  Cu     50               Mo      1
  Ni    25               Se    0,75
  Cd 0,5                  As     5
  Pb    50                 F 100
                                           16
ECOTOXICITY:
A compostable material shall not have
          Ecotoxic effects
( 2 plant germination and growth tests)




                                          17
Need for certification
•• Compliance to EN13432 is today assessed within a
   certification process.
•• The Certification is released to ‘‘compostable products
   producers’’ by a third party institute (a certification body)
   based on clear identification of products, scientific
   documentation based on the EN13432 tests requirements,
   continuous surveillance activity.
•• Certification is a ““garantee”” of material performance and
   the certified product/material is ‘‘easily recognizable’’ by
   the public, by means of a LOGO.
•• Certification allows transparency in the market
•• Certification can be a very effective means of
   communication and marketing.

                                                                   18
Certification

•• Certification programmes
   have been established on
   the basis of the EN 13432
•• Well established LOGOs
   are today available in
   Europe.
•• The two main certification
   bodies are Vinçotte
   (Belgium) and DIN
   CERTCO (Germany).

                                     19
Certification Process
             Material                         Laboratory tests


                                EN 13432

Certified Material                                       Certification
carrying a LOGO                 Certificate                Institute



                     Surveillance/inspection activity


                                                                   20
The most recent developments

•• Standard norm ISO17088 has been recently issued
   and it will be the global reference for the next
   years.
•• ISO17088 is perfectly compatible with the
   European Norms.
•• China is developing a standard in this area:
•• ISO 17088 can be a very helpful reference for
   harmonization, in view of a growing global market
   of biodegradable and compostable items.
                                                  21
Summarizing
•• The main standards on biodegradation and composting are:
   –– EN 13432 (focused on packaging)
   –– EN 14995 (with criteria identical to EN 13432, focused on
      plastics)
   –– ISO17088 which is the international reference globally accepted
•• All of the above mentioned standard norms deal with
   biodegradation within the terms of organic recovery
   through composting
•• Certification according to the above mentioned standards
   offers a valid marketing tool and a guarantee of
   performance for the final user.



                                                                        22
Thank you for your attention.


                                23

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An overview on biodegradation and composting

  • 1. An overview on biodegradation: standards and certifications Fernanda Farachi and Francesco Degli Innocenti NOVAMONT S.p.A. 1
  • 2. What is biodegradation? Why is biodegradation ‘‘important’’ today? Which materials/products are ‘‘biodegradable’’? 2
  • 3. everything is ““biodegradable””! •• the organic carbon of any substance, after a series of degradation processes, more or less extreme and more or less prolonged, can be oxidized into carbon dioxide through microbial respiration. 3
  • 4. The term ““biodegradable”” can be misleading In spite of its very large use (and abuse), the term biodegradable is not helpful because it is not informative. The term does not convey any information about the specific environment where the biodegradation is supposed to happen, the rate which will regulate the process (fast, slow, geological), and the extent of biodegradation (partial or total conversion into CO2). 4
  • 5. Why is biodegradation important? •• The impact of polymers on our current society, having a degradation time of decades and decades is different from the impact of polymers degrading with a rate compatible with the input rate in the environment. •• The key factor, in waste management, is the rate of waste production which, nowadays, is very high. •• The vast diffusion of plastics in the society can only be solved by a ““removal rate”” which is similar to the ““production rate””. 5
  • 6. The solution! •• Biodegradation can be a solution to the problem of waste production and management…….. •• ……on condition that ‘‘biodegradation’’ is defined and verified in a ‘‘standard way’’, suitable to the current needs in the environmental area! 6
  • 7. Need for standardisation •• Biodegradable materials and products have been on the market since 15-20years. •• During this period there has been a great effort for the development of : –– Testing procedures able to generate reliable, reproducible and quantitative experimental results. –– Accepted evaluation criteria: standards in order to allow the transparency of the evaluation process and to avoid claims based on qualitative elements. 7
  • 9. The European norm •• EN13432 Requirements for packaging recoverable through composting and biodegradation- Test scheme and evaluation criteria for the final acceptance of packaging. •• EN14995 Plastics - Evaluation of compostability - Test scheme and specifications 9
  • 10. Starting point •• Directive 94/62/EC of 20 December 1994 on packaging and packaging waste •• (Official Journal L 365 , 31/12/1994 p. 0010 –– 0023) •• http://europa.eu.int/eur-lex/en/lif/dat/1994/en_394L0062.html 10
  • 11. Final point •• EN 13432:2000 •• Mentioned by the Official Journal of the European Communities L 190 12/07/2001 P.0021-0023 (Harmonised norm) 11
  • 12. Technical content of EN 13432: the key point is that ‘‘biodegradation’’ is considered in the context of a real organic waste treatment called ‘‘composting’’ 12
  • 13. Compostability is a set of properties 13
  • 14. Biodegradability •• Organic carbon CO2 + water •• Test method: EN 14046 (ISO 14855) •• Matrix: mature compost •• Temperature: 58°C 100 90 80 70 biodegradation % 60 50 40 30 20 10 0 0 1 2 3 4 5 6 7 Time (months) 14
  • 15. Disintegrability (EN 14045) Item under test compost 15
  • 16. Heavy metals and other elements subject to restriction •• Limits to be checked (mg/kg) or ppm Zn 150 Cr 50 Cu 50 Mo 1 Ni 25 Se 0,75 Cd 0,5 As 5 Pb 50 F 100 16
  • 17. ECOTOXICITY: A compostable material shall not have Ecotoxic effects ( 2 plant germination and growth tests) 17
  • 18. Need for certification •• Compliance to EN13432 is today assessed within a certification process. •• The Certification is released to ‘‘compostable products producers’’ by a third party institute (a certification body) based on clear identification of products, scientific documentation based on the EN13432 tests requirements, continuous surveillance activity. •• Certification is a ““garantee”” of material performance and the certified product/material is ‘‘easily recognizable’’ by the public, by means of a LOGO. •• Certification allows transparency in the market •• Certification can be a very effective means of communication and marketing. 18
  • 19. Certification •• Certification programmes have been established on the basis of the EN 13432 •• Well established LOGOs are today available in Europe. •• The two main certification bodies are Vinçotte (Belgium) and DIN CERTCO (Germany). 19
  • 20. Certification Process Material Laboratory tests EN 13432 Certified Material Certification carrying a LOGO Certificate Institute Surveillance/inspection activity 20
  • 21. The most recent developments •• Standard norm ISO17088 has been recently issued and it will be the global reference for the next years. •• ISO17088 is perfectly compatible with the European Norms. •• China is developing a standard in this area: •• ISO 17088 can be a very helpful reference for harmonization, in view of a growing global market of biodegradable and compostable items. 21
  • 22. Summarizing •• The main standards on biodegradation and composting are: –– EN 13432 (focused on packaging) –– EN 14995 (with criteria identical to EN 13432, focused on plastics) –– ISO17088 which is the international reference globally accepted •• All of the above mentioned standard norms deal with biodegradation within the terms of organic recovery through composting •• Certification according to the above mentioned standards offers a valid marketing tool and a guarantee of performance for the final user. 22
  • 23. Thank you for your attention. 23